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新疆昆仑山布喀达坂峰-依吞布拉克一带岩石地球化学特征及元素分布规律 总被引：1，自引：1，他引：1
新疆昆仑山东段布喀达坂峰-依吞布拉克一带区域岩石地球化学特征表明：长城系富集W、Pb；奥陶系富集Au；二叠系富集Cu、Zn、Hg、Sb；三叠系富集Zn、Pb、Ag；三叠纪石英斑岩富集Cu、Zn、Hg、Sb．元素区域分布规律表明：与全国高寒山区平均水平相比，工作区相对富集Ba、Hg、Pb、Sn、Mo元素，贫化铁族元素；工作区可分为北、中、南3个地球化学带．北带形成了富集Au、Ag、Sb、Hg、Cu、Zn、Pb、Mo、Mg及铁族元素，贫化Cr、Co、Ni、Li、Be、Bi元素地球化学带；中带富集Cu、Pb、Zn、Ag、W、Sn、Mo、U、Th，贫化Hg、Li及铁族元素，形成了有色、稀有稀土、放射性元素地球化学带；南带富集Au、As、Sb、Hg、Cu、Zn，形成了贵重、有色元素地球化学带．石英斑岩富集Cu、Zn、Hg、Sb元素．祁漫塔格带元素组合与斑岩型铜钼矿、层控型Pb、Zn矿和夕卡岩型铁多金属矿床元素组合相似．第四系元素含量均一，不存在元素大面积区域性富集与贫化的物理化学条件． 相似文献
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《矿物学报》2017,(4)
西呼和楚鲁地区位于大兴安岭北段,由于森林沼泽覆盖和自然保护等原因,地质调查工作程度低,尚未取得找矿突破。近期开展的地球化学调查成果显示,与陆壳克拉克值相比,区域Ag、Pb、W、As、Sb、Bi元素富集,尤其是在石炭系莫尔根河组和早石炭世闪长岩、晚泥盆世石英闪长岩中含量很高,Cu、Au、Sn相对贫化;大多数成矿元素在区域内分布不均匀,尤其是Au、Ag、Mo、Bi在侏罗系满克头鄂博组、石炭世二长花岗岩和闪长岩体出露区分异极强,Cu在泥盆系大民山组、早白垩世花岗岩中,Au在石炭系莫尔根河组、晚泥盆世石英闪长岩中呈强分异型分布,在局部区域存在富集甚至强烈富集,较为利于成矿。区域主要成矿元素为Au、Pb、Ag、Mo、Cu,伴生成矿元素为W、As、Sb、Sn、Mn、Bi、Zn,主要成矿类型为热液型、火山岩型。根据区域地球化学特征,预测区域成矿潜力较大的地区为锡尼河-那日斯毛德、大架子山、一支沟-小孤山等地。 相似文献
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云南澜沧老厂是三江成矿带南段最重要的铅锌铜钼多金属矿床之一.根据不同的赋矿特征、含矿岩性、矿石构造及成矿元素将澜沧老厂多金属矿床矿石类型系统地划分为铅锌硫化矿石、铅锌氧化矿石、颗粒状含铜黄铁矿石、块状含铜黄铁矿石、夕卡岩型矿石及斑岩型钼矿石6种类型.矿体产状、微量元素地球化学、年代学证据均表明铅锌硫化矿石、颗粒状含铜黄铁矿石及块状含铜黄铁矿石为火山喷流沉积型成因（VMS型）,而铅锌氧化矿石、夕卡岩型矿石及斑岩型钼矿石为斑岩热液型成因.其中,铅锌硫化矿石、颗粒状含铜黄铁矿石及块状含铜黄铁矿石的主控矿因素为地层;铅锌氧化矿石为构造;夕卡岩型矿石为岩性;斑岩型钼矿石为岩体. 相似文献
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云南澜沧老厂是三江成矿带南段最重要的铅锌铜钼多金属矿床之一.根据不同的赋矿特征、含矿岩性、矿石构造及成矿元素将澜沧老厂多金属矿床矿石类型系统地划分为铅锌硫化矿石、铅锌氧化矿石、颗粒状含铜黄铁矿石、块状含铜黄铁矿石、夕卡岩型矿石及斑岩型钼矿石6种类型.矿体产状、微量元素地球化学、年代学证据均表明铅锌硫化矿石、颗粒状含铜黄铁矿石及块状含铜黄铁矿石为火山喷流沉积型成因（VMS型），而铅锌氧化矿石、夕卡岩型矿石及斑岩型钼矿石为斑岩热液型成因.其中，铅锌硫化矿石、颗粒状含铜黄铁矿石及块状含铜黄铁矿石的主控矿因素为地层；铅锌氧化矿石为构造；夕卡岩型矿石为岩性；斑岩型钼矿石为岩体. 相似文献
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冈底斯明则-程巴斑岩-夕卡岩型Mo-Cu矿床成矿时代与含矿岩石成因 总被引：2，自引：1，他引：1
冈底斯东南缘克鲁-冲木达矿带以发育渐新世斑岩-夕卡岩型Mo-W-Cu成矿作用而有别于冈底斯中新世斑岩-夕卡岩型Cu-Mo-Au矿带,但是对渐新世成矿岩石类型及成因以及渐新世与中新世斑岩成矿作用存在差异的原因尚不清楚,严重制约了该带矿产资源潜力评价.为此,本文选择矿带内程巴斑岩型Mo矿床及明则夕卡岩型Cu矿床开展了成岩与成矿年代学及含矿岩石成因研究.明则矿区与夕卡岩矿化有关的二长岩的结晶年龄为30.4±0.6Ma,表明夕卡岩矿化时代约30Ma,这与程巴斑岩型Mo矿床矿石中辉钼矿Re-Os同位素分析所揭示的约30Ma矿化时代一致.明则二长岩的SiO2含量为55％ ～57％,K2O含量为2.7％ ～5.0％,属于钾玄岩,具有较高的MgO含量(3.5％～6.9％)、Mg#值(57.6～67.2)以及相容元素含量(Cr =34×10-6 ～379×10-6;Ni为48×10-6～116×10-6).而程巴花岗闪长岩的SiO2含量为65％ ～ 67％,K2O含量为3.2％～4.1％,属于高钾钙碱性岩,具有较低的MgO含量(1.7％～2.1％)、Mg#值(49.5～51.1)以及相容元素含量(Cr =20×10-6～39×10-6;Ni为16×10-6 ～25×10-6).二长岩和花岗闪长岩均显示富集轻稀土元素与大离子亲石元素,亏损高场强元素,具有弱的Eu负异常,但二长岩的REE含量明显高于花岗闪长岩,且具有较低的Sr/Y比值(24 ～49),后者Sr/Y比值为54～68.两种岩石均具有类似的Hf同位素组成,二长岩的εHf(t)值为+2.8～+6.8,花岗闪长岩εHf(t)值为+4.2～ +6.1.综合分析表明,二长岩是受大洋板片流体交代的富集岩石圈地幔部分熔融的产物,而花岗闪长岩是增厚的新生下地壳部分熔融的产物,二者在形成过程中可能发生了幔源镁铁质岩浆与壳源长英质岩浆的混合作用,这种壳幔相互作用导致区域斑岩-夕卡岩型Cu-Mo矿化,但由于该区隆升剥蚀强烈,上部的斑岩型Cu矿体基本被剥蚀而没有保存下来,因此现今表现为斑岩型Mo矿床. 相似文献
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西藏革吉县尕尔穷铜金矿矽卡岩特征及成因意义 总被引：1，自引：0，他引：1
通过对矽卡岩岩石学特征、矿物学特征研究,发现矽卡岩主要产于大理岩和石英闪长岩、花岗斑岩接触带上,垂向上多有大理岩-硅化角岩-矽卡岩化大理岩-硅灰石矽卡岩-透辉石矽卡岩-石榴子石矽卡岩-石英闪长岩的分带特征。矽卡岩岩石地球化学特征、稀土元素和微量元素特征显示矽卡岩主要为钙矽卡岩,具有弱Eu负异常和轻稀土富集等特征;同时具有富集Rb、Th、Cs、U等大离子亲石元素和亏损Hf、Ti、Y等高场强元素特征。矽卡岩地球化学特征受大理岩和石英闪长岩、花岗斑岩的控制和影响,显示其与大理岩、石英闪长岩和花岗斑岩成因上有密切关系。通过对班公湖-怒江成矿带成矿背景和时空关系的讨论,指示了尕尔穷矿床成因是与岩浆热液有关的接触交代型矿床。 相似文献
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小赛什腾铜矿赋存于华里西期闪长岩、闪长斑岩中,全岩矿化,岩体普遍含铜,岩体中w(Cu)平均值＞500×10-6;铜矿体主要由含铜闪长斑岩、闪长岩等组成,矿石呈中细粒状、斑状结构,细脉浸染状、块状构造;矿体、矿化体与围岩逐渐过渡,界线不清,整个岩体中普遍可见弱孔雀石化.化探异常在平面上由岩体中心到围岩存在明显的元素分带现象,即,W,Mo,(Bi)→Cu,Au→As,(Hg),表现出与典型斑岩型铜矿相似的地球化学特征.岩体蚀变有硅化、碳酸盐化、绿帘石化、绿泥石化、绢云母化、黄铁矿化,少量钾化,在与大理岩的接触带附近发育夕卡岩化. 相似文献
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通过对辽宁西部肖家营子钼矿地质矿产特征及所处区域、矿区的地球化学特征分析及总结,初步建成了肖家营子斑岩—矽卡岩型钼矿的地质—地球化学找矿模型:地质条件以出露地层为雾迷山组含燧石条白云岩和含燧石结核白云岩,岩浆活动十分强烈且成矿前断裂构造发育为特征;区域地球化学异常表现为出现Mo、W、Au、Cu、Pb等异常,且各单元素高值区内的浓集中心显著;成矿局部表现为岩体、接触带及地层分布的元素组分分带性显著,且以Mo、W、Cu、Au为近矿指示元素组合。矿床地质—地球化学找矿模型的建立,可以为寻找同类型矿床开展的预测远景区圈定、找矿靶区挑选、资源量估算等工作提供重要依据。 相似文献
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The Geza Andean-type arc is located in the southwestern Sanjiang tectonic belt (i.e. Jinsha, Lancang, and Nujiang River) of SW China, which is a product of the subduction of the Garzê–Litang oceanic crust beneath Zhongdian landmasses in the Late Triassic (235–204 Ma). The Geza Andean-type arc is an important belt of Cu-rich polymetallic mineralization that was recently discovered in China. Prolonged regional tectono-magmatic activity and several episodes of rich mineralization throughout the tectonic evolution of the Andean-type arc produced the super-large Pulang porphyry Cu deposits, the large Xuejiping porphyry Cu deposits, and the large Hongshan skarn-porphyry Cu polymetallic deposits. Here we report new LA-ICP-MS zircon U–Pb age of Songnuo and Qiansui intrusive rocks, and whole-rock major and trace element compositions of the Late Triassic mineralized porphyries from Geza in this region. Zircon U–Pb dating of the Qiansui quartz diorite porphyrite revealed a crystallization age of 220.3 ± 0.66 Ma, for the Songnuo quartz monzonite porphyry, a crystallization age of 204.7 ± 0.72 Ma. The Geza Andean-type arc granitic belt can be divided into three porphyry subzones based on the stage of Andean-type arc orogenic development and the distribution, composition, and geochemical characteristics of the intrusive rocks. Lithogeochemical characteristics show that the porphyry and Andean-type arc granite are of the same rock series (high-K calc-alkaline) and genetic type (I-type granite). The trace element geochemistry of these rocks is similar to that of Andean-type arc granite, which is enriched in Ba, Rb, La, Hf, chalcophile elements (Cu, Pb), and siderophile elements (Mo, Ni), and depleted in Nb, Ta, P, and Ti. In the Geza Andean-type arc, similarities in the major element, REE, and trace element compositions between porphyry and local acidic volcanic rocks suggest that they have the same or similar magmatic source rocks. The petrological characteristics of granite in the Geza Andean-type arc are similar to those of adakitic rocks, and the formation of porphyry and porphyry-related deposits resulted from magmatic hydrothermal fluids that originated in the upper mantle and lower crust. The porphyry Cu mineralization was probably produced from the accumulation and migration of ore-forming hydrothermal fluids and the resultant alteration of host rocks. 相似文献
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斑岩型钼矿床的形成机制与地球化学过程 总被引：1，自引：1，他引：0
斑岩型钼矿床是世界钼矿床中最重要的种类,其中90%以上的钼矿床都和斑岩有关。斑岩型钼矿床主要分布于环太平洋成矿带和特提斯成矿带上,主要与板块俯冲过程有关,可以分为斑岩铜钼矿床、高氟型斑岩钼矿床和低氟型斑岩钼矿床。我们通过对全球斑岩型钼矿床的时空分布与钼元素地球化学性质分析,认为斑岩型钼矿床的物质来源是钼元素通过表生地球化学作用进行初始富集后形成的富钼沉积物。新元古代晚期(750～542Ma)大气氧再次升高之后,富钼的黑色页岩等才大量出现,因此斑岩型钼矿床主要形成于500Ma之后。富钼黑色页岩等沉积物在板块俯冲过程中脱水,形成富含Mo和Re的变质流体,同时两者发生分异。这种变质流体交代上覆地幔楔使Mo和Re留存在其中。随着俯冲洋壳的部分熔融,形成富Cu(Au)的岩浆,穿过富含Re(Mo)的上覆地幔楔,形成斑岩型铜钼矿床,因此这类矿床的辉钼矿Re含量更高。而随后出现的板块后撤,使软流圈上涌,板片上大量多硅白云母分解,形成了富含F的岩浆,穿过富含Mo的上覆地幔楔,进而形成高氟型斑岩矿床。低氟型钼矿床很可能与俯冲关系较小,富钼沉积物通过造山过程被深埋,在适当的条件下形成低氟型斑岩钼矿床。 相似文献
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罗卜地斑岩体属钙碱性岩系、中酸性岩类,共岩浆属混源型,同位素地质年龄为５２．７６Ｍａ。罗卜地斑岩体属同期多次序贯入侵位的复式岩体;成矿微量元素及矿化剂微量元素均具有显著异常;爆破角砾冉及其相应的垂直裂隙发育。通过对罗卜地斑岩石地球化学及其地质特征的综合分析研究,一致地表明罗卜地斑岩体为铜（铜）矿化类型斑岩体,具良好的成矿远景 。 相似文献
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冷水坑斑岩型银铅锌矿床成矿流体特征研究 总被引：7，自引：0，他引：7
斑岩型银铅锌矿床世界上并不多见, 目前我国典型斑岩型银铅锌矿床仅冷水坑一处。笔者通过对冷水坑斑岩型银铅锌矿床的流体包裹体地球化学、稳定同位素地球化学研究, 结合岩相学研究、激光拉曼探针(LRM)和扫描电镜/能谱(SEM/EDS)测试, 揭示了冷水坑斑岩型银铅锌矿床成矿流体特征及演化过程, 并进一步探讨了成矿物质来源和矿床成矿机制。研究表明, 冷水坑矿床成矿流体及主要成矿元素(硫)来自于斑岩系统, 大气水在整个成矿过程中均有不同程度的参与。 相似文献
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Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China 总被引：6，自引：0，他引：6
Jun-Ting Qiu Xin-Qi Yu M. Santosh De-Hui Zhang Shuai-Qi Chen Peng-Ju Li 《Mineralium Deposita》2013,48(5):545-556
The Tongcun Mo porphyry deposit in northwest Zhejiang is hosted in three porphyry units: Huangbaikeng, Songjiazhuang, and Tongcun, from southwest to northeast. U–Pb zircon ages of 162?±?3.0 Ma for the Huangbaikeng porphyry, 159.9?±?3.0 Ma for the Songjiazhuang porphyry, and 167.6–155.6 Ma for the Tongcun porphyry indicate that these intrusions formed during the Jurassic and are most likely associated with the northwestward subduction of the Izanagi Plate. Trace element compositions of zircons from the Tongcun deposit constrain the oxygen fugacity (fO2) of the magma using zircon Ce anomalies and Ti-in-zircon temperatures. The average magmatic fO2 for the porphyries in the Tongcun deposit is fayalite–magnetite–quartz (FMQ)?+?2.7, which is similar to the Shapinggou (FMQ?+?3.2) and Dabaoshan (FMQ?+?3.5) Mo porphyry deposits, but much higher than that of the reduced Cretaceous ore-barren Shangjieshou porphyry (FMQ-1.1) around 8 km away from the Tongcun deposit. The distinct difference in magmatic oxygen fugacity between the Jurassic and Cretaceous porphyries may help to explain the absence of Mo porphyry mineralization in northwest Zhejiang during the Cretaceous. 相似文献
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Delineation and explanation of geochemical anomalies using fractal models in the Heqing area,Yunnan Province,China 总被引：8，自引：0，他引：8
Jun Deng Qingfei WangLiqiang Yang Yanru WangQingjie Gong Huan Liu 《Journal of Geochemical Exploration》2010
The Heqing area, located in the Sanjiang ore belt, China, consists of the Beiya gold orefield related to the alkaline porphyry, the Emeishan volcanic mafic rocks and a series of sedimentary rocks. Thirty-nine elements of stream sediment samples taken in the 1:200,000 geochemical survey in the Heqing area can be classified into four groups using principal component analysis. Two fractal models, i.e., the concentration–area model and the number–size model, are applied in determination of the thresholds for the representative elements in the four groups. The thresholds obtained from the two models are similar. According to the thresholds, the element concentration distribution can be divided into 3 segments, each of them is mainly correlated to one type of rocks, including the alkaline porphyry related to gold-mineralized rocks, mafic rocks and sedimentary rocks. This paper reveals that the various geological events can be characterized by the different fractal models of element distribution. 相似文献
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The Naruo porphyry Cu deposit is the third largest deposit discovered in the Duolong metallogenic district. Previous research has focused mainly on the geochemistry of the ore-bearing granodiorite porphyry; the metallogenesis remains poorly understood. In the present work, on the basis of outcrops and drilling core geological mapping, phases of early mineralization diorite, two inter-mineralization granodiorite porphyries, and late-mineralization granodiorite porphyry have been distinguished. Furthermore, the alteration zones were outlined, and the vein sequence was identified. The diorite and three porphyry phases were subjected to Laser Ablation Inductively Coupled Plasma Mass Spectrometry (La–ICP–MS) zircon U–Pb dating and in situ Hf isotope analyses as well as bulk major element, trace element, and Sr–Nd isotopic analyses. Molybdenite Re–Os dating was also conducted.The zircon U–Pb dating results show that the diorite and porphyry intrusions were emplaced at about 120 Ma, and the molybdenite Re–Os isochron age is 118.8 ± 1.9 Ma; this indicates that the Naruo porphyry Cu deposit was formed during a continuous magmatic–hydrothermal process. All of the diorite and granodiorite porphyry samples showed arc magmatic characteristics. Moreover, the moderate (87Sr/86Sr)i ratios and low εNd(t) and εHf(t) values of the diorite and porphyry intrusions suggest the source region of the juvenile lower crust. The lower (87Sr/86Sr)i and (143Nd/144Nd)i ratios and higher εNd(t) values and incompatible element concentrations than those in the granodiorite porphyry samples indicate a two-stage magmatic generation process for the intrusions. The early mineralization diorite has a high Cu concentration, implying that the source is enriched in Cu. However, the slightly lower Cu content of the late-mineralization granodiorite porphyry samples might imply Cu release from magmas and deposition within the metallogenic stage. The multiple stages of intrusions and subsequent volcanism within the Duolong metallogenic district, together with high Sr/Y features, indicate persistent magmatism during the metallogenic epoch, which is necessary for maintaining the activity of magmatic–hydrothermal and mineralization processes. Thus, the high Cu content in the source region, mantle-derived melt upwelling, and multiple stages of persistent magmatism were favorable for the formation of the Naruo porphyry Cu deposit.The high Fe2O3/FeO ratios of the diorite and granodiorite porphyry intrusions show very high oxidation features, which is coincident with estimated magmatic oxidation state calculated by the zircon trace element compositions. The high oxidation facilitates sulfur and chalcophile metals to be scavenged into the magmatic–hydrothermal systems, which is crucial for the metallogenesis of the Naruo porphyry Cu deposit. 相似文献
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中亚巴尔喀什成矿带晚古生代岩浆活动与斑岩铜矿成矿时代 总被引：3，自引：0，他引：3
巴尔喀什成矿带是中亚成矿域重要的晚古生代斑岩铜钼成矿带。通过该成矿带科翁腊德、博尔雷和阿克斗卡地区与斑岩铜成矿作用密切相关的花岗斑岩类岩体锆石SHRIMP U-Pb定年,主量、稀土和微量元素地球化学,Sr、Nd同位素示踪分析,进一步厘定了斑岩铜成矿作用的时代,并推测了板块构造环境。斑岩铜成矿时代分为两期：早期约为327 Ma,形成科翁腊德和阿克斗卡超大型斑岩铜矿床;晚期约为316 Ma,形成博尔雷大型斑岩铜矿床。与成矿有关的斑岩类主要为高钾钙碱性系列花岗岩,可能为火山岛弧环境,部分具有埃达克岩特征和经典岛弧花岗岩类特征。斑岩类εSr(t)和εNd(t)的变化范围分别为-6.35~34.03和-0.46~5.53。其中,科翁腊德-博尔雷地区斑岩类来源于亏损地幔与大陆地壳表层物质（老地壳物质）的显著混染作用,而阿克斗卡地区斑岩类直接来自于亏损地幔。将巴尔喀什成矿带与我国西准噶尔成矿带进行了对比,认为可能属于同一个晚古生代斑岩铜钼成矿带。 相似文献
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斑岩矿床的成矿机制是一种典型的力-热-流多物理场耦合的岩浆-热液过程,因而从成矿动力学数值计算模拟的角度研究斑岩矿床成矿作用过程,对揭示斑岩岩浆-热液系统动力学演化机制及其成矿响应情况具有十分重要的意义。德兴铜矿(包括朱砂红、铜厂和富家坞)作为目前中国华南已发现的最大斑岩型铜矿床,是研究(大型/超大型)斑岩矿床成矿作用过程的一个典型的重要窗口。前人已在矿床地质、地球化学、年代学、同位素以及成矿流体等诸多方面开展了大量的研究工作,但从成矿动力学数值模拟的角度对德兴铜矿成矿作用过程进行的研究目前相对较少。为此,本文以德兴斑岩铜矿床为主要研究对象,首先通过总结分析其成矿过程的地质概念模型,进而将侵入体形态(包括长轴及短轴长度)和倾伏角、控矿断裂倾角与宽度作为几何模型中的变量,构建由这些变量组合控制的几何实体模型。在此基础上,进一步分析斑岩矿床成矿过程数值模拟中应力场、流体场以及热力场三者的耦合关系及其数学-物理方程,构建德兴斑岩铜矿床的成矿动力学模型,建立相应的有限元数值模拟模型。最终,设置不同的岩石物理参数、边界条件与初始条件,进行力-热-流三场耦合的数值模拟实验,并根据不同侵入体产状及断裂构造条件下的模拟结果探究德兴铜矿床断裂和侵入体产状对成矿的控制作用。主要结论如下:(1)较小的断裂构造宽度更易造成岩矿石局部破裂,便于流体弥散而形成浸染状或微-细脉状的斑岩矿化;(2)较大体积的岩体以及较小的岩体倾伏角度对斑岩铜矿床的形成相对有利;(3)朱砂红矿床较铜厂和富家坞矿床岩体体积小,而倾伏角相对较大,导致岩体冷却速度快,表面及附近扩容空间小,因而成矿深度大,而金属储量小。揭示了德兴铜矿床斑岩侵入体与断裂构造产状的控矿机制,增进了对德兴铜矿矿床成因和控矿要素的认识。 相似文献