首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
The occurrence of dental/skeletal fluorosis among the people in the study area provided the motivation to assess the distribution, severity and impact of fluoride contamination in groundwater of Bankura district at Simlapal block, West Bengal, India. To meet the desired objective, groundwater samples were collected from different locations of Laxmisagar, Machatora and Kusumkanali regions of Simlapal block at different depths of tube wells in both pre- and post-monsoon seasons. Geochemical results reveal that the groundwaters are mostly moderate- to hard-water type. Of total groundwater samples, 37% are situated mainly in relatively higher elevated region containing fluoride above 1.5 mg/L, indicating that host aquifers are severely affected by fluoride contamination. Machatora region is highly affected by fluoride contamination with maximum elevated concentration of 12.2 mg/L. Several symptoms of fluorosis among the different age-groups of people in Laxmisagar and Machatora areas are indicating consumption of fluoridated water for prolonged period. The groundwater samples were mainly Na–Ca–HCO3 type and rock dominance indicating the dissolution of minerals taking place. Ion exchange between OH? ion and F? ion present in fluoride-bearing mineral is the most dominant mechanism of fluoride leaching. High concentration of Na+ and HCO3 ? increases the alkalinity of the water, providing a favorable condition for fluoride to leach into groundwater from its host rocks and minerals.  相似文献   

2.
Birbhum district in West Bengal, India, is one of the most severely affected districts by fluoride-contaminated groundwater. Fluoride content as high as 20.4 mg/L has been reported. Several cases of fluoride-related disorder such as dental fluorosis and skeletal fluorosis have been reported to be endemic in the district. Proper management of groundwater is very crucial. This contribution has been carried out for delineating potential fluoride-contaminated zones (PFCZ) in Birbhum district with the implementation of weighted overlay analysis in GIS environment. Twelve different potentially influential environmental parameters are integrated and evaluated. The final output map was categorised into two subclasses, i.e. ‘low’ and ‘high’, where the low region represents fluoride concentration of 1.5 mg/L and below and the high region represents fluoride concentration above 1.5 mg/L. The outcome reveals that approximately 24.35% of the study area falls under PFCZ, whereas about 75.65% of the study area falls under the safe zone with respect to potential fluoride contamination. On validation of the PFCZ, the reported fluoride contamination data in groundwater shows an overall 87.50% accuracy in prediction via superimposition method and 89.06 and 85.85% success and prediction rates, respectively, when validated with success and prediction rates.  相似文献   

3.
The Singrauli region is known for fluoride contamination and its effect on human population. In this work the possible sources of fluoride contamination in Rihand reservoir water is constrained. They include slurry water, fly ash and coal samples of various thermal power plants, coal seams and granites of the region. Petrographic study depicted the presence of fluoride bearing minerals - flour apatite in pink granite. Preliminary scanning electron microscope studies revealed presence of fluorine peak in coal samples. The chemical analysis confirmed the presence of fluoride in fly ash (12.6 mg/kg), drain water (5.34 mg/l), soil (6.1 mg/kg), coal (3.1 mg/kg). They confirmed the source of fluoride from coal of thermal power plant which utilized coal from Singrauli coal seam (1.6 mg/kg). Further the Rihand reservoir water is also enriched by fluoride contaminant (upto 4.7 mg/l). This contaminates groundwater of the area as well. The contaminated water used for drinking and agriculture affects health of inhabitants in the area. It is concluded that the main source of fluoride contamination in the study area is due to coal burnt in thermal power plant and pink granite formation of the area, both anthropogenic and geogenic sources are implied.  相似文献   

4.
罗山自然保护区地下水化学特征研究   总被引：2，自引：0，他引：2  
吴玺  程旭学  马岳昆  李戍 《地下水》2012,(1):23-26,79
罗山自然保护区是宁夏中部的水源涵养林区。通过对罗山地下水进行取样分析、综合运用描述性分析、因子分析的方法,对地下水化学成分的统计特征及其在空间上的变化规律进行了分析研究。结果表明:①罗山浅层地下水中HCO3-和SO42-绝对含量较高,为地下水中的主要离子。以罗山为中心,向四周辐射,地下水化学类型特征及演变规律;地下水中的Mg2+、Na+、Cl-、SO42-、NO3-和TDS的相关程度很高,主要是来自沉积砂岩、板岩中的长石、石英和绢云母;区内硫酸根离子、氯离子和水的总硬度普遍超标,咸水区对人体有害的氟化物含量超标,部分微咸水区的氟化物含量超标,淡水区未出现超标现象。  相似文献   

5.
松嫩平原地下水化学特征   总被引：7，自引：0，他引：7  
苑丽华 《地质与资源》2006,15(2):122-124,132
根据新一轮地下水资源调查的水质资料,通过对2000多个地下水样的水质分析结果研究,发现与上世纪80年代相比,松嫩平原地下水化学类型和主要化学组分含量都发生了很大变化,农业污染严重.地下潜水硝酸根平均含量达77.03mg/L,超过Ⅳ级水质标准的样品数量占到26.9%;亚硝酸根平均含量为0.14mg/L,超过Ⅳ级水质标准的样品数量占14.53%.在主要农业区的地下潜水水化学类型中,阴离子出现硝酸型水.  相似文献   

6.
氟是维持人体健康所必需的微量元素,过多或过少的摄入都会造成相应的健康问题。本研究从氟的来源、迁移和富集等角度,揭示了内蒙古呼和浩特市托克托县高氟地下水的空间分布规律及其在潜水和承压水中富集的原因。对研究区60个水样(30个潜水和30个承压水)进行了统计分析、水化学特征研究、聚类分析以及相关性分析。结果表明：潜水中F- 浓度为0.40~7.20(2.30±1.80) mg/L,承压水中F- 浓度为0.29~12.70(1.67±2.48) mg/L;地下水中F-浓度与HCO-3、Na+、溶解性总固体(TDS)和电导率(EC)呈正相关,与Ca2+呈一定的负相关关系。高氟水的水化学类型主要为HCO3·Cl-Na型。受地下水流场的控制,高氟潜水(>5 mg/L)主要分布在地下水的排泄区;承压水中F- 的富集主要受含水层岩性的影响,氟高浓度(>1.5 mg/L)分布区主要集中在研究区南部的湖积台地区域。  相似文献   

7.
The groundwaters from Zhongxiang City, Hubei Province of central China, have high fluoride concentration up to 3.67 mg/L, and cases of dental fluorosis have been found in this region. To delineate the nature and extent of high fluoride groundwaters and to assess the major geochemical factors controlling the fluoride enrichment in groundwater, 14 groundwater samples and 5 Quaternary sediment samples were collected and their chemistry were determined in this study. Some water samples from fissured hard rock aquifers and Quaternary aquifers have high fluoride concentrations, whereas all karst water samples contain fluoride less than 1.5 mg/L due to their high Ca/Na ratios. For the high fluoride groundwaters in the fissured hard rocks, high HCO3 − concentration and alkaline condition favor dissolution of fluorite and anion exchange between OH− in groundwater and exchangeable F− in some fluoride-bearing minerals. For fluoride enrichment in groundwaters of Quaternary aquifers, high contents of fluoride in the aquifer sediments and evapotranspiration are important controls.  相似文献   

8.
A total of 194 groundwater samples were collected from wells in hard rock aquifers of the Medak district, South India, to assess the distribution of fluoride in groundwater and to determine whether this chemical constituent was likely to be causing adverse health effects on groundwater user in the region. The study revealed that the fluoride concentration in groundwater ranged between 0.2 and 7.4 mg/L with an average concentration of 2.7 mg/L. About 57% of groundwater tested has fluoride concentrations more than the maximum permissible limit of 1.5 mg/L. The highest concentrations of fluoride were measured in groundwater in the north-eastern part of the Medak region especially in the Siddipeta, Chinnakodur, Nanganoor and Dubhaka regions. The areas are underlain by granites which contain fluoride-bearing minerals like apatite and biotite. Due to water–rock interactions, the fluoride has become enriched in groundwater due to the weathering and leaching of fluoride-bearing minerals. The pH and bicarbonate concentrations of the groundwater are varied from 6.6 to 8.8 and 18 to 527 mg/L, respectively. High fluoride concentration in the groundwater of the study area is observed when pH and the bicarbonate concentration are high. Data plotted in Gibbs diagram show that all groundwater samples fall under rock weathering dominance group with a trend towards the evaporation dominance category. An assessment of the chemical composition of groundwater reveals that most of the groundwater samples have compositions of Ca2+–Mg2+–Cl? > Ca2+–Na+–HCO3 ? > Ca2+–HCO3 ? > Na+–HCO3 ?. This suggests that the characteristics of the groundwater flow regime, long residence time and the extent of groundwater interaction with rocks are the major factors that influence the concentration of fluoride. It is advised not to utilize the groundwater for drinking purpose in the areas delineated, and they should depend on alternate safe source.  相似文献   

9.
Fluoride (F?) is essential for normal bone growth, but higher concentration in the drinking water causes health problems which are reported in many states of India. Andhra Pradesh is one of the states which suffer from excess fluoride in groundwater particularly in the hard rock terrain. In this context, a study was conducted in Andhra Pradesh based on chemical analysis of water samples from hydrograph net work stations (dug wells) and exploratory bore wells. The concentration of fluoride in groundwaters ranges from traces to 9.75 mg/l. The occurrence of fluoride is mostly sporadic, uneven and varies with depth. The highly affected districts include Nalgonda and Warangal in Telangana region, Prakasam in coastal region, Anantapur and Kurnool in Rayalaseema region. In certain areas of Nalgonda district, 85% of wells have fluoride more than permissible limit (> 1.5 mg/l) for drinking water. High F? is present in all the geological formations, predominantly in granitic aquifers, compared to the other formations. The average value of fluoride is high in the deeper zone (1.10 mg/L), compared to the shallow zone (0.69 mg/L). The fluoride-rich minerals present are the main sources for fluoride concentrations in groundwater. Residence time, evapotranspiration and weathering processes are some of the other supplementary factors for high fluoride concentrations in groundwater. Long-term data of hydrograph net work stations (dug wells) reveal that fluoride concentrations do not show any marked change of trend with respect to time. The concentration of fluoride is found to increase with increase of Na+and HCO 3 ? , and decrease with increase of Ca2+. Sodium bicarbonate waters are more effective in releasing fluoride from minerals into groundwater. High fluoride waters are of Na+ type. The paper presents a brief account of the study and its results.  相似文献   

10.
Groundwater samples were collected from Mettur taluk of Salem district, Tamilnadu, India for two different seasons (pre-monsoon and post-monsoon) and analyzed for fluoride ion along with other chemical parameters. The major litho units of the study area are Charnockites, peninsular gneiss, and calc gneiss of meta-sedimentary group. The fluoride concentration ranges from 0.1 to 2.8?mg/L and 0.4 to 4.0?mg/L during pre-monsoon (PRM) and post-monsoon (POM) seasons, respectively. Results showed that collected water samples were contaminated by the presence of fluoride ion. During PRM and POM, 21% and 56% of samples recorded higher fluoride when compared with Indian Drinking Water Standard (1?mg/L) and (9% and 35%) of samples recorded higher fluoride when compared with World Health Organization tolerance limit (1.5?mg/L). The ratio of Na/Ca indicates high sodium content in groundwater enhances the dissolution of fluoride at higher pH. Hydrogeochemical facies indicates water-rock interaction as main source for high fluoride in groundwater. A positive correlation between pH, Mg, and F indicates high alkaline nature of water promotes fluoride leaching from source rocks into ground water. Factor analysis indicates hydro-geochemical processes like weathering, ion exchange, and anthropogenic contributes to groundwater chemistry. The saturation index indicates dissolution and precipitation contributes fluoride dissolution along with mixing.  相似文献   

11.
High fluoride content in the groundwater is reported from parts of the Gad River Basin, Sindhudurg district, coastal Maharashtra, India. The fluoride content of up to 5 mg/l has been found in the groundwater in laterite, basalt and the Precambrian basement (gneiss) aquifers in the region. The presence of high fluoride in groundwater well above the permissible levels for consumption poses a serious health threat to the rural populace in the region. The presence of tourmaline bearing pegmatites in the Precambrian basement is considered as a potential fluorine source. Deep circulation of fluoride rich groundwater between the latetritised basalts and the underlying crystalline basement could be responsible for the occurrence of fluoride in both the shallow and deeper aquifers of the region.  相似文献   

12.
Groundwater is one of the most important natural resources of drinking water on the earth planet. In rural areas of Yemen, groundwater is the main resource for drinking as well as for domestic purposes. According to the World Health Organization, one of the most important elements that has to be found in drinking water is fluorine (fluoride) but within the range of concentration of 0.5 up to 1.5 mg/l. Otherwise, any concentration of fluoride out of that range may cause serious diseases in human’s body such as fluorosis, kidney chronic disease, and/or nephrotoxicity. Taiz City, the third important and largest city in Yemen, has been suffering from dental fluorosis for a few decades. The main resource for drinking water in this city and adjacent areas is Al-Howban Basin (the study area) from where 33 groundwater samples were collected from 33 stations. These samples were preserved and then chemically analyzed according to the American Public Health Association Standards. The results reflected high levels of fluoride concentrations up to 3.6 mg/l in groundwater of many stations. GIS mapping was used to produce a geospatial distribution map of fluoride concentrations using ArcGIS-inverse distance weighted (IDW) tool. As a result, three zones of risks were identified in the study area: mild risk zone which covers the major part of the study area, moderate risk zone, and zone of no risk (optimum level zone). The last two zones occupy small portions of the study area. Consequently, dental and skeletal fluorosis, kidney, and/or nephrotoxic diseases are highly expected to be detected in the study area. Groundwater treatment measurements and health precautions are strongly recommended to be taken by local authorities in the near future.  相似文献   

13.
The present study focuses on the hydrogeochemical composition of groundwater in Chhatarpur area with special focus on nitrate and fluoride contamination, considering the fact that groundwater is the only major source of drinking water here. Carbonate and silicate mineral weathering followed by ground water–surface water interactions, ion exchange and anthropogenic activities are mainly responsible for high concentrations of cations and anions in the groundwater in the region. The average concentration of nitrate and fluoride found in 27 samples is 1.08 and 61.4 mg/L, respectively. Nitrate enrichment mainly occurs in areas occupied with intense fertilizer practice in agricultural fields. Since the area is not dominated by industrialization, the possibility of anthropogenic input of fluoride is almost negligible, thus the enrichment of fluoride in groundwater is only possible due to rock–water interaction. The highly alkaline conditions, which favor the fluorite dissolution, are the main process responsible for high concentration of fluoride.  相似文献   

14.
Presence of fluoride in groundwater is a public health problem in the so-called endemic fluorosis belt of the central Iran, where the groundwater is the major source of drinking water in most urban and rural areas. Therefore, an attempt has been made to determine the hydrogeochemical factors controlling fluoride enrichment in the groundwater resources at this belt. Fluoride concentrations ranged from 0.20 to 1.99 mg/L (1.02 ± 0.47) in groundwater samples. The presence of different F-bearing minerals and also clay minerals in the soils and aquifer materials was confirmed using XRD analysis. To identify probable sources of dissolved F? and investigate groundwater quality, multivariate statistical analyses were carried out. Geochemical modeling indicated that all samples were undersaturated with respect to fluorite, halite, gypsum and anhydrite and mostly oversaturated with respect to calcite and dolomite. Contrary to most high-fluoride regions in the World, the high F? content was dominated by Na–Cl- and Ca–SO4-type groundwater in the study area. Besides, fluoride showed negative relationship with pH and HCO3 ? in groundwater. In order to assess the bioavailability of fluoride in soils, a two-step chemical fractionation method was applied. The results showed that fluoride in soils mostly accompanied with the residual and water-soluble fractions and was poorly associated with soil’s bonding sites. Calculated aqueous migration coefficient demonstrated that fluoride in the studied soils was mobile to easily leachable to the groundwater. Finally, the results demonstrated that combination of water–rock interaction and influence of clay minerals is geochemical mechanism responsible for controlling fluoride enrichment in groundwater.  相似文献   

15.
天然成因的高氟地下水是世界范围内备受关注的环境问题和饮用水安全问题。前人对高氟地下水的形成过程已开展了大量研究,但是对于高原盆地复杂水文地质条件下不同类型含水层组(第四系松散层含水层、基岩裂隙或岩溶含水层以及新生代古近纪以来的碎屑岩含水层)高氟地下水的分布和形成过程尚不明确。本文以化隆—循化盆地为研究区,通过采集、测试研究区内的各类地下水样品,分析研究区内不同类型含水层中地下水的化学特征及同位素特征。结果表明,高氟地下水(1.007.73 mg/L)主要分布在沿黄河的河谷区域和巴燕低山丘陵区域的泉水和潜水中以及深部的承压水中,在垂向上高氟地下水无明显分布规律。接受黄河水入渗补给的河谷潜水中氟离子浓度较低,补给黄河的河谷潜水中氟离子浓度较高。贫钙富钠的弱碱性苏打型水有利于地下水中氟的富集。泉水和潜水中氟主要来源于萤石的溶解,而承压水中氟除了来源于萤石外,还来源于其他含氟矿物。对于潜水和第四系松散层泉水,蒸发浓缩作用促进了地下水中氟的富集。另外,阴离子竞争吸附作用、阳离子交换吸附作用是泉水(第四系松散层泉水和基岩裂隙泉水)和潜水中氟元素富集的主要原因,而承压水中氟离子浓度受竞争吸附作用影响较大,阳离子交换吸附作用影响较小。研究成果可为化隆—循化盆地低氟地下水的勘查和开发提供科学依据。  相似文献   

16.
The aim of the present study is to locate and decipher the groundwater quality,types,and hydrogeochemical reactions,which are responsible for elevated concentration of fluoride in the Chhindwara district in Madhya Pradesh,India.Groundwater samples,quality data and other ancillary information were collected for 26 villages in the Chhindwara District,M.P.India during May 2006.The saturation index was computed for the selected samples in the region,which suggest that generally most of the minerals are saturated with respect to water.The concentration of fluoride in the region varies from 0.6 to 4.74 mg/l,which is much higher as per the national and international water quality standards.The study also reveals that the fluoride bearing rock formations are the main source of the higher concentration of fluoride in groundwater along with the conjuncture of land use change.Moreover,the area is a hard rock terrain and consists of fractured granites and amygdaloidal and highly jointed compact basalt acting as good aquifer,which is probably enriching the high content of fluoride in groundwater.High concentration of fluoride is found in deeper level of groundwater and it is possible due to rock-water interaction,which requires further detailed investigation.The highly alkaline conditions indicate fluorite dissolution,which works as a major process for higher concentration of fluoride in the study area.The results of this study will ultimately help in the identification of risk areas and taking measures to mitigate negative impacts related to fluoride pollution and toxicity.  相似文献   

17.
王攀  靳孟贵  路东臣 《地球科学》2020,45(6):2232-2244
地下水是河南省永城市重要的供水水源,浅层地下水水质污染严重制约了该市经济发展和居民生活质量的提高.在实地调查采样分析的基础上,运用水化学图解法、数理统计法、地球化学模拟法等方法综合分析了永城市浅层地下水的水化学特征和形成机制,探讨了该市浅层地下水污染来源和主要影响因素.结果表明:随含水介质和人类活动影响强度的变化,浅层地下水中K+、Ca2+、NO3-、Cl-、SO42-的浓度和COD（chemical oxygen demand）随深度增加而减少,而Na+、F-、Mg2+、HCO3-的浓度和TDS（total dissolved solids）随深度增加而上升.在煤矿区及煤化工区浅层地下水中SO42-浓度大于250 mg/L,远远高于其他区域的SO42-浓度,而在农业区浅层地下水中NO3-浓度大于30 mg/L,远远高于其他区域的NO3-浓度.综合分析表明:煤矿及其化工业废水和生活污水排放、过量使用化肥农药是永城市浅层地下水污染的主要因素.   相似文献   

18.
Hydrogeochemical investigations were carried out in the Dashtestan, the eastern part of Borazjan, with a focus on fluoride content. The study area is underlain by a complex geology that is dominated by three lithological units, namely marl, alluvial sediments, and carbonate rocks. To assess the major geochemical factors controlling the fluoride enrichment in water, 37 groundwater and 12 surface water samples were collected from the three lithological units. Fluoride concentrations ranged up to 3?mg/L, and average concentrations varied from 1.12 (in carbonate aquifers) to 1.73 (in alluvial aquifers) to 1.82?mg/L (in marl aquifers). To study the influence of rocks and soils on groundwater quality, an additional 41 soil and rock samples were also taken and analyzed for fluoride. The order of average fluoride content in both rocks and soils is: marl?>?alluvial sediments?>?limestone, which confirms that marl is a likely source of fluoride.  相似文献   

19.
High fluoride and arsenic concentrations in groundwater have led to serious health problems to local inhabitants at Yuncheng basin, Northern China. In this study, groundwater with high fluoride and arsenic concentration at Yuncheng basin was investigated. A majority of the samples (over 60%) belong to HCO3 type water. The predominant water type for the shallow groundwater collected from southern and eastern mountain areas was Ca/Mg-Ca-HCO3 types. For the shallow groundwater from flow through and discharge area it is Na-HCO3/SO4-Cl/SO4/Cl type. The predominant water type for the intermediate and deep groundwater is of Na/Ca/Mg-Ca-HCO3 type. According to our field investigation, fluoride concentration in groundwater ranges between 0.31 and 14.2 mg/L, and arsenic concentration ranges between 0.243 and 153.7 μg/L. Out of seventy collected groundwater samples, there are 31 samples that exceed the World Health Organization (WHO) standard of 1.5 mg/L for fluoride, and 15 samples exceeds the WHO standard of 10 μg/L for arsenic. Over 40% of high fluoride and arsenic groundwater are related to the Na-HCO3 type water, and the other fifty percent associated with Na-SO4-Cl/HCO3-SO4-Cl type water; little relation was found in calcium bicarbonate type water. A moderate positive correlation between fluoride and arsenic with pH were found in this study. It is due to the pH-dependent adsorption characteristics of F and As onto the oxide surfaces in the sediments. The observed negative correlation between fluoride and calcium could stem from the dissolution equilibrium of fluorite. The high concentration of bicarbonate in groundwater can serve as a powerful competitor and lead to the enrichment of fluoride and arsenic in groundwater. Most of the groundwater with high fluoride or arsenic content has nitrate content about or over 10 mg/L which, together with the observed positive correlations between nitrate and fluoride/arsenic, are indicative of common source of manmade pollution and of prevailing condition of leaching in the study area.  相似文献   

20.
Spatial variations of fluoride concentration in groundwater in the town of Saldungaray, Argentina affect water quality for human supply and decrease the aquifer reserves. The study region is a piedmont area, located near a hill area (west) and the fluvial valley of the Sauce Grande River (east). Two hydrogeological units can be identified: bedrock and clastic sediments. These sediments consist of sandy silt with a variable amount of calcium carbonate. Its greatest thickness occurs near the river where it is 60 m. Groundwater flow coincides with topography. Fresh water is exploited from this unit and it has low salt contents (dissolved solids 400 to 800 mg/l). Fluoride concentration varies between 0.2 and 5 mg/l. The groundwater flow and hydrogeological characteristics related to spatial variations of fluoride content are analyzed. The quality of water is a critical parameter in determining the overall quality of human lives, and the occurrence of high fluoride concentrations can have a pronounced impact on groundwater quality.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号