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1.
M. Kruhm-Pimpl 《洁净——土壤、空气、水》1993,21(3):145-152
The results of a series of investigations are presented, performed by the governmental chemical laboratory Karlsruhe (CLUA) in order to determine pesticides in drinking water for purposes of food monitoring. 231 samples of 8 municipal water supplies (groundwater wells/no bank filtrate) and 34 private water supplies close to the bank of the river Rhine (groundwater wells/partly bank filtrate) were analysed. The sampling sites were located between Mannheim and Greffern, Germany. In 1986 high amounts of atrazine and simazine were determined in the drinking water wells of several private water supplies, especially at the sampling sites in the south. The likewise high chloride content of the samples was taken as a proof of bank filtrate contributing to the water. The decrease of atrazine load in the river water of the Rhine since 1987 has its parallel in the analytical results for the concerned drinking water wells. Obviously the pesticide contamination of water from bank filtrate pumping wells is mainly depending on the pesticide load of the river water. The application of fertilizers and pesticides in the fields seems not to be a significant source of the pesticide contamination of dringing waters derived from bank filtrate water. For reasons of public health a monitoring of pesticide content in bank filtrate pumping wells of private water supplies is recommended. 相似文献
2.
W. Gilsbach 《洁净——土壤、空气、水》1993,21(2):89-102
The applicability of gas chromatography for the determination of pesticides in aquatic systems is described. Potential and limitations of different methods for derivatization, chromatographic separation and detection are discussed. The analytical strategies for determination of pesticides with different chemical properties are given presenting examples from governmental laboratory analytical experience. 相似文献
3.
In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner. 相似文献
4.
GC/MS Nontarget Analysis to Examine an Organic Groundwater Contamination. Part I: Sampling – Analysis – Identification GC/MS nontarget analysis is a combination of an extraction sequence and a GC/MS analysis without standards. The extraction sequence should enrich a wide range of organic substances with different chemical and physical properties. The GC/MS analysis without standards evaluates the total chromatogram whereas the possibilities of compound identification are limited. This kind of view is suited very well if the task of examinations are unknown organic contaminations and the conventional target analysis has to be expanded to a large number of compounds with the uncertainty of detecting the main contaminants. The extraction sequence is similar to the EPA 625 analysis of base/neutral and acid extractable organic compounds. Basis are liquid extraction and solid-phase extraction at different pH values. This extraction procedure covers approximately 30 % of total organic carbon of these groundwater samples from a contaminated area near a low temperature carbonization plant. Relevant groups of organic compounds analyzed in the contaminated groundwater or in the reference sample are substituted aromatics, phenols, benzoamines (anilines), and derivates of benzothiophene. Differences in the trace substance mixtures between the contaminated samples and the reference sample are demonstrated by applying modern graphical methods. 相似文献
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6.
B. BUTTKUS 《Geophysical Prospecting》1975,23(4):712-748
The application of homomorphic filtering in marine seismic reflection work is investigated with the aims to achieve the estimation of the basic wavelet, the wavelet deconvolution and the elimination of multiples. Each of these deconvolution problems can be subdivided into two parts: The first problem is the detection of those parts in the cepstrum which ought to be suppressed in processing. The second part includes the actual filtering process and the problem of minimizing the random noise which generally is enhanced during the homomorphic procedure. The application of homomorphic filters to synthetic seismograms and air-gun measurements shows the possibilities for the practical application of the method as well as the critical parameters which determine the quality of the results. These parameters are:
- a) the signal-to-noise ratio (SNR) of the input data
- b) the window width and the cepstrum components for the separation of the individual parts
- c) the time invariance of the signal in the trace.
7.
Christian Lehr Philipp Rauneker Marcus Fahle Tobias L. Hohenbrink Steven Böttcher Marco Natkhin Björn Thomas Ralf Dannowski Bernd Schwien Gunnar Lischeid 《水文研究》2017,31(3):750-752
Physical models are a well‐established tool in education to strengthen hydrological understanding. They facilitate the straightforward visualization of hydrological processes and allow the communication of hydrological concepts, research and questions of general interest to the public. In order to visualize the water cycle in a landscape of postglacial sediments, in particular the subsurface part, a physical model was constructed. In two videos, (1) a detailed construction manual and (2) visualization examples of hydrological concepts and processes are presented. With our contribution, we like to encourage professionals in the field of hydrology to share methods and tools of knowledge transfer and communication of hydrological concepts. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
8.
The problem of predicting future short-term chemical behaviour in acidic and acid-sensitive streams is addressed. A relatively simple method is presented which combines a chemical technique for splitting the hydrograph into ground water and soil water components, based on the conservative component acid neutralization capacity, with the long-term hydrochemical model (MAGIC) in a ‘two-box’ mode. This method, coupled with a chemical speciation program (ALCHEMI), is used to assess short-term variations in stream chemistry with change in atmospheric deposition chemistry. The method is applied for a semi-natural moorland catchment in mid-Wales (Afon Gwy). For both hydrogen ion and inorganic aluminium, the modelled stream mixing relationships are non-linear, particularly at low hydrogen ion concentrations. The results also show that the relationship between hydrogen ion and inorganic aluminium concentrations varies with time in the stream. This result has important implications as it implies that aluminium concentrations will not recover, with reduced anthropogenic sulphur deposition, as rapidly as has previously been thought. Two methods, for use with critical load evaluation of ecological stress, are presented for describing the changes occurring: the hydrogen ion and inorganic aluminium concentration duration curve; the hydrogen ion and inorganic aluminium incident frequenty diagram. 相似文献
9.
K.-E. Quentin 《洁净——土壤、空气、水》1989,17(4):359-363
Summary: In the drinking-water regulation of the Federal Republic of Germany limit values in the range of 0.1 μg/l are established for pesticides. Identification and quantitative determination of pesticides in this concentration range require a very high expenditure concerning analysis, devices and equipment, analytical methods having been available so far only on a limited scale. The sum limit value of 0.5 μg/l pesticides may create special difficulties. In general, in view of the approx. 300 possible substances first of all a screening has to be proposed concerning the exceeding of limit values based on knowledge from the catchment area and its potential loading as the first step of investigation. Suitable methods of determination are partly available in gas chromatography and high-pressure liquid chromatography. Promising in the future development are the biochemical methods of enzyme inhibition (cholinesterase) and of immunoassay with radioactive and enzyme labelling. Nevertheless, for the foreseeable future standard methods will be available only for approx. Two thirds of the total of 300 substances, so that discussing the effectiveness of the limit values should be carried on. 相似文献
10.
David T. Adamson Thomas E. McHugh Michal W. Rysz Roberto Landazuri Charles J. Newell 《Ground Water Monitoring & Remediation》2012,32(1):59-72
The use of in‐field analysis of vapor‐phase samples to provide real‐time volatile organic compound (VOC) concentrations in groundwater has the potential to streamline monitoring by simplifying the sample collection and analysis process. A field validation program was completed to (1) evaluate methods for collection of vapor samples from monitoring wells and (2) evaluate the accuracy and precision of field‐portable instruments for the analysis of vapor‐phase samples. The field program evaluated three vapor‐phase sample collection methods: (1) headspace samples from two locations within the well, (2) passive vapor diffusion (PVD) samplers placed at the screened interval of the well, and (3) field vapor headspace analysis of groundwater samples. Two types of instruments were tested: a field‐portable gas chromatograph (GC) and a photoionization detector (PID). Field GC analysis of PVD samples showed no bias and good correlation to laboratory analysis of groundwater collected by low‐flow sampling (slope = 0.96, R2 = 0.85) and laboratory analysis of passive water diffusion bag samples from the well screen (slope = 1.03; R2 = 0.96). Field GC analysis of well headspace samples, either from the upper portion of the well or at the water‐vapor interface, resulted in higher variability and much poorer correlation (consistently biased low) relative to laboratory analysis of groundwater samples collected by low‐flow sample or passive diffusion bags (PDBs) (slope = 0.69 to 0.76; R2 = 0.60 to 0.64). These results indicate that field analysis of vapor‐phase samples can be used to obtain accurate measurements of VOC concentrations in groundwater. However, vapor samples collected from the well headspace were not in equilibrium with water collected from the well screen. Instead, PVD samplers placed in the screened interval represent the most promising approach for field‐based measurement of groundwater concentrations using vapor monitoring techniques and will be the focus of further field testing. 相似文献
11.
A. Chovanec 《洁净——土壤、空气、水》1997,25(5):233-241
Pesticides in Austrian Running Waters – a Country-wide Overview The analyses of pesticides in Austrian running waters are major part of the country-wide water quality monitoring system which has been established in 1991. This paper summarizes the data which were collected for 29 substances between December 1991 and June 1995. The monitoring activities focus on herbicides because they are the most important pesticide group in Austria. Substances of the triazines and phenoxyalkanecarboxylic acid group analyzed within the programme represent the major part of the total amount of herbicides applied. The most detected pesticides were atrazine and its metabolite deethylatrazine. Peak concentrations were obtained in rivers situated in the eastern and southern regions of Austria with intensive agriculture. Other substances play a minor role as contaminants in running waters. These findings correspond to the data obtained by investigations of groundwater in porous media. 相似文献
12.
A discussion is presented on the conditions required and limitations of the guaranteeing of quality in water analysis as the basis for the necessary standardization of analytical methods. The following concepts are of particular importance: principle of analysis, method of analysis, technique of analysis, specification for analysis, measured value, analytical value, result of measurement, result of analysis, precision, repeatability, reproducibility, detection limit, determination limit, sensitivity and rate of retrieval. Prequisite for the ensuring of quality proper are the standard addition method and the ring analysis. In the water analysis the guaranteeing of quality is of particular importance due to the multifarious matrix as well as for the interpretation of the analytical results as a basis for important decisions in the national economy. 相似文献
13.
J. Putzien 《洁净——土壤、空气、水》1984,12(6):577-593
The increasing nitrate concentrations in the ground water and drinking water which are caused by intensified fertilizing lead to the risk of methaemoglobinaemia of babies and increase the cancerogenic, teratogenic and mutagenic risk for the total population. In the drinking water conditioning the nitrate concentration can be reduced by different techniques. By ion exchange first the SO4-ions and then the nitrate-ions are removed. Very favourable is the exchange for HCO and the regeneration by means of carbon dioxide and CaCO3, for which a mass balance of substances is given. With 0.55 DM/m3 also the reverse osmosis in a mixture with raw water is practicable and also electrodialysis can be applied, whereas the biological techniques of the heterotrophic or autotrophic denitrification still include unsolved technological problems due to the necessity of an organic substrate or of H2. The special features of each of these techniques and the hygienic and also the corrosion-chemical consequences are indicated. 相似文献
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15.
Improving Water Quality by submerged and emergent Macrophytes. — A Review of Ecotechnological Application. Measures of ecotechnology using submerged and emergent macrophytes in native stands or planted littoral stands on the one hand, ingenious swimming plant mats on the other, may be assessed to be successful if applied in combination with additional measures, for instance — reorganization (sanition) of all the area collecting water — biomanipulation of pelagic food chains. Plantation of submerged macrophytes as oxygenators in standing and impounded waters to improve water quality should be avoided. To the contrary, the strategy should be taking measures in order to maximize the light penetrated euphotic zone (zeu) and simultaneously minimize the mixed zone (zmix) in order to improve spontaneous settlements of submerged macrophyte stands. 相似文献
16.
The new German standard specification DIN 32645 defines detection, identification and determination limit of analytical experiments and contains formulas for their calculation. The detection limit is a qualitative value, only at the determination limit a quantitative statement is possible. The identification limit is no limit of decision for analyses. The expenditure for calculating these parameters is considerable. Therefore, a computer program was developed and tested at the analysis of herbicides with GC-MS after enrichment with solid phase extraction (SPE). It proved that the program is also very useful at the development of analytical methods, because it allows a quick examination of changes of the analytical method. After optimization detection limits for the herbicides were achieved which amount 10–20% of the limit of the German drinking water regulation. 相似文献
17.
The magnitude of soil water repellency in a dry sclerophyll eucalypt forest was measured periodically over four years. The varying responses from a range of sites within the forest are discussed and the effect of amount and frequency of rainfall is shown. It was found that some weeks of consistently wet weather were required for water repellency breakdown, and a frequency of rainfall much greater than normal in the study area for it to remain broken down. Even after an extended period of breakdown, it was found that repellency can be reestablished after one week of hot dry weather. Laboratory tests were used to examine the major repellency processes; three were identified and the relative importance of each considered in the context of the field study. The relative influence of each depended on the physical and chemical characteristics of the sites. The repellent soil samples were more repellent to water of throughfall origin, and even more repellent to stemflow than to distilled water. The repellency response also varied with the type of vegetative cover present. The influence of these phenomena on the preservation of water repellency and the relevance of repellency in macropore infiltration processes are discussed. 相似文献
18.
A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.
Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.
Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils. 相似文献
19.
On-site analysis of trichloroethylene (TCE) in aqueous samples by head- space sample preparation and gas chromatography (HS/GC) provides for quick and precise concentration estimates. This analytical approach is well suited for the on-site determination of volatile organic compounds (VOCs) in a variety of sample matrices, including ground water and saturated and unsatured soils. For these reasons, HS/GC can be used to establish analyte concentrations on a near real time basis to help select appropriate casing material during monitoring well installation. This application and the collection of multiple well samples during sampling events facilitates the hydrogeological site interpretation and the formulation of remediation strategies. 相似文献
20.
Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part II: Increased Trihalomethane Formation in Chlorinated Swimming-pool Water A comparison of two analytical standard procedures for the determination of trihalomethanes (THM) in water (headspace gas chromatography and pentane extraction/gas chromatography) yielded strongly differing results. Under the conditions recommended by the German Standard Method DIN 38407-F5 (60…80°C for at least 60 min) degradation of thermo-labile chlorination products occurs resulting in elevated THM concentrations. The reactions involved are partly pH-dependant, and these can be suppressed by sample acidification. The degradation of trihalogen acetic acids, however, can only be influenced by minimizing the equilibration time and temperature. Other intermediate chlorination products (haloacetonitriles) are also degraded to THM after preceding hydrolysis to the corresponding carboxylic acids. Comparative results obtained with a purge and trap method at ambient temperature, i.e. without thermal stress during the enrichtment step, are lower than with static headspace GC but still high in comparison to the pentane extraction method. Presumably volatile THM-precursors are also trapped and subsequently decomposed upon thermal desorption from the trap. As the static headspace GC is the most rational method of LHKW determination available, the recommended experimental sample handling conditions should be modified in a way that deterioration reactions are reduced as far as possible. 相似文献