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1.
Geological and geochemical data indicate that the formation of the granulite-like rocks in the contact aureole of the Yurchik gabbronorite intrusion of the Ganal Range, Kamchatka, was caused by the contact metamorphism, metasomatism, and local melting of the initial volcanosedimentary rocks of the Vakhtalka Sequence of the Ganal Group. The temperature in the inner part of the aureole reached 700–800°C and caused the transformation of the basic volcanic rocks of the sequence into two pyroxene-plagioclase, clinopyroxene-amphibole-plagioclase, and amphibole-plagioclase hornfelses, while sedimentary rocks were converted into garnet-biotite ± cordierite hornfelses. The hornfelsed basic volcanic rocks were locally subjected to metasomatic alteration and magmatic replacement with formation of biotite-orthopyroxene-plagioclase metasomatic bodies containing biotite-orthopyroxene-plagioclase ± garnet veinlets and aggregates. During these processes, sedimentary interlayers were converted into garnet enderbites at 700–800°C and 3.2–4.8 kbar. The comparison of the chemical composition of basic volcanic rocks of the Vakhtalka Sequence and their transformation products indicates that the metasomatic alteration and magmatic replacement correspond to siliceous-alkaline metasomatism (granitization) and cause subsequent and uneven influx of SiO2, Al2O3, Na2O, K2O, Rb, Ba, Zr, Nb, and Cl and removal of Fe, Mg, Mn, Ca, Cr, Co, Ti, Y, and S. REE data on basic metavolcanic rocks, hornfelses, and metasomatites suggest that the processes of hornfelsation, metasomatism, and magmatic replacement of the initial volcanic rocks were accompanied by significant increase in LREE and slight decrease in HREE. The Sr and Nd isotope study of the rocks in the aureole showed that the initial basic volcanic rocks of the Vakhtalka Sequence are isotopically close to both mature island arc tholeiites and mid-ocean ridge basalts. The metasomatic alteration and magmatic replacement of volcanic rocks in the aureole lead to the decrease of 143Nd/144Nd and increase of 87Sr/86Sr approximately parallel to mantle array. Pb isotopic ratios in the studied rocks become more radiogenic from initial metavolcanic rocks to metasomatites. It is suggested that the processes of metamorphism, metasomatism, and magmatic replacement were caused by highly mineralized mantle fluids, which percolated along magmatic channels serving as pathways for gabbroid magma.  相似文献   

2.
The petrography, major element, and trace element (TE) compositions of minerals from two types of modal metasomatites (metasomatized peridotites and pyroxenites) from kimberlite pipes Udachnaya and Komsomol'skaya-Magnitnaya, Yakutia, have been studied. It is shown that texturally and chemically equilibrated metasomatites A consist of a set of superimposed minerals: phlogopite + diopside ± ilmenite ± apatite ± sulfides ± graphite. Their major and trace element compositions have specific features. The contents of TEs in garnet and clinopyroxene from these metasomatites are close to those in garnet and clinopyroxene from low-temperature coarse-grained peridotites richest in TEs. The distribution of a significant portion of TEs between garnet and clinopyroxene from A-type metasomatites and from coarse-grained lherzolites rich in TEs is close to experimental values reported for minerals coexisting with carbonatitic and basaltic fluids. We assume that this metasomatic process was nearly synchronous with the global metamorphism and cratonization of the mantle lithosphere and that high-density silicate–carbonate fluidmelts were metasomatizing agents.Another large mantle metasomatism process in the lithosphere of the Siberian craton was associated with the Middle Paleozoic kimberlite magmatic event, induced by the Yakutian thermochemical plume. Metasomatic minerals (Mg phlogopite + Cr diopside + chromite ± sulfides ± graphite) intensely replaced the minerals of the primary paragenesis, particularly, garnet. These reaction metasomatites show a sine-shaped REE pattern in garnet and disequilibrium between garnet and clinopyroxene. It is supposed that the reaction metasomatism in the mantle lithosphere of the Siberian craton was associated with ingress of reduced asthenospheric fluids at early stages of the kimberlite formation cycle. Metasomatic graphite formed in metasomatites of both types, and this fact evidences for two diamond formation epochs in the history of the mantle lithosphere of the Siberian craton.  相似文献   

3.
The Shivar pluton, a large granodiorite–monzonite intrusion in NW Iran, was intruded into Cretaceous sedimentary rocks during the Oligo‐Miocene. Its thermal aureole contains a variety of pelitic, basic and calc‐silicate hornfelses. Mineral parageneses in the pelitic and calc‐silicate hornfelses are studied here and mineralogical zones are determined. The maximum pressure of contact metamorphism is estimated to have been about 2.2 kbar on the basis of mineral parageneses in the pelitic rocks, indicating that the intrusion was emplaced no deeper than 8 km in the crust. Crystal size distribution (CSD) studies in the calc‐silicate hornfelses indicate that the degree of overstepping was high near the igneous contact. Secondary solid phases (SSP) inhibited growth of calcite grains in the calc‐silicate rocks and impure marbles. Garnet had a greater inhibitory effect as a SSP than tremolite or clinopyroxene. The time required for coarsening of calcite is calculated for two samples collected at different distances from the igneous contact. The time required for calcite coarsening is about 33 000 years for the sample 800 m from the contact and about 226 000 years for the sample 120 m from the contact. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

4.
FLOYD  P. A. 《Journal of Petrology》1965,6(2):223-245
At Tater-du, in the south of the Penwith peninsula, Cornwall,occurs a small isolated part of the Land's End aureole whichhas not been described in detail before. The aureole rocks hereare mostly banded amphibolitic hornfelses, some of which areof metasomatic origin. The metasomatic hornfelses can be divided into (1) Fe-Mg hornfelsescontaining anthophyllite, cummingtonite, and cordierite; (2)Ca hornfelses containing diopside, grossularite, epidote minerals,and axinite; and (3) K hornfelses containing a very high proportionof biotite. All three types are considered to have been derivedfrom hornblende hornfelses (‘greenstone-hornfelses’)of basic intrusive origin. Data are presented indicating their originally intrusive natureand similarity to other metasomatic hornfelses in the aureoleat Kenidjack and Botallack (Tilley, 1935). The Fe-Mg and Cahornfelses are considered to have resulted from the internalmigration of the Ca ion during metamorphism and the K hornfelsesfrom the allochemical addition of K from the granite.  相似文献   

5.
The paper presents a comparative mineralogical-geochemical characterization of amphibolites and basic metasomatic rocks in the Belomorian belt. The metasomatites are spread much more locally than the amphibolites. The metasomatic rocks compose bodies of very diverse morphology, some of which are similar to the morphologies of amphibolite bodies (podiform and tabular bodies and lenses). The metasomatites are characterized by a great diversity of their petrographic varieties, whereas the usual assemblage of the amphibolites is amphibole ± garnet + plagioclase + quartz. Although one of the varieties of both rock types contains the same assemblage (garnet-hornblende), the metasomatites contain no quartz, have different quantitative proportions of their minerals, their compositions, and different overall contents of amphibole and garnet. The metasomatites are more mafic and contain 85–100% mafic minerals, whereas the amphibolites contain only 60–65% mafic minerals. The rocks have different concentrations of most major and some trace elements, including REE. The basic metasomatites are poorer than the amphibolites in SiO2, Al2O3, Na2O, K2O, LREE, and HREE but richer in MgO and Cr2O3. The Cr concentrations in some of the metasomatites are higher than the clarkes of this element in crustal ultrabasic rocks. The main Cr concentrator in the rocks was determined to be amphibole: some grains of this mineral contain as much as 6800 ppm Cr. The element is unevenly distributed even within single grains. Amphiboles of the amphibolites do not contain Cr at all. Another difference of amphiboles from the metasomatic rocks and amphibolites is the depletion of this mineral in the former rocks in Al and Fe, the absence of K, but high concentrations of MgO and 1.5–2.0 times higher. A remarkable feature of the compared rocks is their geneses. The amphibolites of the Belomorian belt are metamorphosed mafic Archean rocks, whereas the basic metasomatites were produced by Fe-Mg-Ca metasomatism (basification) closely related to the granitization of various rocks, first of all, amphibolites. It is important to distinguish between these rocks of various genesis and age, particularly when geological survey is conducted.  相似文献   

6.
Late Variscan granites intruded Brioverian (Upper Proterozoic) and Lower Paleozoic pelitic sequences to the north of the South Armorican shear zone. In the vicinity of the granites, Brioverian garnet micaschists contain pre/syn-S2 assemblages with garnet + staurolite and post-S2 assemblages with staurolite ± andalusite. Andalusite appeared pre/syn- and post-S2 in garnet-free micaschists. The garnets in the Brioverian micaschists are zoned with increasing Mg and decreasing Mn and Ca from core to inner rim. Only poor garnet zonations occur in Paleozoic hornfelses of enclaves in the Rostrenen granite. The results of a microstructurally controlled application of garnet–biotite geothermometers and garnet–plagioclase geobarometers are similar to P–T trends obtained by the Gibbs method of garnet zonation modelling in the system NCFMnMASH. The P–T paths of a pre/syn-S2 regional metamorphism are clockwise between 500–550°C/8 kbar and 700°C/5 kbar, followed by cooling decompression. They contrast with isobaric contact metamorphism between 500 and 700°C at 2.5–3 kbar in Paleozoic hornfelses. This points to a two-stage Variscan metamorphism with a pre-granitic pressure-dominated event in the Brioverian micaschists, followed by Late Variscan contact metamorphism, and suggests the existence of a pre-granitic tectonic boundary between the micaschists and overlying low-grade sequences.  相似文献   

7.
云南个旧锡矿床花岗岩接触带的交代现象   总被引：5，自引：0，他引：5  
赵一鸣  李大新 《地球学报》1987,9(2):237-252
我国个旧锡矿是闻名中外最大的锡矿床之一,矿床中除含锡外,还伴生铜、钴、锌、钨、铋、铍及稀有元素。矿化主要产于燕山期花岗岩接触带及其附近的三叠纪碳酸盐围岩中的交代岩。本文着重讨论含锡花岗岩接触带交代岩的类型。矿物组合、分带性、岩石化学特征及其与矿化的关系,把各类含矿交代建造作为一个有成团联系的统一体——交代系列来考虑。  相似文献   

8.
The degree of recrystallization of carbonaceous material (CM), as monitored by Raman microspectroscopy, was examined as a function of metamorphic grade in two well‐studied contact aureoles containing carbonaceous pelites: the Nelson aureole, British Columbia and the Ballachulish aureole, Scotland. Here, we use (a) the R2 ratio extracted from the Raman spectrum of CM as a proxy for the degree of graphitization (0.0 in perfect graphite then increasing with structural defects) and (b) the second‐order S1 band (~2,700 cm?1) as a marker for the tridimensional ordering of CM. The Nelson aureole (garnet–staurolite–andalusite–sillimanite–K‐feldspar sequence, ~550–650°C, 3.5–4.0 kbar) was developed in rocks that were unmetamorphosed prior to contact metamorphism, whereas the Ballachulish aureole (cordierite–andalusite–K‐feldspar–sillimanite sequence, ~550–700°C, ~3.0 kbar) was developed in rocks that had been metamorphosed to garnet grade conditions (~7 kbar, ~500°C) c. 45 Ma before contact metamorphism. Thirty‐one samples were examined from Nelson and 29 samples from Ballachulish. At Nelson, the R2 ratio steadily decreases from ~0.25 to 0.0 as the igneous contact is approached, whereas at Ballachulish, the R2 ratio remains largely unchanged from regional values (~0.20–0.25) until less than 100 m from the igneous contact. The second‐order S1 band reveals that carbonaceous material (CM) was transformed to highly “ordered” locally tridimensional graphitic carbon at Ballachulish by regional metamorphism prior to contact metamorphism, whereas CM was still a disordered turbostratic (bidimensional) material before contact metamorphism in the case of Nelson. Pretexturation of CM likely induced sluggish recrystallization of CM and delayed graphitization in the Ballachulish aureole. Temperatures of recrystallization of the CM in the two aureoles were estimated using different published calibrations of the thermometry based on Raman Spectroscopy of Carbonaceous Material (RSCM), with differences among the calibrations being minor. In the Nelson aureole, temperatures are in reasonable agreement with those indicated by the metapelitic phase equilibria (all within 50°C, most within 25°C). In the Ballachulish aureole, the retarded crystallization noted above results in increasing underestimates of temperatures compared to the metapelitic phase equilibria (up to ~75°C too low within 200 m of the igneous contact). Our study calls for careful attention when using RSCM thermometry in complexly polymetamorphosed rocks to assess properly the meaning of the calculated temperature.  相似文献   

9.
The paper presents results of a detailed petrologic study of metasomatites and their host metagabbroids in the northwestern part of Kiy Island, Onega Bay, White Sea. The first evidence is acquired that coronitization and amphibolization of the host rocks took place at the peak of Svecofennian metamorphism at Т = 700–640°C, Р = 9–10 kbar, and \({a_{{H_2}O}}\) = 0.2–0.3. Accompanying metasomatism has formed a number of long (up to several meters long) melanocratic hornblendite and garnet–amphibole veins 0.3–2 m thick. In this area, metasomatites of another type make up single relatively thin amphibole–zoisite lenses that sometimes host ruby-like corundum. The fluid phase that induced metasomatism was poor in salts (Na,K)Cl, and hence, the rocks do not contain sodic plagioclase, and their amphibole is tschermakite but not pargasite. The compositions of the metasomatites of the two types are proved to be complementary, and this indicates that they were most likely produced by high-temperature metasomatism but not via the removal of components by fluid from migmatization zones.  相似文献   

10.
Abstract The Rockley Volcanics from near Oberon, New South Wales occur within the aureole of the Carboniferous Bathurst Batholith and have been contact metamorphosed at P ∼ 100 ± 50MPa (10.5kbar) and a maximum T ∼ 565°C in the presence of a C–O–H fluid. Prior to contact metamorphism the volcanics were regionally metamorphosed and altered with the extensive development of actinolite, chlorite, plagioclase, quartz and calcite. The contact metamorphosed equivalents of these rocks have been subdivided into: Ca-poor (cordierite + gedrite), Mg-rich (amphibole + olivine + spinel), mafic (amphibole + plagioclase) and Ca-rich (amphibole + garnet + diopside; diopside + plagioclase; garnet + diopside + wollastonite) rocks.
The chemistry of the minerals in the hornfelses was controlled by the bulk rock chemistry and fluid composition. Pargasites and hastingsites as well as an unusual phlogopite with blue green pleochroism, are found in Ca-rich hornfelses. A comparison of the assemblages with experimentally derived equilibria suggests that the fluid phase associated with the Ca-rich hornfelses was water-rich (Xco2= 0.1 to 0.3) while that associated with the Mg-rich hornfelses was enriched in CO2 (Xco2 > 0.7). The different hornfels types have reacted to contact metamorphism independently in both their solid and fluid chemistries.  相似文献   

11.
This paper presents the results of a study of the Paleoproterozoic basal garnet-kyanite-staurolite-two-mica paraschists from the Kukasozero structure of the Karelides of Northern Karelia, Baltic Shield, underlying Neoarchean acid metavolcanic rocks, and schists with quartz, phengite, kyanite, staurolite, garnet, and tschermakite located in the Paleoproterozoic rocks and considered to be metasomatic in origin. It was established that the sedimentary protolith of the Paleoproterozoic paraschists contains detritus of Neoarchean igneous rocks as follows from detrital 2737 ± 11 Ma zircons with oscillatory magmatic zoning. Metavolcanic 2757 ± 13 Ma rocks, close in age and composition, are known directly in the framework of the Kukasozero structure and are considered to be the most likely source of the sedimentary schist protolith. The coincidence of the Nd-model ages of paraschists (t DM is 2.73–2.76 Ga) with the age of detrital zircons indicates no contribution of older rocks to the protolith composition. The age of magmatic crystallization of metavolcanic rocks directly underlying the Paleoproterozoic paraschists is 2681 ± 18 Ma and coincides with the age of porphyry granites in the western framework of the structure (2680.3 ± 3.6 Ma). No detrital zircons of similar age were found in basal paraschists, but the restricted amount of dated zircons does not allow us to draw a final conclusion about the absence of detritus of the underlying metavolcanic rocks in the paraschist protolith. It was confirmed that phengite-bearing schists are the products of acid metasomatism of the Paleoproterozoic amphibolites and amphibole schists (metavolcanic rocks). The metasomatic features were revealed in garnet-kyanite-staurolite-two-mica paraschists, so the strict identification of their sedimentary protolith is impossible. The paraschists do not represent metamorphosed weathering crust, because acid metasomatism gives a false impression of the greater maturity of the primary sedimentary rocks.  相似文献   

12.
A petrological and thermobarometric study of the Lago Teleccio hornfelses was undertaken to reconstruct the polymetamorphic evolution and constrain the P–T conditions of Permian contact metamorphism. The Lago Teleccio metasedimentary rocks record a Variscan regional metamorphism characterized by amphibolite facies mineral assemblages including quartz, plagioclase, K‐feldspar (Kfs 1), biotite, garnet (Grt 1) and staurolite; this was followed by a late‐Variscan mylonitization event. Metamorphism of the Variscan metamorphic rocks at the contact with a Permian granitic intrusion produced static recrystallization and/or new growth of quartz, garnet (Grt 2), plagioclase, K‐feldspar (Kfs 2), cordierite, green spinel, biotite and prismatic sillimanite (Contact 1). This thermal event, which occurred at a peak pressure of 0.23–0.35 GPa, temperature of 670–700 °C and aH2O of 0.75–1, was followed either during post‐contact metamorphism cooling or, more likely, during the early‐Alpine metamorphism by the breakdown of cordierite into an anhydrous kyanite + orthopyroxene + quartz assemblage. The poorly developed early‐Alpine eclogite facies metamorphism (Alpine 1) was characterized by relatively anhydrous mineral associations and low strain, which locally produced coronitic and pseudomorphous microstructures in metasedimentary rocks, with scanty formation of jadeite, zoisite and a new high‐pressure garnet (Grt 3). Greenschist facies retrogression (Alpine 2) was characterized by the local development of a chlorite‐ and muscovite‐bearing mineral association, suggestive of aqueous fluid incursion. In the hornfelses, the limited extent of metamorphic overprinting is suggested by the fine grain size of the Alpine mineral associations, which formed at the expense of the Permian contact metamorphic associations, and was favoured by the anhydrous mineralogy of the hornfelses.  相似文献   

13.
Watkinson et al. (1978) have reinterpreted the Zn-Cu deposits in the Ransko massif as xenoliths of volcanogenic ores enclosed in and contact-metamorphosed by a basic magma. A detailed reexamination of different xenoliths within the massif, and their comparison with the cordierite hornfelses carriers of Zn-Cu ores, has shown essential differences between them, and confirmed the previous opinions on the metasomatic origin of the deposits. The cordierite hornfels originated by selective magnesian metasomatism of intrusive rocks rich in feldspar (quartz diorite, troctolite), particularly by the replacement of feldspars by cordierite. Around the stocks of cordierite hornfels, a conspicuous concentric metasomatic zonation of rocks developed in mafic intrusives. The Zn-Cu deposits of the Ransko massif resemble sulfide deposits connected with magnesian metasomatism, especially those of the Hitachi area in Japan.  相似文献   

14.
The geological position, composition of mineral assemblages, and typomorphism of major minerals from garnet-bearing rocks at the Berezitovoe gold-base-metal deposit in the Upper Amur Region have been studied in detail. These are ore-bearing metasomatic rocks and metamorphosed porphyritic dikes. The garnet-bearing metasomatic rocks reveal zoning, which is caused by various degrees of metasomatic transformation of the Paleozoic porphyritic granodiorite that hosts the ore zone. The metasomatic replacement of granodiorite was accompanied by loss of Na, Ca, Ba, Sr and gain of K, Mn, and Rb. Garnet-bearing metamorphosed intermediate dikes occur within the metasomatic zone. The PT conditions of metamorphism and metasomatism are similar and estimated at 3.9 kbar and 500°C from various mineral equilibria. The results of physicochemical simulation of garnet-bearing mineral assemblages carried out by minimizing the Gibbs free energy and the geological data show that garnet-bearing mineral assemblages arose at the Berezitovoe deposit as a result of local high-temperature thermal metamorphism of previously formed low-temperature metasomatic rocks close in composition to classic beresite. In this connection, we propose considering garnet-bearing metasomatic rocks as high-temperature metamorphosed beresites.  相似文献   

15.
The genesis of Liangguo corundum deposit in the southern Gangdese magmatic arc, east-central Himalaya, remains unknown. The present study shows that the corundum-bearing rocks occur as lenses with variable sizes in the Eocene gabbro that intruded into marble. These corundum-bearing rocks have highly variable mineral assemblage and mode. The corundum-rich rocks are characterized by containing abundant corundum, and minor spinel, ilmenite and magnetite, whereas the corundum-poor and corundum-free rocks have variable contents of spinel, plagioclase, sillimanite, cordierite, ilmenite and magnetite. The host gabbro shows variable degrees of hydration and carbonization. The corundum grains are mostly black, and rarely blue, and have minor Fe O and TiO_2. The spinel is hercynite, with high Fe O and low Mg O contents. The corundum-bearing rocks have variable but high Al_2O_3, FeO and TiO_2, and low SiO_2 contents. Inherited magmatic and altered zircons of the corundum-bearing rocks have similar U e Pb ages(~47 Ma) to the magmatic zircons of the host gabbro, indicating corundum-bearing rock formation immediately after the gabbro intrusion. We considered that emplacement of gabbro induced the contact metamorphism of the country-rock marble and the formation of silica-poor fluid. The channeled infiltration of generated fluid in turn resulted in the hydrothermal metasomatism of the gabbro, which characterized by considerable loss of Si from the gabbro and strong residual enrichment of Al. The metasomatic alteration probably formed under Pe T conditions of ~2.2 -2.8 kbar and ~650 -700℃. We speculate that SiO_2, CaO and Na_2O were mobile, and Al_2O_3, FeO, TiO_2 and high field strength elements remained immobile during the metasomatic process of the gabbro. The Liangguo corundum deposit, together with metamorphic corundum deposits in Central and Southeast Asia, were related to the Cenozoic Himalayan orogeny, and therefore are plate tectonic indicators.  相似文献   

16.
Contact metamorphism of greenschist facies Neoproterozoic turbidites by the Cretaceous Bugaboo Batholith in southeastern British Columbia has resulted in a well‐developed contact aureole. The aureole is about 1 km wide and can be divided into three main zones: (i) spotted phyllite zone, extending from the first appearance of spots of cordierite or andalusite to the last occurrence of primary chlorite; (ii) cordierite + andalusite + biotite zone, comprising hornfelses or schists with abundant porphyroblasts of cordierite and andalusite and, at higher grades, fibrolitic sillimanite; and (iii) K‐feldspar zone, characterized by hornfelses and schists that, in the inner part of this zone, are variably migmatitic. Four parts of the aureole were examined, three of which are characterized by schists, and one of which (Cobalt Lake area) is characterized by hornfelses and has exceptional exposure and comparatively unaltered rocks. Petrographic, modal, mineral‐compositional and whole rock‐compositional data were collected from the Cobalt Lake transect, allowing the prograde reaction sequence to be inferred. Notable features of the aureole at Cobalt Lake include: initial development of andalusite and plagioclase at the expense of paragonite‐rich white mica; a narrow interval across which cordierite, andalusite and biotite increase markedly at the expense of chlorite; gradual development of andalusite and biotite at the expense of cordierite and muscovite upgrade of chlorite consumption; and near‐simultaneous development of andalusite + K‐feldspar and sillimanite, the latter indicating a pressure of contact metamorphism of ~3 kbar. In other parts of the aureole, the development of sillimanite downgrade of the initial development of K‐feldspar suggests slightly higher pressures of contact metamorphism. Lack of correspondence between the observed sequence of reactions in the aureole and those predicted thermodynamically suggests that modifications to some of the thermodynamic data or activity–composition models may be required. Textural features in the aureole suggest the influence of kinetic factors on metamorphic recrystallization, including: (i) deformation‐catalysed reaction in the schists compared to the hornfelses, as indicated by different mineral‐growth sequences inferred from microstructures, and (ii) heating rate‐controlled recrystallization, as indicated by the decrease in grain size of hornfelses with increasing metamorphic grade.  相似文献   

17.
Analysis of magmatic and sedimentary rocks of several large igneous provinces has demonstrated that the release of gas during plutonic-metamorphic processes may be linked to global climate change and mass extinctions. Aguablanca, one of the largest Cu–Ni–PGE deposits in Europe, formed during the Variscan orogeny when a mafic magma intruded limestones and shales, creating a contact aureole composed of marble, skarn and hornfels. Our petrological and geochemical investigation of the aureole provides evidence that a combination of the two processes led to the formation of the ore deposit: The assimilation of terrigenous sediments supplied S to the magma while the assimilation of carbonates changed the oxygen fugacity and decreased the solubility of sulfur in the magma. The metamorphic assemblages in the contact aureole are directly related to heterogeneity of the protolith and particularly to the original proportions of calcite and clay. We modeled carbon dioxide degassing during contact metamorphism and showed that pure limestone is relatively unproductive because of its high reaction temperature. The presence of clay, however, leads to the formation of calc-silicates and significantly enhances CO2 degassing. Our estimations suggest that degassing of the Aguablanca contact aureole released about 74.8 Mt of CO2, a relatively low volume that we attribute to the composition of the host rock, mainly a pure limestone. A far larger volume of carbon dioxide was emitted by the contact metamorphism of dolostones in the contact aureole of Panzhihua (part of Emeishan large igneous province, SW China). We propose that the level of emission of carbon dioxide depends strongly on the nature of the protolith and has to be considered when predicting environmental impact during the emplacement of large igneous provinces.  相似文献   

18.
交代作用在自然界十分普遍。它与内生、变质成矿作用关系尤为密切,许多矿床主要以交代方式形成,常伴生广泛和强烈的围岩蚀变现象,形成各类交代岩。这些交代岩石与矿体常形影相随,有着紧密的时空成因联系。研究交代岩的类型、矿物共生组合、分带性及其含矿性,不但能揭示矿床形成的物理化学条件和成岩成矿机理,而且还可以为预测隐伏矿体提供重要找矿标志。  相似文献   

19.
We investigated the contact zone between peridotite lenses and host gneisses located on the northern side of the Hochwart peak, also known as Vedetta Alta (Ulten Zone, Alto Adige -Südtirol) where metasomatic contact bands occur. The country rocks are gneisses consisting mainly of quartz, K-feldspar, garnet, kyanite, biotite and muscovite. The ultramafic body consists of a hectometre-sized garnet peridotite and harzburgite lens. The reaction zone shows mineralogic zoning from phlogopite-rich to tremolite-anthophyllite-talc-rich rocks from the host gneiss towards the peridotite. In some cases, lenses of serpentine and talc in association with chlorite, and trondhjemitic pods develop at the ultramafic rocks border to the gneisses. Trondhjemite dikes with pegmatoid texture also crosscut the peridotite body. Phlogopite aggregates with accessory zircon, Cl-apatite and tourmaline and phlogopite-hornblende aggregates also occur. The combination of petrography, mineral chemistry and mass balance calculations constrains the gains and losses of elements during metasomatism. Reaction zone formation involved extensive addition of H2O, K2O and LILE from the fluid, whereas MgO, CaO and Al2O3 were removed from the peridotite. Thus, the formation of the reaction zones between the mantle rocks and the gneisses was triggered by considerable fluid/melt circulation, causing crystallisation of mainly phlogopite, anthophyllite and talc, and the release of a trondhjemitic residual melt. Field mapping provides evidence that the internal structures of the host migmatites (folds) and those of the peridotites (foliation, fluid texture) are discordant. Pseudosection calculations give insights into the P-T conditions (T 660–700°C; P 0.5–0.7 GPa) of metasomatism responsible for the formation of reaction zones, which is related to the retrograde path of the Ulten Zone peridotites. Our results suggest that the redistribution of major and trace elements in subduction zones is strongly influenced by metasomatic reactions occurring at the slab-mantle interface.  相似文献   

20.
苏鲁褶皱带形成于元古宙 (2 2 33～ 185 5Ma)典型优地槽构造环境 ,主要由石榴橄榄岩、石榴辉石岩、榴辉岩等侵入岩 (柯石英深度相地幔岩浆房中形成 )和它们的火山沉积建造围岩一起经褶皱、变质而形成。变质作用经历了先蓝片岩相 (前花岗岩 )后片麻岩混合岩相过程。由于变质作用的不规律性 ,苏鲁褶皱带可分为 2个构造带 :(1)东部构造带 (蓝片岩 )和 (2 )西部构造带 (片麻岩混合岩 )。根据A·都城秋穗所识别的变质带系统 ,可将其作为一个双变质带。东部构造带以出现许多块状、条带状榴辉岩辉石岩橄榄岩组合的残余岩块为特征 ,其中还残留着高压的矿物 (石榴石、绿辉石、柯石英 ) ,而且有被混合岩和各种交代岩替代的显著标志。在中生代 ,苏鲁元古褶皱带受造山作用的影响活化 ,导致许多花岗岩体的侵入 ,使交代岩广泛发育。  相似文献   

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