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1.
Shirouma-Oike volcano, a Quaternary composite volcano in central Japan, consists mostly of calc-alkaline andesitic lavas and pyroclastic rocks. Products of the earlier stage of the volcano (older group) are augite-hypersthene andesite. Hornblende crystallized during the later stage of this older group, whereas biotite and quartz crystallized in the younger group.Assemblages of phenocrysts in disequilibrium, such as magnesian olivine(Fo30)/quartz, iron-rich hypersthene(En55)/iron-poor augite(Wo43.5, En42.5, Fs14.0), and two different types of zoning on the rim of clinopyroxene are found in a number of rocks. Detailed microprobe analyses of coexisting minerals reveal that phenocrysts belong to two distinctly different groups; one group includes magnesian olivine + augite which crystallized from a relatively high-temperature (above 1000°C) basaltic magma; the second group, which crystallized from relatively low temperature (about 800°C) dacitic to andesitic magma, includes hypersthene + hornblende + biotite + quartz + plagioclase + titanomagnetite ± ilmenite (in the younger group) and hypersthene + augite + plagioclase + titanomagnetite ± hornblende (in the older group). The temperature difference between the two magmas is clarified by Mg/Fe partition between clinopyroxene and olivine, and Fe-Ti oxides geothermometer. The compositional zoning of minerals, such as normal zoning of olivine and magnesian clinopyroxene, and reverse zoning of orthopyroxene, indicate that the basaltic and dacitic-andesitic magmas were probably mixed in a magma reservoir immediately before eruption. It is suggested that the basaltic magma was supplied intermittently from a deeper part to the shallower magma reservoir, in in which dacitic-andesitic magma had been fractionating.  相似文献   

2.
Calc-alkaline intermediate rocks are spatially and temporally associated with high-Mg andesites (HMAs, Mg#>60) in Middle Miocene Setouchi volcanic belt. The calc-alkaline rocks are characterized by higher Mg# (strongly calc-alkaline trend) than ordinary calc-alkaline rocks at equivalent silica contents. Phenocrysts in the intermediate rocks have petrographical features such as: (1) coexisting reversely and normally zoned orthopyroxene phenocrysts in single rock; (2) sieve type plagioclase in which cores are mantled by higher An%, melt inclusion-rich zone; and (3) reversely zoned amphibole phenocrysts with opacite cores. In addition, mingling textures and magmatic inclusions were observed in some rocks. These petrographic features and the mineral chemistry indicate that magma mixing was the most important process in producing the strongly calc-alkaline rocks. The core composition of normally zoned orthopyroxene phenocrysts and the mantle composition of reversely zoned orthopyroxene phenocrysts have relatively high Mg# (85–90) in maximum. Although basaltic and high-Mg andesitic magmas are candidate as possible mafic end-member magmas, basaltic magma is excluded in terms of phenocryst assemblage and bulk composition. HMA magmas are suitable mafic end-member magmas that precipitated high Mg# (90) orthopyroxene, whereas andesitic to dacitic magma are suitable felsic end-members. In contrast, it is difficult to produce the strongly calc-alkaline trend through fractional crystallization from a HMA magma, because it would require removal of plagioclase together with mafic minerals from the early stage of crystallization, whereas the precipitation of plagiolase is suppressed due to the high water content of HMA magmas. These results imply that Archean Mg#-rich TTGs (>45–55), which are an analog of the strongly calc-alkaline rocks in terms of chemistry and magma genesis, can be derived from magma mixing in which a HMA magma is the mafic end-member magma, rather than by fractional crystallization from a HMA magma.  相似文献   

3.
Eruption episodes, where a series of eruption events are generically related, can include the eruption of a wide spectrum of volcanic activity over decadal periods. This paper concentrates on the opening phases of an eruption episode which occurred approximately 1800 yrs BP from Mt Taranaki, New Zealand. These events spanned the eruption of differing bulk compositions and styles from two distinct vent locations; an andesitic sub-plinian eruption from the summit vent and a scoria cone-building eruption of basaltic magma from a satellite vent. Compositional profiles and zoning textures of plagioclase, amphibole and clinopyroxene phenocrysts from the opening andesitic event show evidence of magma mixing and subsequent crystallisation just prior to the initiation of the eruption episode. Titanomagnetite grain morphology and Ti variation suggest that the magma mixing event occurred within a few days to weeks before the eruption acting as a trigger for it. We present a magmatic model which is constrained by the petrological observations and eruptions of the episode. In this model magma differentiation at depth causes its rise and recharging of a mid-crustal magma storage area at 5–7 km. Although the recharging magma differed slightly in oxygen fugacity and temperature, it was compositionally and physically similar enough to the residing andesitic magma to allow efficient mixing. The petrological characteristics described here can be readily observed and enable identification of mixing events in other recent eruption episodes.  相似文献   

4.
The 29.5 Ma Wah Wah Springs Formation which erupted from the Indian Peak Caldera has an estimated volume of > 3900 km3 making it one of the largest ignimbrites on earth. The magma was calc-alkaline, dacitic (68 wt. % SiO2) and phenocryst-rich (38 vol.%). Phenocrysts include plagioclase (An 47), magnesio-hornblende, Mg-biotite, quartz, Fe-Ti oxides, diopsidic-augite, and rare Ca-poor pyroxene, in order of decreasing abundance. Apatite, zircon and pyrrhotite occurs as inclusions within phenocrysts. Atmospheric glass losses (1040 km3) account for bulk-rock compositions that have SiO2 contents ranging from 63 to 67 wt.%. Glass compositions are high-silica rhyolite.Phenocrysts equilibrated at temperatures ranging from about 790 to 850°C and oxygen fugacities approximately 2.6 log units above the QFM buffer. Confining pressure estimates using the aluminum-in-hornblende geobarometer calibrated for calc-alkaline volcanic rocks suggest a mean pressure of 230±50 MPa corresponding to 7.5±1.5 km depth. These estimates are consistent with caldera formation accompanying emplacement.Crystal compositions for phenocrysts and mineral inclusions within phenocrysts are remarkably homogeneous throughout the outflow tuff, although minor zoning does occur. Given the dacitic composition of the magma, the weakly zoned phenocryst population cannot be modeled to produce the observed high-silica glass (melt) indicating open-system behavior for the magma. The high-silica rhyolite glass is interpreted to be an artifact of efficient magma mixing accompanying addition of highly evolved magma, or melt to intermediate composition magma. Mixing was followed by magma hybridization. Additional support for this hybridization model includes: (1) physically and chemically distinct populations of augite; (2) minor but unbiquitous resorbed plagioclase, biotite and hornblende phenocrysts; and (3) reverse zoning in some of the plagioclase euhedra within pumice lapilli.  相似文献   

5.
 The 1963 eruption of Gunung Agung produced 0.95 km3 dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100  °C at an assumed pressure of 2 kb, f O2>NNO, and an average melt volatile content (H2O±CO2) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×1012 g (Mt) of SO2 and 3.4 Mt of Cl released from the 0.65 km3 of juvenile tephra which contributed to stratospheric injection of H2SO4 aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO2 release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO2 was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO2 emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO2 emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions. Received: 29 June 1994 / Accepted: 25 April 1996  相似文献   

6.
Volcanoes of the East Japan volcanic arc are divided into two groups on the basis of their phenocryst assemblages; volcanoes with lavas or pyroclastic rocks containing quartz phenocrysts and no hornblende phenocrysts (type A), and those with rocks containing hornblende phenocrysts and no quartz phenocrysts (type B). Type A volcanoes occur only in the narrow region along the volcanic front, whereas type B volcanoes are distributed in the area closer to the Sea of Japan.Recent experimental studies on calc-alkaline andesite-dacite under H2O-saturated and -undersaturated conditions indicate that the liquidus temperature (maximum thermal stability limit) of quartz decreases drastically with increasing H2O content in magma, whereas the liquidus temperatures of hornblende and biotite are relatively constant with variations in the H2O content and bulk chemical composition of the magma.It is suggested from the lateral variation of mafic phenocryst assemblages [1] and from the above result that the temperature of the parental magmas of these volcanoes increases, and their H2O contents decrease, towards the volcanic front in the East Japan volcanic arc.Such lateral variations in the H2O contents of magmas under the East Japan volcanic arc are in agreement with those of other incompatible elements (K, Rb, REE, etc.). If H2O-undersaturated partial melting of upper mantle peridotite can be represented by the univariant line (olivine, Ca-rich clinopyroxene, orthopyroxene and liquid coexist) in the system H2OMg2SiO4z.sbnd;CaMgSi2O6z.sbnd;SiO2, the decrease of H2O content in the magma suggests that the melting temperature of the peridotitic mantle may gradually increase, and so the degree of partial melting may increase, towards the volcanic front. The lateral variation of other incompatible elements can also be explained by this model.  相似文献   

7.
Chausudake Volcano is representative of the active volcanoes in northeastern Japan, and has a record of many historical eruptions. Because its 16-ky eruptive history is well documented, Chausudake is well-suited for examining the temporal change of magma chamber processes and for assessing potential hazards. The activity of the Chausudake Volcano can be divided into six magmatic units (CH1-CH6). Most of its products have similar characteristics, but those from unit CH1 show wider variation. Most rocks are andesite and have plagioclase, clinopyroxene, orthopyroxene, and Fe-Ti oxides as phenocrysts, with or without olivine or quartz. Mafic inclusions, which are observed in most products, are basaltic andesites that have various combinations of the same phenocryst species. Petrographic features observed in host rocks and mafic inclusions, such as disequilibrium phenocrysts and resorbed textures, suggest magma mixing/co-mingling. Whole rock compositions of both host rocks and mafic inclusions show linear trends in variation diagrams, which suggest that the rocks are derived from the mixing/co-mingling between mafic and felsic end members. Bulk silica content of the mafic end-member magma is estimated to be ca. 52%, and contains Mg-rich olivine and An-rich plagioclase. The temperature of this end member is estimated to have been higher than 1,100 °C. Bulk silica content of the felsic end-member magma is estimated to be ~66%, and contains Mg-poor pyroxenes, An-poor plagioclase, and quartz phenocrysts, with a temperature of between 800 and 900 °C. Trace element compositions show that the end members have different origins, but have changed little over the entire 16-ky of activity. The mafic end-member magmas might come from a lower-crustal homogeneous, large magma chamber, whereas the felsic end-member magmas may be partial melts of crustal materials produced by the heat of the mafic end member. Felsic end-member magma may have accumulated in the middle crust before CH1 activity. The mixing ratio of the felsic to mafic end members was 0.5:0.5 to 0.4:0.6 for the CH1 unit, and ca. 0.4:0.6 for the other units. Considering that ca. 75% of the total volume of the eruptive products form the first unit, its wider compositional variation is attributed to more heterogeneous mixing ratios.  相似文献   

8.
 Ruapehu volcano erupted intermittently between September and November 1995, and June and July 1996, producing juvenile andesitic scoria and bombs. The volcanic activity was characterized by small, sequential phreatomagmatic and strombolian eruptions. The petrography and geochemistry of dated samples from 1995 (initial magmatic eruption of 18 September 1995, and two larger events on 23 September and 11 October), and from 1996 (initial and larger eruptions on 17–18 June) suggest that episodes of magma mixing occurred in separate magma pockets within the upper part of the magma plumbing system, producing juvenile andesitic magma by mixing between relatively high (1000–1200  °C)- and low (∼1000  °C)- temperature (T) end members. Oscillatory zoning in pyroxene phenocrysts suggests that repeated mixing events occurred prior to and during the 1995 and 1996 eruptions. Although the 1995 and 1996 andesitic magmas are products of similar mixing processes, they display chronological variations in phenocryst clinopyroxene, matrix glass, and whole-rock compositions. A comparison of the chemistry of magnesian clinopyroxene in the four tephras indicates that, from 18 September through June 1996, the tephras were derived from at least two discrete high-temperature (high-T) batches of magma. Crystals of magnesian clinopyroxene in the 23 September and 11 October tephras appear to be derived from different high-T magma batches. Whole-rock and matrix-glass compositions of all tephras are consistent with their derivation from distinct mixed melts. We propose that, prior to 1995 there was a shallow low-temperature (low-T) magma storage system comprising crystal-rich mush and remnant magma from preceding eruptive episodes. Crystal clots and gabbroic inclusions in the tephras attest to the existence of relict crystal mush. At least two discrete high-T magmas were then repeatedly injected into the mush zone, forming discrete and mixed magma pockets within the shallow system. The intermittent 1995 and 1996 eruptions sequentially tapped these magma pockets. Received: 1 April 1998 / Accepted: 22 December 1998  相似文献   

9.
Tertiary dacites and rhyodacites in SE Spain contain garnets, both as phenocrysts in the lavas and within their enclosed metamorphic venoliths. Microprobe analyses show that calc-alkaline and metamorphic rocks garnets are quite similar in composition (almandine-rich). However, the zoning patterns displayed in the two types of garnets differ. Garnets included in lavas show normal zoning (or a slight enrichment of Mn at the borders), while garnets in xenoliths have Mn-enriched rims or reverse zoning. The differences in zonation, as well as in petrographic features, indicate that the garnets in volcanic rocks crystallized directly from the calc-alkaline magma at an early stage of its crystallization. On the other hand, the uniform composition of dacitic and rhyodacitic garnets, as well as its low pyrope and grossular content, suggest that the conditions in which the garnets crystallized were rapidly exceeded.  相似文献   

10.
The Bishop Tuff represents a single eruption of chemically zoned rhyolitic magma. Six whole rock samples spanning the compositional and temperature range yield initial87Sr/86Sr of 0.7060–0.7092 andδ18O of 5.9–10.3‰. Six constituent sanidines yield smaller ranges of initial87Sr/86Sr of 0.7061–0.7069 andδ18O of 6.7–7.9. In contrast143Nd/144Nd ratios for the six whole rocks and two constituent magnetites exhibit negligible variation with a mean of0.51258 ± 1. These data are used to show that the phenocrysts were precipitated from an already chemically zoned liquid, that the zoning process involved negligible assimilation of, or exchange with, country rocks and that the extreme Sr and O isotopic disequilibria are probably the result of post-eruptive interaction with meteoric water. The parent magma had?Nd = ?0.9, ?Sr = +23 andδ18O = 7‰ and was formed from mantle-derived magmas and/or melts of lower crustal rocks isotopically similar to parts of the Sierra Nevada Batholith.  相似文献   

11.
The mafic volcanic rocks and hypabyssal rocks in the Chon Dean‐Wang Pong area are possibly the southern extension of the western Loei Volcanic Sub‐belt, Northeast Thailand. They are least‐altered, and might have been formed in Permian–Triassic times. The rocks are commonly porphyritic, with different amounts of plagioclase, clinopyroxene, orthopyroxene, amphibole, Fe–Ti oxide, unknown mafic mineral, and apatite phenocrysts or microphenocrysts, and are uncommonly seriate textured. The groundmass mainly shows an intergranular texture, with occasionally hyalophitic, intersertal and ophitic–subophitic textures. The groundmass constituents have the same minerals as the phenocrysts or microphenocrysts and may contain altered glass. The groundmass plagioclase laths may show a preferred orientation. Chemically, the studied rock samples can be separated into three magmatic groups: Group I, Group II, and Group III. These magmatic groups are different in values for Ti/Zr ratios. The averaged Ti/Zr values for Group I, Group II, and Group III rocks are 83 ± 6, 46 ± 12, and 29 ± 5, respectively. In addition, the Group I rocks have higher P/Zr, but lower Zr/Nb relative to Group II and Group III rocks. The Group I and Group II rocks comprise tholeiitic andesite–basalt and microdiorite–microgabbro, while the Group III rocks are calc‐alkalic andesite and microdiorite. According to the magmatic affinities and the negative Nb anomalies on normal mid‐oceanic ridge basalt (N‐MORB) normalized multi‐element plot, arc‐related lavas are persuasive. The similarity between the studied lavas and the Quaternary lavas from the northern Kyukyu Arc, in terms of chondrite‐normalized rare earth element (REE) patterns and N‐MORB normalized multi‐element patterns, leads to a conclusion that the mafic volcanic rocks and hypabyssal rocks in the Chon Daen–Wang Pong area have been formed in a volcanic arc environment.  相似文献   

12.
The Bishop Tuff, a well known Quaternary high-silica rhyolite in east-central California, is widely considered the type example of a vertically and monotonically zoned pyroclastic deposit that represents zoning in the source magma reservoir, inverted during the process of pyroclastic emplacement. However, the deposit of plinian pumice, which forms the base of the Bishop Tuff and represents the initial 10% or so of all magma erupted during the event that produced the Bishop Tuff, contains features at odds with monotonie zoning for the reservoir. Relative to overlying ignimbrite, the plinian deposit contains a reversal in trace-element zoning. Moreover, the 87Sr/86Sr is significantly higher than that in overlying ignimbrite (about 0.7084 vs 0.7064), and melt inclusions trapped in quartz phenocrysts exhibit notable variability of trace-element concentrations, even within a single host crystal (e.g., U: 10.77 to 8.91 ppm).These data have been previously interpreted as due to processes of chemical fractionation and evolution operating within a magma system closed to chemical interactions with its roof rocks. For example, the reversal in trace-element zoning has been explained by the first-erupted magma being erupted from somewhat below the top of a monotonically zoned reservoir. However, we submit that the reversed zoning and other above-noted features can be explained equally well as consequences of minor assimilation of roof rocks into a magma reservoir that was erupted from the top down.The basal part of the Bishop Tuff exhibits extreme concentrations and depletions of trace elements, relative to the average composition of crustal rocks. For example, the upward decrease of Sr in the Bishop magma reservoir (downward decrease in the ignimbrite) results in concentrations as low as 2–4 ppm. Because of the attendant ‘chemical leverage’, assimilation of < 1 wt.% of Sierra Nevada batholith rocks typical of the area could readily reverse an ‘uncontaminated’ Sr (and other trace elements) trend of zoning and could also substantially raise 87Sr/86Sr. Small-scale trace-element variability in the uppermost part of the Bishop magma reservoir, as recorded by the above-mentioned melt inclusions, may simply reflect melt heterogeneity produced by the process of assimilation.  相似文献   

13.
Compositional and isotopic zoning patterns in plagioclase and amphibole phenocrysts from El Chichón record multiple cycles of country rock assimilation, magma injection, hybridization, and mixing. Laser ablation ICP-MS and electron microprobe analyses of plagioclase crystals from 7 eruptions spanning 3100 years reveal four types of zoning. These compositional and isotopic zones are often associated with textural changes observed in the crystals in thin section (e.g. sieved or patchy regions). Amphiboles are frequently zoned in Al and Si, and, in two magmas, may have clinopyroxene rims. Interestingly, most plagioclase show multiple and repeated zoning patterns. Moreover, all magmas contain all zoning patterns and textures, and crystals with substantially different sequences of zones occur within mm of one another. The most reasonable explanation for the origin of these textures is a frequently recharged chamber. Plagioclase zones with increasing anorthite contents (An) and decreasing 87Sr/86Sr ratios record injection by a hotter, possibly wetter, and more primitive magma (lower 87Sr/86Sr ratio). Zones with decreasing An and increasing 87Sr/86Sr ratios record assimilation of country rock and/or hybridization of the host and injected magmas; injection of hot magma may provide the heat for country rock assimilation. Changes in An without corresponding changes in 87Sr/86Sr ratio likely record slight variations in pressure or temperature during crystallization, or the far-field thermal effects of magma injection. Variations in 87Sr/86Sr ratio unaccompanied by Anzoning record assimilation of country rock. Amphibole zoning patterns also record periodic heating events; amphibole with clinopyroxene rims record episodes where the magma was heated beyond the amphibole stability field. Bulk compositional homogeneity and the juxtaposition of many crystals with disparate zoning patterns in single pumice require the magmatic system to be well mixed. Strontium diffusion rates indicate that the plagioclase zoning patterns cannot have persisted at magmatic pressures and temperatures for more than ~ 500 years, thus cycles of injection and assimilation occur on timescales equal to or shorter than the eruption recurrence interval. Long-term compositional and isotopic homogeneity indicate that there is a balance between recharge, assimilation, and crystallization.  相似文献   

14.
Physical and chemical analyses of distal tephra from the 1912 eruption of Novarupta, Alaska, show considerable variations in glass and mineral compositions. A combination of a 150°C range in temperature deduced from iron-titanium oxide geothermometry, and curved patterns in bivariant element plots of glass compositions indicate that a chamber of compositionally zoned magma existed prior to the eruption. Magma-mixing cannot explain these features. The magma chamber may have resembled the model recently proposed by McBirney (1980). A highly silicic, quartz-phyric magma with mean phenocryst compositions of An25 plagioclase, Fs42 orthopyroxene, at a temperature of 880°C and a water pressure of 1.4 kbar, was located above a more mafic, hotter magma, bearing phenocrysts of An45 plagioclase and Fs35, orthopyroxene.Our results on distal tephras compare favorably with those from a recently completed study at source by Hildreth (1983), suggesting that useful petrologic information about distant volcanoes can be obtained from both types of deposits. Compositionally heterogeneous abyssal tephra layers are common in the Gulf of Alaska. Eruptions from chambers of zoned magma may account for many of these layers.  相似文献   

15.
Volcanism in the Taupo Volcanic Zone (TVZ) and the Kermadec arc-Havre Trough (KAHT) is related to westward subduction of the Pacific Plate beneath the Indo-Australian Plate. The tectonic setting of the TVZ is continental whereas in KAHT it is oceanic and in these two settings the relative volumes of basalt differ markedly. In TVZ, basalts form a minor proportion (< 1%) of a dominant rhyolite (97%)-andesite association while in KAHT, basalts and basaltic andesites are the major rock types. Neither the convergence rate between the Pacific and Indo-Australian Plates nor the extension rates in the back-arc region or the dip of the Pacific Plate Wadati-Benioff zone differ appreciably between the oceanic and continental segments. The distance between the volcanic front and the axis of the back-arc basin decreases from the Kermadec arc to TVZ and the distance between trench and volcanic front increases from around 200 km in the Kermadec arc to 280 km in TVZ. These factors may prove significant in determining the extent to which arc and backarc volcanism in subduction settings are coupled.All basalts from the Kermadec arc are porphyritic (up to 60% phenocrysts) with assemblages generally dominated by plagioclase but with olivine, clinopyroxene and orthopyroxene. A single dredge sample from the Havre Trough back arc contains olivine and plagioclase microphenocrysts in glassy pillow rind and is mildly alkaline (< 1% normative nepheline) contrasting with the tholeiitic nature of the other basalts. Basalts from the TVZ contain phenocryst assemblages of olivine + plagioclase ± clinopyroxene; orthopyroxene phenocrysts occur only in the most evolved basalts and basaltic andesites from both TVZ and the Kermadec Arc.Sparsely porphyritic primitive compositions (Mg/(Mg+Fe2) > 70) are high in Al2O3 (>16.5%), and project in the olivine volume of the basalt tetrahedron. They contain olivine (Fo87) phenocrysts and plagioclase (> An60) microphenocrysts. These magmas have ratios of CaO/Al2O3, A12O3/TiO2 and CaO/TiO2 in the range of MORB and MORB picrites and can evolve to the low-pressure MORB cotectic by crystallisation of olivine±plagiociase. Such rocks may be the parents of other magmas whose evolutionary pathways are complicated by interaction of crystal fractionation, crystal accumulation and mixing processes and the filtering action of crust of variable density and thickness. The interplay of these processes likely accounts for the scatter of data about the cotectic. More evolved rocks from both TVZ and KAHT contain clinopyroxene and orthopyroxene phenocrysts and their compositions merge with basaltic andesites and andesites. Stepwise least-squares modelling using phenocryst assemblages in proportions observed in the rocks suggest that crystal fractionation and accumulation processes can account for much of the diversity observed in the major-element compositions of all lavas.We conclude that the parental basaltic magmas for volcanism in the TVZ and KAHT segments are similar thereby implying grossly similar source mineralogy. We attribute the diversity to secondary processes influencing liquids as they ascended through complex plumbing systems in the sub arc mantle and cross.  相似文献   

16.
A new geochronological and geochemical study was carried out to better constrain the petrogenesis and eruptive history of Monte Amiata, a large Pleistocene trachydacitic volcano of Southern Tuscany. Previous studies suggested a magma mixing origin between calc-alkaline silicic melts from the Tuscan Magmatic Province (TMP) and potassic mafic melts like those found in the Roman Magmatic Province (RMP). Two eruptive episodes–the first at ca. 300 kyr, the second at ca. 200 kyr–were distinguished from the few available ages. However, both the involvement of a RMP-like melt as mafic end-member and the timing of volcanic activity remained to be ascertained. The K–Ar ages obtained on plagioclase, sanidine and glass separated from Mt Amiata volcanic rocks demonstrate the sanidine is the most suitable phase for K–Ar dating. Sanidine yields ages of 304–293 kyr for the basal trachydacitic unit (BTC), 298–280 kyr in the domes unit (DLC) and unexpected older ages of 312–308 kyr for the more mafic summit lava unit (OLL). A careful re-examination of the literature ages together with those obtained in this study shows that they tend to a common age of ca. 300 kyr whatever the volcanic unit. We interpret this as a reset of the K–Ar chronometer in response to a consequent recharge of the silicic magma reservoir by hot mafic melts. This recharge most probably triggered the first volcanic eruption of Mt Amiata magmas. In our model, we suppose an initially chemically-stratified magma chamber; the input of deep hot mafic melts reset the crystals clock and probably allowed the eruption of the huge amount of trachydacitic crystal mush. We propose that the controversial BTC unit could have emplaced during a non-explosive eruption if we consider either pre-eruption passive degassing or extrusion of the trachydacites as magmatic foam.First Pb isotopic data of mafic enclaves from the trachydacitic units, together with major and trace elements and new Sr and Nd data support the magma mixing as the dominant process at the origin of the Mt Amiata volcanic rocks. The similar LILE/HFSE ratios evidenced in this contribution between the magmatic enclaves of Mt Amiata and RMP volcanic rocks, together with their comparable Sr, Nd and Pb isotopic compositions, definitively argue for the involvement of a RMP-like melt in the mixing. The Mt Amiata is thus indisputably a hybrid volcano between TMP and RMP in terms of petrogenesis and ages.  相似文献   

17.
Upper Cretaceous volcanic rocks were collected at 24 sites along the Pontides, N-NE Turkey, for rock magnetic and geochemical studies. Rock magnetic and petrographic methods showed that the lavas are characterized predominantly by titanomagnetites with a mixture of pseudo-single and multi-domain grains, whereas in tephrite single domain titanohematite was dominant. Measurements of magnetic susceptibility and the geochemical properties on different volcanic rock types provide important knowledge about the magnetic stability of the rocks. The magnetic properties are interpreted in terms of the composition, concentration, magma generation. Tephrite and phonotephrites with the highest intensities (5200 mA/m) and high magnetic susceptibility values (2585 × 10−5), largest grain sizes and Fe/Ti values, showing minor or no alteration are the most magnetic stable samples in contrast to dacites with the lowest intensity-magnetic susceptibility (520 mA/m − 573 × 10−5) and high alteration degree. The basanite samples show very low NRM (48–165 mA/m) but very high magnetic susceptibility (2906–3100 × 10−5) values suggesting the alteration of Fe-Ti minerals. It is shown that the magnetic properties of the basic to acidic rocks show a systematic variation with magma differentiation and could be related to fractional crystallization. Major and trace elements revealed that the lavas are compatible with complex magma evolution, with mineral phases of olivine+magnetite+clinopyroxene in basic series, amphibole+ +clinopyroxene in intermediate rocks and plagioclase+clinopyroxene+biotite in acidic series.  相似文献   

18.
Glass separates from 115 ash layers derived from the Kamchatkan (DSDP Site 192; 34 layers), the eastern Aleutian (DSDP Site 183; 56 layers) and the Alaska Peninsula (DSDP Site 178; 25 layers) volcanic arcs have been analyzed for up to 28 elements. In addition, the abundance and diversity of associated mafic phenocrysts have been evaluated. The resulting data set has made possible an evaluation of the late Miocene to Recent changes in composition of ashes derived from North Pacific volcanic arcs and of the factors controlling the evolution of highly siliceous magmas.We find no evidence for a general transition from arc tholeiite to calc-alkalic magma parentage of ashes derived from the volcanic arcs during the last 10 m.y., but instead find 0.1- to 0.5-m.y. intervals during which particular types of volcanism are prevalent. Most convincing is the transition from arc tholeiite to calc-alkalic for ashes derived from Kamchatka during the last 0.8 m.y., a change believed to be associated with a landward shift in the site of magma generation. Considered together, ashes derived from North Pacific volcanic arcs have been becoming more siliceous during the last 1.5 m.y. and may be associated with accelerated subduction during the same time interval.Hydrous phenocrysts (e.g., biotite) are typically associated with low-silica deep-sea ashes, but not with terrestrial volcanic rocks of comparable silica contents, suggesting the important role of water in the evolution of siliceous magma. REE patterns and relative abundances of mafic phenocrysts demonstrate the importance of fractional crystallization in controlling the evolution of highly siliceous arc magmas. REE increase with increasing silica, but become less concentrated in ashes with SiO2 > 64%. Eu anomalies increase throughout the SiO2 range. Initial fractionation is dominated by clinopyroxene and plagioclase with amphibole strongly influencing fractionation above 64% SiO2.  相似文献   

19.
The common occurrence of compositionally and mineralogically zoned ash flow sheets, such as those of the Timber Mountain Group, provides evidence that the source magma bodies were chemically and thermally zoned. The Rainier Mesa and Ammonia Tanks tuffs of the Timber Mountain Group are both large volume (1200 and 900 km3, respectively) chemically zoned (57–78 wt.% SiO2) ash flow sheets. Evidence of distinct magma batches in the Timber Mountain system are based on: (1) major- and trace-element variations of whole pumice fragments; (2) major-element variations in phenocrysts; (3) major-element variations in glass matrix; and (4) emplacement temperatures calculated from Fe-Ti oxides and feldspars. There are three distinct groups of pumice fragments in the Rainier Mesa Tuff: a low-silica group and two high-silica groups (a low-Th and a high-Th group). These groups cannot be related by crystal fractionation. The low-silica portion of the Rainier Mesa Tuff is distinct from the low-silica portion of the overlying Ammonia Tanks Tuff, even though the age difference is less than 200,000 years. Three distinct groups occur in the Ammonia Tanks Tuff: a low-silica, intermediate-silica and a high-silica group. Part of the high-silica group may be due to mixing of the two high-silica Rainier Mesa groups. The intermediate-silica group may be due to mixing of the low- and high-silica Ammonia Tanks groups. Three distinct emplacement temperatures occur in the Rainier Mesa Tuff (869, 804, 723 °C) that correspond to the low-silica, high-Th and low-Th magma batches, respectively. These temperature differences could not have been maintained for any length of time in the magma chamber (cf. Turner, J.S., Campbell, I.H., 1986. Convection and mixing in magma chambers. Earth-Sci. Rev. 23, 255–352; Martin, D., Griffiths, R.W., Campbell, I.H., 1987. Compositional and thermal convection in magma chambers. Contrib. Mineral. Petrol. 96, 465–475) and therefore eruption must have occurred soon after emplacement of the magma batches into the chamber. Emplacement temperatures of the pumice fragments from the Ammonia Tanks Tuff show a continuous gradient of temperatures with composition. This continuous temperature gradient is consistent with the model of storage of magma batches in the Ammonia Tanks group that have undergone both thermal and chemical diffusion.  相似文献   

20.
Three magmatic units (Grande Cascade pyroclastic deposits, Grande Cascade lava flow, Durbise nuée ardente deposits) from the Quaternary volcano Sancy (Mont-Dore area, Auvergne, France) show textural evidences of magma mixing between a silica undersaturated basic magma (alkali basalt and hawaiite) and an acid magma (quartz-bearing trachyte). Three kinds of mixed rock types are described: basic inclusions within an acid host, « emulsified rocks » showing infracentimetric basic globules disseminated within an acid groundmass, and « banded rocks » in which elongated acid and basic zones alternate. The chemical compositions of mixed rocks plot systematically onto linear trends in petrographic diagrams. Microprobe analyses of the groundmass show similar linear variations between basic and acid end-members. The mineralogical associations of these mixed rocks are highly complex and present many disequilibrium features. Olivine is stable in the basic component and becomes rimmed by orthopyroxene in the acid one. Zoning patterns of feldspars are complex. Clinopyroxene, kaersutite and phlogopite phenocrysts have increasing component Mg contents from core to rim both in the basic and the acid. Titanomagnetite and hemoilmenite phenocrysts were equilibrated at 900-800° C under high oxygen fugacities.Mixing results primarily from a mechanical disintegration of partly liquid basic inclusions within their acid host, and also from a mechanical transfer of phenocrysts from one component to the other, in which they often remain surrounded by a coating of their original groundmass. Chemical data on the groundmass indicates that some « true » hybridization between coexisting acid and basic liquids may also have occurred. The extent of mixing is controlled by the type of emplacement. For pyroclastic deposits a chemical gap exists between basic inclusions and their acid hosts; in contrast, mechanical mixing was enhanced during the emplacement of the viscous Grande Cascade lava flow, and complete transitions occur between basic and acid components. The two end-members are genetically associated, the latter deriving from the former by crystal fractionation. Mixing appears as a late-stage phenomenon in the petrogenetic history of the Mont-Dore series; in the case of the Grande Cascade lava flow, its extent is primarily dependent on emplacement modalities.  相似文献   

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