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1.
We performed pan evaporation experiments with the objective of exploring the behaviour of the long-standing Craig–Gordon (C–G) stable isotope model for evaporation under different conditions of air turbulence. The water lost through evaporation was automatically replenished so that a steady isotopic composition was reached, the value of which depended on the isotopic composition of the replenishment water and environmental parameters like temperature, relative humidity and isotopic composition of the atmospheric vapour, and the air turbulence index. The pans were exposed to artificial winds ranging from 0 to 2.5 m/s to change the air turbulence index, which governs the repartition between vapour transported by molecular diffusion and turbulent diffusion. Our data revealed that for wind speeds >0.5 m/s the isotopic composition of the evaporating water deviated from that predicted by the C–G model. This deviation was hypothetically attributed to microdroplets of liquid water removed by the wind without any isotopic fractionation. Isotope mass balance equations allowed us to quantify this water loss, which at wind speeds of ~2 m/s reached 10% of the total evaporation losses. An alternative kinetic evaporation model was proposed whereby the equilibrium layer and the atmospheric laminar layer above the evaporating water of the C–G model were destroyed by the wind and evaporated water molecules were directly injected into the atmosphere. In this model, the isotopic fractionations were due to the slower kinetics of hydrogen bond breakage between molecules in liquid water when heavy isotopes are involved. Accordingly, our data suggested that for isotope water balance studies where winds are frequently above 2 m/s, the C–G model may be inadequate without appropriate corrections for spray vaporization, or the introduction of appropriate kinetic isotope fractionation factors.  相似文献   

2.
This study examined the weekly water vapour isotopic composition (δ18Ov) in Thailand. The water vapour was cryogenically collected from eight sites across the country. Two observational samples were collected over one 24-h period each week (a daytime and a night-time sample), from September 2013 to September 2014. The primary aim was to investigate the environmental factors influencing water vapour isotopes. The results revealed differences in water vapour isotopic values between day and night samples. Three periods of depleted δ18Ov were associated with large-scale convective systems in September, December, and May. The statistical relationship between the climate variables and water vapour isotopes indicated that the amount of precipitation and relative humidity were the primary controls on both diurnal and seasonal isotopic variability. The temperature did not affect the δ18Ov, mainly because the atmospheric processes are a function of vertical convection rather than temperature in tropical regions. The water vapour deuterium excess (d-excess) showed greater variability in 2013 than in 2014. The d-excess variation reflected the differences in convection occurring in the day and night. In addition, the vapour phase data were combined with the local meteoric water line to identify the local water vapour line and the interaction between the isotopic composition of water vapour and liquid water. The water vapour isotopic patterns paralleled the precipitation isotopes on rainy days because of equilibrium isotopic exchange. Water vapour and precipitation were isotopically similar under low humidity but showed greater differences from each other under wetter conditions. The study results provide insight into water vapour isotopic characteristics in tropical regions and constrain the role of large-scale atmospheric processes relative to isotopic variability of water vapour in Thailand and nearby countries.  相似文献   

3.
The project captured a subset of the hydrological cycle for the tropical island of O'ahu, linking precipitation to groundwater recharge and aquifer storage. We determined seasonal storm events contributed more to aquifer recharge than year-round baseline orographic trade wind rainfall. Hydrogen and oxygen isotope values from an island-wide rain collector network with 20 locations deployed for 16 months and sampled at 3-month intervals were used to create the first local meteoric water line for O'ahu. Isotopic measurements were influenced by the amount effect, seasonality, storm type, and La Niña, though little elevation control was noted. Certain groundwater compositions from legacy data showed a strong similarity with collected precipitation from our stations. The majority of these significant relationships were between wet season precipitation and groundwater. A high number of moderate and heavy rainfall days during the dry season, large percentage of event-based rainfall, and wind directions outside of the typical NE trade wind direction were characteristics of the 2017–2018 wet season. This indicates that the majority of wet season precipitation is from event-based storms rather than typical trade wind weather. The deuterium-excess values provided the strongest evidence of a relationship between groundwater and different precipitation sources, indicating that this may be a useful metric for determining the extent of recharge from different rain events and systems.  相似文献   

4.
Stable water isotope ratios are measured as a tracer of environmental processes in materials such as leaves, soils, and lakes. Water in these archives may experience evaporation, which increases the abundance of heavy isotopologues proportionally to the gradients in humidity and isotope ratio between the evaporating water and the surrounding atmosphere. The isotope ratio of the atmosphere has been difficult to measure until recently, and measurements remain scarce. As a result, several assumptions have been adopted to estimate isotope ratios of atmospheric water vapour. Perhaps the most commonly employed assumption in terrestrial environments is that water vapour is in isotopic equilibrium with precipitation. We evaluate this assumption using an eight‐member ensemble of general circulation model (GCM) simulations that include explicit calculation of isotope ratios in precipitation and vapour. We find that across the model ensemble, water vapour is typically less depleted in heavy isotopologues than expected if it were in equilibrium with annual precipitation. Atmospheric vapour likely possesses higher‐than‐expected isotope ratios because precipitation isotope ratios are determined by atmospheric conditions that favour condensation, which do not reflect atmospheric mixing and advection processes outside of precipitation events. The effect of this deviation on theoretical estimates of isotope ratios of evaporating waters scales with relative humidity. As a result, the equilibrium assumption gives relatively accurate estimates of the isotope ratios of evaporating waters in low latitudes but performs increasingly poorly at increasing latitudes. Future studies of evaporative water pools should include measurements of atmospheric isotope ratios or constrain potential bias with isotope‐enabled GCM simulations.  相似文献   

5.
The Chirripó hydrological research site (CHRS) is located within the Chirripó National Park, Costa Rica (between 3100 and 3820 m asl) whereby ~100 km2 are covered by Páramo, a high-elevation tropical grassland ecosystem. A lake district with approximately 30 lakes of glacial origin is also protected in this area. The CHRS has been monitored since April 2015 with the aim of establishing the first water isotope baseline for the Central American Páramo. At a regional scale, the water isotope ratios (δ2H and δ18O) in precipitation and surface water at CHRS are useful for describing the governing moisture transport from the Caribbean Sea and Pacific Ocean and the complex rainfall producing systems across the N–S mountain range of Central America. These data are also providing unique information about the evaporation and water balance conditions of tropical glacial lakes and the formation of orographic and convective precipitation in high-elevation tropical ecosystems. Current data sets from CHRS include continuous lake water temperature and meteorological conditions (i.e., precipitation amount, air temperature and relative humidity), as well as water stable isotopes in precipitation, stream water, and lake water (daily to biweekly sampling frequency). Stream water is collected at several locations across the topographic gradient whereas lake water is sampled in the three main lake systems of CHRS. CHRS serves as a reference site for conducting pilot isotopic research in high-elevation ecosystems to advance the atmospheric, hydrogeological and ecohydrological studies in these understudied biomes. All data from April 2015 to November 2020 are publicly available.  相似文献   

6.
Stable isotopic compositions of precipitation (δ18Op, δ2Hp and d-excessp) and atmospheric vapour (δ18Ov, δ2Hv and d-excessv) with high spatial–temporal resolution are crucial in revealing hydrologic cycle. Based on the variation characteristics of δ18Op/δ18Ov, δ2Hp/δ2Hv and d-excessp/d-excessv in the headwaters of the Shule River (HSR) on hourly and daily scales from June to September 2018, this study analysed the relationships between δ18Op/δ2Hp and δ18Ov/δ2Hv combined with the equilibrium fractionation model, as well as δ18Op/δ18Ov and meteorological factors. The slopes of local meteoric water line (LMWL) and the δ2Hv-δ18Ov fitting equation were similar (7.96 and 7.94) with both intercepts exceeding 10, reflecting the great contribution of recycling moisture. The values of δ18Ov/δ2Hv were lower than δ18Op/δ2Hp but with consistent variation patterns throughout the period. The equilibrium simulation results suggested that precipitation and atmospheric vapour almost approached isotopic equilibrium state, especially during monsoon intrusion period. Affected by monsoon intrusion, the slopes and intercepts of the LMWLs and the δ2Hv-δ18Ov fitting equations were smaller than those during non-monsoon period and d-excess and δ18O were negatively correlated. Relative humidity had significant negative correlations with δ18Op and δ18Ov in the whole period, however, the positive correlations between δ18Op/δ18Ov and temperature were observed during non-monsoon and monsoon intrusion period, respectively. Our results demonstrated that precipitation and atmospheric vapour isotopic compositions exhibited consistency under the influence of diverse moisture sources, while more complex relationships were found between δ18Op/δ18Ov and meteorological factors. This research provided evidence for using the isotopic compositions of atmospheric vapour to indicate moisture sources, and can improve understanding of the water cycle and eco-hydrological process from the perspective of the interaction between water and gas phases of the inland river basin in northwest China.  相似文献   

7.
Despite the widely held assumption that trees negatively affect the local water budget in densely planted tree plantations, we still lack a clear understanding of the underlying processes by which canopy cover influences local soil water dynamics in more open, humid tropical ecosystems. In this study, we propose a new conceptual model that uses a combination of stable isotope and soil moisture measurements throughout the soil profile to assess potential mechanisms by which evaporation (of surface soil water and of canopy‐intercepted rainfall) affects the relationship between surface soil water isotopic enrichment (lc‐excess) and soil water content. Our conceptual model was derived from soil water data collected under deciduous and evergreen plants in a shade grown coffee agroforestry system in Costa Rica. Reduced soil moisture under shade trees during the “drier” season, coinciding when these trees were defoliated, was largely the result of increase soil water evaporation as indicated by the positive relationship between soil water content and lc‐excess of surface soil water. In contrast, the evergreen coffee shrubs had a higher leaf area index during the “drier” season, leading to enhanced rainfall interception and a negative relationship between lc‐excess and soil water content. During the wet season, there was no clear relationship between soil water content and between lc‐excess of surface soil water. Greater surface soil water under coffee during the dry season may, in part, explain greater preferential flow under coffee compared with under trees in conditions of low rainfall intensities. However, with increasing rainfall intensities during the wet season, there was no obvious difference in preferential flow between the two canopy covers. Results from this study indicate that our new conceptual model can be used to help disentangling the relative influence of canopy cover on local soil water isotopic composition and dynamics, yet also stresses the need for additional measurements to better resolve the underlying processes by which canopy structure influences local water dynamics.  相似文献   

8.
Long-term atmospheric water vapour hydrogen (δ2H), oxygen (δ18O) and deuterium excess (d-excess) can provide unique insights into the land-atmosphere coupling processes. The in-situ measurements of atmospheric water vapour δ2H, δ18O and d-excess were conducted above a reed wetland of Liaodong Bay (2019–2020). We found significant inter-annual variations in atmospheric water vapour isotopes between the two growing (May–September) seasons. The δ2H, δ18O and d-excess of atmospheric water vapour exhibited different seasonal and diurnal cycles concerning the vertical measurement heights, especially in 2019. The isotopic differences of atmospheric water vapour among vertical measurement heights were more evident in the daytime. Rainfall events directly impacted the diurnal patterns of water vapour isotopes, and the influences depended on rainfall intensities. However, only weak correlations existed between water vapour isotopes and local meteorological factors (R2 = 0.01–0.16, p < 0.001), such as water vapour concentration (w), Relative Humidity (RH) and surface air temperature (Ta). Based on the back-air trajectory analyses, the spatial–temporal dynamics of atmospheric water vapour isotopes are highly synchronized with monsoon activities. Different water vapour sources influence the water vapour isotope in this region and the higher d-excess value is related to the intense convection brought by the monsoon. High-resolution measurements of atmospheric water vapour isotopes will improve our understanding of the hydrological cycles in coastal areas.  相似文献   

9.
Deuterium and oxygen‐18 are common environmental tracers in water used to investigate hydrological processes such as evaporation and groundwater recharge, and to trace moisture source. In this study, we collected event precipitation from 01 January 2010 to 28 February 2011 at a site in Changsha, Yangtze River Basin to estimate the influence of moisture source and atmospheric conditions on stable isotope compositions. The local meteoric water line, established as δD = (8.45 ± 0.13) δ18O + (17.7 ± 0.9) (r2 = 0.97, n = 189), had a higher slope and intercept than global meteoric water line. Temperature–δ18O exhibited complex correlations, with positive correlations during Nov.–Apr. superior to during Jun.–Sep., which was attributed to distinctive moisture sources, but vague the overall period; amount effect examined throughout the year. Linear regressions between δ18O and δD value in different precipitation event size classes revealed progressively decreasing slope and intercept values with decreasing precipitation amount and increasing vapour pressure deficit, indicating that small rainfall events (0–5 mm) were subject to secondary evaporation effects during rainwater descent. In contrast, snowfall and heavy precipitation events exhibited high slope and intercepts for the regression equation between δ18O and δD. High concentrations of heavy isotopes were associated with precipitation events sourced from remote westerly air masses, degenerated tropical marine air masses from the Bay of Bengal (BoB), and inland moisture in the pre‐monsoon period, as determined from backward trajectories assessed in the HYSPLIT model. Meanwhile, low concentrations of heavy isotopes were found to correspond with remote maritime moisture from BoB, the South China Sea, and the west Pacific at three different air pressures in summer monsoon and post‐monsoon using HYSPLIT and records of typhoon paths. These findings suggest that stable isotope compositions in precipitation events are closely associated with the meteorological conditions and respond sensitively to moisture source in subtropical monsoon climates. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

10.
The water balance equation dictates that streamflow may be reduced by transpiration. Yet temporal disequilibrium weakens the relationship between transpiration and streamflow in many cases where inputs and outputs are unbalanced. We address two critical knowledge barriers in ecohydrology with respect to time, scale dependence and lags. Study objectives were to correlate components of the water balance equation at hourly to annual scales, quantify time lags, and simplify critical components of the water budget during wet and dry conditions. We tested interrelationships among precipitation, vapour pressure deficit, transpiration, soil moisture, and streamflow within the confines of a 60‐hectare forested watershed in the western Cascades of Oregon. The Pacific Northwest is an ideal location to compare wet and dry seasons because of its Mediterranean climate. Soil moisture explained more than 80% of the variation in streamflow at all temporal scales investigated. Streamflow was most strongly coupled to soil moisture in the wet season because of gravitational drainage patterns; strong coupling of transpiration to vapour pressure deficit was dominant in the dry season and driven by low humidity. We observed progressively longer hourly time lags between soil moisture and streamflow in the dry season, which relates to an increasing soil moisture deficit that took an average of 48 days to refill after the onset of winter rains. We propose that transpiration drives seasonal patterns in soil moisture that relate to patterns in streamflow only after long time lags. In other words, soil moisture mediates the influence of transpiration on streamflow. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km2 San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.  相似文献   

12.
This work provides a comprehensive physically based framework for the interpretation of the north Australian rainfall stable isotope record (δ18O and δ2H). Until now, interpretations mainly relied on statistical relationships between rainfall amount and isotopic values on monthly timescales. Here, we use multiseason daily rainfall stable isotope and high resolution (10 min) ground‐based C‐band polarimetric radar data and show that the five weather types (monsoon regimes) that constitute the Australian wet season each have a characteristic isotope ratio. The data suggest that this is not only due to changes in regional rainfall amount during these regimes but, more importantly, is due to different rain and cloud types that are associated with the large scale circulation regimes. Negative (positive) isotope anomalies occurred when stratiform rainfall fractions were large (small) and the horizontal extent of raining areas were largest (smallest). Intense, yet isolated, convective conditions were associated with enriched isotope values whereas more depleted isotope values were observed when convection was widespread but less intense. This means that isotopic proxy records may record the frequency of which these typical wet season regimes occur. Positive anomalies in paleoclimatic records are most likely associated with periods where continental convection dominates and convection is sea‐breeze forced. Negative anomalies may be interpreted as periods when the monsoon trough is active, convection is of the oceanic type, less electric, and stratiform areas are wide spread. This connection between variability of rainfall isotope anomalies and the intrinsic properties of convection and its large‐scale environment has important implications for all fields of research that use rainfall stable isotopes.  相似文献   

13.
Isotopic exchange with atmospheric vapour can strongly influence the isotopic values of evaporating surface water bodies (e.g., lakes), influencing our understanding of hydrological processes across aquatic and terrestrial environments. Rather than measure the isotopic values of the atmosphere directly, it is much more common to estimate values by assuming equilibrium with local precipitation. This assumption may introduce large errors, thereby biasing hydrological inferences and understanding. The pattern and magnitude of this error has been quantified only in a few circumstances. We compared observations of vapour and precipitation isotope values over a four-year record collected in a montane environment in the central Rocky Mountains of North America. We further investigated factors and conditions promoting disequilibrium. Scenario comparisons assessed the impact of theoretical and methodological elements on the accuracy of the equilibrium assumption. We found that the equilibrium assumption was not well supported by direct and continuous observations of vapour isotopes using tower-based laser isotope spectroscopy, particularly during the summer months. Across all scenarios, errors associated with the equilibrium assumption were high, credibly ranging from 14 to 154 ‰ for δ2H and 1.5 to 16.3 ‰ for δ18O. Environmental covariates (e.g., vapour pressure deficit, air pressure) helped explain some of the apparent disequilibrium. Although the equilibrium assumption for estimating atmospheric vapour isotope values may not be applicable in a continental montane environment, our findings highlight opportunities for using direct vapour isotope measurements to better understand vapour sources, air mass mixing, and phase changes over complex mountainous terrain, which in turn may better constrain regional- to global-scale hydrological process estimates, such as evapotranspiration rates and the water budgets of mountain lakes.  相似文献   

14.
Numerous socio-economic activities depend on the seasonal rainfall and groundwater recharge cycle across the Central American Isthmus. Population growth and unregulated land use changes resulted in extensive surface water pollution and a large dependency on groundwater resources. This work combines stable isotope variations in rainfall, surface water, and groundwater of Costa Rica, Nicaragua, El Salvador, and Honduras to develop a regionalized rainfall isoscape, isotopic lapse rates, spatial–temporal isotopic variations, and air mass back trajectories determining potential mean recharge elevations, moisture circulation patterns, and surface water–groundwater interactions. Intra-seasonal rainfall modes resulted in two isotopically depleted incursions (W-shaped isotopic pattern) during the wet season and two enriched pulses during the mid-summer drought and the months of the strongest trade winds. Notable isotopic sub-cloud fractionation and near-surface secondary evaporation were identified as common denominators within the Central American Dry Corridor. Groundwater and surface water isotope ratios depicted the strong orographic separation into the Caribbean and Pacific domains, mainly induced by the governing moisture transport from the Caribbean Sea, complex rainfall producing systems across the N-S mountain range, and the subsequent mixing with local evapotranspiration, and, to a lesser degree, the eastern Pacific Ocean fluxes. Groundwater recharge was characterized by (a) depleted recharge in highland areas (72.3%), (b) rapid recharge via preferential flow paths (13.1%), and enriched recharge due to near-surface secondary fractionation (14.6%). Median recharge elevation ranged from 1,104 to 1,979 m a.s.l. These results are intended to enhance forest conservation practices, inform water protection regulations, and facilitate water security and sustainability planning in the Central American Isthmus.  相似文献   

15.
Stable water isotopes (δ18O and δ2H) are an important source signature for understanding the hydrological cycle and altered climate regimes. However, the mechanisms underlying atmospheric water vapour isotopes in the northeast Qinghai‐Tibetan Plateau of central Asia remain poorly understood. This study initially investigated water vapour isotopic composition and its controls during the premonsoon and monsoon seasons. Isotopic compositions of water vapour and precipitation exhibited high variability across seasons, with the most negative average δ18O values of precipitation and the most positive δ18O values of water vapour found during the premonsoon periods. Temperature effect was significant during the premonsoon period but not the monsoon period. Both a higher slope and intercept of the local meteoric water line were found during the monsoon period as compared with in the premonsoon period, suggesting that raindrops have been experienced a greater kinetic fractionation process such as reevaporation below the cloud during the premonsoon periods. The δ2H and δ18O signatures in atmospheric water vapour tended to be depleted with the occurrence of precipitation events especially during the monsoon period and probably as a result of rainout processes. The monthly average contribution of evaporation from the lake to local precipitation was 35.2%. High d‐excess values of water vapour were influenced by the high proportion of local moisture mixing, as indicated by the gradually increasing relative humidity along westerly and Asian monsoon trajectories. The daily observation (observed ε) showed deviations from the equilibrium fractionation factors (calculated ε), implying that raindrops experienced substantial evaporative enrichment during their descent. The average fraction of raindrops reevaporation was estimated to be 16.4± 12.9%. These findings provide useful insights for understanding the interaction between water vapour and precipitation, moisture sources, and help in reconstructing the paleoclimate in the alpine regions.  相似文献   

16.
Deciduous forest covers vast areas of permafrost under severe dry climate in eastern Siberia. Understanding the water cycle in this forest ecosystem is quite important for climate projection. In this study, diurnal variations in isotopic compositions of atmospheric water vapour were observed in eastern Siberia with isotope analyses of precipitation, sap water of larch trees, soil water, and water in surface organic layer during the late summer periods of 2006, 2007, and 2008. In these years, the soil moisture content was considerably high due to unusually large amounts of summer rainfall and winter snowfall. The observed sap water δ18O ranged from ?17.9‰ to ?13.3‰, which was close to that of summer precipitation and soil water in the shallow layer, and represents that of transpired water vapour. On sunny days, as the air temperature and mixing ratio rose from predawn to morning, the atmospheric water vapour δ18O increased by 1‰ to 5‰ and then decreased by about 2‰ from morning to afternoon with the mixing ratio. On cloudy days, by contrast, the afternoon decrease in δ18O and the mixing ratio was not observed. These results show that water vapour that transpired from plants, with higher δ18O than the atmospheric water vapour, contributes to the increase in δ18O in the morning, whereas water vapour in the free atmosphere, with lower δ18O, contributes to the decrease in the afternoon on sunny days. The observed results reveal the significance of transpired water vapour, with relatively high δ18O, in the water cycle on a short diurnal time scale and confirm the importance of the recycling of precipitation through transpiration in continental forest environments such as the eastern Siberian taiga. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

17.
Intercomparison of soil pore water extraction methods for stable isotope analysis has been a focus of recent studies in relation to plant source waters, which found a wide isotopic variance depending on the extraction method. Few studies have yet explored extraction effects for mobile pore waters that relate to hillslope runoff. This is because it is extremely difficult in natural systems to control the boundary conditions in order to assess and compare impacts of pore water extraction on resulting hillslope flow. With our new semicontrolled experiments on outdoor mini‐hillslopes, we studied mixing and runoff processes by means of stable isotopes of water and quantified relations between pore water extraction methods. We tested the null hypothesis that nondestructive and destructive pore water sampling methods sample the same soil water pool. Three hillslopes were mounted on load cells, filled with loamy sand textured soils from the Landscape Evolution Observatoryat Biosphere 2, equipped with soil moisture and temperature sensors, a bottom outflow, and a surface runoff gauge for isotope sampling. We followed the precipitation isotopic composition over and through the soil profile. One hillslope was instrumented with suction cups, on the second we installed sampling ports for in‐situ soil water vapour measurements, and the third hillslope was sampled destructively for applying the centrifugation and vapour equilibrium methods. All hillslopes were sampled at four depths (0–10, 10–20, 20–30, and 30–40 cm) at three different downslope positions. 2H and 18O analyses were performed via laser spectroscopy. We found no isotopic differences between rainfall, surface runoff, and bottom outflow. The in situ vapour ports' soil isotope data showed the widest spread over all hillslope positions and depths. Centrifugation's and suction cups' isotope results plotted closest to the local meteoric water line and within the range of hillslope runoff and bottom outflow data. Hillslope position did not influence the soil isotope results. These results suggest caution be used in the field when selecting an extraction technique for matching soil waters to runoff waters. Soil suction lysimeters and centrifugation appeared to be the most appropriate tools in this regard.  相似文献   

18.
Hydrological processes of lakes in the Tibetan Plateau are an important indicator of climate change. Due to the high elevation, inaccessibility and limited availability of historical observations, water budget evaluation of typical lake basins has been inadequate. In this study, stable isotopes are used to trace the multiple water sources contributing to two adjacent lakes on the north slope of the Himalayas, Gongmo‐tso and Drem‐tso. The two lakes have nearly the same elevation, lake area and climatic condition. However, the isotopic composition of the two lakes presents significant differences. Qualitative observations attribute the differences to hydrological discrepancies: Gongmo‐tso is a through‐flow lake, whereas Drem‐tso is a terminal lake. Quantitative analyses, including water and isotope mass balance modelling, clarify the fluxes and isotopic compositions among the various hydrological elements. The isotopic composition of input water, calculated as the summation of rainfall and upstream runoff, is estimated using the local meteoric water line (LMWL) combined with the time series of lake water isotope values. The isotopic composition of evaporation is calculated with a linear resistance model using local meteorological data. The results show that Drem‐tso is a closed lake in a hydrological steady state with relatively more enriched lake water isotope values resulting mainly from evaporation. In contrast, through‐flow accounts for more than 88% of the water input into Gongmo‐tso. The large amount of upstream runoff with lower isotopic composition and enrichment due to evaporation are the major contributions to the observed lake water isotope values. Isotopic modelling of the two neighbouring lakes is effective for isotopic and hydrological research in this region with limited in situ observations. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

19.
While the hydrological balance of forest ecosystems has often been studied at the annual level, quantitative studies on the factors determining rainfall partitioning of individual rain events are less frequently reported. Therefore, the effect of the seasonal variation in canopy cover on rainfall partitioning was studied for a mature deciduous beech (Fagus sylvatica L.) tree over a 2‐year period. At the annual level, throughfall amounted to 71% of precipitation, stemflow 8%, and interception 21%. Rainfall partitioning at the event level depended strongly on the amount of rainfall and differed significantly (p < 0·001) between the leafed and the leafless period of the year. Therefore, water fluxes of individual events were described using a multiple regression analysis (ra2 > 0·85, n = 205) with foliation, rainfall characteristics and meteorological variables as predictor variables. For a given amount of rainfall, foliation significantly increased interception and decreased throughfall and stemflow amounts. In addition, rainfall duration, maximum rainfall rate, vapour pressure deficit, and wind speed significantly affected rainfall partitioning at the event level. Increasing maximum hourly rainfall rate increased throughfall and decreased stemflow generation, while higher hourly vapour pressure deficit decreased event throughfall and stemflow amounts. Wind speed decreased throughfall in the growing period only. Since foliation and the event rainfall amount largely determined interception loss, the observed net water input under the deciduous canopy was sensitive to the temporal distribution of rainfall. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

20.
We examined rainfall anomalies associated with the El Niño–Southern Oscillation (ENSO) in northern Sarawak, Malaysia, using the oxygen isotopic composition of rainfall. Two precipitation‐sampling campaigns were conducted for isotope analysis: (a) at the Lambir Hill National Park (4.2° N, 114.0° E) from July 2004 to October 2006 and (b) at the Gunung Mulu National Park (3.9° N, 114.8° E) from January 2006 to July 2008. The records from these campaigns were merged with a previously published rainfall isotope dataset from Gunung Mulu site to create a 7‐year‐long record of the oxygen isotopic composition of Sarawak rainfall. The record exhibits clear intraseasonal variations (ISVs) with periods ranging from 10 to 70 days. The ISVs of 10‐ to 90‐day band‐pass filtered oxygen isotopic composition are linked to the synoptic‐scale precipitation anomalies over the southern South China Sea (SCS). The lead–lag correlation map of precipitation with the filtered oxygen isotope anomalies shows that an anomalous wet condition responsible for the decrease in oxygen isotopic composition appears over the SCS in association with the passage of north‐eastward propagation of the boreal summer intraseasonal oscillation (BSISO) in the summer monsoon season. The anomalous wet condition in spring is connected with eastward‐propagating Madden–Julian oscillation (MJO), whereas the sustained wet condition in winter is responsible for the occurrence of the Borneo vortex (BV) over the SCS. ENSO modulates the frequency of these synoptic conditions on a seasonal and longer time scale, showing a strong correlation between the seasonal isotopic anomalies and the Southern Oscillation index. We therefore discern, from the significant correlation between the isotope anomalies and area‐averaged Sarawak rainfall anomalies (R = ?0.65, p < 0.01), that ENSO‐related precipitation anomalies are linked to the seasonal modulation of the BSISO and MJO activity and BV genesis.  相似文献   

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