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1.
Water–rock–gas system is simulated using a technique based on the fundamental principles of modern hydrogeochemistry regarding the formation parameters of natural-water chemistry to show that groundwater pollution hazard at a gold-bearing placer is acute for any site of water exchange changing from passive to active. Under passive water exchange, the products of sulfide oxidation are accumulated; whereas under active water exchange, the oxidation products are leached out to form acid drainage flows. The treatment of acid drainage water and the neutralization of acid solutions are more effective under reduction or weakly alkaline conditions. 相似文献
2.
Gaschromatographic Determination of Diethylenetriaminepentaacetic Acid in Surface Water. A method for the determination of diethylenetriaminepentaacetic acid (DTPA) is reported. The determination is based on the preconcentration on a strong base anion exchange resin, esterification with n-propanol and following gaschromatographic separation using a N-selective detector. The sensitivity of the method, including enrichment, is 1 μg/L in river water. The identity of DTPA in river water was proved by mass spectrography. The method can be used also for the quantitative determination of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), cyclohexanediaminetetraacetic acid (CDTA) and ethyleneglycolbis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid (EGTA). The method was used to examine river water. An investigation along the river Rhine, taking grab samples from January and february 1992 showed that DTPA was present in some sampling places in similiar concentrations as NTA and EDTA. 相似文献
3.
云南腾冲青海——酸性湖泊的环境特征 总被引：3，自引：0，他引：3
火山口湖成因和持续酸性地下水补给是腾冲青海呈现酸性湖泊环境的地质基础,通过对青海环境的实际调查和水、土、生物样品的分析、鉴定,结果表明：湖水具较低pH值、极低的阳离子组成和矿化度;沉积物中Ca、Mg、Al、Fe等元素有明显流失;湖泊生物种群少且生物量低,缺失蓝藻和腹足类、瓣鳃类、甲壳类动物等为区别于一般中、碱性湖泊最显著的特点,酸性水介质湖泊系统元素地球化学行为的变化及其对生物的影响－－生物贫化和耐酸种扩张,既是腾冲青海的基本特点,也是酸性湖泊环境形成的动力机制。 相似文献
4.
Occurrences of pharmaceutically active compounds in surface water and sewage water have been widely reported. Investigations show the presence of several classes of pharmaceuticals such as antirheumatics (e.g., diclofenac), analgesics (e.g., propyphenazone), and blood lipid regulators (clofibric acid), even in ground water. Compared to their occurrences in surface water, however, the reported incidences of drugs in ground water are much rarer. This may be due to the input, but also to transport processes and degradation in the aquifer. In field studies investigating ground water sampled at a bank infiltration site at Lake Tegel, Berlin, Germany, clofibric acid was found at concentrations up to 290 ng/L, and propyphenazone up to 250 ng/L, whereas concentrations of diclofenac were around the detection limit. The aim of this study was to investigate the ground water transport behavior of the pharmaceuticals clofibric acid, propyphenazone, and diclofenac with a laboratory soil column experiment. Results show that clofibric acid exhibits no degradation and almost no retardation (Rf = 1.1). Diclofenac (Rf = 2.0) and propyphenazone (Rf = 1.6) are retarded, whereas significant degradation was not observed for both pharmaceuticals under the prevailing conditions in the soil column. We conclude that the concentration distribution of the pharmaceuticals at the bank filtration site at Lake Tegel is controlled by sorption, desorption, and input variation, rather than by degradation. 相似文献
5.
我国南方桉树(Eucalyptus)人工林区水库突发性泛黑形成机理初探 总被引：2，自引：0，他引：2
桉树(Eucalyptus)在我国南方大规模种植,最快两三年成材,经济价值高,但近来却被认为是"抽水机"、"绿色沙漠",甚至传言"有毒".特别是近年来桉树人工林区水库出现的"泛黑"现象——水体呈现黑褐色并伴有涩味,给种植地附近居民造成了很大的恐慌.并且其黑水形成机理、物质来源及触发条件等尚不清楚.基于此,本文选取我国南方桉树人工林区典型水库,开展了水体"泛黑"现象成因研究:于2015年8月2016年4月对广西南宁市那降水库、天雹水库、百合水库分别进行了4次水体垂直分层采样,测定其理化指标,并结合当地水库管理站提供的水文数据进行综合分析.结果表明,桉树人工林区水库泛黑与特定季节及特殊气候条件有关,水体温度分层结构失稳是黑水物质运移的主要动力因素;夏季水库水温分层结构稳定,限制了底层致黑物质向上迁移,溶解氧等水质指标分层明显,秋冬季节分层消失,水体发生垂直交换,给底层致黑物质提供了上翻的作用力,导致"泛黑"现象发生.硫化物、单宁酸、铁、锰等物质季节性及空间分异特征与水温季节性分层特性密切相关.桉树林区水库水体铁和锰浓度最高可达2.93和3.46 mg/L,桉树茎、叶在水体中浸出大量单宁酸,在硫化物、单宁酸、铁、锰同时存在的条件下,发生铁、锰与硫化物,硫化物与单宁酸,铁、锰与单宁酸等一系列反应,生成黑色络合物,导致水库泛黑.研究结果可为保障桉树人工林区饮用水源地安全提供指导,并为桉树人工林区水库黑水深入研究奠定基础,引领更多学者进行深入研究. 相似文献
6.
为进一步明确山西忻州奇村水汞观测过程中存在的干扰因素,分别对硫酸单一试剂、综合试剂、空气湿度、同一个水样多次观测等项进行了试验。试验表明,现用硫酸及其他试剂的汞污染均不明显,对水汞观测构不成于扰;观测室内空气高湿度对水汞观测有一定干扰,且湿度越大,干扰越强,高湿度导致测值大幅突跳;通常所测的水汞含量实为在鼓泡延续时间及空气流量固定不变特定情况下的相对含量,两者的改变会对测值的可比性产生人为干扰。 相似文献
7.
The presence of acid pharmaceuticals in water environments poses a potential threat to ecosystems and human health. Recent research has shown that photo oxidation processes are much more effective for removing these pharmaceuticals. However, the existence of humic acid (HA) could inhibit the clearance efficiency of this process. In this study, we investigated the photochemical degradation of six selected acid pharmaceuticals in surface water and effluent from wastewater treatment plants using the UV/H2O2 process. The results showed that HA can act as a photo sensitizer or a . OH sink, and its concentration had a significant inhibitory effect on the degradation of acid pharmaceuticals. Most of these pharmaceuticals were inhibited during this process when HA was added to deionized water solutions. In addition, the effects of chloride, bicarbonate, and nitrate on the degradation of these pharmaceuticals were different. The removal efficiency of these acid pharmaceuticals is lower in natural samples than in deionized samples because of the complex constituents in the latter. 相似文献
8.
Data on fluorine concentration in water in the Middle Klyaz’ma Basin during summer low-water period have been obtained. Fluorine background concentration has been determined in streams (Klyaz’ma R., small rivers, and creeks), water bodies (drainage ditches, lakes), and subsoil waters. Anthropogenic fluorine hydrochemical anomalies have been determined and localized with respect to urbanized industrial areas. An assumption has been made and experimentally substantiated, according to which fluorine concentration in subsoil water is governed by the processes of its distribution between water and host rocks. It has been established that the interaction of soils with snowmelt water and alluvial deposits with river water in neutral and acid media is accompanied by fluorine removal from solution, while in a weakly alkaline medium, fluorine passes from solid phase into solution. The effect of dissolved organic matter on the process of fluorine leaching from rock minerals also depends, primarily, on the equilibrium pH value: in weakly alkaline media, the presence of organic acids contributes to fluorine mobilization, while in weakly acid media, it reduces mobilization rate. 相似文献
9.
A method for determining the critical loads of acid fallout for surface waters is described. Adaptation of the method for estimating the degree of water acidification in the Kola North is demonstrated in the process of large-scale investigations carried out in this region. The limiting value of the acid-neutralizing capacity of waters needed for preventing the aquatic ecosystems from degradation is substantiated. The loads of acid fallout in 17% of 460 examined water systems are found to exceed the critical limits and create the conditions for further development of adverse processes in water systems. 相似文献
10.
F.J Cook W Hicks E.A Gardner G.D Carlin D.W Froggatt 《Marine pollution bulletin》2000,41(7-12):319-326
Disturbed acid sulphate soils are potent sources of acidity in coastal waterways. Monitoring studies of the drainage water for sites at East Trinity, Cairns and Pimpama, south-east Queensland indicate that considerable acidity is found in the drainage water from these sites. Hydrogen (H+), ferrous (Fe2+) and aluminium (Al) ions are the dominant acid cations involved. When drainage water is mixed with fresh or marine waters the effect of H+ on acidity generation is immediate. Aluminium can release acidity on hydrolysis, while the oxidation of Fe2+ to Fe3+ both acidifies and removes dissolved oxygen from the water. Strongly acidic waters with low levels of dissolved oxygen concentration are undesirable for most forms of aquatic life. Export of acidity from acid sulphate soil is likely to have a major effect on inshore fisheries and breeding grounds especially in periods of flood following drought or periods of low rainfall, where large volumes of acidity can be flushed/leached into sensitive aquatic/marine habitats. Impacts may include low dissolved oxygen, fish kills, epizootic ulceration syndrome and damage to oysters. During the processes of oxidation and hydrolysis, iron and aluminium flocs form, that can smother benthic communities. Heavy metals are found in the drainage water at elevated levels and may also be of concern for aquatic organisms. Chronic effects such as habitat degradation, mortality of marine worms, bivalves, invasion of acid tolerant species (both plant and animal) and avoidance of habitat have been documented elsewhere. These areas require further research. 相似文献
11.
Cyanuric acid is a suspected gastrointestinal or liver toxicant in humans. Therefore, determination of trace cyanuric acid is very important, in this work a novel, sensitive, and reliable method was developed using differential pulse polarography. Optimum conditions for analytical determination were found to be at a pH of 9.5, Britton–Robinson at a reduction potential of ?105 mV. Experimental results indicate an excellent linear correlation between the peak current and the concentration in the range of cyanuric acid from 0.5 to 27.0 µM (0.06–3.5 µg mL?1) with a correlation coefficient of 0.997. The limit of detection and limit of quantification were obtained as 0.15 and 0.5 µM (0.02–0.06 µg mL?1), respectively. The proposed method was successfully applied to the determination of cyanuric acid in pool water and in spiked milk. Cyanuric acid level in swimming pool water was found as 2.54 ± 0.47 µg mL?1 (19.7 ± 2.29 µM) in swimming pool water for N = 4 and 95% confidence interval. The recoveries were found to be sufficient. Also, the standard deviation of the data was low which shows high accuracy and precision of proposed differential pulse polarographic method. The influences of some other commonly found inorganic salts on the determination of cyanuric acid were also examined. Some interfering species were eliminated using complexing agents, e.g., EDTA. 相似文献
12.
Humic compounds are one of the major substances that affect the COD value of the surface water of Lake Kojima. The humic compounds in the lake water were studied with a spectrofluorophotometer. The 3-dimensional fluorescence spectrum suggests that two kinds of fluorescent substances exist in the lake water. One shows an fluorescence excitation maxim (Ex) at about 240 nm and an emission maxim (Em) at 413 nm. The other has an Ex at 330 nm and an Em at 418 nm. The former peaks are associated with humic acid and the latter peaks are associated with fulvic acid. These peak intensities are proportional to the COD values. The fulvic acid in the lake water may be enriched by the effluent from domestic water treatment plants. 相似文献
13.
Application of Natural Attenuation to Ground Water Contaminated by Phenoxy Acid Herbicides at an Old Landfill in Sjoelund, Denmark 总被引：1，自引：0，他引：1
Nina Tuxen Palle Ejlskov Hans-Jørgen Albrechtsen Lotte A. Reitzel Jørn K. Pedersen Paul L. Bjerg 《Ground Water Monitoring & Remediation》2003,23(4):48-58
Investigations of geology, hydrogeology, and ground water chemistry in the aquifer downgradient from Sjoelund Landfill, Denmark, formed the basis for an evaluation of natural attenuation as a remediation technology for phenoxy acid herbicides at the site. Concentrations of phenoxy acids were up to 65 μg/L in the ground water, primarily 4-chlor-2-methylphenoxypropionic acid (MCPP) and 2,4-dichlorophenoxypropionic acid (dichlorprop). Mass removal of the phenoxy acids was shown within 50 to 100 m of the landfill by calculation of contaminant fluxes passing transects at three distances. There was accordance between increasing oxygen concentrations and decreasing phenoxy acid concentrations with distance from the landfill, indicating that aerobic degradation was a major mass removal process. Presence of high concentrations of putative anaerobic phenoxy acid metabolites suggested that anaerobic degradation was also occurring. Laboratory degradation experiments using sediment and ground water from the aquifer supported aerobic and anaerobic degradability of MCPP at the site. It was concluded that natural attenuation may be applicable as a remedy for the phenoxy acids at the Sjoelund Landfill site, although uncertainties related to calculations of chloride and phenoxy acid fluxes at a complex site and identification of specific in situ indicators were encountered. Thus, there is a pronounced need for development and broader experience with evaluation tools for natural attenuation of phenoxy acids, such as specific metabolites, changes in enantiomeric fractions, compound-specific stable carbon isotope ratios, or microbial fingerprints. 相似文献
14.
A.M.D. van Rotterdam-Los A. Heikens S.P. Vriend M.J. van Bergen P.F.M. van Gaans 《Journal of Volcanology and Geothermal Research》2008
Volcanogenic contamination of irrigation water, caused by effluent from the hyperacid Ijen crater lake, has severely affected the properties of agricultural soils in East Java, Indonesia. From a comparison of acidified topsoil with subsoil and with top- and subsoil in a reference area, we identified processes responsible for changes in soil and soil solution chemistry induced by acid irrigation water, with emphasis on the nutrients Ca, Mg, Fe, and Mn, and on Al, which may become phytotoxic under acid conditions in soils. Compositional data for bulk soil composition and selective extractions with 1 M KCl and 0.2 M acid ammonium oxalate are used in a mass balance approach to specify element fluxes, including uptake by rice plants. The results show that input via irrigation water has produced an increase in the total aluminum content in the affected topsoil, which is of the same order of magnitude as the increase in labile Al. High bioavailability of Al, as reflected by concentrations in KCl extracts, is consistent with elevated concentrations observed in rice plants. In contrast, and despite the high input via irrigation water, Ca and Mg concentrations have decreased in all measured soil fractions through dissolution of amorphous phases and minerals, and through competition of Al for adsorption sites on the exchange complex and plant roots. Strong leaching is also evident for Fe and especially Mn. In terms of the overall mass balance of the topsoil, plant uptake of Al, Ca, Fe, Mg and Mn is negligible. If the use of acid irrigation would be stopped and the soil pH were to increase to values above 4.5, the observed phytotoxicity of Al will be halted. However, crops may then become fully dependent on the input from irrigation water or fertilizer for essential elements, due to the previous removal from the topsoil through leaching. 相似文献
15.
Kathleen C. Benison Deidre LaClair Jessica Walker 《Earth and Planetary Science Letters》2008,270(3-4):330-337
Physical sedimentology experiments have shown that sulfuric acid solutions may have formed some surface features seen on Mars. Recent data returned from Mars show the presence of jarosite, sulfate salts, hematite, phyllosilicates, and opaline silica, all of which precipitate from some terrestrial sulfuric acid solutions. There is a plethora of geochemical, mineralogical, and sedimentological data indicative of past sulfuric acid systems on Mars, but there has never been a comprehensive study published regarding sulfuric acid as a physical sedimentological agent. In the laboratory, we ran liquids of various compositions over sediments in order to test how these liquids entrain, transport, and deposit sediments. Pure water and concentrated sulfuric acid solutions produced the same general features, such as channels, gullies, and alluvial fans. However, sulfuric acid solutions yielded some distinct sedimentary features not produced by pure water runs. These features, narrow, deeply incised channels of consistent widths, rounded discrete fans, and air bubble “craters”, are similar to some Martian landscape features. These experimental results indicate that acid solutions should be considered a possible sedimentological agent on Mars. 相似文献
16.
Peter B. McMahon Don A. Vroblesky Paul M. Bradley Francis H. Chapelle Cheryl D. Gullett 《Ground water》1995,33(2):207-216
Total concentrations of formate, acetate, and isobutyrate varied from less than 5 to greater than 9,000 μmol/l over distances of < 3 m in ground water from a shallow hydrocarbon contaminated aquifer. Laboratory incubations of aquifer material indicate that organic acid concentrations were dependent on the amount of hydrocarbon loading in the sediment and the relative rates of microbial organic acid production and consumption. In heavily contaminated sediments, production greatly exceeded consumption and organic acid concentrations increased. In lightly contaminated sediments rates were essentially equal and organic acid concentrations remained low. Concentrations of dissolved calcium, magnesium, and iron generally were one to two orders of magnitude higher in organic acid-rich ground water than in ground water having low organic acid concentrations. Carbonate and Fe(III)-oxyhydroxide minerals were the likely sources of these elements. Similarly, concentrations of dissolved silica, derived from quartz and k-feldspar, were higher in organic acid-rich ground water than in other waters. The positive relation (r = 0.60, p < .05, n = 16) between concentrations of silica and organic acids suggests that the microbially mediated buildup of organic acids in ground water enhanced quartz/k-feldspar dissolution in the aquifer, although it was not the only factor influencing their dissolution. A model that included organic acid microequivalents normalized by cation microequivalents significantly strengthened the correlation (r = 0.79, p < .001, n = 16) between dissolved silica and organic acid concentrations, indicating that competition between silica and cations for complexation sites on organic acids also influenced quartz/k-feldspar dissolution. Physical evidence for enhanced mineral dissolution in organic acid-rich waters included scanning electron microscopy images of highly corroded quartz and k-feldspar grains from portions of the aquifer containing organic acid-rich ground water. Microporosity generated in hydrocarbon contaminated sediments may adversely affect remediation efforts that depend on the efficient injection of electron acceptors into an aquifer or on the recovery of solutes from an aquifer. 相似文献
17.
大气酸沉降会导致地表水体酸化和富营养化,同时气候变暖也会影响湖泊水体环境,湖泊生态系统如何响应二者相互作用是全球变化研究的热点之一.我国西南地区是全球酸沉降负荷最高的地区之一,然而目前对酸沉降影响下地表水环境变化规律知之甚少.本文以重庆四面山龙潭湖为研究对象,通过沉积岩芯的210Pb测年和硅藻分析,并结合流域历史资料数据,揭示龙潭湖过去近百年来水环境变化及其主要驱动因子.结果表明,1926-1968年,龙潭湖以Achnanthidium minutissimum和Encyonema silesiacum占优势;随后,Lindavia bodanica快速增加至峰值后逐渐减少,伴随Aulacoseira alpigena和Aulacoseira ambigua含量上升.硅藻组合中以适应中性和弱碱性水体的属种为主,嗜酸性属种含量很少,表明目前水体总体维持弱碱性,这得益于当地紫色砂页岩和森林土壤对于酸沉降的缓冲作用.尽管目前龙潭湖仍维持弱碱性,1980s以来硅藻推导水体酸碱度下降、中富营养种增加,表明酸沉降降低水体碱度并提高营养水平.气候变暖加剧水体热力分层和营养富集,导致适应扰动、贫营养环境的L.bodanica减少.2010年以来,中富营养属种略有减少反映湖泊富营养化有所减缓. 相似文献
18.
以艾比湖流域主要入湖河流为研究对象,在5月（丰水期）和8月（枯水期）分别沿博尔塔拉河（博河）和精河进行采样,采用平行因子模型（PARAFAC）和三维荧光区域积分法对水体三维荧光特性进行研究并对其与水质的关系在枯、丰水期下的变化进行探讨.结果表明①河流DOM在枯水期与丰水期都含有C1（240、425 nm） UVC类腐殖质,C2（225、290 nm）紫外区内络氨酸类有机物,C3（230/280、330 nm）蛋白类有机物,C4（265、260 nm）腐殖质类共4种组分.通过对水体三维荧光进行区域积分可以看出DOM荧光成分的占比在不同时期的变化.博河在枯水期时EEM光谱中的区域Ⅲ富里酸含量低于丰水期,枯水期时区域Ⅱ芳香类蛋白质、区域Ⅳ可溶性微生物代谢物以及区域Ⅴ类腐殖质酸高于丰水期;对于精河来说,区域Ⅱ芳香类蛋白质和区域Ⅳ可溶性微生物代谢物在枯水期的含量高于丰水期,区域Ⅲ富里酸和区域Ⅴ类腐殖质酸的含量枯水期低于丰水期,这表明水体腐质化程度较高.②本研究选取了一些常规的荧光指数来描述枯、丰水期水体的荧光指数特性.经研究发现,精河的荧光指数、自生源指数和腐殖化指数在不同时期的变化幅度较小,而博河的变化幅度较大.③将荧光指数与水质参数进行相关性分析并建模,结果表明枯水期自生源指数（BIX）与化学需氧量呈显著正相关,相关系数R=0.688;丰水期时BIX与铵态氮浓度呈显著负相关,相关系数R=-0.493.通过对比分析艾比湖主要入湖河流的三维荧光光谱特性与水质在枯、丰水期时的关系进一步表明水体中DOM的特性以及在枯、丰水期下的差异,为艾比湖流域的治理改善提供一定的理论支持和参考依据. 相似文献
19.
Hans Pichler 《Bulletin of Volcanology》1965,28(1):293-310
In exceptional cases also acid hyaloclastites can be originated by submarine extrusion of acid lavas. Acid hyaloclastites — which hitherto were not known — could be found for the first time on the western Ponza-Islands/Tyrrhenian Sea, Italy. The formation of acid hyaloclastites is closely connected with the process of auto-brecciation proceeding during the extrusion of acid lavas; both processes work together and cause the disintegration of parts of extruding lavabodies (domes etc.) into a mass of volcano-clastic materials. Hyaloclastization that is both the chilling of fluid lava in contact with water, ice or water bearing country rocks and the shattering of the congealed glassy skin by the pressure of the inflowing lava. Auto-brecciation that is destruction of parts of the extruding mass, not only by movements proceeding during the slow cruption but also by explosive phenomena depending on the release of the vapors. Hyaloclastization and auto-brecciation of acid lavas are an example of convergency: through both processes more or less similar deposits are formed. Thus brecciated acid hyaloclastites are not to be distinguished from auto-breccias. Two occurrences of brecciated lavas in California are interpreted as acid and intermediate hyaloclastites. Both are originated by the intrusion of rhyolitic respectively of andesitic lavas into water-bearing country rocks. In particularity for Iceland the possibility is discussed, that the formation of acid hyaloclastites also may occur in case of subglacial eruptions of acid lavas. 相似文献
20.
A field study was conducted using a combination of intrinsic and artificial tracers to estimate travel times and dilution during transport of infiltrate from a reclaimed water infiltration basin to nearby monitoring wells. A major study objective was to validate boric acid enriched in (10)B as an artificial tracer. Basin 10E at the Rio Hondo Spreading Grounds in Whittier, California, was the site of the test. The basin normally receives a mixture of treated municipal waste water, purchased State Project water, and local runoff from the San Gabriel River. Approximately 3.5 kg of (10)B-enriched boric acid was dispersed among 2.05 x 10(5) m(3) of basin water to initiate the experiment. The resultant median delta(11)B in the infiltration basin was -71 per thousand. Prior to tracer addition, the basin water had an intrinsic delta(11)B of +2 per thousand. Local monitoring wells that were used to assess travel times had delta(11)B values of +5 per thousand and +8 per thousand at the time of tracer addition. Analytic results supported an assumption that boron is conserved during ground water transport and that boron enriched in (10)B is a useful artificial tracer. Several intrinsic tracers were used to reinforce the boric acid tracer findings. These included stable isotopes of oxygen (delta(18)O) and hydrogen (deltaD), sulfate concentration, and the boron to chloride ratio. Xenon isotopes, (136)Xe and (124)Xe, also supported boron isotope results. Xenon isotopes were added to the recharge basin as dissolved gases by investigators from the Lawrence Livermore National Laboratory. 相似文献