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1.
South China karst aquifer storm-scale hydrochemistry   总被引:7,自引:0,他引:7  
Liu Z  Groves C  Yuan D  Meiman J 《Ground water》2004,42(4):491-499
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2.
Hydrological and hydrochemical processes in the critical zone of karst environments are controlled by the fracture‐conduit network. Modelling hydrological and hydrochemical dynamics in such heterogeneous hydrogeological settings remains a research challenge. In this study, water and solute transport in the dual flow system of the karst critical zone were investigated in a 73.5‐km2 catchment in southwest China. We developed a dual reservoir conceptual run‐off model combined with an autoregressive and moving average model with algorithms to assess dissolution rates in the “fast flow” and “slow flow” systems. This model was applied to 3 catchments with typical karst critical zone architectures, to show how flow exchange between fracture and conduit networks changes in relation to catchment storage dynamics. The flux of bidirectional water and solute exchange between the fissure and conduit system increases from the headwaters to the outfall due to the large area of the developed conduits and low hydraulic gradient in the lower catchment. Rainfall amounts have a significant influence on partitioning the relative proportions of flow and solutes derived from different sources reaching the underground outlet. The effect of rainfall on catchment function is modulated by the structure of the karst critical zone (e.g., epikarst and sinkholes). Thin epikarst and well‐developed sinkholes in the headwaters divert more surface water (younger water) into the underground channel network, leading to a higher fraction of rainfall recharge into the fast flow system and total outflow. Also, the contribution of carbonate weathering to mass export is also higher in the headwaters due to the infiltration of younger water with low solute concentrations through sinkholes.  相似文献   

3.
A benchmark test for flow in karstic aquifers is presented in the form of an exact solution of the harmonic variations of water flux and head within a karst conduit that is imbedded within a three-dimensional porous matrix having a free surface. The variations are driven by a prescribed variation of head applied at one end of the conduit. The benchmark consists of expressions for the spring discharge as a function of time and the conduit head and flux as functions of distance along the conduit and time. These expressions contain three dimensionless parameters, permitting development of a wide range of specific benchmark tests. The expressions are particularly simple in the case of an infinitely deep aquifer. This limiting solution should provide the most severe test for two-dimensional models of karst aquifer flow. Another limiting case of interest is that in which the conduit diameter is equal to the water depth. This limiting solution should provide the easiest test for two-dimensional models.  相似文献   

4.
Discharge exceedance probabilities are calculated for a simple model karst aquifer composed of a few multilevel conduits with recharge from a single sinking stream with an exponential flow exceedance distribution. It is assumed that outflow instantaneously matches inflow, so that the conduit volume is constant but discharge is governed by the head in a volumeless shaft at the top end of the system. It is shown that small single conduit aquifers will frequently overflow at the surface during floods and the exceedance probability of flow through the aquifer and over the surface can be defined as a function of the inflow distribution and the form of the aquifer. Systems with multiple conduits will overflow less frequently, but each conduit will exhibit a flow distribution characteristic of its form and position in the vertical hierarchy. Comparison of these findings with actual flow data from a conduit aquifer shows that the approach is valid, although imprecise. The model is unlikely to be applied directly, as it requires unusually detailed data. However, it provides for the first time an indication of typical flow durations for surface overflows and individual conduits in a karst aquifer. Contrasts in flow duration will have a profound influence on solutional and sedimentary processes in the karst system.  相似文献   

5.
Conduit properties and karstification in the unconfined Floridan aquifer   总被引:3,自引:0,他引:3  
Exchange of water between conduits and matrix is an important control on regional chemical compositions, karstification, and quality of ground water resources in karst aquifers. A sinking stream (Santa Fe River Sink) and its resurgence (River Rise) in the unconfined portion of the Floridan Aquifer provide the opportunity to monitor conduit inflow and outflow. The use of temperature as a tracer allows determination of residence times and velocities through the conduit system. Based on temperature records from two high water events, flow is reasonably represented as pipe flow with a cross-sectional area of 380 m2, although this model may be complicated by losses of water from the conduit system at higher discharge rates. Over the course of the study year, the River Rise discharged a total of 1.9 x 10(7) m3 more water than entered the River Sink, reflecting net contribution of ground water from the matrix into the conduit system. However, as River Sink discharge rates peaked following three rainfall events during the study period, the conduit system lost water, presumably into the matrix. Surface water in high flow events is typically undersaturated with respect to calcite and thus may lead to dissolution, depending on its residence time in the matrix. A calculation of local denudation is larger than other regional estimates, perhaps reflecting return of water to conduits before calcite equilibrium is reached. The exchange of matrix and conduit water is an important variable in karst hydrology that should be considered in management of these water resources.  相似文献   

6.
Karst spring responses examined by process-based modeling   总被引:8,自引:0,他引:8  
Birk S  Liedl R  Sauter M 《Ground water》2006,44(6):832-836
Ground water in karst terrains is highly vulnerable to contamination due to the rapid transport of contaminants through the highly conductive conduit system. For contamination risk assessment purposes, information about hydraulic and geometric characteristics of the conduits and their hydraulic interaction with the fissured porous rock is an important prerequisite. The relationship between aquifer characteristics and short-term responses to recharge events of both spring discharge and physicochemical parameters of the discharged water was examined using a process-based flow and transport model. In the respective software, a pipe-network model, representing fast conduit flow, is coupled to MODFLOW, which simulates flow in the fissured porous rock. This hybrid flow model was extended to include modules simulating heat and reactive solute transport in conduits. The application of this modeling tool demonstrates that variations of physicochemical parameters, such as solute concentration and water temperature, depend to a large extent on the intensity and duration of recharge events and provide information about the structure and geometry of the conduit system as well as about the interaction between conduits and fissured porous rock. Moreover, the responses of solute concentration and temperature of spring discharge appear to reflect different processes, thus complementing each other in the aquifer characterization.  相似文献   

7.
In China, 9·5% of the landmass is karst terrain and of that 47,000 km2 is located in semiarid regions. In these regions the karst aquifers feed many large karst springs within basins of thousands of square kilometres. Spring discharges reflect the fluctuation of ground water level and variability of ground water storage in the basins. However, karst aquifers are highly heterogeneous and monitoring data are sparse in these regions. Therefore, for sustainable utilization and conservation of karst ground water it is necessary to simulate the spring flows to acquire better understanding of karst hydrological processes. The purpose of this study is to develop a parsimonious model that accurately simulates spring discharges using an artificial neural network (ANN) model. The karst spring aquifer was treated as a non‐linear input/output system to simulate the response of karst spring flow to precipitation and applied the model to the Niangziguan Springs, located in the east of Shanxi Province, China and a representative of karst springs in a semiarid area. Moreover, the ANN model was compared with a previous time‐lag linear model and it was found that the ANN model performed better. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

8.
The permeable conduit wall in a karst aquifer allows for water and solute to be exchanged between conduits and the limestone matrix. Contaminant sequestered in the limestone matrix is flushed into conduits following flood events. The contaminant released from the permeable wall will then mix with conduit water and will be transported downgradient in the conduit. A one-dimensional advection-dispersion equation is presented to describe this mixing-transport incorporating water flow and solute flux through the conduit wall. An analytical solution ignoring conduit dispersion is derived using the method of characteristics. Scale analysis is performed to provide a general guideline to estimate when conduit dispersion can be neglected. The solution also can be used to compute the distribution of solute in the matrix before flushing.  相似文献   

9.
Hydrological and biogeochemical processes in karst environments are strongly controlled by heterogeneous fracture-conduit networks. Quantifying the spatio-temporal variability of water transit time and young water fractions in such heterogeneous hydrogeological systems is fundamental to linking discharge and water quality dynamics in the karst critical zone. We used a tracer-aided conceptual hydrological model to track the fate of each hour of rain input individually. Using this approach, the variability of transit time distributions and young water fraction were estimated in the main landscape units in a karst catchment of Chenqi in Guizhou Province, Southwest China. The model predicted that the mean young water (i.e., <~2 months old) fraction of ground conduit flow is 0.31. Marked seasonal variabilities in water storage and hydrological connectivity between the conduit network and fractured matrix, as well as between hillslopes and topographic depression, drive the dynamics of young water fraction and travel time distributions in each landscape unit. Especially, the strong hydrological connectivity between the land surface and underground conduits caused by the direct infiltration through large fractures and sinkholes, leads the drastic increasement in young water fraction of runoff after heavy rain. Even though the contribution of young water to runoff is greater, the strong mixing and drainage of small fractures accelerate the old water release during high flows during the wet season. It is notable that the young water may sometimes be the most contaminated component contributing to the underground conduit network in karst catchments, because of the direct transfer of contaminants from the ground surface with rain water via large fractures and sinkholes.  相似文献   

10.
Hao Y  Yeh TC  Wang Y  Zhao Y 《Ground water》2007,45(1):46-52
There are approximately 470,000 km(2) of karst aquifers that feed many large springs in North China. Turbulent flow often exists in these karst aquifers, which means that the classical ground water model based on Darcy's law cannot be applied here. Ground water data are rare for these aquifers. As a consequence, it is difficult to quantitatively investigate ground water flow in these karst systems. The purpose of this study is to develop a parsimonious model that predicts karst spring discharge using gray system theory. In this theory, a white color denotes a system that is completely characterized and a black color represents a system that is totally unknown. A gray system thus describes a complex system whose characteristics are only partially known or known with uncertainty. Using this theory, we investigated the karst spring discharge time series over different time scales. First, we identified three specific components of spring discharge: the long-term trend, periodic variation, and random fluctuation. We then used the gray system model to simulate the long-term trend and obtain periodic variation and random fluctuation components. Subsequently, we developed a predictive model for karst spring discharge. Application of the model to Liulin Springs, a representative example of karst springs in northern China, shows that the model performs well. The predicted results suggest that the Liulin Springs discharge will likely decrease over time, with small fluctuations.  相似文献   

11.
A structure model was used to analyse solute‐transport parameter estimates based on tracer breakthrough curves. In the model system, groundwater flow is envisioned to be organised in a complex conduit network providing a variety of short circuits with relative small carrying capacities along different erosion levels. The discharge through the fully filled conduits is limited owing to void geometries and turbulent flow; thus, a hierarchic overflow system evolves where conduits are (re‐)activated or dried up depending on the flow condition. Exemplified on the Lurbach–Tanneben karst aquifer, the applicability of the model approach was tested. Information derived from multi‐tracer experiments performed at different volumetric flow rates enabled to develop a structural model of the karst network, under constraint of the geomorphological and hydrological evolution of the site. Depending on the flow rate, groundwater is divided into up to eight flow paths. The spatial hierarchy of flow paths controls the sequence of flow path activation. Conduits of the topmost level are strongly influenced by reversible alteration processes. Sedimentation or blocking causes an overflow of water to the next higher conduit. Flow path specific dissolutional denudation rates were estimated using the temporal development of the partial discharge. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

12.
Cross-correlation analyses on field data collected in karst aquifer systems can be used to develop a conceptual understanding of the aquifer. This includes the use of many data sets from the same aquifer to develop an understanding of how properties vary spatially. We focus on a method for characterizing the distribution of recharge, which is becoming increasingly important in regions where urban development encroaches on these important sources of water. Spatially varying precipitation data and cross-correlation analysis provide a means of spatially characterizing recharge locations on a karst aquifer. Our work expands on the numerical experiments conducted by Padilla and Pulido-Bosch (1995) using the numerical ground water model MODFLOW to introduce spatially varying parameters. The numerical experiments include conduit-controlled, matrix-controlled, and mixed karst systems with more than one precipitation time series input. The results show that spatially varying parameters can be inferred based on the cross-correlation of precipitation data and spring discharge. Simulations were completed using aquifer parameters derived from studies of the Barton Springs segment of the Edwards Aquifer. The simulations indicate that spatial variability within an aquifer can be inferred using cross-correlation analysis. A field study using these methods is summarized for Barton Springs near Austin, Texas.  相似文献   

13.
Flow and transport simulation in karst aquifers remains a significant challenge for the ground water modeling community. Darcy's law–based models cannot simulate the inertial flows characteristic of many karst aquifers. Eddies in these flows can strongly affect solute transport. The simple two-region conduit/matrix paradigm is inadequate for many purposes because it considers only a capacitance rather than a physical domain. Relatively new lattice Boltzmann methods (LBMs) are capable of solving inertial flows and associated solute transport in geometrically complex domains involving karst conduits and heterogeneous matrix rock. LBMs for flow and transport in heterogeneous porous media, which are needed to make the models applicable to large-scale problems, are still under development. Here we explore aspects of these future LBMs, present simple examples illustrating some of the processes that can be simulated, and compare the results with available analytical solutions. Simulations are contrived to mimic simple capacitance-based two-region models involving conduit (mobile) and matrix (immobile) regions and are compared against the analytical solution. There is a high correlation between LBM simulations and the analytical solution for two different mobile region fractions. In more realistic conduit/matrix simulation, the breakthrough curve showed classic features and the two-region model fit slightly better than the advection-dispersion equation (ADE). An LBM-based anisotropic dispersion solver is applied to simulate breakthrough curves from a heterogeneous porous medium, which fit the ADE solution. Finally, breakthrough from a karst-like system consisting of a conduit with inertial regime flow in a heterogeneous aquifer is compared with the advection-dispersion and two-region analytical solutions.  相似文献   

14.
Modeling flow and transport using both temperature and dye tracing provides constraints that can improve understanding of karst networks. A laminar flow and transport model using the finite element subsurface flow model simulated the conduit connection between a sinking stream and spring in central Pennsylvania to evaluate how conduit morphology might affect dye transport. Single and overly tortuous conduit models resulted in high concentrations as dye flowed back into the conduit from the matrix after dye injections ceased. A forked conduit model diverted flow from the main conduit, reducing falling limb dye concentration. Latin hypercube sampling was performed to evaluate the sensitivity of 52 parameter combinations (conduit hydraulic conductivity, conduit cross-sectional area, matrix transmissivity, matrix porosity, and dispersivity) for four conduit geometry scenarios. Sensitivity of arrival time for 50% of the dye indicated no parameter combinations which simulate falling limb dye concentrations for tortuous geometries, confirming the importance of the forked geometry regardless of other parameters. Temperature data from high-resolution loggers were then incorporated into the forked conduit model to reproduce seasonal spring temperature using variable sink inflow. Unlike the dye trace models, the thermal models were sensitive to other model parameters, such as conduit cross-sectional area and matrix transmissivity. These results showed this dual approach (dye and temperature) to karst network modeling is useful for (1) exploring the role of conduit and matrix interaction for contaminant storage, (2) constraining karst conduit geometries, which are often poorly understood, and (3) quantifying the effect of seasonal trends on karst aquifers.  相似文献   

15.
Combination of a conduit flow law with the exceedance probability of stream discharge allows the estimation of the exceedance probability of water level in a simple conduit aquifer. The probability of water levels higher than available relief is interpreted as the probability of surface as opposed to underground runoff. Very high probability of surface runoff implies a fluvial environment, whereas very low probabilities define a mature karst or ‘holokarst’, Intermediate probabilities identify ‘fluviokarst’. Overflow probability depends on available relief, mean discharge, and especially conduit radius. Growth rate of the underground conduit depends on saturation deficit which thus controls the rate of evolution of the fluvial landscape, through fluviokarst to holokarst. However, variations of discharge and sedimentation through time can cause dramatic reversion of karst drainage into less mature states. Landscapes experiencing such periodic rejuvenation will have a confused morphology. A functional definition of landscape may be more objective and pertinent than arbitrary interpretation of form.  相似文献   

16.
A method to estimate reactive transport parameters as well as geometric conduit parameters from a multitracer test in a karst aquifer is provided. For this purpose, a calibration strategy was developed applying the two-region nonequilibrium model CXTFIT. The ambiguity of the model calibration was reduced by first calibrating the model with respect to conservative tracer breakthrough and later transferring conservative transport parameters to the reactive model calibration. The reactive transport parameters were only allowed to be within a defined sensible range to get reasonable calibration values. This calibration strategy was applied to breakthrough curves obtained from a large-scale multitracer test, which was performed in a karst aquifer of the Swabian Alb, Germany. The multitracer test was conducted by the simultaneous injection of uranine, sulforhodamine G, and tinopal CBS-X. The model succeeds to represent the tracer breakthrough curves (TBCs) of uranine and sulforhodamine G and verifies that tracer-rock interactions preferably occur in the immobile fluid region, although the fraction of this region amounts to only 3.5% of the total water. However, the model failed to account for the long tailing observed in the TBC of tinopal CBS-X. Sensitivity analyses reveal that model results for the conservative tracer transport are most sensitive to average velocity and volume fraction of the mobile fluid region, while dispersion and mass transfer coefficients are least influential. Consequently, reactive tracer calibration allows the determination of sorption sites in the mobile and immobile fluid region at small retardation coefficients.  相似文献   

17.
Karst Aquifer GIS‐based model (KAGIS model) is developed and applied to Mela aquifer, a small karst aquifer located in a Mediterranean region (SE Spain). This model considers different variables, such as precipitation, land use, surface slope and lithology, and their geographical heterogeneity to calculate both, the run‐off coefficients and the fraction of precipitation which contributes to fill the soil water reservoir existing above the aquifer. Evapotranspiration uptakes deplete water, exclusively, from this soil water reservoir and aquifer recharge occurs when water in the soil reservoir exceeds the soil field capacity. The proposed model also obtains variations of the effective porosity in a vertical profile, an intrinsic consequence of the karstification processes. A new proposal from the Nash–Sutcliffe efficiency index, adapted to arid environments, is presented and employed to evaluate the model's ability to predict the water table oscillations. The uncertainty in the model parameters is determined by the Generalized Likelihood Uncertainty Estimation method. Afterwards, when KAGIS is calibrated, wavelet analysis is applied to the resulting data in order to evaluate the variability in the aquifer behaviour. Wavelet analysis reveals that the rapid hydrogeological response, typical of a wide variety of karst systems, is the prevailing feature of Mela aquifer. This study proves that KAGIS is a useful tool to quantify recharge and discharge rates of karst aquifers and can be effectively applied to develop a proper management of water resources in Mediterranean areas.  相似文献   

18.
Hu LT  Chen CX 《Ground water》2008,46(4):642-646
Concurrent existence of confined and unconfined zones of an aquifer can arise owing to ground water withdrawal by pumping. Using Girinskii's potential function, Chen (1974, 1983) developed an approximate analytical solution to analyze transient ground water flow to a pumping well in an aquifer that changes from an initially confined system to a system with both unconfined and confined regimes. This article presents the details of the Chen model and then compares it with the analytical model developed by Moench and Prickett (1972) for the same problem. Hypothetical pumping test examples in which the aquifer undergoes conversion from confined to water table conditions are solved by the two analytical models and also a numerical model based on MODFLOW. Comparison of the results suggests that the solutions of the Chen model give better results than the Moench and Prickett model except when the radial distance is very large or aquifer thickness is large compared with drawdown.  相似文献   

19.
Analysis of methods to estimate spring flows in a karst aquifer   总被引:2,自引:0,他引:2  
Sepúlveda N 《Ground water》2009,47(3):337-349
Hydraulically and statistically based methods were analyzed to identify the most reliable method to predict spring flows in a karst aquifer. Measured water levels at nearby observation wells, measured spring pool altitudes, and the distance between observation wells and the spring pool were the parameters used to match measured spring flows. Measured spring flows at six Upper Floridan aquifer springs in central Florida were used to assess the reliability of these methods to predict spring flows. Hydraulically based methods involved the application of the Theis, Hantush-Jacob, and Darcy-Weisbach equations, whereas the statistically based methods were the multiple linear regressions and the technology of artificial neural networks (ANNs). Root mean square errors between measured and predicted spring flows using the Darcy-Weisbach method ranged between 5% and 15% of the measured flows, lower than the 7% to 27% range for the Theis or Hantush-Jacob methods. Flows at all springs were estimated to be turbulent based on the Reynolds number derived from the Darcy-Weisbach equation for conduit flow. The multiple linear regression and the Darcy-Weisbach methods had similar spring flow prediction capabilities. The ANNs provided the lowest residuals between measured and predicted spring flows, ranging from 1.6% to 5.3% of the measured flows. The model prediction efficiency criteria also indicated that the ANNs were the most accurate method predicting spring flows in a karst aquifer.  相似文献   

20.
Li G 《Ground water》2011,49(4):584-592
Often the water flowing in a karst conduit is a combination of contaminated water entering at a sinkhole and cleaner water released from the limestone matrix. Transport processes in the conduit are controlled by advection, mixing (dilution and dispersion), and retention-release. In this article, a karst transport model considering advection, spatially varying dispersion, and dilution (from matrix seepage) is developed. Two approximate Green's functions are obtained using transformation of variables, respectively, for the initial-value problem and for the boundary-value problem. A numerical example illustrates that mixing associated with strong spatially varying conduit dispersion can cause strong skewness and long tailing in spring breakthrough curves. Comparison of the predicted breakthrough curve against that measured from a dye-tracing experiment between Ames Sink and Indian Spring, Northwest Florida, shows that the conduit dispersivity can be as large as 400 m. Such a large number is believed to imply strong solute interaction between the conduit and the matrix and/or multiple flow paths in a conduit network. It is concluded that Taylor dispersion is not dominant in transport in a karst conduit, and the complicated retention-release process between mobile- and immobile waters may be described by strong spatially varying conduit dispersion.  相似文献   

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