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1.
山东黄河冲积平原区是山东省地氟病的重病区,危害严重。选择其中的郓城、嘉祥、博兴3县进行土壤氟含量、饮水氟含量、儿童尿氟、儿童氟斑牙检出率、氟斑牙指数、成人尿氟、成人氟骨症检出率等指标进行调查,结果表明区内土壤、饮水氟含量和群体的尿氟含量普遍较高,高氟的危害和地方性氟中毒病情十分严重。在分析氟元素在土壤、饮水中的分布及变化规律的基础上,开展地方性氟中毒病与生态地球化学环境相关性研究,认为地方性氟中毒病与土壤中氟含量、饮水氟含量呈正相关关系。  相似文献   

2.
Hydrogeochemical investigations were carried out in the Dashtestan, the eastern part of Borazjan, with a focus on fluoride content. The study area is underlain by a complex geology that is dominated by three lithological units, namely marl, alluvial sediments, and carbonate rocks. To assess the major geochemical factors controlling the fluoride enrichment in water, 37 groundwater and 12 surface water samples were collected from the three lithological units. Fluoride concentrations ranged up to 3?mg/L, and average concentrations varied from 1.12 (in carbonate aquifers) to 1.73 (in alluvial aquifers) to 1.82?mg/L (in marl aquifers). To study the influence of rocks and soils on groundwater quality, an additional 41 soil and rock samples were also taken and analyzed for fluoride. The order of average fluoride content in both rocks and soils is: marl?>?alluvial sediments?>?limestone, which confirms that marl is a likely source of fluoride.  相似文献   

3.
Thermal water samples from Yellowstone National Park (YNP) have a wide range of pH (1-10), temperature, and high concentrations of fluoride (up to 50 mg/l). High fluoride concentrations are found in waters with field pH higher than 6 (except those in Crater Hills) and temperatures higher than 50 °C based on data from more than 750 water samples covering most thermal areas in YNP from 1975 to 2008. In this study, more than 140 water samples from YNP collected in 2006-2009 were analyzed for free-fluoride activity by ion-selective electrode (ISE) method as an independent check on the reliability of fluoride speciation calculations. The free to total fluoride concentration ratio ranged from <1% at low pH values to >99% at high pH. The wide range in fluoride activity can be explained by strong complexing with H+ and Al3+ under acidic conditions and lack of complexing under basic conditions. Differences between the free-fluoride activities calculated with the WATEQ4F code and those measured by ISE were within 0.3-30% for more than 90% of samples at or above 10−6 molar, providing corroboration for chemical speciation models for a wide range of pH and chemistry of YNP thermal waters. Calculated speciation results show that free fluoride, F−, and major complexes (, AlF2+, and ) account for more than 95% of total fluoride. Occasionally, some complex species like , FeF2+, , MgF+ and may comprise 1-10% when the concentrations of the appropriate components are high. According to the simulation results by PHREEQC and calculated results, the ratio of main fluoride species to total fluoride varies as a function of pH and the concentrations and ratios of F and Al.  相似文献   

4.
A study was undertaken to examine the content and spatial distribution of fluoride in drinking water. Water samples (735) from public water systems covering all Estonian territory were analysed using SPADNS method. In order to specify the natural source of fluoride, the chemistry data from five aquifer systems utilised for water supply were included into the study. Fluoride concentrations in tap water, to a great extent, ranged from 0.01 to 6.95 mg/l. Drinking water in southern Estonia, where terrigenous Middle-Devonian aquifer system is exploited, has a fluoride concentration lower than recommended level (0.5 mg/l), thus promoting susceptibility to dental caries. The western part of the country is supplied by water with excess fluoride content (1.5–6.9 mg/l). Groundwater abstracted for drinking purposes originates from Ordovician and Silurian carbonate rocks. The content of fluoride in Silurian–Ordovician aquifer system is associated with the groundwater abstraction depth and the main controlling factors of dissolved fluoride are the pH value and the chemical type of water.  相似文献   

5.
氟是维持人体健康所必需的微量元素,过多或过少的摄入都会造成相应的健康问题。本研究从氟的来源、迁移和富集等角度,揭示了内蒙古呼和浩特市托克托县高氟地下水的空间分布规律及其在潜水和承压水中富集的原因。对研究区60个水样(30个潜水和30个承压水)进行了统计分析、水化学特征研究、聚类分析以及相关性分析。结果表明：潜水中F- 浓度为0.40~7.20(2.30±1.80) mg/L,承压水中F- 浓度为0.29~12.70(1.67±2.48) mg/L;地下水中F-浓度与HCO-3、Na+、溶解性总固体(TDS)和电导率(EC)呈正相关,与Ca2+呈一定的负相关关系。高氟水的水化学类型主要为HCO3·Cl-Na型。受地下水流场的控制,高氟潜水(>5 mg/L)主要分布在地下水的排泄区;承压水中F- 的富集主要受含水层岩性的影响,氟高浓度(>1.5 mg/L)分布区主要集中在研究区南部的湖积台地区域。  相似文献   

6.
Groundwater samples were collected from Mettur taluk of Salem district, Tamilnadu, India for two different seasons (pre-monsoon and post-monsoon) and analyzed for fluoride ion along with other chemical parameters. The major litho units of the study area are Charnockites, peninsular gneiss, and calc gneiss of meta-sedimentary group. The fluoride concentration ranges from 0.1 to 2.8?mg/L and 0.4 to 4.0?mg/L during pre-monsoon (PRM) and post-monsoon (POM) seasons, respectively. Results showed that collected water samples were contaminated by the presence of fluoride ion. During PRM and POM, 21% and 56% of samples recorded higher fluoride when compared with Indian Drinking Water Standard (1?mg/L) and (9% and 35%) of samples recorded higher fluoride when compared with World Health Organization tolerance limit (1.5?mg/L). The ratio of Na/Ca indicates high sodium content in groundwater enhances the dissolution of fluoride at higher pH. Hydrogeochemical facies indicates water-rock interaction as main source for high fluoride in groundwater. A positive correlation between pH, Mg, and F indicates high alkaline nature of water promotes fluoride leaching from source rocks into ground water. Factor analysis indicates hydro-geochemical processes like weathering, ion exchange, and anthropogenic contributes to groundwater chemistry. The saturation index indicates dissolution and precipitation contributes fluoride dissolution along with mixing.  相似文献   

7.
The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.  相似文献   

8.
The aim of this paper was to explore new factors that might be reasons for the occurrence of fluoride-rich groundwater in the area around a construction site. During the construction of two deep shafts of the Mizunami Underground Research Laboratory (MIU) in Mizunami city, central Japan, a large quantity of groundwater with high fluoride concentration was charged into the shafts. Chemical investigation carried out during the excavation revealed that fluoride concentrations in the area around the MIU site greatly exceeded those prescribed by Japanese standards. Therefore, the origin of fluoride ion was experimentally investigated. Samples were collected from the core of a deep borehole drilled in the study area. The weathering - and alteration levels of the collected granites varied greatly. Granitic powders were used to measure fluoride content in the granitic rock mass. The fluoride content ranged between 200 and 1300 mg/kg. The powders were reacted with purified water for 80 days. The results of water–rock interaction showed granitic rock to be one of the main sources of fluoride-rich groundwater in Mizunami area. Fluoride concentrations in these solutions that were shaken for 80 days varied between 2 and 7 mg/l. This change may have occurred as a result of the spatial distribution of fluoride ions in the granite mass as evidenced by mineralogical analysis of fluoride content in several specimens. X-ray powder diffraction analysis of the rock before- and after the water–rock interaction tests manifested that the presence of fluorite mineral was relatively small compared to other minerals. The degree of weathering and alteration might be an additional factor causing dissolution of fluoride-rich minerals. However, it was difficult to interpret the change in fluorite composition by X-ray diffraction analysis.  相似文献   

9.
High fluoride content in the groundwater is reported from parts of the Gad River Basin, Sindhudurg district, coastal Maharashtra, India. The fluoride content of up to 5 mg/l has been found in the groundwater in laterite, basalt and the Precambrian basement (gneiss) aquifers in the region. The presence of high fluoride in groundwater well above the permissible levels for consumption poses a serious health threat to the rural populace in the region. The presence of tourmaline bearing pegmatites in the Precambrian basement is considered as a potential fluorine source. Deep circulation of fluoride rich groundwater between the latetritised basalts and the underlying crystalline basement could be responsible for the occurrence of fluoride in both the shallow and deeper aquifers of the region.  相似文献   

10.
This paper deals with mineral and thermomineral water occurrences of the Bujanovac valley in south eastern part of Serbia related to granitoides of the Bujanovac massif along both the margin and the floor of the valley. In past decades (1966–2010) numerous hydrogeological, hydrogeochemical and geophysical explorations were carried out. One of results of these explorations is the completion of test holes and exploratory—production wells. They provide groundwater for three water bottling factories: “Heba”, “Bivoda”, “Prohor” as well as the “Vrelo Bujanovac Banja Spa Centre” for rehabilitation, treatment, and prevention. All stated consumers use the same mineral water aquifer. The content of fluoride in the majority of examined mineral waters is higher than 4 mg/1, whereby they are singled out as typical fluoride waters. The content of calcium ions in them amounts 80 mg/1, and the values of the saturation index in relation to calcium fluoride (SI) range from 0.4 to 0.7 mg/1, which points to mineral waters saturated in relation to fluorite. However, in the study area, there are mineral water occurrences with the content of fluoride significantly lower than in the majority of analysed waters representing hydrochemical anomalies. These waters occur as hydrochemical anomalies in marl and sandstone wherein Secondary mineral water aquifers, originating from cracked granite of the Bujanovac massif, are formed. When mineral waters from granite (with the increased content of fluoride) reach these secondary aquifers, the content of fluoride ions lowers to about 1 mg/1, which is of great significance from the point of view of mineral water utilisation as table bottled water. In this paper, it is proved that, in addition to the presence of some minerals as basic fluorine bearers, the role of the lithological environment where the natural process of defluoridation occurs is significant, which is confirmed by the revitalization of the A-4 well. The paper deals with mineral water deposits of the Bujanovac valley, and the natural way of lowering of fluorine content in the given waters.  相似文献   

11.
在前人研究的基础上,通过水文地质调查、综合物探法、水化学及水质检测方法,探测辽宁省典型地区水化学特征,分析了水化学特征与地下水氟离子的含量关系;不同地貌单元地下水氟离子含量分布不同;主要从高氟地下水形成的物质基础,水文地质环境对氟离子变化的制约,粘性土层是富集氟离子最好场所等方面分析辽宁高氟地下水的形成原因,通过研究了解到高氟地下水一般存在于潜水的上部及粘土层中,这一研究为今后寻找低氟水源提供前期有力资料奠定基础。  相似文献   

12.
Water–rock interaction is one of the prime factors affecting the fluoride contents of surface and groundwater. If fluoride concentration of drinking water has been neglected, excess fluoride can cause serious dental and medical problems on human health, which is well known at Golcuk-Isparta region. In the research area, Egirdir lake, Golcuk lake and surrounding springs have been utilized as drinking water sources. Golcuk lake water and surrounding groundwaters have high fluoride content (1.4–4.6 mg/l), which is above the WHO standards. Fluoride is predominantly supplied by dissolution of fluoride within the fluormicas of volcanics during the circulation of water. Fluoride concentrations of waters have shown variations for dry and rainy seasons depending on the degree of interaction between groundwater and volcanic rocks. It tends to decrease in rainy seasons and increase in dry seasons for all years. In this study, temporal variations and spatial distribution of fluoride concentration in public water system of Isparta were investigated to get benefit using GIS techniques from1990 to 2003 years. Extremely fluoride concentrations were measured in the public water system in 1990 at almost every district of the city. In 2003, fluoride content of the public water system decreased in some district of city due to drinking water has started obtaining from Egirdir lake in 1995. The fluoride contents of Isparta drinking water ought to be modified with suitable mixture of lake waters and groundwater point of view to health impact.  相似文献   

13.
Geochemical study of groundwater from 58 selected fluoride-rich areas in different parts of India that includes eight states indicates that: 1. These groundwaters are alkaline in pH (7.4-8.8) and their electrical conductivity varies from 530-2,680 µS/cm and fluoride concentration from 1.7-6.1 mg/l. Presence of fluoride-bearing minerals in the host rocks and their interaction with water is considered to be the main cause for fluoride in groundwater. 2. The decomposition, dissociation and dissolution are the main chemical processes for the occurrence of fluoride in groundwater. During rock-water interaction, concentration of fluoride in rock, aqueous ionic species and residence time of interaction, etc. are also important parameters. 3. This study indicates that 85% groundwater samples have EC: 1,000-2,000 µS/cm, pH: 7.5-8.5, and HCO3/Ca (epm ratio): 0.8-2.3. 4. The Ca and HCO3 contents of groundwater samples have shown good correlation with fluoride.  相似文献   

14.
The central Main Ethiopian Rift suffers a severe water quality problem, characterized by an anomalously high fluoride (F) content that causes an endemic fluorosis disease. The current study, conducted in the Ziway–Shala lakes basin, indicates that the F content exceeds the permissible limit for drinking prescribed by the World Health Organization (WHO; 1.5 mg/l) in many important wells (up to 20 mg/l), with even more extreme F concentration in hot springs and alkaline lakes (up to 97 and 384 mg/l respectively). The groundwater and surface water from the highlands, typically characterized by low total dissolved solids (TDS) and Ca (Mg)–HCO3 hydrochemical facies, do not show high F content. The subsequent interaction of these waters with the various rocks of the rift valley induces a general increase of the TDS, and a variation of the chemical signature towards Na–HCO3 compositions, with a parallel enrichment of F. The interacting matrixes are mainly rhyolites consisting of volcanic glass and only rare F-bearing accessory minerals (such as alkali amphibole). Comparing the abundance and the composition of the glassy groundmass with other mineral phases, it appears that the former stores most of the total F budget. This glassy material is extremely reactive, and its weathering products (i.e. fluvio/volcano-lacustrine sediments) further concentrate the fluoride. The interaction of these “weathered/reworked” volcanic products with water and carbon dioxide at high pH causes the release of fluoride into the interacting water. This mainly occurs by a process of base-exchange softening with the neo-formed clay minerals (i.e. Ca–Mg uptake by the aquifer matrix, with release of Na into the groundwater). This is plausibly the main enrichment mechanism that explains the high F content of the local groundwater, as evidenced by positive correlation between F, pH, and Na, and inverse correlation between F and Ca (Mg). Saturation indices (SI) have been calculated (using PHREEQC-2) for the different water groups, highlighting that the studied waters are undersaturated in fluorite. In these conditions, fluoride cannot precipitate as CaF2, and so mobilizes freely without forming other complexes. These results have important implications for the development of new exploitation strategies and accurate planning of new drilling sites. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

15.
阿坝州饮水中硒和氟元素与大骨节病关系研究   总被引：1，自引：0，他引：1  
通过测定阿坝州四个大骨节病县饮用水中微量元素硒、氟的含量情况,探讨大骨节病与饮用水硒与氟元素的相关关系,为防治大骨节病提供科学依据。采集阿坝州病区与非病区水样,测定其中硒、氟元素含量,并运用SPSS17.0软件对测定结果进行分析统计。研究表明:阿坝州饮用水中硒、氟元素平均含量为0.47 ug/L～2.32ug/L,0.08 mg/L～0.38 mg/L,病区饮用水中硒、氟与非病区有明显差异(t分别是2.12,3.26,p<0.01),病区硒、氟元素与大骨节患病率之间有明显负相关关系。阿坝州大骨节饮用水中硒元素和氟均与大骨节病有密切关系,建议除进行必需的补硒措施防治大骨病以外,还应该辅助性的增加水氟含量已保证人体需要。  相似文献   

16.
The source of fluoride toxicity in Muteh area,Isfahan, Iran   总被引：1，自引：0，他引：1  
Endemic dental fluorosis has been observed in most inhabitants of three villages of Muteh area, located in northwest of Isfahan province, with mottled enamel related to high levels of fluoride in drinking water (1.8–2.2 ppm). Forty-seven groundwater samples from six villages were collected and fluoride concentrations along with physico-chemical parameters were analyzed. Fluoride concentration in this area varies from 0.2 to 9.2 mg/l with highest fluoride level at Muteh gold mine (Chahkhatun mine). Fluoride concentration positively correlates with pH and HCO3 − indicating that alkaline pH provides a suitable condition for leaching of fluoride from surrounding rocks. The district is mainly covered by three lithological units, namely, metamorphic and granite rocks, alluvial sediments, and carbonate rocks. Factor analysis shows that parameters can be classified into four components: electrical conductivity (EC), total dissolved solids (TDS), Cl−, Na+ and K+, pH and F−, SO4 2−and Mg2+, HCO3 − and Ca2 +. The groundwaters from the three geological units were compared using Mann–Whitney U test. The order of median fluoride concentration is: metamorphic and granite rocks > alluvial sediments > carbonate rocks. Hence, the fluoride content is most probably related to fluoride-bearing minerals such as amphibole and mica group minerals in metamorphic and granitic rocks. The concentration of fluoride in drinking water wells located near the metamorphic complex in Muteh area is above 2 ppm.  相似文献   

17.
《地学前缘(英文版)》2020,11(6):2197-2205
This study investigates the suitability of statistical techniques for evaluating the fluoride content and the groundwater quality from Robles Department (RD) and Banda Department (BD) in Santiago del Estero (Argentina). For the original statistical study, evaluation of nine parameters (fluoride, pH, conductivity, atmospheric and water temperature, total dissolved solids, chloride, hardness, and alkalinity) of 110 collected underground water samples from 23 dispersed rural areas was proposed. Groundwater samples were obtained by sampling taken from wells at different depths. Fluoride levels were determined by a standard colorimetric method in two seasonal periods, the dry (from April to September) and rainy (from October to March) period. The analytical results obtained for physicochemical parameters such as pH, total dissolved solids (TDS), and temperature does not reveal any notable difference between the rainy and dry seasons studied. In both seasons, the atmospheric temperature average was 22 ​°C. With respect to fluoride content, approximately 50% of the analysed groundwater samples exceeded the limit established by current legislation (1.0 ​mg/L), obtaining concentration levels in the range of 0.01–2.80 ​mg/L. This study demonstrates the usefulness of the univariate statistical method (quartiles calculation, interquartile range IQR), multivariate principal component analysis (PCA), and cluster analysis to establish a better understanding of the state of the contamination of the waters in the region studied.  相似文献   

18.
High fluoride and arsenic concentrations in groundwater have led to serious health problems to local inhabitants at Yuncheng basin, Northern China. In this study, groundwater with high fluoride and arsenic concentration at Yuncheng basin was investigated. A majority of the samples (over 60%) belong to HCO3 type water. The predominant water type for the shallow groundwater collected from southern and eastern mountain areas was Ca/Mg-Ca-HCO3 types. For the shallow groundwater from flow through and discharge area it is Na-HCO3/SO4-Cl/SO4/Cl type. The predominant water type for the intermediate and deep groundwater is of Na/Ca/Mg-Ca-HCO3 type. According to our field investigation, fluoride concentration in groundwater ranges between 0.31 and 14.2 mg/L, and arsenic concentration ranges between 0.243 and 153.7 μg/L. Out of seventy collected groundwater samples, there are 31 samples that exceed the World Health Organization (WHO) standard of 1.5 mg/L for fluoride, and 15 samples exceeds the WHO standard of 10 μg/L for arsenic. Over 40% of high fluoride and arsenic groundwater are related to the Na-HCO3 type water, and the other fifty percent associated with Na-SO4-Cl/HCO3-SO4-Cl type water; little relation was found in calcium bicarbonate type water. A moderate positive correlation between fluoride and arsenic with pH were found in this study. It is due to the pH-dependent adsorption characteristics of F and As onto the oxide surfaces in the sediments. The observed negative correlation between fluoride and calcium could stem from the dissolution equilibrium of fluorite. The high concentration of bicarbonate in groundwater can serve as a powerful competitor and lead to the enrichment of fluoride and arsenic in groundwater. Most of the groundwater with high fluoride or arsenic content has nitrate content about or over 10 mg/L which, together with the observed positive correlations between nitrate and fluoride/arsenic, are indicative of common source of manmade pollution and of prevailing condition of leaching in the study area.  相似文献   

19.
Long-term intake of high-fluoride groundwater causes endemic fluorosis. This study, for the first time, discovered that the salt lake water intrusion into neighboring shallow aquifers might result in elevation of fluoride content of the groundwater. Two cross-sections along the groundwater flow paths were selected to study the geochemical processes controlling fluoride concentration in Yuncheng basin, northern China. There are two major reasons for the observed elevation of fluoride content: one is the direct contribution of the saline water; the other is the undersaturation of the groundwater with respect to fluorite due to salt water intrusion, which appears to be more important reason. The processes of the fluorine activity reduction and the change of Na/Ca ratio in groundwater induced by the intrusion of saline water favor further dissolution of fluorine-bearing mineral, and it was modeled using PHREEQC. With the increase in Na concentration (by adding NaCl or Na2SO4 as Na source, calcium content kept invariable), the increase of NaF concentration was rapid at first and then became slower; and the concentrations of HF, HF2−, CaF+, and MgF+ were continuously decreasing. The geochemical conditions in the study area are advantageous to the complexation of F− with Na+ and the decline of saturation index of CaF2, regardless of the water type (Cl–Na or SO4–Na type water).  相似文献   

20.
北京大兴区第四系高氟地下水分布规律研究   总被引：2，自引：1，他引：1  
北京市大兴区供水以地下水为主,研究该区高氟地下水的分布规律及其成因,对指导区域地下水的开发利用和保障居民饮水安全是必要的。在野外调查和以往研究成果的基础上,测试了北京大兴区地下水氟离子浓度。结果表明,高氟水分布区地层岩性以粘性土为主;浅层高氟水主要分布在大兴区的南部及东南部,超标区面积为258.57 km2;深层高氟水主要分布在中部,超标区面积为20.91 km2。建议对浅层高氟地下水加大止水深度,统一并严格设计饮用水井结构;对深层氟超标水,避免饮用或采取降氟措施后再饮用。  相似文献   

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