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1.
In this work, we use Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (13C NMR) data to quantify the changes of major chemical compound classes (carboxylic acid, amide, ester, aliphatic, aromatic and carbohydrate) in high molecular weight (HMW, >1 kDa) dissolved organic matter (DOM) isolated along a transect through the Elizabeth River/Chesapeake Bay system to the coastal Atlantic Ocean off Virginia, USA. Results show that carboxylic acids and aromatic compounds are lost along the transect, while HMW DOC becomes enriched in carbohydrate moieties that could have a mid-transect source, perhaps the intensive red tide bloom (Choclodinium polykrikoides) which occurred during our sampling period. Taking the second derivative of the FTIR spectra resolved three pools of de-protonated carboxylic acids at our Dismal Swamp site (used to represent terrestrial organic matter in this area): one carboxylic acid pool, complexed with iron, seems to be lost between the Dismal Swamp and river sites; the second appears biogeochemically active throughout the riverine transect, disappearing in the coastal ocean sample; the third seems refractory, with the potential to be transported to and to accumulate within the open ocean. Five-member ring esters (γ-lactones) were the major ester form in the Dismal Swamp; aliphatic and acetate esters were the dominant esters in the estuary/marine DOM. No amide groups were detectable in Dismal Swamp DOM; secondary amides were present at the estuarine/marine sites. Coupling FTIR with 13C NMR provides new insights into the biogeochemical roles of carboxylic acid, amide and ester compounds in aquatic ecosystems. 相似文献
2.
The determination of twelve rare-earth elements (REE), scandium, yttrium and hafnium in 32 geochemical reference materials by inductively coupled plasma atomic emission spectrometry (ICP-AES) is reported. Results obtained show good agreement with previously published values and compilations. The method is based on a lithium metaborate fusion of the sample followed by a cation exchange separation. A small amount of oxalic acid added to the 6N HNO3 eluant ensures the complete elution of hafnium with the other 14 elements. 相似文献
3.
《Quaternary Science Reviews》2005,24(14-15):1691-1701
High-resolution pollen data (average interval between samples<15 years) are reported on part of a varved sediment core from Lake Suigetsu, Japan, spanning the interval 15,701 to 10,217 SG vyr BP (Suigetsu varve years Before Present). This new record is compared with a previously proposed event stratigraphy based on pollen-based reconstructed changes of mean annual temperature. The deglacial climate history reconstructed at Lake Suigetsu resembles that observed in the North Atlantic, although the major boundaries of pollen zones are asynchronous with those in the North Atlantic event stratigraphy by several centuries. The onset of the Late Glacial interstadial occurred earlier in Japan than in the North Atlantic. This demonstrates that the climate in Japan was closely linked to the low-latitude Pacific Sea Surface Temperatures that first reacted to orbital forcing. Conversely, the onset of the subsequent cold reversal phase in Japan lagged that of the North Atlantic (Younger Dryas) by several centuries. The duration of this cold phase was about the same as the Younger Dryas event, but the amplitude was much reduced (4±2 °C in Δmean annual temperature). These findings support the hypothesis that this pan-hemispheric cooling event was triggered by North Atlantic forcing, most probably by a meltwater pulse and an associated change in the North Atlantic thermohaline circulation. However, the mechanism which transmitted the change in the North Atlantic to the Far East is unknown. 相似文献
4.
The beryllium and zirconium contents of 45 geochemical reference samples have been determined by inductively coupled plasma after fusion of the samples with lithium metaborate and dissolution of the melt in dilute nitric acid. The method described here is rapid and sample preparation straightforward. Good agreement is shown with previously published results for these two elements. A correction has to be made for an interference due to vanadium in determining the beryllium content, and there is a slight interference due to yttrium in the determination of zirconium. The detection limit for beryllium is about 0.2 μg g-1 and for zirconium about 15 μg g-1 in the sample. 相似文献
5.
The rare-earth elements (REE) and yttrium have been determined in 37 international rock and mineral reference materials. Samples were prepared using conventional rock-dissolution techniques, and the REE and yttrium were separated from the other constituents using cation-exchange chromatography. The REE (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu) and yttrium were determined simultaneously by inductively coupled plasma-atomic emission spectrometry (ICP-AES). Results for four well-characterised USGS standard rocks agree favourably with "recommended" values and with REE determinations made previously by workers using ICP-AES, isotope dilution mass spectrometry, instrumental neutron activaton analysis and X-ray fluorescence spectrometry.
Les éléments de terres rares (TR) et yttrium ont été dosés dans 37 échantillons internationaux de réféence. Les échantillons ont été décomposés par dissolution acide et les TR séparés par résine échangeuse de cations. Les TR (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu) et yttrium ont été dosés simultanément par la spectrométrie d'émission-plasma inductif. Les résultats obtenus pour quatre échantillons de référence bien charactérisés de I'USGS se comparent favorablement avec ceux obtenus par la spectrométrie d'émission-plasma, la dilution isotopique, I'activation neutronique et par la spectrométrie d'é fluorescence-X. 相似文献
Les éléments de terres rares (TR) et yttrium ont été dosés dans 37 échantillons internationaux de réféence. Les échantillons ont été décomposés par dissolution acide et les TR séparés par résine échangeuse de cations. Les TR (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu) et yttrium ont été dosés simultanément par la spectrométrie d'émission-plasma inductif. Les résultats obtenus pour quatre échantillons de référence bien charactérisés de I'USGS se comparent favorablement avec ceux obtenus par la spectrométrie d'émission-plasma, la dilution isotopique, I'activation neutronique et par la spectrométrie d'é fluorescence-X. 相似文献
6.
S.Stephen Streeter 《Quaternary Research》1973,3(1):131-141
Today, below 2500 m, benthonic foraminiferal faunas in the North Atlantic are dominated by a few species. Faunal composition changes slowly with increasing depth and decreasing temperature. Surface sediment and down-core counts of benthonic foraminifera reported by Phleger, Parker, and Peirson (1953) in the reports of the Swedish Deep-Sea Expedition have been supplemented by additional bottom sediment and piston core samples. Present-day benthonic foraminiferal assemblages from the deeper portions of the North Atlantic appear to be controlled more by the distribution of bottom water types than by bathymetry. In most piston cores, the assemblages vary greatly during the last 150,000 yr, suggesting depression and elevation of faunas at the core site through a depth range of several hundred meters. This would indicate that bottom water characteristics have shifted back and forth in this interval of time and, therefore, that bottom circulation partakes in the well-documented shifts recorded for surface waters of the North Atlantic. It appears that dense water, similar to present-day North Atlantic Deep Water, was produced over a wide area north of 45° N during cooler intervals and that it spread widely at depth. 相似文献
7.
The objectives of the North Atlantic Seaboard Programme (NASP), a constituent subproject of IGCP-253
The North Atlantic Seaboard Programme (NASP) is one of the main sub-projects of IGCP-253 (‘Termination of the Pleistocene’) and is concerned with the history of environmental changes in areas adjacent to the North Atlantic during the last glacial-interglacial transition. The organisation and aims of IGCP-253 are briefly outlined, to provide the wider context of the NASP. The specific aims of the NASP are introduced, with reference to the importance of the North Atlantic region in late Quaternary research. Some methodological problems are outlined as is the strategy adopted in regional summaries and an overall North Atlantic synthesis, which are presented separately in the issue of Journal of Quaternary Science of which this introductory paper forms a part. 相似文献
8.
In this paper, the decadal predictability and forecast skill of the Sea Surface Temperature Anomalies (SSTA) in the North Pacific and North Atlantic Ocean were investigated by conducting three sets of perfect model forecast experiments using a global coupled general circulation model. The results show that the annual mean SSTA in the North Pacific is less predictable on decadal time scale, with the forecast skill notably weaker than that of the North Atlantic. By analyzing the predictability and forecast skill of seasonal mean SSTA, it is found that the decadal predictability and forecast skill of the winter mean (JFM) SSTA in the central and western North Pacific are significantly higher than those of other seasons, and the magnitude is comparable with that of the North Atlantic. The predictability and forecast skill of the North Atlantic SSTA also show seasonal variations. Further analysis indicates that the seasonal dependence of the SSTA decadal predictability and forecast skill in the North Pacific is due to the winter-to-winter reemergence mechanism of SSTA in the North Pacific, which results from the seasonal variation of the mixed layer depth of the North Pacific Ocean. While the seasonal dependence of the North Atlantic SSTA predictability and forecast skill might be related to seasonal variations of other processes, such as the Atlantic Decadal Oscillation. The results of this paper suggest that for decadal climate prediction, if the forecast skill of the seasonal mean is taken into account, we might obtain higher than annual mean forecast skill for some seasons. 相似文献
9.
《Geochimica et cosmochimica acta》1999,63(13-14):1991-1999
Vertical profiles of dissolved indium and yttrium were determined in the eastern North Atlantic and the Mediterranean Sea to compare with those of the North Pacific reported earlier. The Y concentrations in the surface waters are 120 pmol/kg in the North Atlantic and 205 pmol/kg in the Mediterranean Sea, which are significantly higher than 80 pmol/kg in the North Pacific. The difference may be attributable to the different strength of input of Y to the oceans from fluvial and aeolian sources. In contrast, the deep water concentration of Y increases in the order of North Atlantic < Mediterranean < North Pacific. This trend is similar to that of dissolved Si, suggesting that Y is involved in the biogeochemical regeneration cycle. The vertical profiles of In are far more complex than Y. The In profile shows a systematic increase from 0.6 pmol/kg at the surface to 1.7 pmol/kg at 2100 m in the North Atlantic, whereas it is almost featureless at a mean concentration of 3.8 ± 0.6 pmol/kg in the Mediterranean Sea. The North Atlantic and Mediterranean In concentrations are considerably higher than those observed in the North Pacific (∼0.1 pmol/kg), and such a large interoceanic variation has been reported before only for Al and Ga. Like Al, the deep water In concentration that decreases in the order of Mediterranean > North > North Pacific exhibits an inverse trend of Y and nutrients. Indium is highly particle-reactive (47% association in the Mediterranean Sea), and must have a short mean oceanic residence time. However, the featureless dissolved In profile in the Mediterranean Sea is clearly different from the profiles of dissolved Al, showing increase with depth Hydes et al 1988, Measures and Edmond 1988, suggesting that significant fractionation of the two elements is taking place in the ocean.The interoceanic variations of dissolved In and Al may be ascribed to the different intensities of external input of which aeolian has been considered to be major rather than fluvial. However, the difference of In and Al concentrations in the deep waters of the above oceanic basins are significantly greater than those of other refractory elements, such as Ce, Ti, Hf, and Zr, whose major sources to the ocean are also considered to be aeolian. Furthermore, the In/Al ratios in seawater are about two orders of magnitude greater than the average crustal ratio. Thus, some additional sources, though not yet certain, may be required to explain the high concentrations of In in the Atlantic and the Mediterranean deep waters. 相似文献
10.
Fourteen rare-earth (plus scandium and yttrium) orthophosphates have been synthesized and characterized for use as electron microprobe reference samples. These reference samples are single-element phosphates that are homogeneous, stable under the electron beam, and free of interfering elements. They have a stoichiometric composition (RPO4) with the element of interest (R) ranging from 32 to 64 weight percent. 相似文献
11.
This study assesses retrospective decadal prediction skill of Sea Surface Temperature (SST) variability in initialized climate prediction experiments (INT) with the Beijing Climate Center Climate System Model (BCC_CSM1.1). Ensemble forecasts were evaluated using observations, and compared to an ensemble of uninitialized simulations (NoINT). The results show as follows: ①The warming trend of global mean SST simulated by the INT runs is closer to the observation than that in the NoINT runs.②The INT runs show high SST prediction skills over broad regions of tropical Atlantic, western tropical Pacific and tropical Indian Oceans. ③ In the North Pacific and the east-central tropical Pacific Ocean, the prediction skills are very weak, and there are few improvements coming from the initialization in the INT runs. ④ In the southern Indian Ocean, the prediction skills of the INT runs are significantly larger than that of the NoINT runs, with the maximum skill at the 3~6 and 4~7 years lead time. The above-mentioned conclusions are similar to the results of other climate models. However, the prediction skill in the North Atlantic Ocean is much lower than that of other models, especially in the subpolar region. The low skills in the Atlantic Ocean may be attributed to the misrepresentation of the lead-lag relationship between the Atlantic meridional heat transport and the SST in the BCC_CSM1.1. 相似文献
12.
William R. Nicholson 《Estuaries and Coasts》1978,1(3):141-150
Over 968,000 adult Atlantic menhaden,Brevoortia tyrannus, were tagged from 1967 to 1969 and over 85,000 juvenile menhaden were tagged from 1969 to 1973. Recoveries of these tagged fish through 1975 provide direct evidence that Atlantic menhaden consist of a single population that over-winters in offshore waters off the southeastern coast of the United States, moves northward in spring and stratifies along the coast by age and size during summer, and moves southward in late autumn. 相似文献
13.
A 9300 yr-old zone of disseminated volcanic ash in North Atlantic sediments between 45° N and 65° N provides a time-synchronous reference layer against which we have compared the stratigraphic level of deglacial warming of ocean surface waters. In the Atlantic north of 45° N the most prominent feature of this warming is the replacement of low-carbonate glacial marine sediment containing only a single species of polar Foraminifera by calcareous oozes containing a diverse temperate fauna and flora. The local terminations of glacial conditions marked by this change are not synchronous at these latitudes, but range from 13,500 yr B.P. or older in the southeast near Great Britain to 6,500 yr B.P. or younger in the northwest near Greenland. Regionally, these local warmings trace the progressive westward and northward retreat of polar water from the North Atlantic. Since the withdrawal of polar water from the North Atlantic coincides with the northward shrinkage of temperate-latitude continental ice sheets, it is the best oceanic analog to continental deglaciation.Faunal, floral, lithologic, and isotopic parameters showing evidence for a sudden deglacial warming may not be time-synchronous; those parameters are subject to a range of environmental controls and may thus respond differently to the causal mechanism for global warming. 相似文献
14.
Rare earth elements in the Pacific and Atlantic Oceans 总被引：1，自引：0，他引：1
Hein J.W. De Baar Michael P. Bacon Peter G. Brewer Kenneth W. Bruland 《Geochimica et cosmochimica acta》1985,49(9):1943-1959
15.
16.
KARI GRØSFJELD SVEND FUNDER MARIT-SOLVEIG SEIDENKRANTZ CHRIS GLAISTER 《Boreas: An International Journal of Quaternary Research》2006,35(3):493-520
Marine sediments from river sections in the Mezen River drainage, northwest Russia, have been analysed for dinoflagellate cysts, foraminifers and molluscs. The sediments were dated by pollen analysis and by reference to the local sea-level history, and are Late Saalian to late Eemian (c. 133 to 119.5 kyr in age). The Late Saalian deglaciation was characterized by Arctic conditions, but a few centuries into the Eemian the Gulf Stream system carried warm Atlantic water into the region. At 129.8 kyr BP there was a marked increase in the influx of Atlantic water, and the advection of warm Atlantic water was stronger and probably penetrated further eastwards than at present. The molluscs, dinoflagellate cysts and foraminifers reflect conditions warmer than present and that the optimum temperature occurred at the time of the early Eemian global sea-level rise. Around 128 kyr BP, the eustatic sea-level rise was curbed by isostatic rebound and accompanying regression and constriction of marine passages to the White Sea. Local, low-saline, stratified basins developed and characterized the next five to six millennia. 相似文献
17.
地球表层系统是由岩石圈、大气圈、水圈和生物圈相互耦合和变化组成的复杂巨系统。白垩纪是地球表层系统研究的典范,在地球表层各圈层发生了众多重大地质事件。晚白垩世巨大的地幔热异常引起海底扩张速度变快,导致大量海底高原和海山的形成;同时,冈瓦纳大陆裂解,南北大西洋贯通,新的大洋水道形成,可能造成大洋环流格局的大变化。洋壳体积的增加可能使白垩纪海平面比现在高出200~300 m,大规模海侵也在晚白垩世中期达到最大范围。在这个过程中,火山作用释放出来的营养物质和火山气体的反馈作用造成的大量陆地营养物质的流入共同促使大洋水体富营养化和普遍缺氧,造成“大洋缺氧事件”。CO2浓度的升高（为现今的4~10倍）是火山排气作用的直接结果,其“温室效应”也被认为可能是促成白垩纪大气和海水高温的重要原因（高于现在10 ℃）。大洋红层（CORB）是最新提出并被广泛接受的白垩纪重要地质事件,被定义为一套分布在从外陆棚到CCD面之下深水盆地的,在富氧、低生产力和贫营养条件下较低速沉积形成的品红-红色-棕色的细粒远洋沉积物。这些发生于地球表层各圈层的重大地质事件以能量循环的方式（具体表现为C、S、P、H、O等元素循环）相互耦合和变化共同支撑着地球表层系统的运转。但是科学界对这些重大地质事件的成因机制及其所引起的全球变化性质还没有形成一致意见,原因之一就是缺乏对陆相沉积记录的研究。陆相白垩系的广泛发育和“松辽盆地白垩系科学钻探”工程的顺利实施共同构成了中国在白垩纪地球表层系统研究上的地域和材料优势,结合中国在白垩纪地球表层系统重大地质事件研究中已经形成的学术优势,从地球系统科学的角度出发,通过多学科交叉研究将是解决以上问题的关键。 相似文献
18.
Maciej M. Telesiński Robert F. Spielhagen Ewa M. Lind 《Boreas: An International Journal of Quaternary Research》2014,43(2):273-285
We present an unprecedented multicentennial sediment record from the foot of Vesterisbanken Seamount, central Greenland Sea, covering the past 22.3 thousand years (ka). Based on planktic foraminiferal total abundances, species assemblages, and stable oxygen and carbon isotopes, the palaeoenvironments in this region of modern deepwater renewal were reconstructed. Results show that during the Last Glacial Maximum the area was affected by harsh polar conditions with only episodic improvements during warm summer seasons. Since 18 ka extreme freshwater discharges from nearby sources occurred, influencing the surface water environment. The last major freshwater event took place during the Younger Dryas. The onset of the Holocene was characterized by an improvement of environmental conditions suggesting warming and increasing ventilation of the upper water layers. The early Holocene saw a stronger Atlantic waters advection to the area, which began around 10.5 and ended quite rapidly at 5.5 ka, followed by the onset of Neoglacial cooling. Surface water ventilation reached a maximum in the middle Holocene. Around 3 ka the surface water stratification increased leading to subsequent amplification of the warming induced the North Atlantic Oscillation at 2 ka. 相似文献
19.
Michael G. Lawrence Alan Greig Kenneth D. Collerson Balz S. Kamber 《Aquatic Geochemistry》2006,12(1):39-72
We present data for the rare earth elements and yttrium (REY) in the National Research Council of Canada natural river water
reference material SLRS-4 and 19 natural river waters from small catchments in South-East Queensland, Australia, by a direct
ICP-MS method. The 0.22 μm filtered river water samples show a large degree of variability in both the REY concentration,
e.g., La varies from 13 to 1157 ppt, and shape of the alluvial-sediment-normalised REY patterns with different samples displaying
light, middle or heavy rare earth enrichment. In addition, a spatial study was undertaken along the freshwater section of
Beerburrum Creek, which demonstrates that ~75% of the total REYs in this waterway are removed prior to estuarine mixing without
evidence of fractionation. 相似文献
20.
Deep-sea sediments can contain relatively high concentrations of rare earth elements and yttrium (REY), with a growing interest in their exploitation as an alternative to land-based REY resources. To understand the processes that lead to enrichment of the REY in deep-sea sediments, we have undertaken a detailed geochemical study of sediments recovered from the Atlantic Ocean, on a transect along ~ 24°N that includes the deep Nares Abyssal Plain and the Canary and North America Basins.Total REY concentrations (ΣREY) range from 7.99 to 513 ppm, and total concentrations of the heavy REY (Eu - Lu) range from 0.993 to 56.3 ppm. REY concentrations are highest in slowly accumulating pelagic red clays, especially in samples that contain ferromanganese micronodules. Factor analysis reveals that hydrogenous Fe- and Mn-(oxyhydr)oxides are the primary REY carrier phase in the red clays. In situ analysis of individual micronodules confirms that they have high ΣREY (up to 3620 ppm). REY concentrations are higher in micronodules that have a hydrogenous source, characterised by higher Fe/Mn, compared to micronodules that have a diagenetic source.The ΣREY content of North Atlantic deep-sea sediments is ~ 4 times lower than in Pacific deep-sea sediments. We calculate that the area of seafloor required to extract ~ 10% of the global annual REY demand is ~ 100 km2, assuming removal of the upper 1 m of sediment. 相似文献