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1.
A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.
Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.
Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils. 相似文献
2.
Brian K. Richards Steven Pacenka Anthony E. Salvucci Sheila M. Saia Luanne F. Whitbeck Peter M. Furdyna Tammo S. Steenhuis 《Ground Water Monitoring & Remediation》2012,32(1):73-82
Private wells in Cayuga and Orange counties in New York were sampled to determine the occurrence of pesticide contamination of groundwater in areas where significant pesticide use coincides with shallow or otherwise vulnerable groundwater. Well selection was based on local groundwater knowledge, risk modeling, aerial photo assessments, and pesticide application database mapping. Single timepoint samples from 40 wells in each county were subjected to 93‐compound chromatographic scans. All samples were nondetects (reporting limits ≤1 μg/L), thus no wells from either county exceeded any of 15 state groundwater standards or guidance values. More sensitive enzyme‐linked immunosorbent assays (ELISA) found two wells with quantifiable atrazine in each county (0.1–0.3 μg/L), one well with quantifiable diazinon (0.1 μg/L) in Orange County, and one well with quantifiable alachlor (0.2 μg/L) in Cayuga County. Trace detections (<0.1 μg/L) in Cayuga County included atrazine (five wells), metolachlor (six wells), and alachlor (one well), including three wells with multiple detections. All 12 Cayuga County wells with ELISA detections had either corn/grain or corn/forage rotations as primary surrounding land uses (although 20 other wells with the same land uses had no detections) and all quantified detections and most trace detections occurred in wells up to 9‐m deep. Orange County trace (<0.1 μg/L) ELISA detections (atrazine three wells, diazinon one well, and metolachlor five wells) and quantified detections were only generally associated with agricultural land uses. Finding acceptable drinking water quality in areas of vulnerable groundwater suggests that water quality in less vulnerable areas will also be good. 相似文献
3.
Four popular, recreational beaches in Miami, FL are Hobie Beach, Virginia Key Beach, Crandon Park Beach, and Bill Baggs Cape Florida State Park. While all of the beaches are within a few miles of each other in Biscayne Bay, they have greatly differing water qualities, as determined by the testing for fecal indicator bacteria performed by the Florida Department of Health. Using the geodesic theory of transport barriers, we identify Lagrangian Coherent Structures (LCSs) in each area. We show how these material curves, which shape circulation and mixing patterns, can be used to explain the incongruous states of the water at beaches that should be comparable. The LCSs are computed using a hydrodynamic model and verified through field experimentation at each beach. 相似文献
4.
Bonilla TD Nowosielski K Cuvelier M Hartz A Green M Esiobu N McCorquodale DS Fleisher JM Rogerson A 《Marine pollution bulletin》2007,54(9):1472-1482
Fecal indicator levels in nearshore waters of South Florida are routinely monitored to assess microbial contamination at recreational beaches. However, samples of sand from the surf zone and upper beach are not monitored which is surprising since sand may accumulate and harbor fecal-derived organisms. This study examined the prevalence of fecal indicator organisms in tidally-affected beach sand and in upper beach sand and compared these counts to levels in the water. Since indicator organisms were statistically elevated in sand relative to water, the study also considered the potential health risks associated with beach use and exposure to sand. Fecal coliforms, Escherichia coli, enterococci, somatic coliphages, and F(+)-specific coliphages were enumerated from sand and water at three South Florida beaches (Ft. Lauderdale Beach, Hollywood Beach, and Hobie Beach) over a 2-year period. Bacteria were consistently more concentrated in 100g samples of beach sand (2-23 fold in wet sand and 30-460 fold in dry sand) compared to 100ml samples of water. Somatic coliphages were commonly recovered from both sand and water while F(+)-specific coliphages were less commonly detected. Seeding experiments revealed that a single specimen of gull feces significantly influenced enterococci levels in some 3.1m(2) of beach sand. Examination of beach sand on a micro-spatial scale demonstrated that the variation in enterococci density over short distances was considerable. Results of multiple linear regression analysis showed that the physical and chemical parameters monitored in this study could only minimally account for the variation observed in indicator densities. A pilot epidemiological study was conducted to examine whether the length of exposure to beach water and sand could be correlated with health risk. Logistic regression analysis results provided preliminary evidence that time spent in the wet sand and time spent in the water were associated with a dose-dependent increase in gastrointestinal illness. 相似文献
5.
在2008年5月12日汶川MS8.0地震和2013年4月20日芦山MS7.0地震中,龙门山中央断裂南段的盐井—五龙断裂均未发现地表破裂现象,加之该断裂浅层地球物理资料极度匮乏,在一定程度上限制了对龙门山断裂带南段地震危险性的评价和发震能力的评估。针对龙门山中央断裂南段的盐井-五龙断裂经过区段的主要乡(镇)所在地多为宽度不大于300m的山间峡谷地区,且探测场区存在交通条件不便、场地工作面狭窄等问题,在浅层地震反射波法探测工作中采用小道间距、小偏移距、多道短排列接收和共反射点多次覆盖观测的地震数据采集方式,并经数据处理后获得地震反射剖面图像。浅层地震探测定位结果结合高密度电阻率成像断面、探槽开挖和钻孔联合剖面资料,共同揭示了NE向的盐井—五龙断裂在宝兴县五龙乡东风村一带精确的空间展布位置、产状规模和近地表构造形态。探测结果表明盐井—五龙断裂于五龙乡北东风村西河两岸的T1阶地处隐伏通过,性质为倾向NW的逆冲断裂,近地表倾角50°~60°,上断点埋深19m。该断裂断错宝兴西河T2、T3阶地,西河右岸T1阶地断裂通过处两侧基岩的断距6~8 m,其破碎带及其影响带宽度约30m。本文浅层地球物理探测成果可对判定盐井—五龙断裂的近地表构造活动提供可靠的地震学证据,也为地震重灾区(宝兴县城)的灾后工程选址重建、地震危险性评价和制定抗震防灾规划提供了科学的基础资料。 相似文献
6.
Pesticides in Nebraska's Ground Water 总被引：1，自引：0，他引：1
《Ground Water Monitoring & Remediation》1989,9(4):126-133
More than 2263 well water samples were collected throughout Nebraska and analyzed for pesticides. Thirteen and one-half percent contained detectable levels of atrazine, but only 22 wells exceeded the health advisory of 3.0 ppb. Although the samples came from almost every county in the state, this sampling is not based solely on a randomly selected group of wells. The highest frequency of detections occurred in irrigated corn-growing areas with less than 50 feet to ground water. These areas were sampled at a greater frequency than the less vulnerable areas. Cyanazine, together with the additional triazines — simazine, propazine, prometone, and ametryne, also were detected in some well waters; however, their frequency of detection was well below that of atrazine. The triazine metribuzin was not detected.
Alachlor, propachlor, and metolachlor also were detected in trace levels in several wells. Five of 2072 samples analyzed for alachlor exceeded the health advisory of 0.4 ppb. Almost all of the contaminated wells were in vulnerable areas. The relatively high frequency of propachlor detections occurred in predominately irrigated corn-growing areas, rather than in areas where propachlor is traditionally applied.
The factors that appear most directly involved in the observed distribution of pesticides in ground water are the intensity of areal usage, pesticide persistence and mobility, irrigation, soil drainage capacity, and depth to ground water.
Fifteen pesticide residues were detected during this study. If ethylene dibromide and carbon tetrachloride, which were detected in ground water adjacent to grain elevators are included, a total of 17 pesticide residues have been detected in Nebraska's ground water. 相似文献
Alachlor, propachlor, and metolachlor also were detected in trace levels in several wells. Five of 2072 samples analyzed for alachlor exceeded the health advisory of 0.4 ppb. Almost all of the contaminated wells were in vulnerable areas. The relatively high frequency of propachlor detections occurred in predominately irrigated corn-growing areas, rather than in areas where propachlor is traditionally applied.
The factors that appear most directly involved in the observed distribution of pesticides in ground water are the intensity of areal usage, pesticide persistence and mobility, irrigation, soil drainage capacity, and depth to ground water.
Fifteen pesticide residues were detected during this study. If ethylene dibromide and carbon tetrachloride, which were detected in ground water adjacent to grain elevators are included, a total of 17 pesticide residues have been detected in Nebraska's ground water. 相似文献
7.
Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present. 相似文献
8.
Methane Occurrences in Aquifers Overlying the Barnett Shale Play with a Focus on Parker County,Texas 
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下载免费PDF全文 Jean‐Philippe Nicot Patrick Mickler Toti Larson M. Clara Castro Roxana Darvari Kristine Uhlman Ruth Costley 《Ground water》2017,55(4):469-481
Clusters of elevated methane concentrations in aquifers overlying the Barnett Shale play have been the focus of recent national attention as they relate to impacts of hydraulic fracturing. The objective of this study was to assess the spatial extent of high dissolved methane previously observed on the western edge of the play (Parker County) and to evaluate its most likely source. A total of 509 well water samples from 12 counties (14,500 km2) were analyzed for methane, major ions, and carbon isotopes. Most samples were collected from the regional Trinity Aquifer and show only low levels of dissolved methane (85% of 457 unique locations <0.1 mg/L). Methane, when present is primarily thermogenic (δ13C 10th and 90th percentiles of ?57.54 and ?39.00‰ and C1/C2+C3 ratio 10th, 50th, and 90th percentiles of 5, 15, and 42). High methane concentrations (>20 mg/L) are limited to a few spatial clusters. The Parker County cluster area includes historical vertical oil and gas wells producing from relatively shallow formations and recent horizontal wells producing from the Barnett Shale (depth of ～1500 m). Lack of correlation with distance to Barnett Shale horizontal wells, with distance to conventional wells, and with well density suggests a natural origin of the dissolved methane. Known commercial very shallow gas accumulations (<200 m in places) and historical instances of water wells reaching gas pockets point to the underlying Strawn Group of Paleozoic age as the main natural source of the dissolved gas. 相似文献
9.
Following a major beach closure due to bacterial contamination, a survey of beachgoers was conducted in Huntington Beach, California in 1999 to assess perceived health risk from swimming. Responses were compared to those of beachgoers at the unaffected Laguna Main Beach. No significant differences were found in risk perception. Respondents were aware of the closures (83%), yet the majority (83%) felt the water was safe for swimming. Proximity of residence to the beach was strongly associated with closure awareness (Spearman's rho=0.427, p<0.0001). Although 83% of respondents felt that water quality was important in deciding to go to the beach, only 25% of respondents who did not plan to swim cited pollution or contamination as a reason not to swim. Most respondents (70%) trusted local health agency officials' decisions about when to open/close beaches. Surveyed beach visitors were likely to bathe (84%) and were not highly concerned with swimming-related health risks. 相似文献
10.
Shikha Sharma Michon L. Mulder Andrea Sack Karl Schroeder Richard Hammack 《Ground water》2014,52(3):424-433
Water and gas samples were collected from (1) nine shallow groundwater aquifers overlying Marcellus Shale in north‐central West Virginia before active shale gas drilling, (2) wells producing gas from Upper Devonian sands and Middle Devonian Marcellus Shale in southwestern Pennsylvania, (3) coal‐mine water discharges in southwestern Pennsylvania, and (4) streams in southwestern Pennsylvania and north‐central West Virginia. Our preliminary results demonstrate that the oxygen and hydrogen isotope composition of water, carbon isotope composition of dissolved inorganic carbon, and carbon and hydrogen isotope compositions of methane in Upper Devonian sands and Marcellus Shale are very different compared with shallow groundwater aquifers, coal‐mine waters, and stream waters of the region. Therefore, spatiotemporal stable isotope monitoring of the different sources of water before, during, and after hydraulic fracturing can be used to identify migrations of fluids and gas from deep formations that are coincident with shale gas drilling. 相似文献
11.
Fission-track dates and planktonic microfossil datum levels provide a revised chronology for the marine Late Cenozoic of southern California. In southern California, the Pliocene/Pleistocene boundary has been placed at the first appearance of Globorotalia truncatulinoides within the Pico Formation, Balcom Canyon, Ventura County. A fission-track age on glass shards from the Bailey Ash close to this level yields a result of 1.12 ± 0.36 m.y. B.P. (millions of years before present). In tropical deep-sea cores, however, G. truncatulinoides has been shown to evolve within the Gilsa paleomagnetic event with an estimated age of 1.8 m.y. B.P. Thus, the first appearance of G. truncatulinoides in southern California is cryptogenic and probably related to the delayed migration into this region of water-mass conditions suitable for this species.Two volcanic ashes from the upper part of the Malaga Formation, Malaga Cove, Los Angeles County, yielded fission-track dates on glass shards of 4.42 ± 0.57 m.y. B.P. (lower ash) and 3.364 ± 0.69 m.y. B.P. (upper ash). These dates, in addition to inferred paleomagnetic ages of planktonic microfossil datum levels suggest that the Delmontian Stage of California ranges in age from ～6 to ～3 m.y. B.P. Therefore, the Miocene/Pliocene boundary considered by Berggren and Van Couvering to be ～5 m.y. B.P. must lie in the lower Delmontian Stage but paleontologic criteria for its recognition in California are not yet available. 相似文献
12.
Kelly WR 《Ground water》2008,46(5):772-781
The rapid expansion of major cities throughout the world is resulting in the degradation of water quality in local aquifers. Increased use of road deicers since the middle of the 20th century in cities in the northern United States, Canada, and Europe has been linked to degraded ground water quality. In this article, Chicago, Illinois, and its outlying suburban areas are used as an example of the effects of urbanization in a historical context. A statistical study of historical water quality data was undertaken to determine how urbanization activities have affected shallow (<60 m) ground water quality. Chloride (Cl− ) concentrations have been increasing, particularly in counties west and south of Chicago. In the majority of shallow public supply wells in the western and southern counties, Cl− concentrations have been increasing since the 1960s. About 43% of the wells in these counties have rate increases greater than 1 mg/L/year, and 15% have increases greater than 4 mg/L/year. Approximately 24% of the samples collected from public supply wells in the Chicago area in the 1990s had Cl− concentrations greater than 100 mg/L (35% in the western and southern counties); median values were less than 10 mg/L before 1960. The greater increase in Cl− concentrations in the outer counties is most likely due to both natural and anthropogenic factors, including the presence of more significant and shallower sand and gravel deposits, less curbing of major highways and streets, and less development in some parts of these counties. 相似文献
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14.
Peter R. Jørgensen Niels H. Spliid Troels Laier Stefan Outzen 《Ground Water Monitoring & Remediation》2016,36(3):33-42
This study investigated the development of pesticide pollution two, three, and 17 years after spills of the herbicides dichlorprop, mecoprop (MCPP), MCPA, 2,4‐D (phenoxy acids), simazine, and terbutylazine (triazines) in a former orchard machinery service yard. The spills had occurred over several decades on a 23‐m thick, mainly anaerobic fractured clayey till aquitard. Angled monitoring wells were installed in the aquitard 3 years after the spills ceased in 1989. In 1993, monitoring revealed that high groundwater concentrations of dichlorprop (677 µg/L) and MCPP (139 µg/L) were accumulated as a zone of maximum pollution in anaerobic and largely immobile pore water at 5 to 6 m depth in the aquitard profile. In contrast, 2,4‐D was determined in only one water sample, and MCPA and simazine and terbutylazine were determined only in low concentrations (below10 µg/L), although these pesticides had been handled at the site in greater amounts than dichlorprop and MCPP according to detailed historic information obtained for the site. Repeated monitoring in the same wells after a further 14 years in 2007 revealed that no identifiable degradation of MCPP had occurred, while dichlorprop had degraded by 75% to 80% (estimated half‐life of approximately 5 years). Furthermore, degradation products related to the phenoxy acids had accumulated, especially 4‐CPP with a maximum concentration of 218 µg/L. In the same zone, MCPA and simazine had almost disappeared. As the pollution was mainly accumulated in largely immobile pore water of the aquitard clayey matrix, and the groundwater recharge was low (30 to 60 mm/year), only minor vertical displacement of the zone with maximum pollution zone had occurred during the 15 years of monitoring. However, concentrations of dichlorprop (0.01 to 0.02 µg/L), MCPP (0.1 to 0.2 µg/L), and 4‐CPP (0.6 to 0.7 µg/L) had spread along textural heterogeneities in the aquitard into the underlying sandy aquifer at 23‐m depth. 相似文献
15.
Measurements of near-bed shear stress were undertaken in the shallow subtidal zone at Durras Beach, NSW, Australia using a sideways-looking acoustic velocity meter installed within the wave boundary layer. The wave climate was swell-dominated and wave conditions comprised shoaling and breaking waves as well as surf bores. The sediment at the field site was medium-grained sand, and observations of bedform geometry were conducted using a pencilbeam-sonar system. Using frequency-filtering techniques, the measured stresses were partitioned into terms representing turbulent (Reynolds) stress, stresses due to gravity and infragravity-scale oscillatory motions, and wave-turbulence-mean current cross-terms. Gravity wave-orbital scale motions contributed the largest fraction of the stresses, comprising 24% on average, followed by long-wave advection of vertical orbital motion (16%). The presence of wave orbital-scale motions near or at the water/sediment interface was likely due to the porous nature of the seabed, facilitating interfacial flow. Shear stresses did not scale with bed roughness but exhibited a linear relationship with the relative wave height. This indicates that for the experimental conditions, surf zone processes overwhelmed bed roughness effects on shear stress and friction. Calculations of the wave friction factor, fw, showed that in a natural surf zone, this was a factor 3–4 larger than conventional predictions. © 2020 John Wiley & Sons, Ltd. 相似文献
16.
The areas that experienced large strains and differential motions in the soil (indicated by breaks in the water and gas pipe distribution systems) and the areas with severely damaged buildings showed remarkable separation during the March 10, 1933, Long Beach, California earthquake. With analogous results for the 1994 Northridge, California earthquake [Soil Dynam. Earthquake Engng. 17 (1998) 41], the observations summarized in this paper show the fallacy of simplistic and popular interpretations, such as those that hold that in the near field the damage to buildings is caused by ‘soft’ or ‘bad ground’ conditions. In fact, significant reduction in the potential damage to buildings may be expected in the areas where the soil experiences ‘moderate to large’ strains. 相似文献
17.
基于强震动观测台钻孔数据, 统计得到了四川、 甘肃地区20 m深的浅硬土层场地平均剪切波速模型． 通过与美国加州地区的波速模型对比, 结合四川、 甘肃地区地震预报的地壳模型, 延拓剪切波速模型至40 km． 应用四分之一波长法计算了浅硬土层场地的平均场地放大系数． 利用场地放大系数, 消除13次余震中浅硬场地的台站场地响应, 反演了龙门山断层上、 下盘的介质品质因子以及13次余震的有效应力降． 通过与普通土层场地的强震动记录对比, 对浅硬土层场地的放大系数进行调整, 得到了深厚土层场地的平均放大系数． 相似文献
18.
The results from field tests on Pine Flat Dam near Fresno, California, are described. The results are then used in the formulation of a three-dimensional mathematical model of the dam and a two-dimensional mathematical model of one of the taller monoliths. The significance of these mathematical models in relationship to the behaviour of concrete gravity dams during earthquakes is also discussed. 相似文献
19.
Michael O. Walters 《Ground Water Monitoring & Remediation》1995,15(4):114-118
Sarasota County is one of 10 generalized areas of the continental United States known to haw high concentrations of naturally occurring radium in fresh ground water (Chandler 1989). Various authors have conducted investigations to examine the distribution of radium in ground water, rivers, and estuaries. They concluded that ground water was the source of radium, but rivers were also enriched with radium as a result of the interaction with ground water. The Glulf of Mexico also has areas with radium enrichment resulting from geothermal springs with concentrations as high as 51 picocuries per liter. During 1986 and 1987. the Health and Rehabilitative Services of the state of Florida collected ground water data for radium analysis of private drinking water wells. These data were used to develop a contour map of radium-226 concentrations for coastal Sarasota County. 相似文献
20.
Aquifers of the peninsulas of Florida and northern Yucatan are Tertiary marine carbonate formations showing many lithologic and faunal similarities. In addition, the tropical to subtropical climates of the two areas are similar, each having annual rainfall of about 1000 to 1500 mm.
Despite similarities in these fundamental controls, contrasts in the hydrologic and geochemical systems are numerous and striking. For example, Florida has many rivers; Yucatan has none. Maximum thickness of fresh ground water in Florida is about 700 meters; in the Yucatan it is less than 70 meters. In Florida the gradient of the potentiometric surface averages about 1 meter per kilometer; in the Yucatan it is exceedingly low, averaging about 0.02 meter per kilometer. In Florida the chemical character of water changes systematically downgradient, owing to solution of minerals of the aquifer and corresponding increases in total dissolved solids, sulfate, calcium, and Mg-Ca ratio; in the Yucatan no downgradient change exists, and dominant processes controlling the chemical character of the water are solution of minerals and simple mixing of the fresh water and the body of salt water that underlies the peninsula at shallow depth.
Hydrologic and chemical differences are caused in part by the lower altitude of the Yucatan plain. More important, however, these differences are due to the lack of an upper confining bed in Yucatan that is hydrologically equivalent to the Hawthorn Formation of Florida. The Hawthorn cover prevents recharge and confines the artesian water except where it is punctured by sinkholes, but sands and other unconsolidated sediments fill sinkholes and cavities and impede circulation. In the Yucatan the permeability of the entire section is so enormous that rainfall immediately infiltrates to the water table and then moves laterally to discharge areas along the coasts. 相似文献