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1.
Maohokite, a post‐spinel polymorph of MgFe2O4, was found in shocked gneiss from the Xiuyan crater in China. Maohokite in shocked gneiss coexists with diamond, reidite, TiO2‐II, as well as diaplectic glasses of quartz and feldspar. Maohokite occurs as nano‐sized crystallites. The empirical formula is (Mg0.62Fe0.35Mn0.03)2+Fe3+2O4. In situ synchrotron X‐ray microdiffraction established maohokite to be orthorhombic with the CaFe2O4‐type structure. The cell parameters are a = 8.907 (1) Å, b = 9.937(8) Å, c = 2.981(1) Å; V = 263.8 (3) Å3; space group Pnma. The calculated density of maohokite is 5.33 g cm?3. Maohokite was formed from subsolidus decomposition of ankerite Ca(Fe2+,Mg)(CO3)2 via a self‐oxidation‐reduction reaction at impact pressure and temperature of 25–45 GPa and 800–900 °C. The formation of maohokite provides a unique example for decomposition of Fe‐Mg carbonate under shock‐induced high pressure and high temperature. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2017‐047). The mineral was named maohokite after Hokwang Mao, a staff scientist at the Geophysical Laboratory, Carnegie Institution of Washington, for his great contribution to high pressure research.  相似文献   

2.
The valences of Ti, V, and Cr in olivine and pyroxene, important indicators of the fO2 of the source region of their host rocks, can be readily measured nondestructively by XANES (X‐ray absorption near edge structure) spectroscopy, but little such work has been done on lunar rocks, and there is some uncertainty regarding the presence of Ti3+ in lunar silicates and the redox state of the lunar mantle. This is the first study involving direct XANES measurement of valences of multivalent cations in lunar rocks. Because high alumina activity facilitates substitution of Ti cations into octahedral rather than tetrahedral sites in pyroxene and Ti3+ only enters octahedral sites, two aluminous basalts from Apollo 14, 14053 and 14072, were studied. Most pyroxene contains little or no detectable Ti3+, but in both samples relatively early, magnesian pyroxene was found that has Ti valences that are not within error of 4; in 14053, this component has an average Ti valence of 3.81 ± 0.06 (i.e., Ti3+/[Ti3+ + Ti4+ = 0.19]). This pyroxene has relatively low atomic Ti/Al ratios (<0.4) due to crystallization before plagioclase, contrary to the long‐held belief that lunar pyroxene with Ti/Al > 0.5 contains Ti3+ and pyroxene with lower ratios does not. Later pyroxene, with lower Mg/Fe and higher Ti/Al ratios, has higher proportions of Ti (all Ti4+) in tetrahedral sites. All pyroxene analyzed contains divalent Cr, ranging from 15 to 30% of the Cr present, and all but one analysis spot contains divalent V, accounting for 0 to 40% (typically 20–30%) of the V present. Three analyses of olivine in 14053 do not show any Ti3+, but Ti valences in 14072 olivine range from 4 down to 3.70 ± 0.10. In 14053 olivine, ~50% of the Cr and 60% of the V are divalent. In 14072 olivine, the divalent percentages are ~20% for Cr and 20–60% for V. These results indicate significant proportions of divalent Cr and V and limited amounts of trivalent Ti in the parental melts, especially when crystal/liquid partitioning preferences are taken into account. These features are consistent with an fO2 closer to IW ? 2 than to IW ? 1. Apollo 15 basalt 15555, analyzed for comparison with A‐14 materials, has olivine with strongly reduced Cr (Cr2+/(Cr2+ + Cr3+) ~0.9). Basalts from different sites may record redox differences between source regions.  相似文献   

3.
Abstract— We studied three fluffy Type A refractory inclusions from Allende that contain orange hibonite. The melilite in the present samples is very Al‐rich, averaging Åk6, Åk14, and Åk12 in the three samples studied. Hibonite in two inclusions, unlike that in Murchison, has low rare earth element abundances of <10 × CI; in the other inclusion, the hibonite, melilite and perovskite have Group II‐like patterns. The hibonite and melilite in all three inclusions studied have excess 26Mg consistent with (26Al/27Al)I = 5 × 10?5. Much of the hibonite and some of the spinel in these inclusions is corroded. These phases are found enclosed in melilite, but based on bulk compositions and phase equilibria, hibonite should not be an early‐crystallizing phase in these inclusions. We conclude that the hibonite and probably some of the spinel is relic. Reversely zoned melilite, rounded spinel and isotopically heavy Mg in the inclusions probably reflect reheating events that involved melting and evaporation. Alteration of the gehlenitic melilite gave rise to some rare phases, including corundum and nearly pure CaTs pyroxene. Studies have shown that blue hibonite contains Ti3+ while orange hibonite does not (Ihinger and Stolper, 1986; Beckett et al., 1988). Orange hibonite formed either under oxidizing conditions (such as at oxygen fugacities at least seven orders of magnitude greater than that of a solar gas at 1700 K), or under conditions reducing enough (e.g., solar) that it contained Ti3+, which was later oxidized in situ. Although V and Ce oxides are volatile at the temperature and range of oxygen fugacities at which orange hibonite is known to be stable, we find that (a) the hibonite is V‐rich (～1 wt% V2O3) and (b) there are no negative Ce anomalies in Allende hibonite. This indicates that the hibonite did not form by condensation under oxidizing conditions. In addition, there are slight excesses of Ti + Si cations relative to Mg + Fe cations (up to 0.1 of 0.8 cations per 19 oxygen anions), probably reflecting the original presence of Ti3+. The results of this study strongly support the suggestion (Ihinger and Stolper, 1986) that Allende hibonite originally formed under reducing conditions and was later oxidized. Oxygen fugacities within ～2–3 orders of magnitude of that of a solar gas are implied; otherwise, strong Ce and V depletions would be observed.  相似文献   

4.
In this paper, we discuss the occurrence of liebermannite (IMA 2013-128), KAlSi3O8, a new, shock-generated, high-pressure tetragonal hollandite-type structure silicate mineral, in the Zagami basaltic shergottite meteorite. Liebermannite crystallizes in space group I4/m with Z = 2, cell dimensions of a = 9.15 ± 0.14 (1σ) Å, c = 2.74 ± 0.13 Å, and a cell volume of 229 ± 19 Å3 (for the type material), as revealed by synchrotron diffraction. In Zagami, liebermannite likely formed via solid-state transformation of primary igneous K-feldspar during an impact event that achieved pressures of ~20 GPa or more. The mineral name is in honor of Robert C. Liebermann, a high-pressure mineral physicist at Stony Brook University, New York, USA.  相似文献   

5.
To assess the variability of redox states among mare basalt source regions, investigation of the valence of Ti, Cr, and V and the coordination environment of Ti in pyroxene and olivine in lunar rocks via XANES (X-ray absorption near-edge structure) spectroscopy has been extended to Apollo 17 basalts: two high-Ti (70017 and 74275) hand samples, and three very low-Ti (70006,371, 70007,289B, and 70007,296) basalt fragments from the Apollo 17 deep drill core. Valences of Ti in pyroxene of both suites range from 3.6 to 4, or from 40% to 0% Ti3+, averaging 15–20% Ti3+. Assuming Ti3+ is more compatible in pyroxene than Ti4+, then even lower Ti3+ proportions are indicated for the parental melts. The VLT pyroxene exhibits a slightly wider range of V valences (2.57–2.96) than the high-Ti pyroxene (2.65–2.86) and a much wider range of Cr valences (2.32–2.80 versus 2.68–2.86); Cr is generally reduced in VLT pyroxene compared to high-Ti pyroxene. Valences of Ti and Cr in VLT pyroxene become less reduced with increasing FeO contents, possibly indicating change in oxygen fugacity during crystallization. Olivine in all samples has very low (<20%) proportions of Ti3+, with no Ti3+ and higher proportions of Ti in tetrahedral coordination in the VLTs than in the high-Ti basalts. Olivine in 74275, including that in a dunite clast, has much higher proportions of Cr2+ than the pyroxene in that sample, consistent with previous studies indicating that the olivine grains in this sample are xenocrysts and possibly indicating oxidation just prior to pyroxene crystallization. Results for this sample, the VLTs, and previously studied Apollo 14 and 15 basalts all indicate that mare magmas were in reducing environments at depth, as recorded in early crystallization products, and that later, presumably shallower environments, were relatively oxidizing; single, characteristic fO2s of formation cannot be assigned to these samples. A process likely to account for this feature seen in multiple samples is loss by degassing of a reducing, H-rich vapor (probably H2) during ascent and/or eruption, causing oxidation of the residual melt, recorded in relatively late-crystallized pyroxene.  相似文献   

6.
Abstract— The crystal structure of druse clinopyroxene from the D'Orbigny angrite, (Ca0.944 Fe2+0.042 Mg0.010Mn0.004) (Mg0.469Fe2+0.317Fe3+0.035Al0.125Cr0.010Ti0.044) (Si1.742Al0.258) O6, a = 9.7684(2), b = 8.9124(2), c = 5.2859(1) Å, β = 105.903(1)°, V = 442.58 Å3, space group C2/c, Z = 2, has been refined to an R1 index of 1.92% using single‐crystal X‐ray diffraction data. The unit formula, calculated from electron microprobe analysis, and the refined site scattering values were used to assign site populations. The distribution of Fe2+and Mg over the M1 and M2 sites suggests a closure temperature of 1000 °C. Mössbauer spectroscopy measurements were done at room temperature on a single crystal and a powdered sample. The spectra are adequately fit by a Voigt‐based quadrupole‐splitting distribution model having two generalized sites, one for Fe2+with two Gaussian components and one for Fe3+with one Gaussian component. The two ferrous components are assigned to Fe2+at the M1 site, and arise from two different next‐nearest‐neighbor configurations of Ca and Fe cations at the M2 site: (3Ca,0Fe) and (2Ca,1Fe). The Fe3+/Fetot ratio determined by Mössbauer spectroscopy is in agreement with that calculated from the electron microprobe analysis. The results are discussed in connection with the redox and thermal history of D'Orbigny.  相似文献   

7.
Ti valence measurements in MgAl2O4 spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti+4. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti+3‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti+4‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ25Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ25Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ25Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti+4 concentrations in spinel.  相似文献   

8.
MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeOtot zonation. Spinels from NWA 763 show Mg‐Fe2+ substitutions. Almost pure MgAl2O4 spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (Tc) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a Tc of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.  相似文献   

9.
Abstract— Phase fields in which hibonite and silicate melt coexist with spinel, CaAl4O7, gehlenitic melilite, anorthite or corundum at 1 bar in the system CaO-MgO-Al2O3-SiO2-TiO2 were determined. The hibonites contain up to 1.7 wt% SiO2. For TiO2, the experimentally determined partition coefficients between hibonite and coexisting melt, DHib/Li, vary from 0.8 to 2.1 and generally decrease with increasing TiO2 in the liquid. Based on Ti partitioning between hibonite and melt, bulk inclusion compositions and hibonite-saturated liquidus phase diagrams, the hibonite in hibonite-poor fluffy Type A inclusions from Allende and at least some hibonite from hibonite-rich inclusions is relict, although much of the hibonite from hibonite-glass spherules probably crystallized metastably from a melt Bulk compositions for all of these CAIs are consistent with an origin as melilite + hibonite + spinel + perovskite phase assemblages that were partially altered and in some cases partially or completely melted The duration of the melting event was sufficient to remove any Na introduced by the alteration process but frequently insufficient to dissolve all of the original hibonite. Simple thermochemical models developed for meteoritic melilite and hibonite solid solutions were used to obtain equilibration temperatures of hibonite-bearing phase assemblages with vapor. Referenced to 10?3 atm, hibonite + corundum + vapor equilibrated at ～1260 °C and hibonite + spinel ± melilite + vapor at 1215 ± 10 °C. If these temperatures reflect condensation in a cooling gas of solar composition, then hibonite ± corundum condensed first, followed by spinel and then melilite. The position of perovskite within this sequence is uncertain, but it probably began to condense before spinel. This sequence of phase appearances and relative temperatures is generally consistent with observed textures but differs from expectations based on classical condensation calculations in that equilibration temperatures are generally lower than predicted and melilite initially condenses with or even after spinel. Simple thermochemical models for the substitution of trace elements into the Ca site of meteoritic hibonites suggest that virtually all Eu is divalent in early condensate hibonites but that Eu2+/Eu3+ decreases by a factor of 20 or more during the course of condensation primarily because the ratio is proportional to the partial pressure of Al, which decreases dramatically as aluminous phases condense. The relative sizes of Eu and Yb anomalies in meteoritic hibonites and inclusions may be partly due to this effect  相似文献   

10.
Radionuclide activities were measured in the low‐background gamma‐ray spectrometry facility GeMSE in eight meteorite falls (Lost City, Tamdakht, Huaxi, Boumdeid, Xining, Kamargaon, Degtevo, and Ouidiyat Sbaa) and two finds (SaU 606 and Mürtschenstock) to evaluate the use of radionuclides for terrestrial age estimates. Results indicate that these meteorites were all derived from small‐ (r < 25 cm) to medium‐sized (r < 65 cm) meteoroids. Short‐lived 48V (t1/2 = 16.0 d) and 51Cr (t1/2 = 27.7 d) were only detected in Oudiyat Sbaa (EH), while 7Be (t1/2 = 53.1 d) was also detected in Degtevo (H) and Kamargaon (L), in agreement with reported fall dates. The 22Na/26Al activity ratio in Huaxi agrees with the previously reported short cosmic‐ray exposure age of this meteorite while 22Na/26Al in Kamargaon likely records a complex exposure history. Bayesian statistical analysis verifies the detection of very low activities of 44Ti (t1/2 = 60 a) in the relatively large H chondrites (>100 g) Degtevo, Huaxi, Tamdakht, Lost City, and SaU 606. Additionally, large samples from Oudiyat Sbaa (EH) and Kamargaon (L) gave positive detections. For H chondrite target compositions, detected 44Ti(Fe+Ni)/26Al averaged 0.055 ± 0.013. Activities of 22Na and 54Mn in SaU 606 show that this meteorite fell between July and September 2012, making SaU 606 the second recent fall from Oman identified using gamma‐ray spectrometry. The upper activity limit of 22Na in the Mürtschenstock meteorite shows that it fell prior to 1999 and is not related to a bolide observation in 2015. Mürtschenstock shows 137Cs ~10× higher than previously determined in Oman meteorites, likely due to Chernobyl fallout.  相似文献   

11.
The SOHO Ultraviolet Coronagraph Spectrometer (UVCS/SOHO) is being used to observe the extended solar corona from 1.25 to 10 R⊙ from Sun center. Initial observations of polar coronal holes and equatorial streamers are described. The observations include measurements of spectral line profiles for HI Lα and Lβ, Ovi 1032 Å and 1037 Å, Mgx 625 Å, Fexii 1242 Å and several others. Intensities for Mgx 610 Å, Sixii 499 Å, and 520 Å, Sx 1196 Å, and 22 others have been observed. Preliminary results for derived H0, O5+, Mg9+, and Fe11+ velocity distributions and initial indications of outflow velocities for O5+ are described. In streamers, the H0 velocity distribution along the line of sight (specified by the value at e-1, along the line of sight) decreases from a maximum value of about 180 km s-1 at 2 R⊙ to about 140 km s-1 at 8 R⊙. The value for O5+ increases with height reaching a value of 150 km s-1 at 4.7 R⊙. In polar coronal holes, the O5+ velocity at e-1 is about equal to that of H0 at 1.7 R⊙ and significantly larger at 2.1 R⊙. The O5+ in both streamers and coronal holes were found to have anisotropic velocity distributions with the smaller values in the radial direction.  相似文献   

12.
The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H2O+ 6158 Å, H Balmer-α 6563 Å, NH2 6330 Å, [C I] 9850 ÅCN 3879 Å, C2 5141 Å, C3 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H2O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H2O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH2O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(1 D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 106 km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H2O+ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO+and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.  相似文献   

13.
The WIYN 3.5-meter telescope and its Multi-Object Spectrograph (MOS) have been used to obtain simultaneous spectra at many points in the coma of Comet Hale-Bopp. Between 1996 October and 1997 April in excess of 7500 individual spectra were obtained, typically 96 at a time. On six nights the “Hydra” fiber positioner was used to sample a ring pattern of points about the nucleus with a minimum spacing of 40 arc seconds and a maximum radius of 22.5 arc minutes. On four nights a new “Densepak” fiber cable was used. In this configuration a 7 × 13 rectangular pattern of 91, 3 arc second fibers on 4 arc second centers was used. In most cases the bench spectrograph was used in the echelle mode with an interference filter to isolate a single order. The wavelength range from 6100 Å to 6400 Å was recorded with resolution of approximately 15,000. This spectral region contains the emission features of [OI], C2, NH2and H2O+. From this mass of data we are beginning to extract the radial, azimuthal and temporal variations of many different spectral features. The radial profiles of [O I] λ6300 Å and NH2 are reasonably well representable by the Haser model formalism, that of H2O+ is not.  相似文献   

14.
Laboratory cross-section data on the excitation of the OII(2s 2p44P → 2s2 2p34S; λ834 Å) resonance transition and on the production of O+ and O2+ ions by electron impact on atomic oxygen are used to show that the ratio σ(λ834 A?)σ(O+ + O2+) is nearly constant for incident electron energies > 50 eV. Under auroral conditions, the total electron-ion pair production rate from electron impact on O can be inferred from λ834 Å volume emission rate measurements using the result that η(O+ + O2+)$?8.4η(λ834 A?). These findings, along with earlier work on the simultaneous ionization-excitation of the 1 Neg (0,0) band of N2+ and the 1 Neg (1, 0) band of O+2, allow the specific ionization rates for the principal atmospheric constituents (O+, O+2, N+2), for the multiply-ionized species (O2+, O2+2, N2+2), and for the dissociatively produced atomic ions to be inferred in aurora from remote satellite observations.  相似文献   

15.
Abstract— Rare, ultrafine-grained Ti oxides (Ti3O5 and the Magnéli phases, Ti5O9 and Ti8O15) have been identified by transmission electron microscopy in the CM2 carbonaceous chondrite, Bells and a carbonaceous chondrite matrix clast from the Nilpena polymict ureilite. In both meteorites the Ti oxides occur in the matrix as isolated grains and clusters of two or more grains. They are euhedral in shape and have grain sizes of 0.05–0.3 μm. Magnéli phases have been recently shown to be a common component in some interplanetary dust particles, but this is the first reported occurrence in a meteorite. The morphological properties and grain size of the Ti oxides are consistent with formation by vapor phase condensation either within the solar nebula or possibly in a presolar environment.  相似文献   

16.
Ureilites are carbon‐rich ultramafic achondrites that have been heated above the silicate solidus, do not contain plagioclase, and represent the melting residues of an unknown planetesimal (i.e., the ureilite parent body, UPB). Melting residues identical to pigeonite‐olivine ureilites (representing 80% of ureilites) have been produced in batch melting experiments of chondritic materials not depleted in alkali elements relative to the Sun’s photosphere (e.g., CI, H, LL chondrites), but only in a relatively narrow range of temperature (1120 ºC–1180 ºC). However, many ureilites are thought to have formed at higher temperature (1200 ºC–1280 ºC). New experiments, described in this study, show that pigeonite can persist at higher temperature (up to 1280 ºC) when CI and LL chondrites are melted incrementally and while partial melts are progressively extracted. The melt productivity decreases dramatically after the exhaustion of plagioclase with only 5–9 wt% melt being generated between 1120 ºC and 1280 ºC. The relative proportion of pyroxene and olivine in experiments is compared to 12 ureilites, analyzed for this study, together with ureilites described in the literature to constrain the initial Mg/Si ratio of the UPB (0.98–1.05). Experiments are also used to develop a new thermometer based on the partitioning of Cr between olivine and low‐Ca pyroxene that is applicable to all ureilites. The equilibration temperature of ureilites increases with decreasing Al2O3 and Wo contents of pyroxene and decreasing bulk REE concentrations. The UPB melted incrementally, at different fO2, and did not cool significantly (0 ºC–30 ºC) prior to its disruption. It remained isotopically heterogenous, but the initial concentration of major elements (SiO2, MgO, CaO, Al2O3, alkali elements) was similar in the different mantle reservoirs.  相似文献   

17.
Photometric and spectroscopic characteristics of the WN5+O6 binary system, V444 Cyg, were studied. The Wilson‐Devinney (WD) analysis, using new BV observations carried out at the Ankara University Observatory, revealed the masses, radii, and temperatures of the components of the system as MWR = 10.64 M⊙, MO = 24.68 M⊙, RWR = 7.19 R⊙, RO = 6.85 R⊙, TWR = 31 000 K, and TO = 40000 K, respectively. It was found that both components had a full spherical geometry, whereas the circumstellar envelope of the WR component had an asymmetric structure. The O – C analysis of the system revealed a period lengthening of 0.139 ± 0.018 syr–1, implying a mass loss rate of (6.76 ± 0.39) ×10–6 M⊙ yr–1 for the WR component. Moreover, 106 IUE‐NEWSIPS spectra were obtained from NASA's IUE archive for line identification and determination of line profile variability with phase, wind velocities and variability in continuum fluxes. The integrated continuum flux level (between 1200–2000 Å) showed a mild and regular increase from orbital phase 0.00 up to 0.50 and then a decrease in the same way back to phase 0.00. This is evaluated as the O component making a constant and regular contribution to the system's UV light as the dominant source. The C IV line, originating in the circumstellar envelope, had the highest velocity while N IV line, originating in deeper layers of the envelope, had the lowest velocity. The average radial velocity calculated by using the C IV line (wind velocity) was found as 2326 km s–1 (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

18.
Keenan  F.P.  Katsiyannis  A.C.  Ramsbottom  C.A.  Bell  K.L.  Brosius  J.W.  Davila  J.M.  Thomas  R.J. 《Solar physics》2004,219(2):251-263

Recent R-matrix calculations of electron impact excitation rates in N-like Si VIII are used to derive theoretical emission line intensity ratios involving 2s 22p 3–2s2p 4 transitions in the 216–320 Å wavelength range. A comparison of these with an extensive dataset of solar active region, quiet-Sun, sub-flare and off-limb observations, obtained during rocket flights of the Solar EUV Research Telescope and Spectrograph (SERTS), indicates that the ratio R 1= I(216.94 Å)/I(319.84 Å) may provide a usable electron density diagnostic for coronal plasmas. The ratio involves two lines of comparable intensity, and varies by a factor of about 5 over the useful density range of 108–1011 cm?3. However R 2= I(276.85 Å)/I(319.84 Å) and R 3=I(277.05 Å)/I(319.84 Å) show very poor agreement between theory and observation, due to the severe blending of the 276.85 and 277.05 Å lines with Si VII and Mg VII transitions, respectively, making the ratios unsuitable as density diagnostics. The 314.35 Å feature of Si VIII also appears to be blended, with the other species contributing around 20% to the total line flux.

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19.
The published data on the temperature dependence of the radiative combination of atomic oxygen with nitric oxide at pressures near 1 torr is examined. Arguments are advanced to suggest that radiation near the cut-off wavelength (～ 3875Å) is coming from the unstabilized activated complex, No12. At 4000Å a positive activation energy of 1 kcal mole?1 is deduced. Application of this temperature dependence with the rate coefficient at 5200Å is made to airglow measurements in aurora. The deduced NO concentration is about 109 cm?3, in general agreement with that deduced from the measured NO+/O+2 ratio as well as an auroral model prediction.  相似文献   

20.
We present multi-colour CCD observations of the low-temperature contact binaries, V453 Mon and V523 Cas. Their light curves are modelled to determine a new set of stellar and orbital parameters. Analysis of mid-eclipse times yields a new linear ephemeris for both systems. A period decrease (dP/dt=2.3×10−7 days/yr) in V453 Mon is discovered. V523 Cas, however, is detected to show a period increase (dP/dt=9.8×10−8 days/yr) because of the mass transfer of a rate of 1.1×10−7 M⊙ yr−1, from a less massive donor. Using these findings we can determine the physical parameters of the components of V523 Cas to be M 1=0.76 (3)M ⊙, M 2=0.39 (2)M ⊙, R 1=0.74 (2)R ⊙, R 2=0.55 (2)R ⊙, L 1=0.19 (3)L ⊙, L 2=0.14 (3)L ⊙, and the distance of system as 46(9) pc.  相似文献   

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