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1.
Geological and geochemical constraints on the genesis of the Xiangquan Tl-only deposit,eastern China
The Xiangquan Tl deposit, located in the northern part of the Middle–Lower Yangtze Valley metallogenic belt, eastern China, is the only known Tl-only deposit. It is hosted in micritic limestone, marl and mudstone of the Lower Ordovician Lunshan Formation. The orebodies are controlled by the Xiao–Xiaolongwang–Dalongwang anticline and two reverse faults, and are generally stratabound and lenticular. Tl is only ore metal contained in disseminated, massive, brecciated and banded ores. The ore is composed of Tl-bearing pyrite, and gangue minerals quartz, fluorite, barite and carbonate. Alteration minerals include fluorite, barite, fine grained quartz and carbonate. Tl occurs isomorphously replacing iron in the lattice of pyrite, and less commonly as tiny independent Tl-bearing minerals which may be lafossaite (TlAsS2) or lorandite (TlCl) appearing as 0.1–1 μm-sized cubic crystals. Xiangquan is a submarine sedimentary deposit and demonstrates that Tl, as a normally dispersed element, can form not only part of poly-metallic deposits but also as independent Tl deposits. 相似文献
2.
分散元素铊成矿作用的相关研究近年来已经取得了重要进展,但矿床中铊的赋存状态研究仍有待深入.香泉独立铊矿床位于长江中下游成矿带北侧的皖东地区,该矿床中铊的赋存状态研究对拓展铊元素成矿研究具有重要意义.本文通过矿相学、微量元素地球化学、电子探针分析和X射线粉晶分析等方法,确定了香泉铊矿床中黄铁矿是铊的主要载体矿物.铊在黄铁矿中主要以类质同象形式替代铁进入黄铁矿晶格,其次以纳米级、次纳米级铊矿物颗粒形式产出. 相似文献
3.
云南富乐铅锌矿床黄铁矿微量(稀散)元素组成及成因信息:LA-ICPMS研究 总被引：2，自引：2，他引：0
川滇黔铅锌矿集区是华南大面积低温成矿域的重要组成部分,区内铅锌矿床是否属于MVT型矿床长期存在争议。该区铅锌矿床以富集Ge等稀散元素为特征,闪锌矿是其主要载体矿物,但稀散元素在黄铁矿中是否富集、赋存状态及微量元素组成特征等研究基本属于空白。本文通过LA-ICPMS研究富乐黄铁矿中微量元素(尤其是稀散元素)的富集特征,发现黄铁矿中也相对富集Ge。本研究样品选自富乐矿床的富乐和富盛两个矿段,包括1350、1410和1536三个中段(由深到浅),LAICPMS分析结果表明,该矿床黄铁矿以富集Cu、As、Co、Ni为特征,局部富集Pb(Sb)和Zn(以方铅矿和闪锌矿显微包裹体形式赋存于黄铁矿中),该类黄铁矿富集的稀散元素主要为Se、Ge及少量Tl、Te,而Cd和In以类质同象形式赋存于含Zn的显微包裹体(闪锌矿)中,类质同象是其余稀散元素主要赋存形式,且黄铁矿中Ge与Cu存在较好相关关系,可能存在Cu~(2+)+Ge~(2+)?2Fe~(2+)耦合置换方式。此外,黄铁矿中稀散元素的富集与成矿元素(特别是Cu)的富集密切相关,随着成矿作用的进行,从矿体深部到浅部,成矿温度逐渐降低,Se/Te比值逐渐升高,且稀散元素与成矿元素呈逐渐增加趋势。研究表明,该矿床黄铁矿的Co/Ni比值基本都小于1. 00,暗示其属于沉积改造型黄铁矿,在Co-Ni和稀散元素Se-Tl含量投影图上,富乐矿床黄铁矿的投影点与MVT型矿床投影区基本一致,而明显有别于SEDEX、VMS和矽卡岩型矿床中黄铁矿的投影区,结合富乐矿床类似于MVT型的地质特征,我们认为富乐矿床属于MVT型铅锌矿床。 相似文献
4.
安徽和县香泉独立铊矿床的地质地球化学特征及成因探讨 总被引：7，自引：2，他引：7
安徽和县香泉铊矿床位于长江中下游成矿带北侧的皖东地区,是目前为止发现的罕见独立铊矿床。和县地区位于扬子板块、华北板块和大别造山带之间的过渡带,区内无岩浆岩出露。矿床的赋矿围岩为奥陶系下统仑山组微晶灰岩、泥灰岩和泥岩,主要控矿构造为断裂和褶皱。矿床主要由一个矿体组成,矿体总体上为似层状和透镜状,分布与地层走向大体一致。矿床中铊高度富集,黄铁矿是铊的主要载体矿物,铊主要以类质同象形式替代铁进入黄铁矿晶格,其次以纳米级、次纳米级铊矿物颗粒形式产出。矿床的围岩主要蚀变类型有萤石化、重晶石化、硅化和碳酸盐化等。矿床的地质地球化学特征研究表明,铊矿床的形成经历了两个成矿期,即海底热水沉积成矿期和低温热液改造成矿期。奥陶纪海底热水形成含铊黄铁矿建造,早白垩纪低温成矿流体对黄铁矿建造进行叠加改造,并使铊进一步活化富集。香泉铊矿床的发现和研究表明,分散元素铊不仅可以富集形成伴生型多元素矿床,还可以形成单一元素的独立铊矿床。 相似文献
5.
T. F. Zhou Y. Fan F. Yuan M. A. Wu M. J. Hou G. Voicu Q. H. Hu Q. M. Zhang S. C. Yue 《Mineralogy and Petrology》2005,85(3-4):243-251
Summary Here we report the first example of a thallium-only deposit, which was discovered in the northeast margin of the Yangtze block,
eastern China, in the transition zone between the Yangtze Block, North China Block and Dabie orogenic belt. Ore from the Xiangquan
deposit will be mined, ore-dressed and smelted independently for thallium. The ore deposit is hosted in Lower Ordovician micrite,
calcilutite and marl within the Dalongwang Mountain Xiao Mountain anticline. The ore zones are fold and fault controlled.
Thallium occurs mainly in pyrite but minor amounts form as lorandite (TlAsS2) and hutchinsonite (TlFeS2). Fluid inclusion studies of two stages of fluorite intimately associated with ore-forming pyrite yielded homogenization
temperatures of 120 to 220 °C with a salinity of 1.5 to 6.0 equivalent wt.% NaCl. Thallium was originally derived by hydrothermal
emanations onto the sea floor and deposited in calcareous sediments. Subsequently in the Early Cretaceous (Yanshanian period)
these source beds were reworked to form thallium enriched minerals in hydrothermal veins. 相似文献
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7.
左家庄金矿位于西秦岭凤太盆地西北部,金矿体赋存在印支早期何家庄岩体的东西向剪切破碎带内。矿石类型以石英硫化物脉型为主,与西秦岭地区沉积岩控矿为主的特征有显著的差别。流体包裹体测温及成分分析表明,左家庄金矿成矿流体具有含CO2、中低温(122~305 ℃)、低盐度(1.2%~11.8% NaCleq)、浅成(约2.4 km)热液的特征。H-O同位素组成(δDH2O集中在-88.8‰~-81.1‰;δ18OH2O在-0.4‰~+7.6‰)显示成矿初始流体以变质水为主,随着流体向上运移不排除有岩浆水和大气降水的加入。Pb同位素组成显示成矿物质来源于浅部上地壳及造山带内;S同位素组成集中(11.4‰~13.4‰),与凤太盆地内泥盆系沉积岩控金矿相似,且与全球范围内泥盆系控矿造山型金矿组成吻合,反映出泥盆系地层为成矿提供了硫源;热液期黄铁矿原位微量元素分析显示左家庄金矿成矿流体富集Au、As、Cu、Sb、Ag、Pb、Bi等元素,该元素组合与前人分析凤太盆地内泥盆系地层(尤其是中、上泥盆统界面)富集元素特征一致。上述分析一致表明泥盆系地层是左家庄金矿成矿物质来源理想场所。多元同位素对比分析表明,左家庄金矿与凤太盆地内其他金矿在成矿流体及成矿物质来源上具有统一性,但是在矿化形式上有显著区别,其差异可能与二者赋矿围岩性质不同有关。成矿流体沿断裂向上运移过程中,当遇到上泥盆统渗透性较高的千枚岩时发生水岩反应,形成以微细浸染状矿化为主的金矿;当碰到岩体内脆性剪切破碎带时,由于压力释放,流体沸腾,导致矿质迅速沉淀在张性破碎带内,形成石英硫化物脉型左家庄金矿。通过与典型造山型金矿成矿特征对比分析,认为左家庄金矿可划归为浅成造山型金矿床。 相似文献
8.
Shuiyindong is one of the largest and highest grade stratabound Carlin-type gold deposits in China. This paper reports on the results of petrographic studies, electron microprobe analyses (EMPA) of arsenian pyrite, and the mass transfer during mineralization and alteration, and it presents the deposit-scale distributions of Au, As, Sb, Hg, Tl, and trace elements in a representative cross section across the Shuiyindong Carlin-type gold deposit, Guizhou Province. The main objectives were to identify the precipitation mechanisms of minerals, or elements from fluids, and the migration paths of ore-forming fluids.Petrographic and EMPA studies indicate that gold in the primary ores is mainly hosted by arsenian pyrite. Mass transfer associated with alteration and mineralization shows that Au, As, Sb, Hg, Tl, and S were significantly added to all mineralized rocks, Fe2O3 and SiO2 were immobile in the main orebodies that are hosted in bioclastic limestone, and CaO, Na2O, Sr, and Li were removed from country rocks. The relations between Fe and S indicate that the sedimentary rocks at the Shuiyindong deposit contain more iron than is needed to combine with all of their contained sulfur to form pyrite. This suggests that sulfidation and decarbonation were the principal mechanism of gold precipitation at the Shuiyindong deposit. Hg, Sb, and As commonly formed sulfide minerals, such as stibnite, realgar, and orpiment, in late-stage quartz–calcite veins, or absorbed by organic matter in argillite. Fluid cooling presumably led to depositions of stibnite, realgar, and orpiment in late-stage quartz–calcite veins. Organic matter likely served as a reductant in argillite for the ore fluids, causing the precipitation of As, Sb, Hg, and S, as well as Au.Deposit-scale distributions of gold and other relevant elements reflect the passage of fluids through the rocks. Rock strata and structures allowed the ore-forming fluids to migrate horizontally along the unconformity surface of the Middle–Upper Permian, converge on the high position of an anticline, and then ascend into the overlying strata along the anticlinal axis. The distributions of the major and trace elements show that elements that accompanied the ore-forming fluids include Au, As, Sb, Hg, Tl, and S, and that Na2O and Li were exhausted in the Longtan Formation at the anticlinal core during gold mineralization. The enrichment of Co, Cr, and Ni in the Longtan Formation at the anticlinal core might be associated with deformation that formed the anticline, or with gold mineralization. Different host rocks were preferentially mineralized by different elements. The bioclastic limestone is commonly enriched in Au, whereas the argillite is preferentially enriched in As, Hg, Sb, and Tl. The zonation of ore-forming elements in the deposit appears to be Sb–Tl–As–Hg–Au–Hg–As (from bottom to top). Enrichment of Au, As, Sb, Hg, and Tl provides useful guidance for the exploration for Carlin-type gold deposits in Guizhou. Anomalies of As and Hg in soil or stream sediment might be an important clue and these elements can be used as indicator elements. Ore-forming fluids migrated along the unconformity surface of the Middle–Upper Permian and the anticlinal axis, so these are favorable sites for exploration for Carlin-type gold deposits in Guizhou. 相似文献
9.
西藏柯月Pb-Zn-Sb-Ag多金属矿床位于雅鲁藏布江缝合带（IYS）与藏南拆离系（STDS）之间的北喜马拉雅成矿带。该矿床经详查验证,4 300 m以浅的矿体赋存于日当组钙质板岩夹薄层泥晶灰岩中,严格受北东向断裂控制,但深部延伸不明。本文通过该矿床I号矿体原生晕地球化学特征分析,对此问题进行初步探讨。研究表明,前缘晕元素为Hg、As、Tl,近矿晕元素为Pb、Zn、Sb、Ag、Au、Cd、Cu、Mn,尾晕元素为Sn、In、Bi;采用改良的格里戈良分带指数法计算分带序列为In-Mn-As-Cu-Zn-Cd-Bi-Pb-Sn-Hg-Tl-Ag-Au-Sb,重心法计算分带序列为In-Mn-As-Cu-Cd-Zn-Hg-Bi-Sn-Pb-Ag-Sb-Tl-Au;同时,讨论原生晕地球化学参数变化规律,并以各元素的几何平均值累乘比建立矿体的剥蚀参数模型及矿体原生晕叠加理想模型。综合以上分析,推测矿床有多次成矿作用叠加,上部存在剥蚀至尾部的矿体,而深部可能有矿体延伸。 相似文献
10.
豫西银家沟硫铁多金属矿床Re-Os和40Ar-39Ar年龄及其地质意义 总被引：4，自引：1，他引：3
河南省银家沟硫铁多金属矿床位于华北克拉通南缘的华熊地块内,是东秦岭地区最大的硫铁多金属矿床,以其硫铁矿储量大及共、伴生元素复杂区别于东秦岭其他以钼为主的矿床.矿化在空间上呈规律性的带状分布,从岩体内向外,依次出现斑岩型钼矿体→斑岩型硫铁矿体→矽卡岩型铁矿体、钼矿体→矽卡岩型硫铁、铜、锌、金矿体→脉型铅、锌、银矿体.选取5件接触带矽卡岩型钼矿体中的辉钼矿样品进行Re-Os同位素定年,获得(142.9±2.1) Ma～(143.7±2.3) Ma的模式年龄,加权平均值为(143.4±0.9) Ma(MSWD=0.071),等时线年龄为(140.0±18.0) Ma(2σ,MSWD=0.095),将(143.4±0.9) Ma认作辉钼矿的结晶年龄,表明银家沟矿床矽卡岩型矿体形成于约143 Ma前;选取1件硅化、绢云母化、黄铁矿化、辉钼矿化钾长花岗斑岩中的绢云母样品定年,获得40Ar-39Ar坪年龄为(143.6±1.4) Ma,相应的39 Ar/36 Ar-40 Ar/39Ar等时线年龄为(143.0±2.0) Ma(MSWD=0.13),将(143.0±2.0)Ma认作绢云母的Ar封闭年龄,表明银家沟矿床斑岩型矿化亦发生在约143Ma前.本次辉钼矿Re-Os和绢云母40Ar-39A定年结果表明,银家沟矽卡岩型和斑岩型矿体均形成于早白垩世初期.银家沟矿床辉钼矿的ω(Re)在38.5×10-6～43.2×10-6之间,成矿物质主要来自由火成物质组成的宽坪群和二郎坪群,成矿与矿区内的钾长花岗斑岩有关.结合前人对东秦岭造山带中生代期间地球动力学背景的研究成果,笔者认为银家沟矿床形成于EW向构造体制向NNE向构造体制大转换阶段,即形成于挤压体制向伸展体制转换的背景. 相似文献
11.
The Nature of Ore‐forming Fluids of the Carlin‐type Gold Deposit in Southwest China: A Case from the Zimudang Gold Deposit 
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下载免费PDF全文 The Zimudang gold deposit is a large Carlin‐type gold deposit in the Southwest Guizhou Province, China, with an average Au content of 6.2 g/t. Gold is mainly hosted in the fault zone and surrounding strata of the F1 fault and Permian Longtan Formation, and the ore bodies are strictly controlled by both the faults and strata. Detailed mineralogy and geochemistry studies are conducted to help judge the nature of ore‐forming fluids. The results indicate that the Au is generally rich in the sulfides of both ores and wall rocks in the deposit, and the arsenian pyrite and arsenopyrite are the main gold‐bearing sulfides. Four subtypes of arsenian pyrite are found in the deposit, including the euhedral and subhedral pyrite, framboidal pyrite, pyrite aggregates and pyrite veins. The euhedral and subhedral pyrite, which can take up about 80% of total pyrite grains, is the dominant type. Au distributed unevenly in the euhedral and subhedral pyrite, and the content of the Au in the rim is relatively higher than in the core. Au in the pyrite veins and pyrite aggregates is lower than the euhedral and subhedral pyrite. No Au has been detected in the points of framboidal pyrites in this study. An obvious highly enriched As rim exists in the X‐ray images of euhedral pyrites, implying the ore‐forming fluids may be rich in As. The relationship between Au and As reveals that the Au may host as a solid solution (Au+) and nanoparticles of native gold (Au0) in the sulfides. The high Co/Ni ratio (>1) of sulfides and the enrichment of W in the ores all reflect that the gold‐bearing minerals and ore‐forming process were mainly related to the hydrothermal fluids, but the magmatic and volcanic activities cannot be neglected. The general existence of Au and As in the sulfides of both ores and wall rocks and the REE results suggest that the ore‐forming fluids may mainly be derived from the basin itself. The enrichment of Tl suggests that the ore‐forming fluids may be enriched in Cl. The Ce and Eu show slightly or apparently negative anomalies, which means the ore fluids were probably formed under reducing environment. The Y/Ho ratios of ore samples fluctuate around 28, implying the bicarbonate complexation and fluorine were both involved in the ore‐forming process. Combined with the previous studies and our results, we infer that the ore‐forming fluids enriched Au, As, HS? and halogen (F, Cl) were derived from the mixture of reducing basinal fluids and magmatic or volcanic hydrothermal fluids. 相似文献
12.
甘肃阳山金矿床微量元素及稳定同位素的地球化学研究 总被引：24，自引：1，他引：24
甘肃省阳山金矿位于川陕甘交界地带 ,为近年发现的一特大微细浸染型金矿床。该矿目前已发现 4个矿段 ,均赋存于浅变质的泥盆系地层中。矿体在平面上呈舒缓波状 ,在剖面上为脉状、似层状。矿石中金属矿物主要为黄铁矿和毒砂 ,金主要以微细粒金 (2～ 3μm)包裹于毒砂、黄铁矿及粘土矿物之中。矿床微量元素含量研究表明 ,矿石中Au、Hg、As、Bi、Sb等元素较为富集 ,并且其间呈明显的正相关关系 ,显示阳山金矿的形成与富含Au、Hg、As、Bi、Sb等低温热液元素的成矿流体活动有关 ,向深部这些元素含量趋于降低 ,表明成矿流体活动趋弱。矿石石英的δD值为 - 6 0‰～ - 72‰ ,δ18OH2 O值为 8 0‰～ 10 1‰ ,表明成矿流体主要为岩浆热液 ;矿石黄铁矿的δ3 4 S值为 - 2 2‰～ - 0 7‰ ,不同于泥盆系地层中沉积黄铁矿的δ3 4 S值 (10 9‰ ) ,表明矿石硫为岩浆硫 ,因而阳山金矿床的形成与岩浆热液活动密切相关 相似文献
13.
Farahnaz Daliran 《Mineralium Deposita》2008,43(4):383-404
The disseminated gold deposit of Agdarreh (24.5 t at 3.7 g/t Au) is hosted in hydrothermally leached Miocene reefal limestone
in the Takab geothermal field, which is part of the Cenozoic Urumieh–Dokhtar volcanic arc of NW Iran. Alteration and mineralisation
are largely bedding controlled blanket-like and include: (1) pre-ore decalcification; (2) first-stage silicification associated
with pyrite (early pyrite with 3–4 wt% As, late pyrite with <1–3 wt% As) and sphalerite; (3) second-stage silicification with
precipitation of galena, Pb–Sb–As sulphides, sulphosalts, tellurides and native bismuth; (4) late-stage cinnabar and barite
in vugs; (5) oxide ore stage and carbonate alteration (complex Mn–Fe-rich oxyhydroxides, arsenates, sulphates, APS minerals
and rutile in residual leached rock and infill of karstic cavities). Gold occurs invisibly in the jasperoids and is enriched
in the Mn–Fe oxyhydroxide surface cap of the jasperoids. Gold mineralisation is associated with the hydrothermal metal suite
of As, Sb, Hg, Te, Se, Tl, Ba, Zn, Ag, Cd, Bi and Pb, and is characterised by very low Cu contents. Arsenian pyrite probably
carried most of the primary (invisible) gold. Native gold occurs in association with the late-stage cinnabar and the oxide
ore.
The Agdarreh deposit shows many similarities with Carlin-type ore and is interpreted to have resulted from near-surface hydrothermal
activity related to the Cenozoic arc volcanism that developed within the extensional Takab graben. The extensive oxidation
at Agdarreh may be partly due to the waning stages of hydrothermal activity. Active H2S-bearing thermal springs are locally depositing extremely high contents of Au and Ag, and travertine is present over large
areas, suggesting that ore-forming hydrothermal activity occurred periodically from the Miocene to Recent in the Takab geothermal
field.
The present paper deals with the geological framework, host rocks, characteristic features of hydrothermal alteration and
mineralisation, and genesis of the Agdarreh deposit. The results of fluid inclusion and stable isotope studies are in progress
and will be given in a forthcoming paper. 相似文献
14.
江西金山金矿含金黄铁矿的Rb-Sr年龄 总被引：6，自引：0，他引：6
前人对江西金山金矿的成矿时代有许多不同的认识,笔者通过对江西金山蚀变岩型矿石中的含金黄铁矿Rb-Sr年龄的测定得出,含金黄铁矿的Rb-Sr等时线年龄为(838±110)Ma,initial87Sr/86Sr=0.7045±0.0020。由此可以推测晋宁期是蚀变岩型金矿体形成的主要时期。黄铁矿Rb-Sr所得的Sr同位素初始比(87Sr/86Sr)i小于陆源硅酸盐的值(0.720),而与玄武岩的值(0.704)接近,结合前人有关的同位素及稀土、微量元素研究,笔者认为金山金矿变质岩型矿体的成矿物质源于变质围岩,成矿流体为来源于深部的变质水。 相似文献
15.
巴彦高勒银多金属矿是大兴安岭南段新发现的一例小型银多金属矿床,矿体多呈脉状、透镜状产于古元古界锡林郭勒杂岩中,受NE向断裂控制。矿石矿物主要有方铅矿、闪锌矿、黄铁矿、辉银矿、黝锑银矿等,脉石矿物主要有萤石、毒砂、石英、绿帘石、绿泥石等。围岩蚀变主要为褐铁矿化、硅化、高岭土化、黄铁矿化、绿泥石化、绿帘石化等。通过在该矿区开展1∶1万土壤地球化学测量,共圈定出编号为Ht-1至Ht-4的4个矿致组合异常区,并发现了对应的矿脉和蚀变带。根据矿体发育部位和围岩蚀变分带特征,推测成矿与热液活动有关,矿床成因为中低温热液型。通过分析成矿地质特征,得出该矿床浅表以褐铁矿化,深部以硅化、高岭土化为重要的找矿标志,北东向构造破碎带是重要的控矿构造,而1∶1万土壤地球化学测量成果圈出的Ag、Pb、Zn单元素地球化学异常及Ag-Sb-Sn-Cu-Pb-Zn组合异常是十分有效的化探标志。 相似文献
16.
冬瓜林金矿床位于哀牢山金矿带的镇沅金矿田。文章在野外地质工作的基础上,运用多元统计的方法,求得微量元素找矿标志;并根据地球化学各参数信息,计算出元素轴向分带序列,建立原生叠加晕理想模型,构建深部矿体预测指标,明确下一步的找矿方向。研究表明:(1)该矿床的成矿元素Au与元素Ni、Co、Cu、Mn、Sb、Sn关系密切,原生晕轴向分带序列从上到下为As-Bi-Mn-Pb-Sb-B-Sn-Cu-Co-Hg-Ni-Zn-Au-Ag-Mo;(2)矿体中前缘晕、尾晕共存现象明显,预示着矿体向下还有很大的延伸,深部找矿应在矿体的北东方向进行;(3)评价指标(B×As×Hg×Sb)D/(Mn×Ni×Co×Sn)D,是有效的预测深部矿体资源潜力指标。 相似文献
17.
豫西银家沟硫铁多金属矿床是与中酸性斑岩小侵入体具成因联系的大型热液交代型矿床;矿床赋矿地层主要为蓟县系龙家园组和巡检司组含燧石条带白云岩;矿床的成矿岩体呈复式微型岩株,中心相为钾长花岗斑岩,边缘相为石英闪长斑岩,岩体为超浅成侵入伴随隐爆作用的次火山相岩浆岩;矿床以硫铁矿为主体,共/伴生有铁、铜、钼、铅、锌、银、金等;矿体以透镜状为主,均为隐伏矿体;成矿分为磁铁矿-赤铁矿阶段、石英-辉钼矿阶段、石英-中粗粒黄铁矿阶段、黄铜矿-磁黄铁矿阶段;铅锌硫化物为最晚期产物。银家沟硫铁多金属矿床具有成矿物质多来源、成矿多阶段的特点。成矿岩体自身携带大量成矿元素,同时萃取了围岩中的多种成矿元素,在环境适合的条件下沉淀成矿。 相似文献
18.
塔东铁矿床与典型的沉积变质矿床相比,其具有特殊性。赋矿地层及矿体中黄铁矿分布广泛且含量高;不同矿体矿石品位表现出明显的差异。黄铁矿的电子探针分析反映有弱的S亏损,说明有热液成因的特点;S亏损程度低代表与岩浆作用有关的热液作用。黄铁矿Re-Os同位素年代反映塔东铁矿热液成矿作用发生于401 Ma±41 Ma,其与矿区西部黑云母斜长花岗岩年龄(407 Ma±28 Ma)极为相近;且塔东铁矿石品位w(mFe)值也因距离西部黑云斜长花岗岩的远近程度不同而表现出"东低西高、浅低深高"的特点。作者据此并结合前人研究成果将塔东铁矿床的成因总结为"海底火山喷发—区域变质—岩浆热液叠加富集成矿"。 相似文献
19.
对安徽新桥矿床进行系统的野外地质调查和矿相学研究发现,层状矿体中的胶状黄铁矿交代矽卡岩磁铁矿矿体,为探讨层状硫化物矿床是早期沉积成因还是岩浆热液成因提供了新的地质约束。对铜陵矿集区内的新桥矿床层状菱铁矿矿体和凤凰山矽卡岩型矿体中的菱铁矿开展了Fe同位素组成的对比研究,结果显示：新桥矿床菱铁矿与典型低温热液脉型矿床和沉积铁矿中的菱铁矿在Fe同位素组成特征上有所不同,而与凤凰山矽卡岩型矿床中的菱铁矿更为接近;新桥矿床中胶状黄铁矿和菱铁矿相对于磁铁矿富集Fe的轻同位素,表明磁铁矿不是过去认为的由胶状黄铁矿和菱铁矿矿胚层经热液改造形成,而是与典型的岩浆热液有关。新桥矿区层状硫化物矿体和矽卡岩型矿体中,近岩体矽卡岩和最早形成的金属矿物磁铁矿比岩体更为富集Fe的轻同位素,而赋矿围岩比岩体更为富集Fe的重同位素。同时,不同矿化阶段形成的含铁矿物和不同空间位置的硫化物中的Fe同位素组成呈现出时空分带现象,Fe同位素组成的时空演化特征与流体出溶、流体演化非常一致,并且符合同位素分馏的基本理论,表明层状硫化物矿体和矽卡岩型矿体具有相同的成矿物质来源,为同一流体体系演化的产物。新桥矿区岩相学的研究结果和Fe同位素组成特征均表明,新桥层状硫化物矿床不是海西期喷流沉积成矿作用的产物,而是燕山期热液成矿作用的产物,为一个典型的热液成因矿床。 相似文献
20.
迄今为止文献中未见有铂矿原生晕研究的报道,通过对大岩子矿区地表和不同中段坑道原生晕的研究,发现在铂-钯矿体周围有清晰的F、Sb、Cd、Hg、As、Ag、Au、Pd、Pt、Cu、Ni元素的原生晕,其中F、Sb、Cd、Hg、As为前缘指示元素,Au、Ag为近矿指示元素,Pt、Pd、Cu、Ni为成矿指示元素.元素的垂直分带序列为(地表至矿体):(F、Sb、Cd、Hg、As)-(Ag、Au)-(Pd、Pt)-(Cu、Ni).地表岩石地球化学测量发现的Ⅲ号Pd、Pt异常带,具有多元素异常组合特征,判断为矿致异常,推测在该异常带下方可望找到隐伏矿体.坑道原生晕研究发现,在PD4中段出现浓集中心醒目、浓度分带清晰的F原生晕,推测在PD4中段下方可能存在新的盲矿体. 相似文献