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1.
During the anaerobic decomposition of organic matter in sediments iodine is released into solution. Three techniques have been applied to independently estimate the resulting flux of soluble I from the sediments to the overlying water of Mud Bay, Georgetown, South Carolina. Flux estimates (summer) range between ~ 5 and 41 μmol/m2/day. The estimates predicted from either the pore water I concentration gradient across the sediment-water interface or the dissolved I production rate are higher than the apparent flux measured directly at the same site. This suggests that I which is released to the pore water under the anoxic conditions below the sediment surface reacts with a sedimentary component at or near the sediment water interface and is lost from solution.  相似文献   

2.
Long records of monthly salinity observations along the axis of Chesapeake Bay, Delaware Bay, and Long Island Sound are used to test a simple advection–dispersion model of the salt distribution in linearly tapered estuaries developed in a previous paper. We subdivide each estuary into three to five segments, each with linear taper allowing a distributed input of fresh water, and evaluate the dispersion in each segment. While Delaware Bay has weak dispersion and a classical sigmoidal salinity structure, Long Island Sound and Chesapeake Bay are more dispersive and have relatively small gradients in the central stretches. Long Island Sound is distinguished by having a net volume and salt flux out of its low-salinity end resulting in a smaller range of salinity and increasing axial gradients at its head rather than the usual asymptotic approach to zero salinity. Estimates of residence times based on model transport coefficients show that Long Island Sound has the most rapid response to fresh-water flux variations. It also has the largest amplitude cycle in river discharge fluctuation. In combination, these cause the large seasonal variation in the salinity structure relative to interannual variability in Long Island Sound as compared with Chesapeake Bay and Delaware Bay.  相似文献   

3.
Many small estuaries are influenced by flow restrictions resulting from transportation rights-of-way and other causes. The biogeochemical functioning and history of such systems can be evaluated through study of their sediments. Ten long and six short cores were collected from the length of Jordan Cove, Connecticut, a Long Island Sound subestuary, and analyzed for stratigraphy, radionuclides (14C, 210Pb, 226Ra, 137Cs, and 60Co), and metals (Ag, Cd, Cu, Pb, Zn, Fe, and Al). For at least 3,800 yr, rising sea level has gradually inundated Jordan Cove, filling it with mud similar to that currently being deposited there. Long-term sediment accumulation in the cove averaged close to 0.1 cm yr−1 over the last three millennia. Recent sediment accumulation rates decrease inland from 0.84 cm yr−1 to 0.40 cm yr−1, and are slightly faster than relative sea-level rise at this site (0.3 cm yr−1). Similarity of depth distributions of trace metals was used to confirm relative sediment accumulation rates. 60Co and Ag are derived from sources outside the cove and its watershed, presumably the Millstone nuclear power plant and regional contaminated sediments, respectively. The combined data suggest that Long Island Sound is an important source of sediment to the cove; a minor part of total sediment is supplied from the local watershed. Trace metal levels are strongly correlated with Fe but not with either organic matter or Al. Sediment quality has declined in the cove over the past 60 yr, but only slightly. Cu, Pb, and Zn data correlate strongly with Fe but not with either organic matter or aluminum. Ratios of Ag to Fe and to trace metals suggest that Ag in the cove is derived almost entirely from Long Island Sound. This result supports the notion that Fenormalized Ag can serve as a better tracer of some kinds of contamination than more common and abundant metals, like Cu, Pb, and Zn. *** DIRECT SUPPORT *** A01BY085 00008  相似文献   

4.
Sediment cores were used to investigate the mercury deposition histories of Connecticut and Long Island Sound. Most cores show background (pre-1800s) concentrations (50-100 ppb Hg) below 30-50 cm depth, strong enrichments up to 500 ppb Hg in the core tops with lower Hg concentrations in the surface sediments (200-300 ppb Hg). A sediment core from the Housatonic River has peak levels of 1,500 ppb Hg, indicating the presence of a Hg point source in this watershed. The Hg records were translated into Hg contamination chronologies through 210Pb dating. The onset of Hg contamination occurred in ~1840-1850 in eastern Connecticut, whereas in the Housatonic River the onset is dated at around 1820. The mercury accumulation profiles show periods of peak contamination at around 1900 and at 1950-1970. Peak Hg* (Hg*= Hg measured minus Hg background) accumulation rates in the salt marshes vary, dependent on the sediment character, between 8 and 44 ng Hg/cm2 per year, whereas modern Hg* accumulation rates range from 4-17 ng Hg/cm2 per year; time-averaged Hg* accumulation rates are 15 ng Hg/cm2 per year. These Hg* accumulation rates in sediments are higher than the observed Hg atmospheric deposition rates (about 1-2 ng Hg/cm2 per year), indicating that contaminant Hg from the watershed is focused into the coastal zone. The Long Island Sound cores show similar Hg profiles as the marsh cores, but time-averaged Hg* accumulation rates are higher than in the marshes (26 ng Hg/cm2 a year) because of the different sediment characteristics. In-situ atmospheric deposition of Hg in the marshes and in Long Island Sound is only a minor component of the total Hg budget. The 1900 peak of Hg contamination is most likely related to climatic factors (the wet period of the early 1900s) and the 1950-1970 peak was caused by strong anthropogenic Hg emissions at that time. Spatial trends in total Hg burdens in cores are largely related to sedimentary parameters (amount of clay) except for the high inventories of the Housatonic River, which are related to Hg releases from hat-making in the town of Danbury. Much of the contaminated sediment transport in the Housatonic River Basin occurs during floods, creating distinct layers of Hg-contaminated sediment in western Long Island Sound. The drop of about 40% in Hg accumulation rates between the 1960s and 1990s seems largely the result of reduced Hg emissions and to a much lesser extent of climatic factors.  相似文献   

5.
In a 3-yr study, late prespawning winter flounder were collected from various stations in Long Island Sound (three of them heavily urbanized) and spawned in the laboratory. For comparative purposes, flounder from two sites in the Boston Harbor area were similarly treated in 1987 and 1988. Of the stations in Long Island Sound, New Haven Harbor alone consistently produced low percent viable hatch and small larvae. Boston Harbor produced the smallest larvae of all sites. There were no significant station-to-station differences in lipid utilization during larval development; yolk reserves at stations showing a low percent viable hatch, small larvae, and low embryonic development rate were probably used in part for stress metabolism. No significant differences in concentrations of polychlorinated biphenyls for collections from Long Island Sound were found either in livers of spawned fish, in sediments, or in eggs of winter flounder. The very low metal concentrations in winter flounder eggs showed no relation to the degree of metal contamination found at stations in Long Island Sound and Boston Harbor.  相似文献   

6.
This paper uses results from the National Oceanic and Atmospheric Administration’s National Status and Trends Program (NS&T) to place the environmental quality of Long Island Sound in a broader perspective. It compares levels of contaminants in blue mussels from ten Long Island Sound sites and in sediments from seven Long Island Sound sites with concentrations in the same media at 87 and 221 other sites, respectively, where comparable samples were obtained. In sediments, the levels of both trace metals and organic contaminants tend to be relatively high for Long Island Sound sites. This is especially true for five of the twelve metals (silver, cadmium, copper, lead, and zinc) and for five of six categories of organic contaminants (total chlordane, low molecular weight polycyclic aromatic hydrocarbons (PAHs), high molecular weight PAHs, total polychlorinated biphenyls, and total dichlorodiphenyltrichloroethanes). In mussels, the organic contaminant categories exhibit relatively high levels, but this is not true for most of the metals. In fact, four of the metals—arsenic, mercury, selenium, and zinc—show evidence of relatively low levels in mussels from Long Island Sound compared to other NS&T locations.  相似文献   

7.
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8.
The total concentration of I is commonly higher in surface terrigenous sediments relative to more deeply buried material. Diagenetic release, loss of dissolved I during burial, and back-reaction of I with the solid phase under oxidizing conditions contribute to I enrichment near the sediment/water interface. In order to differentiate between scavenging of dissolved I by organic matter or metal oxides, the diagenetic behavior of I was examined in the Fe-poor carbonate sediments of Florida Bay, Florida. In this environment I is released by organic decomposition at I/C ratios similar to terrigenous environments (~0.5 mmole/mole), transported to the oxygenated sediment/water interface, and lost to the overlying water. The dissolved I flux from these deposits is roughly equivalent to the production rate within the deposit (~10 μmole/m2/day at 28°C). No significant enrichment is observed in the solid phase.Dissolved iodine transport within the sediment column may also be controlled by non-steady-state lateral diffusion into burrows. These observations, together with laboratory experiments which demonstrate IO?3 scavenging by Fe-oxyhydroxides at pH ≤ 8, imply that enrichment of I in terrigenous surface sediments results predominantly from the initial oxidation of I? to IO?3 by microorganisms, followed by sorption on Fe oxides. Upon burial and reduction during anaerobic decomposition, this metal-associated I is released to solution, in a manner similar to phosphate.  相似文献   

9.
Eighteen sediment samples and six water-column samples were collected in a small (6 km2), coastal embayment (Port Jefferson Harbor, New York) to define a high-resolution spatial distribution of metals and to elucidate sources of contaminants to the harbor. Sediment metal (Ag, Cu, Fe, Ni, Pb, V, and Zn) concentrations varied widely, reflecting differences in sediment grain size, with higher metal concentrations located in the fine-grained inner harbor sediments. Calculated enrichment factors for these sediments show that Ag, Pb, Cu, and Zn are elevated relative to both crustal abundances and their respective abundances in sediments in central Long Island Sound. Metal concentrations were 1.2 to 10 fold greater in water from the inner harbor compared to water from Long Island Sound collected outside the mouth of the harbor. Spatial variations in trace metals in surface waters within the bay parallel the spatial variations of trace metals in sediments within the harbor. Elevated water-column metal concentrations appear to be partially derived from a combination of diagenetic remobilization from contaminated sediments (e.g., Ag) and anthropogenic sources (e.g., Cu and Zn) within the southern portions of the harbor. Although the National Status and Trends Program had reported previously that sediment metal concentrations in Port Jefferson Harbor were low, the results of this study show sediment metals have high spatial variability and are enriched in the inner harbor sediments at levels comparable to more urbanized western north shore Long Island harbors.  相似文献   

10.
New data from a deep-sea core in the eastern North Pacific Ocean indicate that the western margin of the Late Wisconsin Cordilleran Ice Sheet began to retreat from its maximum position after 15,600 yr B.P. Ice-rafted detritus is present in the core below the 15,600 yr B.P. level and was deposited while lobes of the Cordilleran Ice Sheet advanced across the continental shelf in Queen Charlotte Sound, Hecate Strait, and Dixon Entrance. The core data are complemented by stratigraphic evidence and radiocarbon ages from Quaternary exposures bordering Hecate Strait and Dixon Entrance. These indicate that piedmont lobes reached the east and north shores of Graham Island (part of the Queen Charlotte Islands) between about 23,000 and 21,000 yr B.P. Sometime thereafter, but before 15,000–16,000 yr B.P., these glaciers achieved their greatest Late Wisconsin extent. Radiocarbon ages of late-glacial and postglacial sediments from Queen Charlotte Sound, Hecate Strait, and adjacent land areas show that deglaciation began in these areas before 15,000 yr B.P. and that the shelf was completely free of ice by 13,000 yr B.P.  相似文献   

11.
In the Thames Estuary at the eastern end of Long Island Sound, most mussels achieve maximal gonadal development during the summer and larval settlement occurs primarily during the fall. The timing of reproductive events is several months later than has been reported for other populations of mussels in Long Island Sound but corresponds to that of mussels inhabiting the south shore of Long Island. The data support the growing body of evidence which indicates that temperature is not a major factor determining the reproductive period of this bivalve.  相似文献   

12.
Core HU97048‐007PC was recovered from the continental Labrador Sea slope at a water depth of 945 m, 250 km seaward from the mouth of Cumberland Sound, and 400 km north of Hudson Strait. Cumberland Sound is a structural trough partly floored by Cretaceous mudstones and Paleozoic carbonates. The record extends from ～10 to 58 ka. On‐board logging revealed a complex series of lithofacies, including buff‐colored detrital carbonate‐rich sediments [Heinrich (H)‐events] frequently bracketed by black facies. We investigate the provenance of these facies using quantitative X‐ray diffraction on drill‐core samples from Paleozoic and Cretaceous bedrock from the SE Baffin Island Shelf, and on the < 2‐mm sediment fraction in a transect of five cores from Cumberland Sound to the NW Labrador Sea. A sediment unmixing program was used to discriminate between sediment sources, which included dolomite‐rich sediments from Baffin Bay, calcite‐rich sediments from Hudson Strait and discrete sources from Cumberland Sound. Results indicated that the bulk of the sediment was derived from Cumberland Sound, but Baffin Bay contributed to sediments coeval with H‐0 (Younger Dryas), whereas Hudson Strait was the source during H‐events 1–4. Contributions from the Cretaceous outcrops within Cumberland Sound bracket H‐events, thus both leading and lagging Hudson Strait‐sourced H‐events. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

13.
Winter flounder (Pseudopleuronectes americanus) were sampled from three sites located near Norwalk, New Haven, and Niantic, Connecticut, in Long Island Sound during February 1987, to evaluate the degree of chemical contamination and to determine possible effects of contaminant exposure. At each site, sediment and infaunal invertebrates were also collected and analyzed for trace metals and organic chemicals. Specimens of liver and kidney from winter flounder were examined for histopathological conditions, including the presence of macrophage aggregates in liver tissue. Liver samples were also analyzed for DNA damage (i.e., the formation of adducts between DNA and chemical contaminants). Blood samples were collected and analyzed for erythrocyte micronuclei. The sampling site near New Haven was determined to be the most affected site, from the standpoints of greater chemical contamination and possible effects on winter flounder. Concentrations of aromatic hydrocarbons (AHs) and polychlorinated biphenyls (PCBs) were highest in sediment from this site, and the highest prevalences of the histopathological changes and DNA alterations were also found in the livers of winter flounder from this site. No differences in the concentrations of contaminants in fish or in frequencies of erythrocyte micronuclei in fish blood were found between sites. None of the sites sampled had contaminant levels or prevalences of lesions as high as previously found at other East Coast locations (e.g., Boston Harbor, Massachusetts, Raritan Bay, New York). Overall, our results indicate moderate levels of pollution at two of the urban sites in Long Island Sound and provide a framework for expanded studies to better define the extent and impact of chemical pollution in Long Island Sound.  相似文献   

14.
渤海湾西岸全新世沉积速率对河流供给的响应   总被引：2，自引：1，他引：1  
渤海湾西岸由北向南获取了3个钻孔,以全新世海相岩心为研究对象,采用AMS14C(Accelerator Mass Spectrometry14C,加速器质谱14C)测年方法建立年代框架并计算平均沉积速率,结合沉积物粒度组成及沿岸古河流三角洲发育历史,探讨了沉积速率对沿岸河流供给变化的时空响应。结果表明,早全新世—中全新世初期(11~6ka),渤海湾西岸整体沉积速率偏低,仅0.03~0.07cm/a,沉积物粒度较粗;中全新世6.43~4.97ka cal BP期间,NP3孔平均沉积速率为0.60~0.93cm/a,高于同期沿岸南部的CH110孔和BT113孔。沉积物组成以粉砂为主,粘土含量低,向上逐渐变粗,具三角洲反粒序特征。该时段的高沉积速率系渤海湾西北岸对潮白河、永定河及滦河沉积物供给的响应;中全新世晚期3.68~2.67ka cal BP期间,BT113孔沉积速率为0.27~1.4cm/a,高于同期沿岸北部CH110孔和NP3孔,沉积物组成以粉砂为主,粘土含量较NP3孔高,向上逐渐变粗,具三角洲反粒序特征。该时段的高沉积速率系渤海湾西岸南部对黄河沉积物供给的响应;晚全新世2.29~0.24ka cal BP期间,沿岸中部CH110孔沉积速率为0.55~0.91cm/a,高于同期沿岸南部的BT113孔和北部的NP3孔,该高沉积速率为渤海湾西岸中部对黄河和海河供给沉积的先后响应。  相似文献   

15.
Near-bottom hypoxia during summer months has been a documented recurring phenomenon for decades in western Long Island Sound (WLIS); this temperate estuary has also supported, until 1999, a substantial American lobster (Homarus americanus) fishery. In response to a dramatic mass die-off of lobsters that began in WLIS in the late summer of 1999, a benthic habitat survey using a sediment-profile imaging (SPI) camera was conducted in October 1999. Follow-up surveys involving SPI and simultaneous measurements of dissolved oxygen (DO), hydrogen sulfide and ammonia within 10 cm of the bottom were conducted in August, September and November 2000. The SPI images revealed black sediments at or just below the sediment-water interface at a high proportion of stations in both 1999 and 2000, suggesting strongly reducing conditions and elevated levels of sulfides and other reduced end-products in sediment pore-water. Visual redox depths were relatively shallow (less than 2 cm) and spatially variable, and benthic communities appeared to be dominated by small, surface-dwelling opportunists. In August 2000, near-bottom DO concentrations < 2 mg I−1 coincided with shallow redox depths at stations in the Western Narrows region. As DO levels increased from August to November 2000, visual redox depths remained shallow. Both sulfide and ammonia were detected in samples of bottom water taken within about 10 cm of the seafloor in all three 2000 surveys. The results suggest that anaerobic decomposition processes within the organic-rich sediments of WLIS strongly influence conditions at the sediment-water interface during late summer-early fall, the time of year that the lobster mortality event of 1999 began. Releases of reduced end-products (e.g., sulfide and ammonia) into overlying waters, combined with low DO levels and abnormally high water temperatures, represent multiple environmental stressors that may have physiologically weakened the lobsters and increased their susceptibility to deadly pathogens.  相似文献   

16.
During Cruise 62nd of the R/V “Professor Gagarinsky” in September, 2014, the carbonate system of sediments and contents of nutrients and organic carbon in pore water were studied in two geochemical stations located in hypoxia areas in the Peter the Great Bay. It was established that the concentrations of silica, phosphorus, and ammonium increase by 5, 10, and 20 times, respectively, with sediment depth to 70–80 cm. The alkalinity, dissolved inorganic carbon, and the partial pressure of carbon dioxide significantly increase with depth, while рН value and organic matter (ОM) decrease. Changes in the chemical composition of pore water with sediment depth (0–80 cm) are caused by anaerobic microbial degradation of OM, concentration of which in the top sediment layer is 2–3%. The degradation products of OM in the bottom waters of bay and pore waters of bottom sediments indicate that its main sources are diatoms. During hypoxia, the oxygen demand rate by sediment surface near Furugelm Island is estimated to be 5 mmol/(m2 day). A combination of such factors as downwelling circulation, the absence of photosynthetically active radiation, and the high oxygen demand rate at the water/sediment interface provides hypoxia formation in the depressions of the Peter the Great Bay bottom topography.  相似文献   

17.
Significant improvements in water quality have been observed for several decades throughout much of the Hudson-Raritan Estuary, primarily as a result of regional abatement of municipal and industrial discharges. These improvements include area-wide, order-of-magnitude reductions in ambient coliform concentrations and significant increases in dissolved oxygen (DO) concentrations. In contrast to these improvements, DO in bottom waters of the western Long Island Sound (WLIS) appears to have decreased in the last two decades. Although there is no consensus as to why hypoxia in WLIS may have recently become more severe, several related hypotheses have been suggested, including an increase in eutrophication, increased density stratification, and changes in wastewater loads. To determine if eutrophication has increased in WLIS, trends in several indicators of eutrophication were examined from a long-term water quality data set. Since the mid-1980s surface DO supersaturation has increased, bottom minimum DO has decreased, and vertical DO stratification has increased in WLIS. Other areas of the Hudson-Raritan Estuary, such as Jamaica Bay and Raritan Bay, exhibit similar evidence of declining water quality and may be experiencing increasing eutrophication. Temporal changes in vertical density stratification indicate that surface to bottom temperature differences have increased to a greater extent and have had a more significant impact on bottom DO depletion in WLIS than in the shallower Jamaica Bay and Raritan Bay. Additional factors contributing to the observed decline in water quality include recent changes in wastewater loads and possible increases in upstream and nonpoint source loads.  相似文献   

18.
A material balance is constructed for excess 210Pb (relative to 226Ra) as a test of the retentivity of Long Island Sound for a reactive heavy metal. Excess 210Pb is supplied to Long Island Sound chiefly by direct atmospheric deposition [1 ± 0.2(dis·min?1)cm?2·yr?1]. Rivers supply less than 20% of the atmospheric flux, and other inputs, from open ocean waters, 226Ra decay, groundwater seepage, and sewage discharge, appear to be negligible. The total input of excess 210Pb represents approximately the flux required to maintain the inventory of excess 210Pb measured in sediment cores from central Long Island Sound; that is, excess 210Pb is lost from Long Island Sound chiefly by radioactive decay. The retention of excess 210Pb within Long Island Sound is achieved in two steps: a rapid removal of soluble 210Pb onto suspended particles and the ongoing entrapment of particles in the basin by the residual bottom-water influx from the east.  相似文献   

19.
Current meter data were acquired in Long Island Sound over a period of about 6 mo in 1988 at six different transects. The averages of the low-passed residuals represent the contributions from tidal steering and density forcing. It is found that the long-term residual circulation starts out with a classical estuarine pattern at the Race. The flows into and out of the Sound are vertically partitioned by Long Sand Shoal; they gradually revert back to classical vertically layered estuarine circulation as the Central Basin is traversed. Further west, the bottom oceanic water becomes a westward flowing swift jet close to the Connecticut shore, while the East River water is constrained to flow eastward along the Long Island coast. Counterclockwise gyres, identified in the Eastern Narrows and Western Basin, may increase residence times of polluted East River water in the western Long Island Sound.  相似文献   

20.
Three units, correlatable with recent Lake Champlain, late-glacial marine Champlain Sea, and proglacial Lake Vermont sediments, have been identified from about 200 km of high-resolution seismic reflection profiles and eight piston cores collected in southern Lake Champlain. Lake Vermont deposits are nonfossiliferous and range from thin to absent nearshore and on bedrock highs to more than 126 m thick near Split Rock Point. Champlain Sea sediments contain marine foraminifers and ostracodes and are fairly uniform in thickness (20–30 m). Recent Lake Champlain sediments range in thickness from 0 to 25 m. Average sedimentation rates for Lake Vermont are considerably higher (4–8 cm/yr) than those for the Champlain Sea (0.8–1.2 cm/yr) and Lake Champlain (0.14–0.15 cm/yr). Bedrock, till, and deltaic and alluvial deposits were also identified on the acoustic records but were not sampled. An unconformity separating Champlain Sea deposits from Lake Champlain deposits is associated with numerous benches at water depths of 20–30 m. These benches, the alluvial deposits, and the onset of deltaic deposition are probably associated with a low water level stillstand at the close of the Champlain Sea episode.  相似文献   

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