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通过控矿地层和矿床中岩石赋存的有机质研究和对比后指出,粤东北下侏罗统嵩灵组黑色岩系建造是一套富含生物及有机质的含矿建造。沥青、干酪根和焦沥青是构成围岩与矿化岩石中主要的有机质显微组分。有机质热演化处于高成熟一过成熟阶段。这套黑色岩系控矿围岩中有机碳与银、锑等成矿元素具有较好的正相关关系。黑色岩系含矿建造中的有机碳对形成银、锑矿化起了一定的控制作用。有机质的镜质体反射率测定表明,嵩溪银锑矿属低温(150～170 ℃)浅层热液改造型矿床。有机质热成熟异常区是一种特殊的指示矿化作用的找矿勘查标志。 相似文献
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通过1∶5万区域地质调查及典型剖面研究,在滇中禄劝地区二叠系峨眉山组顶部识别出一套厚约20～50 m不等的Nb、Co、Ga、Zr及REE超常富集层。富集层主要岩性为灰紫色泥岩、凝灰质泥岩、凝灰岩,局部夹杏仁状玄武岩。通过对禄劝万鲁布、撒角海一带的富集层刻槽分析显示,Nb2O5含量在82.4×10-6～120.1×10-6,平均值为100.3×10-6,大于风化壳型矿床一般工业指标80×10-6;Ga含量28.8×10-6～35.6×10-6,平均值为32.1×10-6,高于现行的Ga矿资源工业指标要求30×10-6;REE含量在360×10-6～510×10-6,平均值为440.6×10-6,接近风化壳型矿床一般工业指标500×10-6;并呈现出泥岩→凝灰质泥岩→凝灰岩关键金属含量依... 相似文献
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粤东北嵩溪黑色页岩型银锑矿床成矿机制探讨 总被引：2，自引：0，他引：2
粤东北嵩溪银锑矿床位于华南加里东造山带南缘永(定)-梅(县)古生代拗陷带内,寨岗上中生代断陷火山盆地北缘,是我国近年来发现的产于下侏罗统黑色岩系含矿建造的一个大型矿床,其独特的成矿元素Ag-Sb组合已引起人们的极大关注。矿区出露地层仅有侏罗系下统嵩灵组和中统漳平群。该地层为一套变质程度低和含有丰富的生物有机质黑色页岩建造。 相似文献
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贵州务川-沿河地区分布大量萤石矿床(点),这些矿床(点)多与重晶石矿共生,萤石矿赋存在奥陶系桐梓组和红花园组碳酸盐岩内,矿体分布严格受地层与北西向张性断裂控制。本文选择务川涪洋地区双河、鹿坪、一碗水和通木水等萤石矿床开展稀土元素地球化学研究,结果显示,各矿床萤石稀土元素配分模式均为右倾的轻稀土富集型,且具有一定的相似性。∑REE含量分别为28.96×10-6～115.12×10-6、123.10×10-6～124.11×10-6、14.77×10-6～22.35×10-6和20.73×10-6～123.69×10-6,总体具有较强的Eu正异常、Ce负异常,表明这类萤石矿形成于较为氧化环境中。区内萤石属于北西向张性断裂和下奥陶统地层碳酸盐岩控制的中-低温热液充填交代型矿床。结合La/Ho-Y/Ho图解及矿床地质特征,本研究认为区内萤石为同一来源的成矿流体在同一成矿期次不同阶段成矿,其中双河矿床经历了多个阶段成矿叠加... 相似文献
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许多研究者认为,金丰度高的花岗岩和地层就是金矿床的矿源岩和矿源层.随着中子活化法和化学-光谱法的广泛应用,分析精度有了大幅度提高(可达0.01×10-9).大量的国内外资料表明:绿岩地体中变质岩的金丰度较低,平均为0.71×10-9~2.40×10-9,与金矿有关的花岗岩金丰度更低,平均只有0.62×10-9~1.20×10-9.因此,矿源岩和矿源层并不是人们所想像的那些特定的岩石或地层.所有岩石都可能成为矿源岩或矿源层.花岗岩和地层中金的丰度与金矿床之间不存在必然的联系,金成矿与使金活化、迁移和富集的各种成矿机理有关. 相似文献
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湘西北下寒武统铀多金属磷块岩由于富含多种矿产元素,受到国内外地质学者的越来越多的关注,但成因认识仍然众说纷纭。文章在对湘西北黑色岩系非常规铀资源开展地质和放射性调查的基础上,选取下寒武统牛蹄塘组铀多金属磷块岩露头较好的白竹峪矿床开展地质调查、岩石地球化学测量、系统的采样和分析测试,结果表明铀多金属磷块岩主量元素与上地壳所含的对应元素相比,只有CaO和P2O5富集,富集系数分别为9和204。此外,铀多金属磷块岩微量元素U(平均含量为1 350×10-6)、Ni(平均含量为6 822×10-6)和Mo(平均含量为2 104×10-6)均达到相应矿床的工业品位,且Re、Tl和V达到铀矿床综合利用指标。上震旦统灯影组白云岩、下寒武统牛蹄塘组铀多金属磷块岩和黑色碳质泥质页岩及板岩的δU、V/Cr、Ni/Co和δCe值均指示这3种地层形成于缺氧沉积环境,铀多金属磷块岩北美页岩配分曲线显示热水沉积特征,δEu大于1,结合主量元素和微量元素R型聚类分析结果推测铀多金属磷块岩在正常海相沉积的基础... 相似文献
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澳大利亚世纪(Century)铅锌矿床赋存于中元古代劳恩希尔组页岩和粉砂岩中。矿化主要为细粒闪锌矿,其次为方铅矿和黄铁矿。大部分硫化物(80%~90%)在黑色页岩单元中以易碎的交代层状出现,被富菱铁矿粉砂岩层隔开。矿化具有2个大尺度的变化趋势,在白蚁圈断层由北东至南西,Zn品位显著降低,由南东至北西,Zn品位略有降低。层状闪锌矿主要有2种结构,多孔闪锌矿的焦沥青含量较高,无孔闪锌矿焦沥青含量较低。S同位素研究显示,整个成矿流体系统是一个封闭的储层,重S在变形与成矿事件中进一步富集。世纪矿床由变形作用驱使流体迁移到异常高压(压实作用下的)页岩层位时,页岩容矿的矿化作用形成。较热的富含金属的流体和较深盆地的卤水,使得有机质迅速成熟,最终导致硫酸盐的还原和贱金属的沉淀。 相似文献
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HU Kai YU Chensheng MA Dongsheng ZHAI Jianping ZHANG WenlanDepartment of Earth Sciences Nanjing University State Key Laboratoryfor Mineral Deposit Research Nanjing University Nanjing XIAO Zhenyu Guangdong Nonferrous Metals Geological Exploration Bureau Guangzhou Zhang Yuxu Zhu Xiling 《《地质学报》英文版》2002,76(2):249-256
The silver contents of organic matter in the host rocks of the Songxi shale-hosted Ag-Sb deposit of northeastern Guangdong, South China, have been directly determined using the electron microprobe technique. The silver contents in two types of organic matter, marine vitrinite and solid bitumen, vary in the range from 100×10-6to 350×10-6, which are from tens of times to thousands of times higher than those of the host rocks in the ore deposit. The average silver content of the organic matter is also several times higher than the pay grade of silver for commercial mining of the ore deposit. It is quite obvious that the organic matter of the host rocks in the ore district is characterized by an anomalous enrichment of silver. The results of this study indicate that the silver anomalies in the organic matter have been derived from both the host rocks and the silver-bearing fluids of the Songxi black shale ore source. In the course of sedimentation and later hydrothermal reworking, organic matter was able 相似文献
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Organic geochemistry and comparisons of characteristics of the organic matter in wall rocks of the ore-controlling strata and ores of the Lower Jurassic Songling black shale formation and the related Songxi silver-antimony deposit of northeastern Guangdong have been studied in this paper.The results show that the Lower Jurassic Songling shale formation is a suite of biologic-rich and organic-rich ore-bearing marine sedimentary rocks.Micro-components of the organic matter in the Songling black shale formation consists primarily of algae,amorphous marine kerogen,solid bitument,and pyrobitument.The thermal evolution of organic matter is at the over-maturity stage.There is a general positive correlation between total organic carbon(CO)and metallogenetic elements such as Ag and Sb in the black shale formation.Organic matter in the host rocks in the Songxi ore deposit played a role in controlling the silver-antimony depositing environment during the forming process of the black shale ore-bearing formation.In the absence of vitrinite,the relative level of thermal maturity calculated by solid bitument reflectance indicates that the ore-forming temperatute of the Songxi silver-antimony deposit was about 150-170℃,which was considered as an epithermally reworked ore deposit.The roles of organic matter in the formation of the Sonxi ore deposit are a primitive accumulation of the metallogenetic elements(Ag,Sb) in the sea-water cycle system for ore source and a concentration of metals by ion exchange of chelation as well as reductionn of the oxidzed metals. 相似文献
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四川赤普铅、锌矿床生物标志化合物特征研究 总被引：3，自引：0，他引：3
赤普铅、锌矿床的矿体中发育大量沥青,铅、锌矿化形成与沥青密切相关。应用族组分分离和定量及饱和烃色—质分析等方法对铅、锌矿中的沥青族组分和生物标志物进行了研究,并对其地质意义进行了探讨。通过研究取得如下认识:（1）铅、锌矿床内有机质主要来自碳酸盐岩,其次来自页岩,没有陆源有机质的加入;这种混合来源特征受到不同来源成矿流体作用的影响。（2）矿区内有机质反映了热液流体经历了还原、高盐度的物理化学过程。（3）矿区内有机质成熟度高,主要为炭质沥青,反映有机质的演化程度较高;矿体内有机质与围岩内有机质成熟度类似,反映它们经历了类似的地质作用过程。（4）有机质还原碳酸盐岩中的硫酸盐岩,产生还原硫,为铅、锌等硫化物的沉淀创造条件。（5）成矿流体中烃类含量比较高,推断已经演化到高成熟阶段的有机质可能以古油气藏的形式参与了成矿作用;有机质在与含矿流体混合过程中扮演着还原剂的角色。 相似文献
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长坑-富湾超大型银矿床主要产在下石炭统灰岩与上三叠统页岩断层不整合面下的硅质岩及灰岩中,矿化多为脉状,主要由石英、方解石、方铅矿、闪锌矿及银矿物组成。成矿流体Rb-Sr 等时线年龄为68±8.5Ma,表明成矿发生在59.5-76.5 Ma 之间。(87Sr/86Sr)I= 0.7164.成矿流体δ18O 在-0.86‰-4.1‰之间,δD 在-39.8‰-59‰之间,表明成矿流体为循环大气降水或建造水。银矿床铅同位素组成和产于中新元古代地层中茶洞银矿床方铅矿的铅同位素组成基本一致。据成矿年龄、成矿流体氢氧同位素组成及铅同位素组成特点,认为长坑-富湾超大型独立银矿床是晚白垩世至第三纪火山及次火山活动加热循环大气降水及建造水溶解深部矿源岩中经过早期成矿富集的成矿物质,迁移至灰岩与硅质岩及硅质岩与页岩界面时沉淀析出形成的。 相似文献
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Algal-bacterial fabrics of ores and their genetic implications in the longtang lead-zinc deposit at Yanbian,Sichuan 总被引：1，自引：0，他引：1
The Longtang Pb-Zn deposit occurs in the Upper Sinian Guanyinyan Formation. The host rocks include sandy shale, cherty limestone
and dolomitic limestone. The deposit is a typical one of thallogen origin.
The mineral assemblage in the ore is made up of sphalerite, galena, pyrite, enargite, tennantite, seligmannite, asphalt, etc.
The ore-forming process is possessed of multiepisode and multi-stage characters. Generally, sphalerites exhibit algal stromatolitic,
bacterial and algal colloidal textures, providing evidence for the direct involvement of algae and bacteria in mineralization
of ore-forming elements during sedimentary diagenesis. This is the first transmigration of ore-forming elements. However,
pyrite embracing bacteria and galena replacing/filling trichomes are typical organic textures, which are related to organic
carbon and bitumen that can adsorb or reduce ore-forming elements. This is an indirect process of organic mineralization,
i.e., the second transmigration of ore-forming elements. δ34S values are all greater than 5%., indicating the dominance of the heavy sulfur isotopes. The ore-forming temperature deduced
from fluid inclusions ranges from 100°C to 150°C±. All this goes to show that the Longtang Pb-Zn deposit is of thallogen origin.
This project was granted by the National Natural Science Foundation of China. 相似文献
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河南桐柏老湾金矿床的成矿作用是在变基性火山碎屑沉积岩为矿源层的背景上演化的。本文根据矿床氢氧同位素研究,认为矿床的热液成矿期成矿流体为大气降水和老湾花岗岩岩浆水的混合,成矿Ⅰ阶段和Ⅱ阶段以岩浆水为主,成矿Ⅲ阶段以大气降水为主,但在成矿Ⅱ阶段大气降水已占有很大的比例。氦同位素分析表明,在老湾金矿形成过程中有地幔流体加入,且从成矿Ⅱ阶段至Ⅲ阶段,由于大气降水比例增大,其与地幔流体的混合导致成矿流体的3He/4He比值不断减小。 相似文献
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长坑矿田金,银矿床地球化学特征及形成差异分析 总被引：10，自引：0，他引：10
长坑矿田金、银矿体主要产于下石炭统与上三叠统不整合面之下的硅质岩中,金、银矿体分离。金矿体主要为浸染状,富集As、Sb、Hg;银矿体主要为脉状,富集Cu、Pb、Zn。金矿体铅同位素组成与寒武纪—石炭纪地层及硅质岩的相同,银矿体铅同位素组成与金矿体的不同。金、银矿体的氢、氧、碳同位素组成也明显不同。银矿体Rb-Sr等时线年龄为70.4Ma。据上述特征,笔者认为长坑金、银矿床是不同成矿作用形成的,金矿主要是热水沉积形成,银矿主要是燕山期晚期改造形成。 相似文献
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XieShucheng WangHongmei GuoJianqiu LiangBin ZhouXiugao 《中国地质大学学报(英文版)》2003,14(2):127-136
Organic matter, associated with ores, host rocks, ore source rocks and present in fluid inclusions in the Qixiashan lead-zinc polymetailic deposit hosted in Upper Carboniferous dolomites and limestones in East China, was systematically analyzed using Fourier transform infrared spectroscopy, gas chromatography (GC), GC/mass spectrometry and proton-induced X-ray emission. The biomarker ratios of nC21^--/n22^ -alkanes, C23-tricydic/C30-hopane and the tricyclic terpane parameters induding C21/C23, C19-10/C21-29 and C19-25/C26-29 can effectively discriminate ores from host rocks. Extractable organic matter present in fluid inclusions displays similariUes to those enclosed in the ore source rocks in the biomarker ratios, suggesting that a proportion of orphic matter was introduced into the deposit from the ore source strata. The presence of copper and zinc in stage Ⅱ pyrobitumen indicates that some metals may have been transported by an organic fluid or removed from an aqueous fluid by organic matter. 相似文献
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The original ore-fluid of the Huogeqi Cu–Pb–Zn deposit in Inner Mongolia, northern China, was enriched in heavy oxygen isotopes with δ18O values ranging from 9.9 to 11.4 per mil, which is characteristic of the metamorphic devolatilization of pelitic rocks. The δD values determined by direct measurement of syn-ore hydrothermal tremolite range from − 116 to − 82 per mil, lying between the domains of typical metamorphic fluid and meteoric water, which is in equilibrium with organic matter. Oxygen and hydrogen isotope ratios indicate that the ore-fluid was derived from deep-sourced metamorphic fluid and interacted with organic-rich shale during fluid migration, which is consistent with the fluid evolution history revealed by a previous fluid inclusion study. Sulfides in the deposit are characteristically enriched in heavy S isotopes, with an average δ34S value of 13.4 ± 6.2 per mil (1σ, n = 103). The S-isotope ratios are identical to stratabound sulfides generated through the non-bacterial reduction of Neoproterozoic marine sulfate (with δ34S values of ~ 17 per mil). Previous studies on lead isotopes of sulfides revealed that the ore-forming metals (Cu, Pb, and Zn) at the Huogeqi deposit were also remobilized from a stratabound source. This source was syngenetically elevated in its Cu-, Pb-, and Zn-sulfide content as a result of submarine hydrothermal activities forming sulfide-rich layers within a rift tectonic setting. The Fe isotope ratios for sulfides are consistent with those of an intercalated iron-formation within the ore-hosting rocks, suggesting that the Fe in the sulfides was derived from local host rocks during sulfide precipitation and the Fe-rich rocks are favorable lithological units for high-grade mineralization. The heterogeneous sources of ore-fluid, S, ore-forming metals, and Fe are explained by a multistage genetic model, which is supported by the geological characteristic of the deposit. The enriched sulfides were subsequently remobilized and enriched by metamorphic devolatilization during the Permian and Triassic periods. The metamorphic ore-fluid ascended along a shear zone and interacted with organic-rich shale. Sulfides eventually precipitated within the shear zone at a shallower crustal level, especially where the shear zone intersected Fe-rich host rocks. This multistage genetic model has implications for mineral exploration. Greenschist to amphibolite facies terranes containing thick Neoproterozoic rift sequences are ideal regions for potential Cu–Pb–Zn mineralization. In particular, intercalated volcanic rocks within the rift sequences are indicative of high heat-flow and are ideal for the development of submarine hydrothermal systems. The primary structures hosting mineralization and ore shoots in the Huogeqi area are jogs in the shear zones. In addition, Fe-rich lithological units, such as iron-formations, are ideal hosts for high-grade ore. 相似文献