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1.
An upsurge in oil- and gas-well drilling in northwestern Pennsylvania and western New York has been accompanied by several incidents of contamination of ground water by methane. Determining which well is causing the contamination is extremely difficult if more than one gas or oil well is present in the area.
The fact that the solubility of methane decreases as the pressure on ground water decreases provides a quantitative basis for monitoring changes in the amount of methane in the ground water. Quantitative measurements of the volume of methane given off by ground water pumped from a well as the water enters atmospheric pressure permit detection of temporal changes in the gas content which are too subtle to be detected visually. These gas volume changes may, in some cases, be correlated with variations in the pressure of methane in the annulus of nearby individual gas/oil wells and thus may provide a means of pinpointing the gas/oil well that is causing the methane contamination.
The basic principle of the gas-volume monitoring apparatus (GVMA) described in this paper is that as a measured amount of ground water enters atmospheric pressure the gas which comes out of solution is trapped and measured. The GVMA can be constructed of materials costing less than $100 and requires no special skills to assemble or operate. In a recent study conducted in a western New York village, four homeowners were able to collect quantitative gas-volume data from their household water wells daily in about one-half hour. Unlike laboratory analyses for dissolved methane, there is no cost involved in monitoring with the GVMA beyond the initial instrument cost and operator time. Another advantage is that the data are available immediately.  相似文献   

2.
Shale needs to contain a sufficient amount of gas to make it viable for exploitation. The continental heterogeneous shale formation in the Yan-chang (YC) area is investigated by firstly measuring the shale gas content in a laboratory and then investigating use of a theoretical prediction model. Key factors controlling the shale gas content are determined, and a prediction model for free gas content is established according to the equation of gas state and a new petrophysical volume model. Application of the Langmuir volume constant and pressure constant obtained from results of adsorption isotherms is found to be limited because these constants are greatly affected by experimental temperature and pressures. Therefore, using measurements of adsorption isotherms and thermodynamic theory, the influence of temperature, total organic carbon (TOC), and mineralogy on Langmuir volume constants and pressure constants are investigated in detail. A prediction model for the Langmuir pressure constant with a correction of temperatures is then established, and a prediction model for the Langmuir volume constant with correction of temperature, TOC, and quartz contents is also proposed. Using these corrected Langmuir constants, application of the Langmuir model determined using experimental adsorption isotherms is extrapolated to reservoir temperature, pressure, and lithological conditions, and a method for the prediction of shale gas content using well logs is established. Finally, this method is successfully applied to predict the shale gas content of the continental shale formation in the YC area, and practical application is shown to deliver good results with high precision.  相似文献   

3.
Compressibility of porous rocks: Part II. New relationships   总被引:1,自引:0,他引:1  
Pore volume compressibility is one of the physical properties of a reservoir that must be specified in many reservoir-engineering calculations. The main objective of this work is to provide new general formulas for pore volume compressibility versus porosity on the basis of measured compressibilities of some limestone and sandstone rocks in a wide range of porosity values and of varied type; the measurements were performed on Hungarian reservoir rock samples. The obtained laboratory results were compared with the published correlations of consolidated limestone samples as well with values for friable and strongly consolidated sandstones. The validity of using compressibility data from the literature was investigated. The measured data showed poor agreement with the published correlations. The first approach to find better and more accurate rock compressibility correlations consisted of combing all the data available from the literature, using the same formula of Horne’s type. However, this attempt did not give satisfying fitting results. In the next step, by using twelve different fitting formulas, and other comprehensive nonlinear fitting regression programs, new rock compressibility correlations for limestone and sandstone rocks, with better goodness of fit, were developed. These new correlations can be generalized and used for most of oil and gas reservoirs.  相似文献   

4.
In explosive magma eruptions, magma ascends through a conduit as a Poiseuille flow at depth, and gas exsolves gradually and expands as the pressure decreases (bubbly flow regime). When the volume fraction of gas becomes sufficiently large, liquid or solid parts of magma fragment into droplets or ashes, and the flow dynamics becomes governed by the gas phase (gas–ash flow regime). We propose a new flow regime, which we call fractured-turbulent flow regime, between the bubbly flow regime and the gas–ash flow regime. In the new regime, both liquid magma and gas are continuous phases. The high connectivity of the two phases allows the relative velocity between them to increase significantly. We present one sample calculation, which displays basically explosive characteristics, but has three features distinct from previous models. The explosive characteristics are manifested as the fragmentation of the magma and the high speed jet that issues from the vent. The first distinct feature is a nearly lithostatic pressure distribution, which results from the increase of the height of the fragmentation surface. The second one is the atmospheric pressure at the vent; the flow is not choked. The third one is that the relative velocity between the gas and the ash is large at the vent despite the large interaction force between the two phases. The large relative velocity is established in the fractured-turbulent regime, and is maintained in the subsequent gas–ash flow regime.  相似文献   

5.
Reliable estimates of the fluid pressure in the pore space of rocks are critical for different aspects of petroleum exploration and production including injection operations and scenarios of water flooding. Numerous approaches are available for formation pore pressure evaluation, however, these measurements become a challenge inside a cased borehole, and a list of possible options is short: either the casing is to be perforated, or the production tubing needs to be disconnected to perform the pressure tests. We present a method for through-casing evaluation of formation pore pressure without shutting down production. We suggest equipping an observation well with a borehole gravimeter and acquiring time variations of the vertical component of the gravity field. Changes in gravity occur during gas production and are related to time variations of formation pore pressure. Gravity changes obtained in the observation well are supposed to be inverted for time-dependent formation pore pressure variations beyond the casing. Our results and recommendations are based on numerical modeling of pore pressure spatial distribution during gas field exploitation and relevant changes in borehole gravity. Benchmark models were elaborated in order to consider a dynamic process of pressure changes in time and space under conditions similar to those in the Medvezhye gas field (Russia). Different modeling scenarios are considered for early and late stages of gas field exploitation. The sensitivity analysis was performed to estimate quantitatively a sensitivity of borehole temporal gravity changes to variations in formation pore pressure behind the casing. Based on resolution analysis we justify the possibility to extract the gravity measurements directly related to changes in pore pressure from the total changes in the gravity field due to reservoir exploitation. The impact of pore pressure on the gravity field measured in boreholes during the water flooding is also evaluated, and obtained results are discussed.  相似文献   

6.
Quantitative detection of fluid distribution using time-lapse seismic   总被引:1,自引:0,他引:1  
Although previous seismic monitoring studies have revealed several relationships between seismic responses and changes in reservoir rock properties, the quantitative evaluation of time‐lapse seismic data remains a challenge. In most cases of time‐lapse seismic analysis, fluid and/or pressure changes are detected qualitatively by changes in amplitude strength, traveltime and/or Poisson's ratio. We present the steps for time‐lapse seismic analysis, considering the pressure effect and the saturation scale of fluids. We then demonstrate a deterministic workflow for computing the fluid saturation in a reservoir in order to evaluate time‐lapse seismic data. In this approach, we derive the physical properties of the water‐saturated sandstone reservoir, based on the following inputs: VP, VS, ρ and the shale volume from seismic analysis, the average properties of sand grains, and formation‐water properties. Next, by comparing the in‐situ fluid‐saturated properties with the 100% formation‐water‐saturated reservoir properties, we determine the bulk modulus and density of the in‐situ fluid. Solving three simultaneous equations (relating the saturations of water, oil and gas in terms of the bulk modulus, density and the total saturation), we compute the saturation of each fluid. We use a real time‐lapse seismic data set from an oilfield in the North Sea for a case study.  相似文献   

7.
Volatile-filled vesicles are present in minor amounts in all samples of mid-ocean basalt yet collected (and presumably erupted) down to depths of 4.8 km. When such vesicles are pierced in liquid under standard conditions, the volume expansion of the gas is 0.2 ± 0.05 times the eruption pressure in bars or 20 ± 5 times the eruption depth in km. Such expansion could be used as a measure of eruption depth.A variety of techniques: (1) vacuum crushing and gas chromatographic, freezing separation, and mass spectrographic analyses; (2) measurements of phase changes on a freezing microscope stage; (3) microscopic chemical and solubility observations; and (4) volume change measurements, all indicate that CO2 comprises more than 95% by volume of the vesicle gas in several submarine basalt samples from the Atlantic and Pacific. The CO2 held in vesicles is present in quantities about equal to or greater than that presumed to be dissolved in the glass (melt) and amounts to 400–900 ppm of the rock. The rigid temperature of the glass is 800–1000°C and increases for shallower samples. A sulfur gas was originally present in subordinate amounts in the vesicles, but has largely reacted with iron in the vesicle walls to produce sulfide spherules.  相似文献   

8.
本文主要分析了1999年11月29日岫岩偏岭5.6级地震前,辽河盆地内7口观测井的前兆异常特征。观测项目有水位、采液量、采气量及套管压力等。这次地震前兆7口井的观测资料均出现明显的趋势异常和短临前兆异常,并且具有较好的同步性。异常形态多数表现为升-降-升型。油田抽水、注水、采油、采气及大气压、固体潮等干扰因素对观测资料没有影响,异常是真实可信的。  相似文献   

9.
Rn、CO2、Hg、H2等断层气体被广泛应用于断层活动性以及断层结构特征的研究.当前,研究介质中压力变化与断层气间的关系是断层气映震研究的主要技术方法之一.新疆呼图壁地下储气库自建成以来,每年以周期性循环"注入/采出"模式运行,该运行模式带来的储气库气压变化会影响周围地区的地震活动.同时,这一定期加压存储与减压释放气体...  相似文献   

10.
A key task of exploration geophysics is to find relationships between seismic attributes (velocities and attenuation) and fluid properties (saturation and pore pressure). Experimental data suggest that at least three different factors affect these relationships, which are not well explained by classical Gassmann, Biot, squirt-flow, mesoscopic-flow and gas dissolution/exsolution models. Some of these additional factors include (i) effect of wettability and surface tension between immiscible fluids, (ii) saturation history effects (drainage versus imbibition) and (iii) effects of wave amplitude and effective stress. We apply a new rock physics model to explain the role of all these additional factors on seismic properties of a partially saturated rock. The model is based on a well-known effect in surface chemistry: hysteresis of liquid bridges. This effect is taking place in cracks, which are partially saturated with two immiscible fluids. Using our model, we investigated (i) physical factors affecting empirical Brie correlation for effective bulk modulus of fluid, (ii) the role of liquids on seismic attenuation in the low frequency (static) limit, (iii) water-weakening effects and (iv) saturation history effects. Our model is applicable in the low frequency limit (seismic frequencies) when capillary forces dominate over viscous forces during wave-induced two-phase fluid flow. The model is relevant for the seismic characterization of immiscible fluids with high contrast in compressibilities, that is, for shallow gas exploration and CO2 monitoring.  相似文献   

11.
Measurements of dissolved gases have numerous applications in ground water hydrology, and it is now possible to measure the total dissolved gas pressure in situ using a probe. Dissolved gas pressure is measured by submerging a headspace volume with a gas-permeable membrane, allowing dissolved gases in the water to equilibrate with gases in the headspace, then measuring the pressure in the headspace with a pressure transducer. Total dissolved gas pressure (TGP) probes have many potential uses in ground water studies employing dissolved gases, including: (1) determining approximate excess air levels, which may provide information about the time and location of recharge; (2) screening wells for air contamination, which can compromise the accuracy of dissolved gas tracer techniques: (3) detecting a trapped gas phase, which can significantly reduce hydraulic conductivity and impede the transport of dissolved solutes and gases; (4) enabling the use of gas-filled passive diffusion samplers for determining accurate dissolved gas concentrations; and (5) determining relative concentrations of CH4 and CO2 when they are known to be highly abundant. Although TGP probes designed for surface water have been available for several years, TGP probes suitable for ground water applications have only recently become available. Herein we present what are, to our knowledge, the first reported ground water dissolved gas data collected using a TGP probe. We also explain the basic operating principles of these probes and discuss the potential applications listed.  相似文献   

12.
Hydrologic precursors to earthquakes: A review   总被引:4,自引:0,他引:4  
This review summarizes reports of anomalous flow rates or pressures of groundwater, oil, or gas that have been interpreted as earthquake precursors. Both increases and decreases of pressure and flow rate have been observed, at distances up to several hundred kilometers from the earthquake epicenter, with precursor times ranging from less than one day to more than one year. Although information that might rule out nontectonic causes does not appear in many published accounts of hydrologic anomalies, several recent studies have critically evaluated the possible influences of barometric pressure, rainfall, and groundwater or oil exploitation. Anomalies preceding the 1976 Tangshan, China, and the 1978 Izu-Oshima-Kinkai, Japan, earthquakes are especially well-documented and worthy of further examination.Among hydrologic precursors, pressure head changes in confined subsurface reservoirs are those most amenable to quantitative interpretation in terms of crustal strain. The response of pressure head to earth tides determines coefficients of proportionality between pressure head and crustal strain. The same coefficients of proportionality should govern the fluid pressure response to any crustal strain field in which fluid flow in the reservoir is unimportant. Water level changes in response to independently recorded tectonic events, such as earthquakes and aseismic fault creep, provide evidence that a calibration based on response to earth tides may be applied to crustal strains of tectonic origin.Several models of earthquake generation predict accelerating stable slip on part of the future rupture plane. If precursory slip has moment less than or equal to that of the impending earthquake, then the coseismic volume strain is an upper bound for precursory volume strain. Although crustal strain can be only crudely estimated from most reported pressure head anomalies, the sizes of many anomalies within 150 kilometers of earthquake epicenters appear consistent with this upper bound. In contrast, water level anomalies at greater epicentral distances appear to be larger than this bound by several orders of magnitude.It is clear that water level monitoring can yield information about the earthquake generation process, but progress higes on better documentation of the data.  相似文献   

13.
Geochemical precursors to seismic activity   总被引:7,自引:0,他引:7  
Studies of earthquake precursory phenomena during the last several decades have found that significant geophysical and geochemical changes can occur prior to intermediate and large earthquakes. Among the more intensely investigated geochemical phenomena have been: (1) changes in the concentrations of dissolved ions and gases in groundwaters and (2) variations in the concentrations of crustal and mantle volatiles in ground gases. The concentration changes have typically showed no conanomalies trend (either increasing or decreasing), and the spatial and temporal distribution of the observed anomalies have been highly variable. As a result, there is little agreement on the physical or chemical processes responsible for the observed anomalies. Mechanisms proposed to account for precursory groundwater anomalies include ultrasonic vibration, pressure sensitive solubility, pore volume collapse, fracture induced increases in reactive surfaces, and aquifer breaching/fluid mixing. Precursory changes in soil gas composition have been suggested to result from pore volume collapse, micro-fracture induced exposure of fresh reactive silicate surfaces, and breaching of buried gas-rich horizons. An analysis of the available field and laboratory data suggests that the aquifer breaching/fluid mixing (AB/FM) model can best account for many of the reported changes in temperature, dissolved ion and dissolved gas concentrations in groundwater. Ultrasonic vibration and pressure sensitive solubility models cannot reasonably account for the geochemical variations observed and, although the pore collapse model could explain some of the observed chemical changes in groundwater and ground gas, uncertainties remain regarding its ability to generate anomalies of the magnitude observed. Other geochemical anomalies, in particular those associated with hydrogen and radon, seem best accounted for by increases in reactive surface areas (IRSA model) that may accompany precursory deformation around the epicenter of an impending earthquake. Analysis of the probable response of these models to the earthquake preparation process, as well as to other environmental factors, suggests that geochemical monitoring programs can provide information that may be valuable in forecasting the probability of an earthquake; however, because of the complexity of the earthquake preparation process, the absolute prediction of seismic events using geochemical methods alone, does not presently appear to be feasible.  相似文献   

14.
We examine the basic characteristics of inflations at Semeru Volcano, Indonesia, to clarify the pressurization process prior to two different styles of explosive eruptions: Vulcanian eruptions and gas bursts. Analysis of data obtained from tilt meters installed close to the active crater allows clarification of the common features and the differences between the two styles of eruptions. To improve the signal-to-noise ratio and to determine the mean characteristics of the inflations, we stack tilt signals obtained from eruptions of different magnitudes and evaluate the maximum amplitude of the seismic signal associated with these eruptions. Vulcanian eruptions, which explosively release large amounts of ash, are preceded by accelerating inflation about 200–300 s before the eruption, which suggests volume expansion of the gas phase. In contrast, gas bursts, which rapidly effuse water steam accompanied by explosive sounds, follow non-accelerating changes of inflation starting 20 s before each emission. Tilt amplitudes increase with the magnitude of eruptions for both eruption styles. This suggests that the volume and/or pressure of magma or gas stored in the conduit before eruptions controls the magnitude of volcanic eruptions. These results further suggest that the magnitude of eruptions can be predicted from geodetic measurements of volcano inflation.  相似文献   

15.
分析了龙门山断裂带附近的四川中坝气田气井井口压力数据,发现汶川地震前,多口气井出现井口压力异常升降的变化.开采层深3 100 m的7口雷三储气层的气井压力,在4月8日-5月5日井压同步出现了大于35%-130%的上升;开采层深2400m的24口须二储气层的气井中,多数井压在震前出现缓慢下降的异常变化,幅度最大为45%,...  相似文献   

16.
Transient high pore‐water pressures, up to 50 cm higher than ambient pressure, developed over the summer season at various depths in a shallow (1 m) fen peat. The excess pressures had a pattern of gradual increases and sharp drops, and their initiation and release typically corresponded to abrupt changes in atmospheric pressure. We conclude that these phenomena depend on gas bubbles (probably methane) generated by biological activity, both by clogging pores and by building up pressure as they grow. These transient and spatially discontinuous high‐pressure zones were found using pressure transducers in sealed (backfilled) pits, but not in piezometers open to the atmosphere. Piezometers may provide a conduit for the release of gas and pressure, thus rendering them unsuitable for measuring this phenomenon. Although the development of localized zones of high pressure causes erratic and unpredictable hydraulic gradients, we suggest that their effect on the flow of water or solutes is offset by the reduced permeability caused by the bubbles, which allows them to be sustained. These zones, however, probably deflect flows driven by the dominant hydraulic gradients. Furthermore, they may cause the peat volume to adjust (swell). The use and interpretation of traditional methods for estimating hydraulic head and conductivity in peat soils thus require great caution. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

17.
This study attempts to determine the relation between source parameters and mechanical properties of the rock matrix in which the microseismic events occur. For this purpose, accurate geological, mechanical and seismological data were acquired on a gas field experiencing induced seismicity due to its reservoir pressure drop. More than 30 deep boreholes (depth greater than 4 km) are concentrated in a 10×10×5 km volume, providing core samples for both geological and mechanical assessment. In this study, we focus on induced seismic events recorded by the local seismic network, over a three-year-long period. Characteristics of the seismic sources were obtained using spectral analysis and a dynamic model of failure. Results point out correlation between physical parameters of the seismic sources and the geomechanical properties of the rocks involved. Maximal static stress drops are found to be associated with the mechanical strength of the geological strata where the rupture occurs. The fracture size, using a circular model of failure, is also found to be dependent on the geomechanical setting. It is found that the size of the seismic fractures is dependent on the layer thickness and the prefracturation of the medium, both factors influencing the extension of preexisting discontinuities. The parameters of the seismic sources also show important changes when the gas reservoir is reached. The reservoir unit experienced a 45 MPa pore fluid pressure drop over a period of 20 years.  相似文献   

18.
Horizontal drilling and hydraulic fracturing have enabled hydrocarbon recovery from unconventional reservoirs, but led to natural gas contamination of shallow groundwaters. We describe and apply numerical models of gas‐phase migration associated with leaking natural gas wells. Three leakage scenarios are simulated: (1) high‐pressure natural gas pulse released into a fractured aquifer; (2) continuous slow leakage into a tilted fractured formation; and (3) continuous slow leakage into an unfractured aquifer with fluvial channels, to facilitate a generalized evaluation of natural gas transport from faulty natural gas wells. High‐pressure pulses of gas leakage into sparsely fractured media are needed to produce the extensive and rapid lateral spreading of free gas previously observed in field studies. Transport in fractures explains how methane can travel vastly different distances and directions laterally away from a leaking well, which leads to variable levels of methane contamination in nearby groundwater wells. Lower rates of methane leakage (≤1 Mcf/day) produce shorter length scales of gas transport than determined by the high‐pressure scenario or field studies, unless aquifers have low vertical permeabilities (≤1 millidarcy) and fractures and bedding planes have sufficient tilt (~10°) to allow a lateral buoyancy component. Similarly, in fractured rock aquifers or where permeability is controlled by channelized fluvial deposits, lateral flow is not sufficiently developed to explain fast‐developing gas contamination (0‐3 months) or large length scales (~1 km) documented in field studies. Thus, current efforts to evaluate the frequency, mechanism, and impacts of natural gas leakage from faulty natural gas wells likely underestimate contributions from small‐volume, low‐pressure leakage events.  相似文献   

19.
煤岩吸附二氧化碳气体的CT实验研究   总被引:1,自引:0,他引:1  
利用工业CT技术及应变测量研究不同气压下煤岩的二氧化碳气体吸附性质。研究发现:煤样的应变随吸附时间和气体压力的增加而增加,且在不同方向是不同的,吸附气体导致煤样孔隙率增加;煤样CT图像的灰度均值和灰度标准差随吸附时间和气体压力的增长都表现出增加的趋势。结果表明:吸附二氧化碳导致煤样总体发生膨胀变形,这为吸附提供更多的孔隙表面积而使吸附气体量增加,含气煤样的密度也因此而增大;气体吸附导致的煤样密度均值增加的效应大于体积膨胀导致的煤样密度均值减小的效应;吸附使煤样内部物质分布不均匀程度增加。  相似文献   

20.
This paper lays the foundation for the rigorous treatment of the energetics of gas exsolution from a gas-containing liquid, which powers gas-driven volcanic and limnic eruptions. Various exsolution processes (reversible or irreversible, slow or rapid) are discussed, and the maximum amount of kinetic energy derivable from a reversible gas exsolution process is obtained. The concept of dynamic irreversibility is proposed for discussing the kinetic energy available from irreversible gas exsolution processes. The changes of thermodynamic properties during gas exsolution processes are derived. Density–pressure relations for gas–liquid mixtures are presented, including empirical relations for irreversible gas exsolution. The energetics of gas-driven eruptions through both fluid and rigid media, including the role of buoyancy and the role of magma chamber expansion work, are investigated. For reversible processes, the energetics can be used to discuss the dynamics of gas-driven eruptions, leading to maximum erupting velocities and maximum eruptible fractions. For irreversible processes, empirical relations and parameters must be employed. The exit velocities of the Lake Nyos eruption and the 18 May 1980 eruption of Mount St. Helens are modeled by incorporating possible irreversibility.  相似文献   

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