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1.
Abstract— The S(IV)-type asteroid 6 Hebe is identified as the probable parent body of the H-type ordinary chondrites and of the IIE iron meteorites. The ordinary chondrites are the most common type of meteorites falling to Earth; but prior to the present study, no large mainbelt source bodies have been confirmed. Hebe is located adjacent to both the v6 and 3:1 resonances and has been previously suggested as a major potential source of the terrestrial meteorite flux. Hebe exhibits subtle rotational spectral variations, indicating the presence of some compositional variations across its surface. The silicate portion of the surface assemblage of Hebe is consistent (both in overall average and in its range of variation) with the silicate components in the suite of H-type chondrites. The high albedo of Hebe rules out a lunar-style space weathering process to produce the weakened absorption features and reddish spectral slope in the S-type spectrum of Hebe. Linear unmixing models show that a typical Ni-Fe metal spectrum is consistent with the component that modifies an H-chondrite spectrum to produce the S-type spectrum of Hebe. On the basis of the association between the H chondrites and the HE iron meteorites, our model suggests that large impacts onto the relatively metal-rich H-chondrite target produced melt bodies (sheets or pods) that differentiated to form thin, laterally extensive near-surface layers of Ni-Fe metal. Fragments of the upper silicate portions of these melt bodies are apparently represented by some of the igneous inclusions in H-chondrite breccias. Alternately, masses of metal could have been deposited on the surface of Hebe by the impact of a core or core fragment from a differentiated parent body of H-chondrite composition. Subsequent impacts preferentially eroded and depleted the overlying silicate and regolith components, exposing and maintaining large masses of metal at the optical surface of Hebe. In this interpretation, the nonmagmatic IIE iron meteorites are samples of the Ni-Fe metal masses on the surface of Hebe, whereas the H chondrites are samples from between and/or beneath the metal masses.  相似文献   

2.
Abstract– The Grove Mountains (GRV) 021663 meteorite was collected from the Grove Mountains region of Antarctica. The meteorite is composed primarily of olivine (Fa5.4), orthopyroxene (Fs4.7Wo3.0), chromian diopside (En53.6Fs2.4Wo44), troilite, kamacite, and plagioclase (Ab74.5Or4An21.5). Minor phases include schreibersite and K‐feldspar. The meteorite is highly weathered (W3) and weakly shocked (S2). We determine a whole rock oxygen isotopic composition of δ18O = 7.50‰, δ17O = 3.52‰. Comparisons of these data with other primitive achondrites have resulted in the reclassification of this meteorite as a member of the winonaite group. The occurrences of troilite, metal, and schreibersite in GRV 021663 indicate that these minerals were once completely molten. Euhedral inclusions of pyroxene within plagioclase further suggest that these may have crystallized from a silicate melt, while the depletion of plagioclase, metal, and troilite indicates that GRV 021663 could represent a residuum following partial melting on its parent asteroid. Trace element distributions in silicate minerals do not, however, confirm this scenario. As with other winonaite meteorites, the formation of GRV 021663 probably relates to brecciation and mixing of heterogeneous lithologies, followed by varying degrees of thermal metamorphism on the parent body asteroid. Peak metamorphic conditions may have resulted in localized partial melting of metal and silicate mineralogies, but our data are not conclusive.  相似文献   

3.
4.
Abstract— A crusted stone weighing 3.10 kg was found in 1983 near Tabbita in south central New South Wales (ca. 34°03′S, 145°50′E), Australia. Compositions of the ferro-magnesian silicates (olivine Fa24.6; orthopyroxene Fs20.9) show that the meteorite belongs to the L-group of chondrites. Uniformity of silicate compositions and the presence of abundant crystalline plagioclase feldspar (An10.8Ab81.7Or7.5) show that the meteorite belongs to petrologic type 6. Silicates that display undulose extinction, and the absence of any thermal effects induced by shock indicate that Tabbita is shock facies c. Tabbita is distinct from several other L6 chondrites found in the same general area.  相似文献   

5.
Abstract— The Frontier Mountain (FRO) 93001 meteorite is a 4.86 g fragment of an unshocked, medium‐ to coarse‐grained rock from the acapulcoite‐lodranite (AL) parent body. It consists of anhedral orthoenstatite (Fs13.3 ± 0.4Wo3.1 ± 0.2), augite (Fs6.1 ± 0.7Wo42.3 ± 0.9; Cr2O3 = 1.54 ± 0.03), and oligoclase (Ab80.5 ± 3.3Or3.1 ± 0.6) up to >1 cm in size enclosing polycrystalline aggregates of fine‐grained olivine (average grain size: 460 ± 210 μm) showing granoblastic textures, often associated with Fe,Ni metal, troilite, chromite (cr# = 0.91 ± 0.03; fe# = 0.62 ± 0.04), schreibersite, and phosphates. Such aggregates appear to have been corroded by a melt. They are interpreted as lodranitic xenoliths. After the igneous (the term “igneous” is used here strictly to describe rocks or minerals that solidified from molten material) lithology intruding an acapulcoite host in Lewis Cliff (LEW) 86220, FRO 93001 is the second‐known silicate‐rich melt from the AL parent asteroid. Despite some similarities, the silicate igneous component of FRO 93001 (i.e., the pyroxene‐plagioclase mineral assemblage) differs in being coarser‐grained and containing abundant enstatite. Melting‐crystallization modeling suggests that FRO 93001 formed through high‐degree partial melting (≥35 wt%; namely, ≥15 wt% silicate melting and ?20 wt% metal melting) of an acapulcoitic source rock, or its chondritic precursor, at temperatures ≥1200 °C, under reducing conditions. The resulting magnesium‐rich silicate melt then underwent equilibrium crystallization; prior to complete crystallization at ?1040 °C, it incorporated lodranitic xenoliths. FRO 93001 is the highest‐temperature melt from the AL parent‐body so far available in laboratory. The fact that FRO 93001 could form by partial melting and crystallization under equilibrium conditions, coupled with the lack of quench‐textures and evidence for shock deformation in the xenoliths, suggests that FRO 93001 is a magmatic rock produced by endogenic heating rather than impact melting.  相似文献   

6.
Abstract— Aubritic oldhamite (CaS) has been the subject of intense study recently because it is the major rare-earth-element (REE) carrier in aubrites, has a variety of REE patterns comparable to those in unequilibrated enstatite chondrites and has an extraordinarily high melting point as a pure substance (2525 °C). These latter two facts have caused some authors to assert that much of the aubritic oldhamite is an unmelted nebular relict, rather than of igneous origin. We have conducted REE partitioning experiments between oldhamite and silicate melt using an aubritic bulk composition at 1200 °C and 1300 °C and subsolidus annealing experiments. All experiments produced crystalline oldhamite, with a range of compositions, glass and Fe metal, as well as enstatite, SiO2, diopside and troilite in some charges. Rare-earth-element partitioning is strongly dependent on oldhamite composition and temperature. Subsolidus annealing results in larger partition coefficients for some oldhamite grains, particularly those in contact with troilite. All experimental oldhamite/silicate melt partition coefficients are <20 and the vast majority are <5, which is similar to those reported in the literature and is two orders of magnitude less than those inferred for natural aubritic oldhamite. These partition coefficients preclude a simple igneous model, since REE abundances in aubritic oldhamite are greater than would be predicted on the basis of the experimental partition coefficients. Our experimental partition coefficients are consistent with a relict nebular origin for aubritic oldhamite, although experimental evidence that suggests melting of oldhamite at temperatures lower than that reached on the aubrite parent body are clearly inconsistent with the nebular model. Our experiments are consistent also with a complex igneous history. Oldhamite REE patterns may reflect a complex process of partial melting, melt removal, fractional crystallization and subsolidus annealing and exsolution. These mechanisms (primarily fractional crystallization and subsolidus annealing) can produce a wide range of REE patterns in aubritic oldhamite, as well as elevated (100–1000 × CI) REE abundances observed in aubritic oldhamite.  相似文献   

7.
Abstract— Mineralogy, major element compositions of minerals, and elemental and oxygen isotopic compositions of the whole rock attest to a lunar origin of the meteorite Northwest Africa (NWA) 032, an unbrecciated basalt found in October 1999. The rock consists predominantly of olivine, pyroxene and chromite phenocrysts, set in a crystalline groundmass of feldspar, pyroxene, ilmenite, troilite and trace metal. Whole‐rock shock veins comprise a minor, but ubiquitous portion of the rock. Undulatory to mosaic extinction in olivine and pyroxene phenocrysts and micro‐faults in groundmass and phenocrysts also are attributed to shock. Several geochemical signatures taken together indicate unambiguously that NWA 032 originated from the Moon. The most diagnostic criteria include whole‐rock oxygen isotopic composition and ratios of Fe/Mn in the whole rock, olivine, and pyroxene. A lunar origin is documented further by the presence of Fe‐metal, troilite, and ilmenite; zoning to extremely Fe‐rich compositions in pyroxene; the ferrous oxidation state of all Fe in pyroxene; and the rare earth element (REE) pattern with a well‐defined negative europium anomaly. This rock is similar in major element chemistry to basalts from Apollo 12 and 15, but is enriched in light REE and has an unusually high Th/Sm ratio. Some Apollo 14 basalts yield a closer match to NWA 032 in REE patterns, but have higher concentrations of Al2O3. Ar‐Ar step release results are complex, but yield a whole‐rock age of ?2.8 Ga, suggesting that NWA 032 was extruded at 2.8 Ga or earlier. This rock may be the youngest sample of mare basalt collected to date. Noble gas concentrations combined with previously collected radionuclide data indicate that the meteorite exposure history is distinct from currently recognized lunar meteorites. In short, the geochemical and petrographic features of NWA 032 are not matched by Apollo or Luna samples, nor by previously identified lunar meteorites, indicating that it originates from a previously unsampled mare deposit. Detailed assessment of petrographic features, olivine zoning, and thermodynamic modelling indicate a relatively simple cooling and crystallization history for NWA 032. Chromite‐spinel, olivine, and pyroxene crystallized as phenocrysts while the magma cooled no faster than 2 °C/h based on the polyhedral morphology of olivine. Comparison of olivine size with crystal growth rates and preserved Fe‐Mg diffusion profiles in olivine phenocrysts suggest that olivine was immersed in the melt for no more than 40 days. Plumose textures in groundmass pyroxene, feldspar, and ilmenite, and Fe‐rich rims on the phenocrysts formed during rapid crystallization (cooling rates ?20 to 60 °C/h) after eruption.  相似文献   

8.
Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ17O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.  相似文献   

9.
Abstract— Compositional and textural relationships of shock‐melted glasses in the Allan Hills (ALH) 84001 meteorite have been examined by optical microscopy, electron microprobe analysis, and compositional mapping. The feldspathic and silica glasses exhibit features which constrain the relative timing of shock events and carbonate deposition in ALH 84001. The feldspathic glasses are stoichiometric and have compositions plausibly described as forming from igneous plagioclase (An27–39Ab58–68Or3–7) or sanidine (Or51Ab46An3), or from a mixture of these phases (mixed‐feldspar glasses). These observations argue against prior interpretations of feldspathic glasses as unflowed maskelynite, hydrothermal precipitates or alteration products, or shock melts that have undergone alkali volatilization. Carbonate was deposited around previously formed mixed‐feldspar glass clasts, suggesting that carbonate deposition occurred after the shock event that formed the granular bands (crushed zones) in this meteorite. SiO2‐rich glasses appear to be silica remobilized during shock, with little addition of other material. A petrogenetic history of ALH 84001 consistent with the observations of feldspathic and silica glasses is (1) igneous crystallization and cumulate formation; (2) a pre‐carbonate shock event that formed the granular bands (crushed zones) and sheared chromites, and melted igneous plagioclase and sanidine to form mixed‐feldspar glasses; (3) carbonate and silica deposition in the granular bands (veining of plagioclase glasses by SiO2 and deposition of carbonate around mixed‐feldspar and plagioclase glass clasts); (4) a post‐carbonate shock event that resulted in invasion of carbonate by feldspathic melts, shock faulting and decarbonation of carbonate, high‐temperature mobilization of silica melts, and minor dissolution of orthopyroxene by silica melts.  相似文献   

10.
Abstract– Northwest Africa (NWA) 5298 is an evolved basaltic shergottite that has bulk characteristics and mineral compositions consistent with derivation from an oxidized reservoir in Mars. Chemically zoned clinopyroxene (64.5%, augite and pigeonite), with interstitial lath‐shaped plagioclase (29.4%, An40 to An55), constitutes the bulk of this meteorite. The plagioclase has been converted by shock to both isotropic maskelynite and spherulitic, birefringent feldspar representing a quenched vesicular melt. The remainder of the rock consists of minor amounts of Fe‐Ti oxides (ilmenite and titanomagnetite), phosphates (merrillite and apatite), silica polymorph, fayalite, pyrrhotite, baddeleyite, and minor hot desert weathering products (calcite and barite). Oxygen fugacity derived from Fe‐Ti oxide thermobarometry is close to the quartz‐fayalite‐magnetite (QFM) buffer indicating that the late stage evolution of this magma occurred under more oxidizing condition than those recorded in most other shergottites. Merrillite contains the largest abundances of rare earth elements (REE) of all phases, thereby controlling the REE budget in NWA 5298. The calculated bulk rock REE pattern normalized to CI chondrite is relatively flat. The evolution of the normalized REE patterns of the bulk rock, clinopyroxene, plagioclase, and phosphate in NWA 5298 is consistent with closed‐system chemical behavior with no evidence of crustal contamination or postcrystallization disturbance of the REE contents of these phases.  相似文献   

11.
Abstract— We report on the discovery of a new shergottite from South Morocco. This single stone weighing 320 g is referenced as Northwest Africa (NWA) 856 with Djel Ibone as a synonymous name. It is a fresh, fine‐grained basaltic rock consisting mainly of two pyroxenes (total ?68 vol%: 45% pigeonite, En61‐16Wo9–22Fs26–68; 23% augite, En46‐26Wo34‐29Fs21–43) and plagioclase converted to maskelynite (?23 vol%, Ab43–57Or1–5An54‐36). Accessory minerals include merrillite, Cl‐apatite, pyrrhotite, ilmenite, ulvöspinel, silica (stishovite and glass), amorphous K‐feldspar and baddeleyite. Amorphous mixtures of maskelynite and silica occur most commonly as median layers inside maskelynite laths. In addition, melt pockets (?2 vol%) were recognized with relics of maskelynite, pyroxene and both dense silica glass and stishovite occurring as both grains and submicrometer needles. The compositions of the melt pockets are consistent with mixtures of maskelynite and pyroxenes with an average of ?50 vol% maskelynite. The meteorite is highly fractured at all scales. The bulk composition of NWA 856 has been measured for 44 elements. It is an Al‐poor ferroan basaltic rock which strongly resembles Shergotty and Zagami in its major and trace element composition. The nearly flat rare earth element (REE) pattern (La/Lu)n = 0.9, is similar to that of Shergotty or Zagami and differs significantly from NWA 480, another Moroccan shergottite recently described. According to the U, Ba and Sr abundances, NWA 856 is not significantly weathered. The oxygen isotopes (δ18O = +5.03%, δ17O = +3.09%, and Δ17O = +0.47%) are in agreement with the martian origin of this meteorite. On the basis of grain size, pyroxene zoning and composition, abundance of silica inclusions associated with maskelynite, trace element abundances, REE pattern and oxygen isotopes, pairing with NWA 480 is excluded. The similarity with Shergotty and Zagami is striking. The only significant differences are a larger grain size, a greater abundance of silica and melt pockets, a slightly more restricted range of pyroxene compositions and the absence of significant mesostasis.  相似文献   

12.
Abstract— A devitrified glass inclusion from the Guin (UNGR) iron consists of cryptocrystalline feldspars, pyroxenes, and silica and is rich in SiO2, Al2O3, and Na2O. It contains a rutile grain and is in contact with a large Cl apatite. The latter is very rich in rare earth elements (REEs) (~80 × CI), which display a flat abundance pattern, except for Eu and Yb, which are underabundant. The devitrified glass is very poor in REEs (<0.1 × CI), except for Eu and Yb, which have positive abundance anomalies. Devitrified glass and Cl apatite are out of chemical equilibrium and their complementary REE patterns indicate a genesis via condensation under reducing conditions. Inclusion 1 in the Kodaikanal (IIE) iron consists of glass only, whereas inclusion 2 consists of clinopyroxene, which is partly overgrown by low‐Ca pyroxene, and apatite embedded in devitrified glass. All minerals are euhedral or have skeletal habits indicating crystallization from the liquid precursor of the glass. Pyroxenes and the apatite are rich in trace elements, indicating crystallization from a liquid that had 10–50 × CI abundances of REEs and refractory lithophile elements (RLEs). The co‐existing glass is poor in REEs (~0.1–1 × CI) and, consequently, a liquid of such chemical composition cannot have crystallized the phenocrysts. Glasses have variable chemical compositions but are rich in SiO2, Al2O3, Na2O, and K2O as well as in HFSEs, Be, B, and Rb. The REE abundance patterns are mostly flat, except for the glass‐only inclusion, which has heavy rare earth elements (HREEs) > light rare earth elements (LREEs) and deficits in Eu and Yb—an ultrarefractory pattern. The genetic models suggested so far cannot explain what is observed and, consequently, we offer a new model for silicate inclusion formation in IIE and related irons. Nebular processes and a relationship with E meteorites (Guin) or Ca‐Al‐rich inclusions (CAIs) (Kodaikanal) are indicated. A sequence of condensation (CaS, TiN or refractory pyroxene‐rich liquids) and vapor‐solid elemental exchange can be identified that took place beginning under reducing and ending at oxidizing conditions (phosphate, rutile formation, alkali and Fe2+ metasomatism, metasomatic loss of REEs from glass).  相似文献   

13.
Here, the petrological features of numerous primitive achondrites and highly equilibrated chondrites are evaluated to review and expand upon our knowledge of the chondrite–achondrite transition, and primitive achondrites in general. A thermodynamic model for the initial silicate melting temperature and progressive melting for nearly the entire known range of oxidation states is provided, which can be expressed as Tm = 0.035Fa2?3.51Fa + 1109 (in °C, where Fa is the proportion of fayalite in olivine). This model is then used to frame a discussion of textural and mineralogical evolution of stony meteorites with increasing temperature. We suggest that the metamorphic petrology of these meteorites should be based on diffusive equilibration among the silicate minerals, and as such, the chondrite–achondrite transition should be defined by the initial point of silicate melting, not by metal–troilite melting. Evidence of silicate melting is preserved by a distinctive texture of interconnected interstitial plagioclase ± pyroxene networks among rounded olivine and/or pyroxene (depending on ?O2), which pseudomorph the former silicate melt network. Indirectly, the presence of exsolution lamellae in augite in slowly cooled achondrites also implies that silicate melting occurred because of the high temperatures required, and because silicate melt enhances diffusion. A metamorphic facies series is defined: the Plagioclase Facies is equivalent to petrologic types 5 and 6, the Sub‐calcic Augite Facies is bounded at lower temperatures by the initiation of silicate melting and at higher temperatures by the appearance of pigeonite, which marks the transition to the Pigeonite Facies.  相似文献   

14.
Feldspar in ordinary chondrites (OCs) is often associated with thermal metamorphism, as a secondary mineral that forms from the crystallization of matrix and chondrule mesostasis. However, studies of feldspar in equilibrated OCs show that there is a range of plagioclase compositions within chondrules, some of which may be primary products of chondrule crystallization. It is important to recognize primary feldspar within chondrules because it can be used to help understand the secondary effects of thermal metamorphism and aqueous alteration. The presence of primary feldspar also provides important petrologic constraints on chondrule formation time scales. We undertook a careful study of Semarkona (LL3.00) and observed feldspar in 18% of chondrules. The feldspar is plagioclase covering a wide range of compositions (An2–An99) with little K‐feldspar component (<Or3). We show that plagioclase is a primary igneous phase, based on grain morphology and compositions consistent with growth from a melt having the bulk compositions of the host chondrules. Based on experimental studies, the presence of plagioclase suggests chondrules cooled slowly at temperatures close to the solidus. We also observed several secondary features consistent with the aqueous alteration. These features include zoning of Na and Ca in plagioclase, heterogeneity in plagioclase compositions in altered chondrules, development of porosity from the dissolution of chondrule glass, and alteration of glass to phyllosilicates. Alteration of major Al‐bearing phases, like plagioclase and glass, has important implications for interpretations of ages derived from Al‐Mg dating of chondrules, if they have been affected by secondary processes.  相似文献   

15.
Northwest Africa (NWA) 4898 is the only low‐Ti, high‐Al basaltic lunar meteorite yet recognized. It predominantly consists of pyroxene (53.8 vol%) and plagioclase (38.6 vol%). Pyroxene has a wide range of compositions (En12–62Fs25–62Wo11–36), which display a continuous trend from Mg‐rich cores toward Ca‐rich mantles and then to Fe‐rich rims. Plagioclase has relatively restricted compositions (An87–96Or0–1Ab4–13), and was transformed to maskelynite. The REE zoning of all silicate minerals was not significantly modified by shock metamorphism and weathering. Relatively large (up to 1 mm) olivine phenocrysts have homogenous inner parts with Fo ~74 and sharply decrease to 64 within the thin out rims (~30 μm in width). Four types of inclusions with a variety of textures and modal mineralogy were identified in olivine phenocrysts. The contrasting morphologies of these inclusions and the chemical zoning of olivine phenocrysts suggest NWA 4898 underwent at least two stages of crystallization. The aluminous chromite in NWA 4898 reveals that its high alumina character was inherited from the parental magma, rather than by fractional crystallization. The mineral chemistry and major element compositions of NWA 4898 are different from those of 12038 and Luna 16 basalts, but resemble those of Apollo 14 high‐Al basalts. However, the trace element compositions demonstrate that NWA 4898 and Apollo 14 high‐Al basalts could not have been derived from the same mantle source. REE compositions of its parental magma indicate that NWA 4898 probably originated from a unique depleted mantle source that has not been sampled yet. Unlike Apollo 14 high‐Al basalts, which assimilated KREEPy materials during their formation, NWA 4898 could have formed by closed‐system fractional crystallization.  相似文献   

16.
Theoretical seismic properties of the planet Mars are investigated on the basis of the various models which have been proposed for the internal composition of the planet. The latest interpretation of gravity field data (Reasenberg, 1977), assuming a lower value of the moment of inertia, would require a less dense mantle and a larger core than previous models. If Mars is chondritic in composition, the most reasonable models are an incompletely differentiated H-chondrite or a mixture of H-chondrites and carbonaceous chondrites. Seismic profiles, travel times, and free oscillation periods are computed for various models, with the aim of establishing which seismic data is crucial for deciding among the alternatives. A detailed discussion is given of the seismic properties which could—in principle—help answer the following two questions: Is Mars' core liquid or solid? Does Mars have a partially molten asthenosphere in its upper mantle?  相似文献   

17.
Abstract— The Yarle Lakes 001 meteorite was a single stone of 913 g found approximately 20 km north of Watson, South Australia, in 1990 October. It consists of olivine (Fa18.7 ± 0.4, n = 30), low-Ca pyroxene (Fs16.6 ± 0.2 Wo 12 + 0.4, n = 15). feldspar, high-Ca pyroxene, metallic Fe-Ni and troilite. Based on texture and mineral chemistry, Yarle Lakes 001 is classified as a H5 chondrite of shock stage S3.  相似文献   

18.
Abstract— We have performed petrologic and geochemical studies of Patuxent Range (PAT) 91501 and Lewis Cliff (LEW) 88663. PAT 91501, originally classified as an L7 chondrite, is rather a unique, near total impact melt from the L‐chondrite parent body. Lewis Cliff 88663 was originally classified as an “achondrite (?)”, but we find that it is a very weakly shocked L7 chondrite. PAT 91501 is an unshocked, homogeneous, igneous‐textured ultramafic rock composed of euhedral to subhedral olivine, low‐Ca pyroxene, augite and chrome‐rich spinels with interstitial albitic plagioclase and minor silica‐alumina‐alkali‐rich glass. Only ~10% relic chondritic material is present. Olivine grains are homogeneous (Fa25.2–26.8). Low‐Ca pyroxene (Wo1.9–7.2En71.9–78.2Fs19.9–20.9) and augite (Wo29.8–39.0En49.2–55.3Fs11.8–14.9) display a strong linear TiO2‐Al2O3 correlation resulting from igneous fractionation. Plagioclase is variable in composition; Or3.0–7.7Ab79.8–84.1An8.2–17.2.‐Chrome‐rich spinels are variable in composition and zoned from Cr‐rich cores to Ti‐Al‐rich rims. Some have evolved compositions with up to 7.9 wt% TiO2. PAT 91501 bulk silicate has an L‐chondrite lithophile element composition except for depletions in Zn and Br. Siderophile and chalcophile elements are highly depleted due to sequestration in centimeter‐size metal‐troilite nodules. The minerals in LEW 88663 are more uniform in composition than those in PAT 91501. Olivine grains have low CaO and Cr2O3 contents similar to those in L5–6 chondrites. Pyroxenes have high TiO2 contents with only a diffuse TiO2‐Al2O3 correlation. Low‐Ca pyroxenes are less calcic (Wo1.6–3.1En76.5–77.0Fs20.4–21.4), while augites (Wo39.5–45.6En46.8–51.1Fs7.6–9.4) and plagioclases (Or2.6–5.7Ab74.1–83.1An11.2–23.3) are more calcic. Spinels are homogeneous and compositionally similar to those in L6 chondrites. LEW 88663 has an L‐chondrite bulk composition for lithophile elements, and only slight depletions in siderophile and chalcophile elements that are plausibly due to weathering and/or sample heterogeneity.  相似文献   

19.
High Possil and Strathmore are the first (1804) and last (1917) meteorite falls, respectively, of the three recorded in Scotland. Olivine compositions and total Fe contents in High Possil (Fa25.2; 21.35 wt %) and Strathmore (Fa25.3; 20.6 wt %) confirm their classification as L-group chondrites (Mason, 1963), and the presence of abundant plagioclase feldspar shows that both chondrites belong to petrologic type 6. Both chondrites display thermal and mechanical alteration attributable to moderate shock-loading appropriate to facies c (High Possil) and c-d (Strathmore) (Dodd and Jarosewich, 1979). Incipient shock-melting of metal and troilite in both chondrites is the first described from Lc chondrites, and differences in the responses of metallic and silicate minerals to shock-loading are discussed.  相似文献   

20.
A 435 kg piece of the Mont Dieu iron meteorite (MD) contains cm‐sized silicate inclusions. Based on the concentration of Ni, Ga, Ge, and Ir (8.59 ± 0.32 wt%, 25.4 ± 0.9 ppm, 61 ± 2 ppm, 7.1 ± 0.4 ppm, respectively) in the metal host, this piece can be classified as a IIE nonmagmatic iron. The silicate inclusions possess a chondritic mineralogy and relict chondrules occur throughout the inclusions. Major element analysis, oxygen isotopic analysis (Δ17O = 0.71 ± 0.02‰), and mean Fa and Fs molar contents (Fa15.7 ± 0.4 and Fs14.4 ± 0.5) indicate that MD originated as an H chondrite. Because of strong similarities with Netschaëvo IIE, MD can be classified in the most primitive subgroup of the IIE sequence. 40Ar/39Ar ages of 4536 ± 59 Ma and 4494 ± 95 Ma obtained on pyroxene and plagioclase inclusions show that MD belongs to the old (~4.5 Ga) group of IIE iron meteorites and that it has not been perturbed by any subsequent heating event following its formation. The primitive character of MD sheds light on the nature of its formation process, its thermal history, and the evolution of its parent body.  相似文献   

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