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1.
The problem of high fluoride in water sources in Africa and the rest of the developing world has exacerbated in the latest past due to increasing shortage of water. More people are being exposed to high water fluoride resulting in elevated levels of fluorosis in the societies. Fluoride (F) adsorption from solutions using a siliceous mineral from Kenya (M1) was studied on batch basis and results verified on high fluoride water using fixed‐bed column experiments. About 100% batch F adsorption was achieved at 200 mg/L F concentration, 0.5 g/mL adsorbent dosage, 303–333 K, and pH 3.4 ± 0.2. Based on Giles classifications, F adsorption isotherm was found to be an H3 type isotherm. The equilibrium data was correlated to Freundlich and Langmuir models and the maximum Langmuir adsorption capacity was found to be 12.4 mg/g. Column experiments were conducted for different fluoride concentrations, bed depths, and flow rates. The F breakthrough curves were analyzed using the Thomas model and efficient F adsorption was found to occur at low flow rates and low influent concentrations. The Thomas F adsorption capacity (11.7 mg/g) was consistent with the Langmuir isotherm capacity showing that M1 could be applied as an inexpensive medium for water defluoridation.  相似文献   

2.
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3.
This study focused on the electrochemical degradation of hydrolyzed Remazol Black B (CI Reactive Black 5), a common diazo reactive dye, in aqueous solution. In the presence of various auxiliary dye chemicals, a typical Remazol Black simulated exhausted dyebath liquor was treated electrochemically in various basic electrochemical reactor configurations such as batch, batch recirculation and single pass systems. The effect of current density, supporting electrolyte concentration, electrolysis duration, specific electrode surface and fluid flow rate on pollutant removal and energy consumption performance of the systems was critically evaluated. Batch studies show the following operating parameters, current density: 2.5 A/dm2, electrolysis duration: 6 h, and supporting electrolyte concentration: 3 g/L, were optimal for good overall performance of the system. Color removal was complete by 3 h of treatment for all combinations of parameters studied. The pollutant removal performance of the batch recirculation system was found to have improved considerably by increasing the flow rate. Performance of the batch recirculation system was comparatively better than the other rector configurations studied, with respect to capacity utilization and energy consumption.  相似文献   

4.
Limestone defluoridation by fixed bed reactor has been studied with water pre‐acidified with edible organic acids, viz. acetic acid (AA) and citric acid (CA). The study has been carried out by varying acid concentration, contact time (t), number of repeated use of the same limestone bed (n), and chip size of the crushed limestone using fixed fluoride concentration of 10 mg/L in distilled water and groundwater amended to that concentration of fluoride. The presence of both the acids considerably improved the fluoride removal and the removal increased with increase in the acid concentration. Fluoride removal to less than 0.5 and 1.0 mg/L from initial 5 and 10 mg/L, respectively, have been achieved by the method on treatment with single reactor. The mechanism of fluoride removal in the process thought to be the increase in Ca2+ activity by dissolution of limestone, which precipitates as CaF2. XPS analysis reveals that adsorption also contribute to the fluoride removal along with precipitation. The final pH of water remained within acceptable range for drinking water. Initial concentration of fluoride, effects the removal ability of the limestone particles only to some extent. The influence of other anions on fluoride removal process has a little influence which follows the order phosphate > sulfate > bromide > chloride > nitrate.  相似文献   

5.
Recent studies in many developing countries have shown that Small Scale Independent Providers (SSIPs) in low-income areas (LIAs) are practical alternatives to water utilities. This study explored supply dynamics and quality of alternative water sources in four LIAs of Lilongwe City in Malawi using qualitative and quantitative methods. Household-level surveys (n = 120) and transect walks were employed to determine the socio-economic activities in the areas. One-on-one discussions were made with water source owners (SSIPs) (n = 24). Data on policy and institutional frameworks was collected through desktop study and Key Informant Interviews (n = 25). Quality of the water sources (shallow wells and boreholes) was determined by collecting grab samples (n = 24) in triplicate using 500 mL bottles. Selected physico-chemical and microbiological parameters were measured: pH, EC, TDS, turbidity, water temperature, salinity, K, Na, Ca, Mg, Cl−, F−, NO3−, alkalinity, water hardness, Fecal coliform (FC) and Faecal Streptococci (FS) bacteria. Water quality data was compared with Malawi Bureau of Standards (MBS) and World Health Organization (WHO) guidelines for drinking water. Shallow wells were reported (65%, n = 120) to be the main source of water for household use in all areas. Some policies like prohibition of boreholes and shallow wells in City locations were in conflict with other provisions of water supply, sanitation and housing. High levels of FC (0–2100 cfu/100 mL) and FS (0–1490 cfu/100 mL) at several sites (>90%, n = 24) suggest water contamination likely to impact on human health. This calls for upgrading and recognition of the water sources for improved water service delivery.  相似文献   

6.
The density, and therefore the pressure, of CO2 fluid inclusions in minerals can be estimated from the Fermi diad splitting of Raman spectra of CO2. An accurate determination of the pressure of CO2 fluid inclusions enables the estimation of the depth origin of rocks from the deep Earth. A micro-Raman densimeter was applied to ultramafic–mafic xenoliths sampled along the Ohku coast of Oki-Dogo Island in the Sea of Japan (East Sea). The density of CO2 fluid inclusions in the mafic granulite was 1.02–1.05 g/cm3, while those of lherzolites were 0.98–1.02 g/cm3. In contrast, the density of CO2 fluid inclusions measured in olivine gabbro, clinopyroxenite, and harzburgite were lower ranging from 0.86–to 0.99 g/cm3. Taking into account the temperature condition estimated using a pyroxene thermometer, the mafic granulite originated from a depth of 27–30 km and the lherzolites from 25–29 km. The overlapping depth of 27–29 km can be interpreted as the depth including the Moho discontinuity under Oki-Dogo Island 3.3 Ma. This estimation is consistent with geophysical observations.  相似文献   

7.
In this study, an investigation was carried out into the occurrence of sulfamethoxazole (SMX) and trimethoprim (TMP) in the effluent of the university hospital (HUSM) of the UFSM. The degradation of these antimicrobials by the electrocoagulation (EC) process was also examined, in both the aqueous solution and hospital effluent, and a study was conducted in order to identify the subproducts formed. The experiments were optimized through factorial planning and, also, checked by response surface methodology. The best conditions for EC (achieving 58.0% of chemical oxygen demand (COD) reduction) were obtained by using 13 mA cm?2, 500 mg L?1 of NaCl, and 30 mm of interelectrode distance. The quantification of SMX (27.8 µg L?1) and TMP (6.65 µg L?1) in the hospital effluent, and the identification of the degradation products were carried out through liquid chromatography‐mass spectrometry quadrupole linear and ion trapping with electrospray ionization (LC‐ESI‐MS/MS_QTrap). Removals of 88.0% (degradation only) and 33.0% (adsorption only) were achieved for aqueous solutions of SMX and TMP, respectively, under optimized conditions. In hospital effluent samples, fortified with additions of SMX and TMP, corresponding removals of 16.0% (degradation) and 28.0% (adsorption) were achieved. This suggests that the EC process is efficient in degrading SMX in aqueous solution, although the same was not the case with TMP. The degradation products of SMX were identified (m/z 256.0 and 288.5); however, only the latter is mentioned in the literature. Toxicological aspects were not considered in this study.  相似文献   

8.
This paper discusses the effects of water quality on the hydrological and erosion response of non‐saline, non‐sodic soils during simulated rain experiments. It is well known that rain water quality affects the behaviour of saline soils. In particular, rain simulation experiments cannot be run using tap water if realistic values of infiltration rates and soil erosion are to be found. This paper reports on similar effects for non‐saline, non‐sodic soils. Two soils – a well‐aggregated clay‐rich soil developed on marine silty clay deposits and a soil developed on silt loam – were selected and subjected to a series of simulated rainstorms using demineralized water and tap water. The experiments were conducted in two different laboratories in order to obtain results independent of the tap water quality or the rainfall simulator characteristics. The results indicate that time‐to‐ponding is largely delayed by solute‐rich water (tap water). When tap water is used, infiltration rates are significantly overestimated, i.e. by more than 100 per cent. Interrill erosion rates increase by a factor of 2·5–3 when demineralized water is used. The silty clay soil was more affected by the water quality than the silt loam soil, with respect to infiltration and runoff production. Regarding interrill erosion rates, the two tested soils were similarly affected by the water quality. Therefore, it can be concluded that rainfall simulation experiments with non‐dispersive soils (e.g. non‐saline, non‐sodic) must also be conducted using water with very low electrical conductivity (i.e. less than 30–50 µS cm−1), close to that of distilled water. The use of tap water certainly hampers comparisons and the relative ranking of the hydrological and erosion response of different soils, while parameter values, such as final infiltration rate or time‐to‐ponding, cannot be extrapolated and extended to natural situations. Therefore, the majority of hydrological and erosion models and parameter values measured during rainfall simulations in the past should be used with caution for all types of soils. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

9.
In this study, domestic wastewater was used as the electrolyte. The work was carried out with an up-flow tubular reactor, made of stainless steel that was used as cathode, while the anode electrode material was aluminum and varying values of flow regime (25, 50, 75 and 100 mL/s for continuous system), initial pH value (5, 6, 7 and 7.8) and current intensity (10, 15 and 20 A) were applied. For domestic wastewater with natural pH, the effluent pH was >9 in the batch system, while in the continuous system the pH was 8–8.5. Likewise, while the effluent temperature was up to 60°C in the batch system, it was at most 35°C in the continuous system. However, the energy consumption values in the continuous system were considerably lower compared with the batch system. At a current intensity of 10 A, 80 kWh of energy per unit volume was consumed in the batch system, while it was 50 kWh for the continuous system. The present results show that the batch system can be used for small wastewater streams whereas the continuous system can be used for large wastewater streams for domestic wastewater treatment.  相似文献   

10.
Batch and continuous flow adsorption experiments are carried out and the design of a full‐scale facility for removing dissolved natural organic matter (DNOM) from Catalan Lakewater is demonstrated. The adsorption efficiency is proportional to the temperature and the amount of adsorbent unlike pH increase. The highest DNOM removal rate is obtained at 35 °C, pH 4, and an adsorbent amount of 0.8 g L?1. Optimum contact time for batch studies is 60 min at equilibrium. Correlation constants (r) of Langmuir and Freundlich isotherms are 0.8905 and 0.9739, respectively. Based on the Freundlich isotherm, the highest adsorption capacity (qmax) obtained is 2.44 and 6.01 mg DNOM/g granulated activated carbon (GAC) for raw and enriched water, respectively. Consequently, the effects of adsorbent amount, bed depth, empty bed contact time, and organic loading on removal performance are investigated in the rapid small‐scale column test (RSSCT) columns. The targeted effluent concentration of 1 mg DNOM/L can easily be achieved in the columns. At the design capacity of the facility, 15 adsorption columns with dimensions of 7 m height, 4.33 m diameter, and 22 days of operation cycle are required to remove DNOM from raw water.  相似文献   

11.
Water scarcity is one of the main factors limiting agricultural development in arid or semi-arid areas. Accurate Evapotranspiration (ET) observations and estimations are crucial in water cycle studies to estimate water losses from the terrestrial surfaces to the atmosphere to close the regional water budget. The eddy covariance (EC) method is an important technique measure ET and other land surface energy fluxes. However, the underestimation of energy fluxes and the problem of EC energy balance non-closure are far from solved. In this study, a new method is proposed to account for advection in order to correct EC data under advective environments. This advection based method was applied to data from Bushland, TX, which is subject to dry air and strong winds. Observations from two identical EC systems as well as two precision monolithic weighing lysimeters were used in this analysis. Both EC sites showed significant underestimates of evapotranspiration (ET) compared with lysimeter measurements. The daily energy balance closure for NE01 and SE02 sites were 0.78 and 0.74 respectively. The advection correction method provided improved performance in daytime, and it is more suitable for ET estimate than forcing closure under the advective environment. For nighttime, two methods (NCM1 and NCM2) were proposed to correct EC underestimates. Finally, all the corrected ET values were compared with the lysimeter measurements. For NE01 site, the MAD (mean absolute deviation) and the RMSD (root mean square deviation) were 47.72 W/m2 and 67.66 W/m2, respectively; and the r2 (coefficient of determination) was 0.85. For SE02 site, the MAD and RMSD were 30.59 W/m2 and 44.43 W/m2; and the r2 was 0.93. The statistical measures illustrated that the proposed methods are functional and appropriate under an advective environment. The accurate estimate of actual evapotranspiration will benefit both the strategic planning of optimal water uses and the improved understanding the environmental and hydrological processes.  相似文献   

12.
Biological Degradation of 2,4-Dinitrotoluene in a Continuous Bioreactor and Kinetic Studies Experimental results on the aerobic biological degradation with complete mineralization of 2,4-dinitrotoluene (2,4-DNT) are presented. A culture of Pseudomonas sp. DNT from Spain and Nishino was used. The degradation was examined with batch cultures for the determination of kinetic and stoichiometric coefficients. Further experiments were carried out with a continuous culture in a fixed-bed reactor with recirculation in order to obtain high degradation rates. The reactor was packed with ceramic Raschig rings (55 mL) and had a liquid reaction volume of 160 mL. The minimal salt media from Spanggord et al. with and without (NH4)2S)4 as nitrogen source was used as substrate. 2,4-DNT was the sole source of carbon and energy. From batch experiments a yield coefficient YB/S = (0.30 ± 0.05) g g?1 was calculated from a mass balance of the elements. This result was confirmed by calculations using literature data. Fitting the experimental data to the Monod equation, μmax = 0.1 h?1 and KS = 0.01…0.03 mmol L?1 were obtained. It was demonstrated by batch experiments that 2,4-DNT is not only used as the source of carbon and energy but also as the nitrogen source. In the fixed-bed reactor, a degradation of 92…97% was reached with a maximal 2,4-DNT load of 95 mg L?1 h?1. The rate of continuous degradation could be described by a pseudo-first-order reaction (k = 9.73 h?1). The complete mineralization of 2,4-DNT was verified by the measurement of DOC and the formed nitrite and nitrate. The formed nitrite was nitrified simultaneously. It was demonstrated by these experiments that large scale biological treatment of industrial effluent containing 2,4-DNT may be successful.  相似文献   

13.
High pressure experiments using the sink/float method have bracketed the density of hydrous iron-rich ultrabasic silicate melt from 1.35 to 10.0 GPa at temperatures from 1400 to 1860 °C. The silicate melt composition was a 50–50 mixture of natural komatiite and synthetic fayalite. Water was added in the form of brucite Mg(OH)2 and was present in the experimental run products at 2 wt.% and 5 wt.% levels as confirmed by microprobe analyses of total oxygen. Buoyancy marker spheres were olivines and garnets of known composition and density. The density of the silicate melt with 5 wt.% water at 2 GPa and 1500 °C is 0.192 g cm? 3 less than the anhydrous form of this melt at the same P and T. This density difference gives a partial molar volume of water in silicate melt of ～ 7 cm3 mol? 1, which is similar to previous studies at high pressure. The komatiite–fayalite liquids with 0 and 2 wt.% H2O, have extrapolated density crossovers with equilibrium liquidus olivine at 8 and 9 GPa respectively, but there is no crossover for the liquid with 5 wt.% H2O. These results are consistent with the hypothesis that dense hydrous melts could be gravitationally stable atop the 410 km discontinuity in the Earth. The results also support the notion that equilibrium liquidus olivine could float in an FeO-rich hydrous martian magma ocean. Extrapolation of the data suggests that FeO-rich hydrous melt could be negatively buoyant in the Earth's D″-region or atop the core–mantle-boundary (CMB), although experiments at higher pressure are needed to confirm this prediction.  相似文献   

14.
Most vascular plants form symbioses with mycorrhizal fungi that associate with roots and provide nutrients to hosts in exchange for carbohydrates, as well as serve a range of other functions. Mycorrhizal fungi have been studied extensively in upland ecosystems, but we know less about their ecology at aquatic-terrestrial interfaces, especially their distributions at depth. Our objectives were to determine whether abundances of arbuscular mycorrhizal fungi (AMF) change as floodplain islands develop and to describe vertical distributions of AMF from the forest floor to the water table along the freely flowing Tagliamento River in northeastern Italy. We sampled surface sediments (0–10 cm) from three stages of island development on the floodplain—fresh deposits, pioneer islands, and established islands. We also sampled sediments vertically (0–150 cm) from the ground surface to the water table on an established island. We characterized abundance of AMF propagules (colonized roots, spores, and hyphae) within sediments. Roots available to host fungi were absent on fresh deposits; however, some viable spores and hyphae were available at these sites. Pioneer and established islands each had similar hyphal lengths (~860 cm cm−3) and colonized root lengths (~3 cm cm−3). Abundance of spores increased from depositional (3.5 ± 0.9 (±SE) cm−3) to pioneer (17 ± 6.1 cm−3) to established (32 ± 6.3 cm−3) islands. On an established island, AMF propagules were present at all depths sampled, including at the water table, providing first documentation of these symbionts to such depths in a riparian setting. Mycorrhizal fungi likely link aquatic and terrestrial habitats by connecting plants, soil, and ground water and may influence nutrient transfers among these subsystems.  相似文献   

15.
The effect of extraordinary degradation of phenol organics on the SnO2‐Sb2O3/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO2/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO2‐Sb2O3/Ti was superior to that of the PbO2/Ti electrode. At the same time, the SnO2‐Sb2O3/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb2O3 layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO2 part.  相似文献   

16.
Condensed water particles are known to exist in the high latitude upper mesosphere during the summer months. However, the mechanism or mechanisms through which they nucleate remains uncertain. It is postulated here that particles of amorphous solid water (ASW, condensed water with a non-crystalline structure) may nucleate homogeneously in the summer mesosphere. Using classical nucleation theory and a one-dimensional model, it is shown that more than 105 cm?3 amorphous solid water particles can nucleate homogeneously under mesopause conditions. Furthermore, it is shown that homogeneous nucleation competes with heterogeneous nucleation on meteoric smoke particles when the cooling rate is >0.5 K/h. The homogeneous nucleation of amorphous solid water could provide an explanation for the high density of ice particles (many thousands per cm3) thought to be required for electron depletions in the upper mesosphere. A parameterisation for homogeneous nucleation is presented which can be used in other mesospheric cloud models.  相似文献   

17.
In this study, the dechlorination of chlorinated hydrocarbon 3,3′,4,4′-tetrachlorobiphenyl (PCB77) by bimetallic Ni/Fe nanoparticles immobilized on L-lysine/PAA/PVDF membrane was investigated at ambient conditions through the batch mode operation. The membrane support polyvinylidene fluoride (PVDF) was modified by in situ polymerization of acrylic acid in aqueous phase, then L-lysine was covalently bonded to the polymerized acrylic acid chains with the aid of a water-soluble carbodiimide, 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride (EDC). The modification procedure involved cationic ion exchange with Fe2+, reduction to Fe0 with NaBH4 and finally deposition of Ni0. The scanning electron microscopic images showed that the Ni/Fe nanoparticles were successfully immobilized inside the membrane using the polyacrylic acid (PAA) as an inter-linkage between PVDF and L-lysine. A systematic characterization of the composite was performed using ATR-FTIR, HRSEM, EDX, HRTEM, XRD, and contact angle measurement studies and a relatively uniform distribution of Ni/Fe was found in L-lysine/PAA/PVDF membrane because of its hydrophilic nature. The obtained Ni/Fe nanoparticles consist of Fe0 core surrounded by the Ni0 shell. The diameter of Ni/Fe nanoparticles was predominantly within the range 20–30 nm. The immobilized Ni/Fe nanoparticles exhibited a good reactivity towards the dechlorination of the chlorinated hydrocarbon since the concentration of the PCB77 was decreased by catalytic dechlorination with Ni/Fe nanoparticles inside the L-lysine/PAA/PVDF membrane. Dechlorination efficiency of 98% was achieved within 9 h.  相似文献   

18.
Thermal effects related to burial and hydrothermal alteration leads to chemical remanent magnetization (CRM). We present an experimental study of CRM production by heating claystones at 95 °C. A vertical magnetic field of 2 mT was applied to the claystones during heating and the evolution of the remanence during heating in air is monitored intermittently for up to four months. Solid fragments (9 to 26 g) of claystones are included in a Teflon holder that is placed in the oven under a controlled atmosphere. Newly formed grains acquire a CRM and a thermoviscous magnetization (TVRM), both being parallel to the applied magnetic field. CRM is related to the amount of newly formed grains that pass the critical volume during the reaction. To measure the acquired remanence, the claystones are first cooled in a zero magnetic field and then measured using a 2G SQUID magnetometer.In the frame of the research programme on the feasibility of radioactive waste disposal in a deep geological formation, we investigate the magnetic transformation of Mont Terri Lower Dogger claystones (Switzerland) due to thermal imprinting at 95 °C. We simulate the dehydration that occurs in the walls of galleries after excavation when interstitial water evaporates and rehydration when the galleries are refilled allowing water to move towards dehydrated zones. During dehydration, the remanence gains one order of magnitude at the beginning of the experiment and then it follows a linear rate of 0.23 ± 0.07 mA m− 1/day between 3 and 14 days. The magnetic susceptibility increases by a few percent. The increase of the remanence and of the magnetic susceptibility stops after 15 days. Mass monitoring indicates that interstitial water evaporates when remanence and magnetic susceptibility stabilizes. During rehydration, the remanence increases again whilst magnetic susceptibility drops by a few percent. After 20 days, the remanence during rehydration follows a rate of 0.42 ± 0.15 mA m− 1/day. By contrast, when rehydration takes place later, after 66 days, the rate is much lower (0.09 ± 0.04 mA m− 1/day). Low temperature investigation of magnetic properties indicates an initial magnetic assemblage of magnetite and pyrrhotite. Newly formed magnetite and hematite carry the remanence. We propose that magnetite is formed at the expense of pyrite. Hematite results from the progressive oxidation of newly formed magnetite. Our results suggest the possibility that any claystones that pass the oil window can be remagnetized due to the unique action of temperature.  相似文献   

19.
The coupled ocean atmosphere mesoscale prediction system that includes the Navy Coastal Ocean Model has been configured for the Kuroshio Extension region using multiple one-way nested high-resolution grids. The coupled model system was used to simulate a strong cold-air outbreak event from 31 Jan to 7 Feb 2005 in good agreement with meteorological data from a surface buoy data and QuikSCAT scatterometer winds. Latent heat fluxes and sensible heat fluxes were computed during the event with daily averages in excess of 1,500 W/m2 and 500 W/m2, respectively, and combined instantaneous turbulent heat fluxes up to 2,300 W/m2. The largest heat fluxes were found in two large meanders of the Kuroshio and along its southern flank. Strong gradients in turbulent heat fluxes coincided with strong sea surface temperature gradients and were maintained during the cold-air outbreak simulation. The large turbulent heat fluxes lead to significant subtropical mode water formation during the event at a rate about 10 Sv in the cyclonic recirculation region south of the Kuroshio. This increased the volume of core layer mode water within the temperature range 16°C to 18°C by 10% and increased the surface area of that layer directly exposed to the atmosphere by a factor close to 5 in the model domain.  相似文献   

20.
The main objective in this study was to compare the physico-chemical characteristics and biota of a river (Mukuvisi) passing through an urban area to that of a non-urbanised river (Gwebi). Five sites in the Mukuvisi River and five sites in the Gwebi River were sampled for water physico-chemical parameters (pH, conductivity, DO, BOD, TDS, ammonia, Cl, SO42−, PO42−, NO33−, F−, Pb, Cu, Fe, Mn, Zn and Cr) once every month between August, 2012–August, 2013. Cluster analysis based on the physico-chemical parameters grouped the sites into two groups. Mukuvisi River sites formed their own grouping except for one site which was grouped with Gwebi River sites. Principal Component Analysis (PCA) was used to extract the physico-chemical parameters that account for most variations in water quality in the Mukuvisi and Gwebi Rivers. PCA identified sulphate, chloride, fluoride, iron, manganese and zinc as the major factors contributing to the variability of Mukuvisi River water quality. In the Gwebi river, sulphate, nitrate, fluoride and copper accounted for most of the variation in water quality. Canonical Correspondence Analysis (CCA) was used to explore the relationship between physico-chemical parameters and macroinvertebrate communities. CCA plots in both Mukuvisi and Gwebi Rivers showed significant relationships between macroinvertebrate communities and water quality variables. Phosphate, ammonia and nitrates were correlated with Chironomidae and Simulidae. Gwebi River had higher (P < 0.05, ANOVA) macroinvertebrates and fish diversity than Mukuvisi River. Clarias gariepinus from the Mukuvisi River had high liver histological lesions and low AChE activity and this led to lower growth rates in this river.  相似文献   

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