共查询到20条相似文献，搜索用时 15 毫秒
1.
Studies of Metallic and Trace Minerals of the Tiegelongnan Cu‐Au Deposit,Central Tibet,China 总被引：1，自引：0，他引：1
Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit, which consists of a high-sulfidation epithermal system(HSES) and a porphyry system(PS). Molybdenite,chalcopyrite, bornite, tennantite, enargite, digenite, anilite, covellite, and tetrahedrite have been identified by EPMA. Intergrowth, cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite ± bornite ± hematite(stage 2),then bornite ± Cu-sulfides ± Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides ±Cu-sulfides(stage 4). Pyrite is developed throughout all the stages. Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite, chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier. The pervasive binary equilibrium phases of calaverite and altaite constrain f_(Te2) in the range from ～-6.5 to ～-8 and f_(S2)-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly, the dominance of chalcopyrite in the PS, with minor bornite, suggests relatively high temperature conditions. These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems. 相似文献
2.
Panagiotis Christos Voudouris Paul G. Spry Gregory Aarne Sakellaris Constantinos Mavrogonatos 《Mineralogy and Petrology》2011,101(3-4):169-183
A cervelleite-like mineral, two unnamed silver sulfotellurides in the system Ag-Cu-Te-S [Ag2CuTeS, (Ag,Cu)2TeS], Te-rich polybasite and cadmian tetrahedrite occur in gold-bearing quartz veins in metapelites and faults within brecciated marbles of the Cycladic Blueschist Unit in the Kallianou area (southern Evia Island, Greece). The quartz veins and faults are discordant to syn-metamorphic structures and formed during ductile to brittle deformation in the final stages of exhumation of the Styra Nappe extrusion wedge (~21?Ma). Te-rich polybasite (up to 7.4 wt. % Te), cadmian tetrahedrite (up to 12.4 wt. % Cd), together with electrum (23?C54 wt. % Ag) and the sulfotellurides, are the main silver carriers in the mineralization. The two unnamed sulfotellurides, Ag2CuTeS and (Ag,Cu)2TeS are believed to be new quaternary minerals in the system Ag-Cu-Te-S. These minerals and the cervelleite-like phase could have exsolved from galena during cooling (below 200°C). Initial temperatures for the formation of the sulfotellurides, in the form of hessite-intermediate solid solution, at Kallianou may be up to 300°C under logfS2 values between?~ ?11.5 to ?8.3, and logfTe2 from?~ ?14.8 to ?7.8. The values of logfTe2 and logfS2 during re-equilibration (at ~200°C) were constrained to ?19.5 to ?15.2 and to ?15.8 to ?11.5 respectively. 相似文献
3.
中国还原性斑岩矿床研究进展及判别标志 总被引：1，自引：1，他引：0
世界上大多数斑岩矿床的成矿流体为氧化流体(CO_2 CH_4)。然而,Rowins(2000)提出一些斑岩Cu-Au矿床的成矿流体为富含CH_4的还原流体,矿床缺乏磁铁矿、赤铁矿和硬石膏等表征高氧逸度的矿物,而发育大量的磁黄铁矿,矿床规模小,矿床形成与含钛铁矿的还原性的Ⅰ型花岗岩类有关,并将其称之为还原性斑岩Cu-Au矿床。我国学者研究发现,中国不但发育还原性斑岩铜矿床,还发育还原性斑岩-矽卡岩铜矿床和还原性斑岩钼矿床,我们建议将这三种矿床统称为还原性斑岩矿床。本文基于课题组近十年来的研究工作,并结合前人的研究成果,综合分析了中国发育的大中型还原性斑岩矿床的典型实例,在此基础上,重点阐明中国大型还原性斑岩矿床的特点、流体中CH_4来源及其有关的成矿作用、容矿围岩特点、成矿岩浆氧化还原状态及其成因、矿床形成的构造背景等。与Rowins(2000)提出的还原性斑岩铜矿床规模小的特点不同,中国发育的一些还原性斑岩矿床规模大;我们研究还识别出该类矿床发育独特的热液矿物和矿石矿物,比如,还原性斑岩铜矿发育热液钛铁矿,矿石矿物以黄铜矿为主,罕见斑铜矿、辉铜矿等矿物;还原性斑岩钼矿床出现热液钛铁矿,矿石矿物以辉钼矿为主,罕见黑钨矿和锡石等矿物;还原性斑岩-矽卡岩铜矿床的矽卡岩期发育钙铝榴石、钙铁辉石等还原性矽卡岩矿物和大量的磁黄铁矿,热液期以发育黄铜矿而非斑铜矿和辉铜矿等矿石矿物为特征。因此,还原性斑岩矿床除了Rowins(2000)提出的发育富CH_4还原流体和磁黄铁矿等识别标志之外,还可辅以独特的脉石矿物(如钛铁矿、钙铝榴石、钙铁辉石等)和简单的矿石矿物(如黄铜矿、辉钼矿等)这两个标志进行识别。中国还原性斑岩矿床含矿岩体的围岩中普遍发育还原性岩石(如含碳质沉积岩或火山沉积岩、含亚铁的火山岩或火山沉积岩等);对于成矿流体中CH_4、C_2H_6等还原性气体的来源,多数学者认为CH_4、C_2H_6等还原性气体主要源于还原性围岩,部分源于岩浆。关于还原性斑岩矿床的成矿岩体是否为含钛铁矿的、还原性的花岗岩类,目前研究较少且存在争议,多数学者认为成矿原始岩浆为氧化性岩浆,但其氧逸度偏低,少数学者认为成矿岩浆始终为还原岩浆。还原性斑岩矿床与经典的斑岩矿床的成矿构造背景类似,二者没有明显区别。还原性斑岩矿床显示的还原性热液蚀变和成矿特点均与成矿流体富含CH_4还原气体密切相关,因此,富含CH_4还原流体是还原性斑岩矿床形成的关键。 相似文献
4.
Indium Mineralization in Copper–Tin Stratiform Skarn Ores at the Saishitang–Rilonggou Ore Field,Qinghai, Northwest China 
下载免费PDF全文
下载免费PDF全文 Jianping Liu Xiangping Gu Yongjun Shao Yuzhou Feng Jianqing Lai 《Resource Geology》2016,66(4):351-367
The Saishitang–Rilonggou Ore Field (SROF), which includes the Saishitang, Tongyugou, and Rilonggou ore deposits as well as other scattered occurrences, is located in the Elashan region in Qinghai Province, and is a significant Cu–Sn ore field in NW China. These ores are hosted in stratiform skarn deposits with the main metals being Cu and Sn, as well as Zn, Pb, Au, Ag, and trace elements (e.g. Ga, Ge, Se, and In). Bulk‐rock geochemical analyses of 50 ore samples from the three deposits show that In contents in the Saishitang deposit range from 0.03 to 39 ppm (average 12.7 ppm, n = 19), with 1000 In/Zn values that vary from >0.01 to 29.83 (average 4.29). Indium contents in the Tongyugou deposit vary from 7.51 to 131 ppm (average 28.37 ppm, n = 13), with 1000 In/Zn values from 0.74 to 48 (average 17.55). Finally, indium contents in the Rilonggou deposit vary from 0.73 to 120 ppm (average 36.15 ppm, n = 18), with 1000 In/Zn values from 0.33 to 47 (average 8.52). Indium is hosted mainly in sphalerite, while some other In‐bearing minerals (e.g., roquesite, stannoidite, and stannite) are present locally within the ore field. Roquesite, which replace or fill bornite, occurs in bornite‐rich ores in the Saishitang deposit. This is the first reported Chinese locality of roquesite. Based on previously reported Zn resources, a total of 136 tons of In is calculated to be hosted in the SROF, with 30, 66, and 40 tons of In attributed to the Saishitang, Tongyugou, and Rilonggou deposits, respectively. The differences in indium contents among the deposits and their respective geological histories and characteristics suggest that the origin of indium relates to volcanogenic metallogenesis in an early Permian volcano‐sedimentary basin. Based on the evaluation of In resources, future mining operations should include the recovery of indium in the Tongyugou and Rilonggou deposits. 相似文献
5.
The Eastern Tianshan Orogenic Belt (ETOB) in NW China is composed of the Dananhu–Tousuquan arc belt, the Kanggurtag belt, the Aqishan–Yamansu belt and the Central Tianshan belt from north to south. These tectonic belts have formed through arc–continent or arc–arc collisions during the Paleozoic. A number of Fe(‐Cu) deposits in the Aqishan–Yamansu belt, including the Heifengshan, Shuangfengshan and Shaquanzi Fe(‐Cu) deposits, are associated with Carboniferous–Early Permian volcanic rocks and are composed of vein‐type magnetite ores. Metallic minerals are dominated by magnetite and pyrite, with minor chalcopyrite. Calcite, chlorite, and epidote are the dominant gangue minerals. Pyrite separates of ores from those three deposits have relatively high and variable Re contents ranging from 3.7 to 184 ppb. All pyrite separates have very low common Os, allowing us calculation of single mineral model ages for each sample. Pyrite separates from the Heifengshan Fe deposit have an 187Re–187Os isochron age of 310 ± 23 Ma (MSWD = 0.04) and a weighted mean model age of 302 ± 5 Ma (MSWD = 0.17). Those from the Shuangfengshan Fe deposit have an isochron age of 295 ± 7 Ma (MSWD = 0.28) and a weighted mean model age of 292 ± 5 Ma (MSWD = 0.33). The Shaquanzi Fe‐Cu deposit has pyrite with an isochron age of 295 ± 7 Ma (MSWD = 0.26) and a weighted mean model age of 295 ± 6 Ma (MSWD = 0.23). Pyrite separates from these Fe(‐Cu) deposits have δ34SCDT ranging from ?0.41‰ to 4.7‰ except for two outliers. Calcite from the Heifengshan Fe deposit and Shaquanzi Fe‐Cu deposit have similar C and O isotope compositions with δ13CPDB and δ18OSMOW ranging from ?5.5‰ to ?1.0‰ and from 10‰ to 12.7‰, respectively. These stable isotopic data suggest that S, C, and O are magmatic‐hydrothermal in origin. The association of low‐Ti magnetite and Fe/Cu‐sulfides resembles those of Iron–Oxide–Copper–Gold (IOCG) deposits elsewhere. Our reliable Re–Os ages of pyrite suggest that the Fe(‐Cu) deposits in the Aqishan–Yamansu belt formed at ～296 Ma, probably in a back‐arc extensional environment. 相似文献
6.
7.
V. V. Maslennikov N. R. Ayupova S. P. Maslennikova A. Yu. Lein A. S. Tseluiko L. V. Danyushevsky R. R. Large V. A. Simonov 《Lithology and Mineral Resources》2017,52(4):334-334
The ore-formational, ore-facies, lithological, and mineralogical-geochemical criteria are defined for the detection of hydrothermal ecosystem fauna in ores of the volcanic-hosted massive sulfide deposits in the Urals. Abundant mineralized microfauna is found mainly in massive sulfide mounds formed in the jasperous basalt (Buribai, Priorsk, Yubileinoe, Sultanov), rhyolite—basalt (Yaman-Kasy, Blyava, Komosomol’sk, Sibai, Molodezhnoe, Valentorsk), and the less common serpentinite (Dergamysh) formations of the Urals (O—D2). In the ore-formational series of the massive sulfide deposits, probability of the detection of mineralized fauna correlates inversely with the relative abundance of felsic volcanic rocks underlying the ores. This series is also marked by a gradual disappearance of colloform pyrite, marcasite, isocubanite, pyrrhotite, and pyrite pseudomorphoses after pyrrhotite; increase of the amount of bornite, fahlores, and barite; decrease of contents of Se, Te, Co, and Sn in chalcopyrite and sphalerite; and inсrease of Tl, As, Sb, and Pb in the colloform pyrite. Probability of the detection of mineralized fauna in the morphogenetic series of massive sulfide deposits decreases from the weakly degraded sulfide mounds to the clastic stratiform deposits. The degradation degree of sulfide mounds and fauna preservation correlates with the attenuation of volcanic intensity, which is reflected in the abundance of sedimentary and volcanosedimentary rocks and the depletion of effusive rocks in the geological sections. 相似文献
8.
Rhenium is one of the rarest elements of the earth crust (abundance ratio 0.7 mg/t). In the Karelian region, Re and accompanying
Os were discovered in a copper-molybdenum-porphyry ore formation, represented by the Lobash deposit, the Jalonvaara occurrences
etc., and in a noble-metal-Cu-U-vanadium ore formation (Padma Group occurrences). Molybdenites from the above deposits are
enriched in Re and Os (Lobash: 13–187 g/t Re, 0.4–6 g/t Os). So far, however, no rhenium minerals proper have been revealed
in the Karelian deposits and occurrences of the above formations or elsewhere. As a result of the microprobe study of mineral
assemblages of cupreous sandstones from the Voronov Bor deposit (bornite ore) and sulphide-copper-nickel ore from the Rybozero
deposit, osmium-cupreous rheniite (Re, Cu, Os, Fe)1S2 that contains 56.53–60.25% Re, 4.61–10.99% Cu, 1.52–3.77% Os and up to 4.75% Fe was revealed and studied for the first time. 相似文献
9.
文章以水口山矿田内的3个典型铅锌多金属矿床——康家湾铅锌金银矿床、老鸦巢铅锌金矿床和鸭公塘铅锌铁铜矿床的矿石为研究对象,通过野外地质调查、室内显微鉴定、电子探针分析和LA-ICPMS微量元素分析测试,研究了本区稀散元素的赋存状态、分布规律以及与主成矿元素(Pb、Zn、S、Fe)的关系等,总结出稀散元素在本区的富集规律.研究表明:本区矿石中闪锌矿、黄铁矿、黄铜矿、方铅矿主要富集Cd、In、Te3种稀散元素.康家湾铅锌金银矿床In/Zn比值为0.86,老鸦巢铅锌金矿床In/Zn比值为5.10,而鸭公塘铅锌铁铜矿床In/Zn比值为611.20,且w(In)为33.83×10-6～365.62×10-6,因此,康家湾铅锌金银矿床和老鸦巢铅锌金矿床矿石中的In是以类质同象赋存于闪锌矿和黄铜矿的晶格中,而鸭公塘铅锌铁铜矿床矿石中的In可能以硫铟铜矿的形式赋存.水口山矿田的Te主要有2种赋存形式:一种以类质同象形式赋存于硫化物(黄铁矿)中;另一种以矿石中形成其独立矿物辉碲铋矿(分子式为Bi2TeS2)和碲银矿(分子式为Ag2Te)存在. 相似文献
10.
《地学前缘(英文版)》2023,14(3):101533
Chalcopyrite and bornite are the main Au-bearing minerals at Cu porphyry deposits, volcanogenic massive sulfide (VMS) deposits, Cu-Ni deposits of the mafic magmatic complexes, and ores of submarine sulfide edifices. Bornite and intermediate solid solutions with wide compositional variations (bnss and iss – high-temperature chalcopyrite, correspondingly), which can scavenge economic concentrations of Au, appear in the Cu-Fe-S system at ore-forming conditions. However, the state of Au in bnss and iss is yet unknown. To solve this conundrum, we synthesized samples with net chemical composition of bnss and iss, studied them by in situ X–ray absorption spectroscopy (XAS), and used the experimental data to explain the Au distribution among natural ore-forming minerals. The sulfide samples were obtained at 495–700 °C in Au-saturated system by means of salt flux method. The bnss contained ～1.2–1.6 log units more Au than iss: up to 18 wt.% Au in bnss vs 0.4 wt.% Au in iss at 700 °C. An increase of temperature resulted in the sharp increase of Au concentration in both phases, ～1 log unit per 100 °C at f(S2) close to S(l) saturation. Analysis of Au L3-edge spectra recorded at 25–675 °C revealed that at 25 °C Au exists mainly in the metallic state. At t > 500 °C the spectral features of Au° disappear, and “chemically bound” Au predominates. The Au form of occurrence in the iss field is interpreted as Au-bearing clusters with a stromeyerite-like (CuAgS) structure. Digenite Cu2–xS and bnss contain Au in a mixture of stromeyerite-like and petrovskaite-like (Au0.8Ag1.2S) clusters. The chemical composition of both forms is close to CuAuS, where the nearest Au neighbors are two S atoms at RAu-S = 2.34–2.36 Å. Results of the present study allow to determine the state of Au and its concentration in the main Cu-bearing minerals of sulfide ores as a function of the T-f(S2)-compositional parameters. Due to the sharp increase of the CuAuS clusters stability with increasing temperature, in high-temperature ores formed at t > 350 °C Au enriches Cu-bearing minerals in comparison with Cu-free or Cu-deficient ones. As a result, in these ores native gold, being a product of decomposition of the Au-bearing clusters, is associated with Cu-rich minerals – chalcopyrite, bornite, digenite, chalcocite. 相似文献
11.
青藏高原两个斑岩-浅成低温热液矿床成矿亚系列及其"缺位找矿"之实践 总被引：8，自引：8，他引：8
斑岩_浅成低温热液型铜金矿床是西藏最新发现的组合矿床类型,其具有巨大的找矿潜力。笔者在西藏多龙矿集区铁格隆南铜金矿床、雄村矿集区主要矿体系统地质编录、综合研究的基础上,对其矿床地质背景、矿体形态产状、矿物组合、蚀变特征、成岩成矿年龄等进行了系统的总结,在前人研究的基础上,提出班怒成矿带与早白垩世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,以及冈底斯成矿带与早侏罗世—晚侏罗世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,是西藏最重要的寻找斑岩型_浅成低温热液型铜金矿的矿床成矿系列。依据"缺位找矿"理论,预测多龙矿集区尕尔勤、地堡那木岗、铁格隆山是浅成低温热液型铜金矿床的进一步勘查评价区,色那、拿顿角砾岩筒是寻找独立高硫化型浅成低温热液金矿床的重要靶区。铁格隆南浅成低温热液矿体叠加在斑岩型矿体之上,高硫化型浅成低温热液矿床浅部发育多孔状硅帽和明矾石_地开石_高岭石蚀变组合,金属矿物以硫砷铜矿_铜蓝_蓝辉铜矿_黝铜矿_黄铜矿_斑铜矿_黄铁矿等铜硫二元体系矿物组合为主,其中黄铁矿_黄铜矿_斑铜矿形成较早,矿床规模可突破1200万吨。雄村铜金矿集区发育低硫化型浅成低温热液多金属金矿体,矿体呈脉状,或在火山机构边缘构造中独立产出,或叠加于斑岩型铜金矿体之上产出,以绢云母化、叶蜡石化、伊利石化发育,闪锌矿、黝铜矿、磁黄铁矿_黄铁矿为主要金属矿物组合为特征,洞嘎、普钦木_哑达是低硫化型浅成低温热液矿床的勘查评价区,深部有找到斑岩型铜金矿的可能。上述2套矿床成矿系列亚系列都与燕山期斑岩铜金矿床的流体演化有关,具有特殊的蚀变矿物、金属矿物组合,寻找独立的浅成低温热液型金矿是下一步需要重视的找矿方向。 相似文献
12.
兰坪盆地白秧坪银铜多金属矿集区中银、钴、铋、镍的赋存状态与成因意义 总被引：7，自引：1，他引：6
白秧坪银铜多金属矿集区位于兰坪盆地北部。矿集区可分为东、西两个成矿带。赋矿地层主要为上三叠统三合洞组碳酸盐岩、第三系始新统保相寺组碎屑岩和下白垩统景星组碎屑岩。矿体主要以脉状、网脉状及透镜状形式产出。作者通过显微镜观察、电子探针和扫描分析等综合分析技术,确认白秧坪银铜多金属矿集区中矿物组成相当丰富,已鉴定出的矿物超过50种,既有大量硫化物、硫盐、氧化物、硫酸盐、碳酸盐,又有自然金属及金属互化物、卤化物等。除常见矿物为黄铁矿、毒砂、白铁矿、黄铜矿、方铅矿、闪锌矿、黝铜矿、砷黝铜矿、铜蓝、斑铜矿、辉铜矿、雌黄、菱铁矿、方解石、铁白云石、重晶石、天青石和石英外,作者还鉴定出一些银、钴、铋、镍、砷、锑的矿物,如自然铋、辉铋矿、辉银矿、辉砷钴矿、硫钴镍矿、硫铜铋矿、硫铋铜矿、辉砷镍矿、车轮矿、硫砷铜矿、单斜硫砷铅矿、灰硫砷铅矿等。矿石中矿物种类较多,组成较复杂,存在Co,Bi,Ni等元素的矿物,构成白秧坪银铜多金属矿集区的一大特色。在兰坪盆地白秧坪银铜多金属矿集区各矿段内,除了Cu、Pb、Zn构成工业矿体外,矿石中Ag、Co、Ni、Bi及As、Sb、Ba等元素的含量也相当高,可作为Cu-Pb-Zn-Ag-Co-Ni-Bi矿石来综合开发利用。白秧坪银铜多金属矿集区中Ag、Co、Ni、Bi等元素富集条件为低温、中低盐度,形成压力较小的浅成环境;成矿流体是一种富含CO2的Ca2+-Na+-SO24-Cl-类型、由大气降水演化而成的盆地热卤水。成矿物质主要来源于含有基性火山岩的兰坪盆地基底变质岩系。 相似文献
13.
云南官房铜矿床矿石矿物特征及银的赋存状态 总被引：1，自引：0，他引：1
通过显微镜鉴定、电子探针(EPMA)及扫描电镜能谱分析(SEM/EDS)等方法,首次对官房铜矿的矿物组合和银的赋存状态进行了研究。初步查明,矿石矿物为中-低温热液成因,并受火山机构及断裂构造的控制;银矿物主要为碲银矿和辉银矿。矿石中银与铜呈明显正相关关系,而方铅矿中不含银。银主要以类质同象的形式赋存于含铜矿物或黄铁矿中;银的独立矿物含量低,且多呈包裹体的形式存在于黄铜矿、斑铜矿及黄铁矿中,或以微细粒状赋存于矿物颗粒间和斑铜矿的表面。 相似文献
14.
The Cu-Ag-S minerals, stromeyerite and mckinstryite, have been found for the first time in a stratabound polymetallic pyritic deposit in the Caledonides of central Norway. The surface specimens examined contained approximately 0.5% Ag, 1.8% Cu, 15.0% Zn and over 10 g/t Au and showed the mineral association pyrite, sphalerite, chalcopyrite, galena, tennantite, bornite, Cu-Ag sulphides, covelline, native Au, a Cu-Sn sulphide, and a new mineral of composition Ag5CuTeS2. The Cu-Ag sulphides appear to be replacing preexisting sulphides, with the exception of pyrite and sphalerite. The nature of this replacement is discussed. Analyses, by microprobe, of the Cu-Ag-S phases are reported and compared with published data. The stromeyerite shows an average composition Cu1.01Ag S, the mckinstryite Cu0.77Ag1.19S. Values are reported of the reflectance at 542 nm for both minerals. The data indicate that stromeyerite is optically positive with Rg: 30.7%, Rm: 27.3%, Rp: 25.8% while mckinstryite is negative with Rg: 32.5%, Rm: 31.9%, Rp: 27.6%. 相似文献
15.
中甸普朗还原性斑岩型铜矿床：矿物组合与流体组成约束 总被引：11，自引：8，他引：3
成矿流体高氧逸度是斑岩铜矿床模式的一个基本原则。虽然亚洲单个矿体储量最大的普朗铜矿床的成矿母岩——普朗复式岩体具氧化性岩浆特点,但其矿物组合及流体成分却与还原性斑岩型铜金矿床一致:矿石中以发育大量磁黄铁矿为特征,构成黄铜矿-磁黄铁矿-黄铁矿为主的矿物组合,不发育表征高氧逸度的原生磁铁矿和硫酸盐(硬石膏等)矿物;成矿流体中含较多CO2、CO和CH4等还原性组分,氧逸度低于铁橄榄石-磁铁矿-石英缓冲剂。成矿流体中还原性组分可能来源于普朗复式岩体周围的含碳质千枚岩或深部铁镁质岩浆。还原性流体中铜元素的溶解度比氧化性流体中的低,但金元素的溶解度不受氧化还原条件的影响;而CH4可使SO2还原形成S2-,为辉钼矿的形成提供物质基础;可能是导致普朗铜矿床Cu品位偏低而伴生大量Au、Mo矿化的主要原因之一。普朗铜矿床还原性特征的厘定有益于深入研究其矿床成因、乃至区域斑岩型铜矿床成矿机制。 相似文献
16.
A.V. Kutyrev E.G. Sidorov A.V. Antonov V.M. Chubarov 《Russian Geology and Geophysics》2018,59(8):935-944
In the alluvial deposits of the Prizhlimny Creek (southern part of the Koryak Highland), grains of platinum-group minerals are found along with gold. We have established that the grains are native platinum (Pt, Fe) containing Cu (up to 5 wt.%), Os (up to 8 wt.%), and Rh (up to 2 wt.%). Inclusions in the platinum are native osmium (the content of Ir impurity reaches 12 wt.%, the average content being 0.2–4 wt.%), an unnamed intermetallic compound of composition PtRh, sulfides and arsenides of PGE (cooperite, laurite, malanite, cuproiridsite, cuprorhodsite, sperrylite, hollingworthite, unnamed compounds PdS, (Ir,Ru)S2, (Ir,Pt)S2, Cu, and Fe (bornite, chalcopyrite), chromite, and Cr-magnetite. Replacement of native-osmium crystals by compound IrO2 is described. It has been established that this compound formed during oxidation accompanied by the replacement of isoferroplatinum by native platinum. The data obtained agree with the results of study of platinum-group mineral assemblages from placers localized in weakly eroded Ural–Alaskan-type massifs whose apical parts formed under high oxygen activity conditions. Clinopyroxenites of the Prizhimny massif are considered to be the potential source of PGE. 相似文献
17.
A. Cepedal M. Fuertes-Fuente A. Martín-Izard S. González-Nistal L. Rodríguez-Pevida 《Mineralogy and Petrology》2006,87(3-4):277-304
Summary Gold ores in skarns from the Río Narcea Gold Belt are associated with Bi–Te(–Se)-bearing minerals. These mineral assemblages
have been used to compare two different skarns from this belt, a Cu–Au skarn (calcic and magnesian) from the El Valle deposit,
and a Au-reduced calcic skarn from the Ortosa deposit. In the former, gold mineralization occurs associated with Cu–(Fe)-sulfides
(chalcopyrite, bornite, chalcocite-digenite), commonly in the presence of magnetite. Gold occurs mainly as native gold and
electrum. Au-tellurides (petzite, sylvanite, calaverite) are locally present; other tellurides are hessite, clausthalite and
coloradoite. The Bi-bearing minerals related to gold are Bi-sulfosalts (wittichenite, emplectite, aikinite, bismuthinite),
native bismuth, and Bi-tellurides and selenides (tetradymite, kawazulite, tsumoite). The speciation of Bi-tellurides with
Bi/Te(Se + S) ≤ 1, the presence of magnetite and the abundance of precious metal tellurides and clausthalite indicate fO2 conditions within the magnetite stability field that locally overlap the magnetite-hematite buffer. In Ortosa deposit, gold
essentially occurs as native gold and maldonite and is commonly related to pyrrhotite and to the replacement of l?llingite
by arsenopyrite, indicating lower fO2 conditions for gold mineralization than those for El Valle deposit. This fact is confirmed by the speciation of Bi-tellurides
and selenides (hedleyite, joséite-B, joséite-A, ikunolite-laitakarite) with Bi/Te(+ Se + S) ≥ 1. 相似文献
18.
V. V. Maslennikov N. R. Ayupova S. P. Maslennikova A. Yu. Lein A. S. Tseluiko L. V. Danyushevsky R. R. Large V. A. Simonov 《Lithology and Mineral Resources》2017,52(3):173-191
The ore-formational, ore-facies, lithological, and mineralogical-geochemical criteria are defined for the detection of hydrothermal ecosystem fauna in ores of the volcanic-hosted massive sulfide deposits in the Urals. Abundant mineralized microfauna is found mainly in massive sulfide mounds formed in the jasperous basalt (Buribai, Priorsk, Yubileinoe, Sultanov), rhyolite–basalt (Yaman-Kasy, Blyava, Komosomol’sk, Sibai, Molodezhnoe, Valentorsk), and the less common serpentinite (Dergamysh) formations of the Urals (O–D2). In the ore-formational series of the massive sulfide deposits, probability of the detection of mineralized fauna correlates inversely with the relative abundance of felsic volcanic rocks underlying the ores. This series is also marked by a gradual disappearance of colloform pyrite, marcasite, isocubanite, pyrrhotite, and pyrite pseudomorphoses after pyrrhotite; increase of the amount of bornite, fahlores, and barite; decrease of contents of Se, Te, Co, and Sn in chalcopyrite and sphalerite; and decrease of Tl, As, Sb, and Pb in the colloform pyrite. Probability of the detection of mineralized fauna in the morphogenetic series of massive sulfide deposits decreases from the weakly degraded sulfide mounds to the clastic stratiform deposits. The degradation degree of sulfide mounds and fauna preservation correlates with the attenuation of volcanic intensity, which is reflected in the abundance of sedimentary and volcanosedimentary rocks and the depletion of effusive rocks in the geological sections. 相似文献
19.
Mineralogical and paragenetic studies of the metallic and nonmetallic constituents of the carbonate-hosted cupriferous ores of the Acton Vale-Upton sector, Klippen Belt, Quebec, have revealed the following. The deposits are characterized by a simple mineralogy and a complex paragenesis. Several generations of pyrite and chalcopyrite are associated with sphalerite, galena, pyrrhotite, covellite, bornite, idaite, djurleite, malachite, azurite, Fe oxides, and minor barite. The deposits are characterized by three discrete mineral assemblages which are composed of syndiagenetic minerals, epigenetic minerals, and supergene minerals. They are hosted by concordantly interbedded lithologies that have been hydrothermally altered by intrusions. The deposits are characterized by massive lenticular bodies, stockworks, vugs, veins, and by cockade and replacement textures, solution collapse breccias, and karst phenomena. The deposits have been enriched in recent times by supergene processes. Considering that the lithostratigraphic sequence constitutes an ideal structural trap for ascending mineralizing fluids, it is the authors' opinion that the deposits are unconventional epigenetic, carbonate-hosted, Cu-dominant and/or Pb-Zn-Ba bodies which in their original form were too low grade to be economic. They required postdepositional remobilization and concentration to upgrade their protores. Based on the assumption that the ores were derived from the expulsion of metal-rich formation waters during compaction and that they were, at one point, contaminated and set in motion by magmatic solutions emanating from rising plutons of post-Taconic age, it is inferred that the thermal energy necessary to remobilize the ores was provided by the intrusions of the Acton Vale-Upton sector. 相似文献
20.
维拉斯托-拜仁达坝锌铜多金属矿床为近几年大兴安岭中南段西坡发现的较大的2个银多金属矿床,主要对2个矿床矿石矿物组合分析和对比,对主要的矿石矿物组合进行扫描电子显微镜-能谱分析和电子探针分析显示:从早期到晚期,矿物组合从高温钨酸盐和氧化物-复硫化物-硫化物-低温含锑硫盐矿物(锑化物);银的赋存状态主要为可见银矿物,其次为晶格银(类质同象)和次显微包裹银,其中生成顺序依次为含银黝铜矿+银锑黝铜矿+黝锑银矿-辉锑铅银矿+柱硫锑铅银矿+深红银矿+锑银矿.根据不同成矿阶段的矿物组合和流体包裹体特征得出:成矿早期在氧化偏酸性环境下,W、Sn等以钨酸、钨酸盐等形式迁移,Zn2+、Pb2+、Cu+等金属离子以氯络合物形式迁移;随着黑钨矿气化沉淀及成矿流体物理化学条件的变化,成矿中-晚期成矿环境变为弱碱性还原条件,成矿流体中金属离子以硫氢络合物迁移为主,伴着温度降低和围岩的水-岩作用,硫氢络合物分解,导致磁黄铁矿等硫化物、硫锑银矿物、硫锑铅矿等依次沉淀. 相似文献