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1.
Twelve lavas have been sampled on Amsterdam Island, which is an extinct shield volcano located on a transform fault crossing the south-eastern branch of the Indian Ocean rise. Chemical analyses show that the lavas have mainly tholeiitic affinities, ranging from olivine tholeiites to plagioclase basalts with accumulation of bytownite. The high alumina lavas are similar to bytownite cumulates dredged from the Indian Ocean rise, and the low alumina lavas resemble tholeiites of Hawaii. The volcano appears to be in an early stage of evolution from oceanic ridge basalt to an alkaline volcano.  相似文献   

2.
Evidence for heterogenes primary MORB and mantle sources,NW Indian Ocean   总被引：1，自引：0，他引：1  
Basalts from 5 Deep Sea Drilling Project (DSDP) sites in the northwest Indian Ocean (Somali Basin and Arabian Sea) have general geochemical features consistent with a spreading origin at the ancient Carlsberg Ridge. However, compared to most MORBS from other oceans they have low normative olivine, TiO2, and Zr contents. There is no evidence that the mantle source of these northwest Indian Ocean basalts was enriched in incompatible elements relative to the Atlantic and Pacific ocean mantles. In detail, incompatible element abundances in these DSDP basalts establish that they evolved from several compositionally distinct parental magmas. In particular, basalts from site 236 in the Somali Basin have relatively high SiO2 and low Na, P, Ti, and Zr contents. These compositional features along with low normative olivine contents are similar to those proposed for melts derived by two-stage (or dynamic) melting. Published data also indicate there is no enrichment in incompatible elements at the southwest Indian Ocean triple junction, although southwest Indian Ocean basalts have slightly higher 87Sr/86Sr than normal Atlantic MORB. The data suggest that there are significant subtle geochemical variations in the Indian Ocean mantle sources, but are insufficient to show whether these variations have a systematic temporal or geographic distribution.  相似文献   

3.
The basalts and dolerites from Saint-Paul island, located on the east section of the Indian ridge, are reinvestigated. New chemical rock analysis show that they are caracterized by high Fe, low Mg, and various Al contents; they belong to quartz tholeiites and olivine tholeiites of Yoder and Tilley's classification. Two clinopyroxene analysis allow to confirm this tholeiitic relationship. Compared with abyssal tholeiites, those of Saint-Paul are dissimilar in respect to Al2O3/CaO and FeO/MgO ratios, Sr and Rb contents (231–308 ppm and 6 to 29 ppm respectively) and 87 Sr/86 Sr values (0,7041–0,7065). Bearing in mind the structural position of the island, this differences are discussed in light of experimental data. Saint-Paul's basalts and dolerites are products a magma fractionated according to a Fernner trend and probably issued from deeper part of the upper mantle than abyssal tholeiites.  相似文献   

4.
Rodrigues Island is composed of a differentiated series of transitional-mildly alkaline olivine basalts. The lavas contain phenocrysts of olivine (Fo88–68)±plagioclase (An73–50), together with a megacryst suite involving olivine, plagioclase, kaersutite, clinopyroxene, apatite, magnetite and hercynite-rich spinels. Troctolitic-anorthositic gabbro xenoliths are widely dispersed throughout the lavas and are probably derived from the upper parts of an underlying layered complex: the megacrysts may originate from coarse, easily disaggregated differentiates near the top of this body.Modelling of major and trace element data suggests that the majority of chemical variation in the lavas results from up to 45% fractionation of olivine, clinopyroxene, plagioclase and magnetite at low pressures, in the ratio 2035396. The clinopyroxene-rich nature of this extract assemblage is significantly different to that of the xenoliths, and suggests that clinopyroxene-rich gabbros and/or ultrabasic rocks may lie at greater depth.Sr and Nd isotopic data (87Sr/86Sr 0.70357–070406,143Nd/144Nd 0.51283–0.51289) indicate a mantle source with relative LREE depletion, and emphasise an unusual degree of uniformity in Indian Ocean island sources. A small group of lavas with strong HREE enrichment suggest a garnet-poor source for these, while high overall Al2O3/ CaO ratios imply high clinopyroxene/garnet ratios in refractory residua.  相似文献   

5.
Geochemical characteristics of Desur-type basalt flows in the southern and southwestern part of Belgaum in Karnataka, India have been investigated to understand their petrogenesis. The basalts are compact, hard, massive, and show characteristic microporphyritic textures with abundant well-twinned and un-twinned plagioclase phenocrysts and minor clinopyroxene set in a fine-grained groundmass consisting of plagioclase, clinopyroxene, glass and Fe-Ti oxides. Thin sections show sub-ophitic, intergranular and intersertal textures. The basalts are Fe-rich tholeiites (13.4–13.8 wt %), characterized by high TiO2 (3.64 to 3.94 wt %); moderate MgO contents (4.79 to 5.41 wt %), low K2O contents (<0.58 wt %) and low Mg# (42.4–45.9). They are enriched in large ion lithophile elements, moderately enriched in the light rare earths (chondrite-normalized LaN/YbN 3.37–4.24), and exhibit nearly flat heavy rare-earth patterns that lack significant Eu anomalies (Eu/Eu* 0.86–1.10). Primitive-mantle-normalized element patterns for these rocks show characteristic troughs at K and Sr, absence of a Nb anomaly, and a low Zr/Nb ratio (<15), which suggest insignificant contamination by many types of continental crust, whereas, enrichments in the large ion lithophiles, La, P and Th could suggest enriched source characteristics. Based on the geochemical characteristics of the basalts, it is inferred that the Desur basalts representing the youngest flows of the Deccan Basalt Group are derived by partial melting of a peridotite source, and subsequent fractionation gave rise to the compositions of the basalts that are found in the Belgaum region.  相似文献   

6.
The Bulawayan Group in the Midlands greenstone belt can be divided into three formations. The Mafic Formation is composed principally of pillowed, low-K tholeiites and minor bedded chert. The Maliyami Formation and conformably overlying Felsic Formation are composed of calc-alkaline tholeiites, andesites, and dacites with andesites dominating in the Felsic Formation. Minor rhyolite quartz porphyries and ultramafic bodies also occur in the section. The Bulawayan Group near Que Que is perhaps the least altered and metamorphosed Archean greenstone succession known. The absence of andesite and related rocks, the association of bedded chert, and the consistently low K2O, Rb, and Sr contents of Mafic Formation tholeiites suggest that they represent Archean oceanic rise tholeiites. The compositions of tholeiites and andesites of the Maliyami Formation, however, suggest that they represent an emerging arc system. The Felsic Formation is interpreted as a more advanced stage in the evolution of this arc system.Trace-element model calculations favor an origin for Mafic Formation tholeiites involving about 30% partial melting of a lherzolite source. Similar calculations are consistent with an origin for Maliyami Formation tholeiites, Maliyami and Felsic Formation andesites, and Midlands rhyolites involving, respectively, 50, 20–30, and 10% equilibrium melting of eclogite or garnet amphibolite (of Mafic Formation tholeiite composition). The low K2O, Rb, and Sr contents of Mafic Formation tholeiites suggest that they were derived from an upper mantle source as depleted in these elements as the oceanic upper mantle is today.A plate tectonic model is proposed for the Bulawayan Group in which the Mafic Formation is derived from a depleted lherzolite source beneath a spreading center in a marginalsea basin and the Maliyami and Felsic Formations and associated rhyolites are produced by partial melting of eclogite in a descending slab located west of the basin.  相似文献   

7.
The Chakradharpur Granite—Gneiss complex (CKPG) is exposed as an elliptical body within the arcuate metamorphic belt sandwiched between the Singhbhum Granite in the south and the Chotonagpur Granite—Gneiss to the north. It consists of an older bimodal suite of grey gneiss and amphibolites, intruded by a younger unit of pegmatitic granite. The bimodal suite represents the basement to the enveloping metasediments.The average major-element chemistry of the grey gneiss conforms to the definition of trondhjemite and includes both low-Al2O3 and high-Al2O3 types. The amphibolites can be grouped into a low-MgO and a high-MgO type. Rocks of the younger unit range in composition from granodiorite to quartz monzonite. The two granitic units also differ significantly in their Rb, Sr and Ba contents, and in the REE distribution pattern. The grey gneiss shows a highly fractionated REE pattern and a distinct positive Eu anomaly, with Eu/Eu* values increasing with increase in SiO2 %. In samples of the younger granite, the REE pattern is less fractionated, with higher HREE abundance relative to the grey gneiss and usually shows a negative Eu anomaly. The two types of REE patterns in amphibolites are interpreted to represent the two broad groups identified on the basis of major element chemistry.On the basis of chemical data, a two-stage partial melting model for the genesis of grey gneiss is suggested, involving separation of hornblende and varying amounts of plagioclase in the residual phase. Varying amounts of plagioclase in the residuum result in the wide range of Al2O3 content of the partial melt from which the trondhjemites crystallised. Residual hornblende produces the highly fractionated REE pattern, but a relatively higher HREE content of the trondhjemites compared to those produced by separation of garnet in the residual phase. The high level of Ba together with moderate levels of Sr in the trondhjemites can also be explained by plagioclase in the residue, whose effectiveness in partitioning Ba compared to Sr is lower. Of the two groups of amphibolites, the low-MgO type shows relative depletion of LREE compared to the high-MgO type. It contains varying amounts of plagioclase and is tentatively suggested to represent the residue. The other group, with a slightly fractionated REE pattern (CeN/ YbN = 2.01), is generally considered to represent the source material for the trondhjemites. This may have been generated by 5–15% partial melting of mantle peridotites, containing higher concentrations of LIL elements than those which produced average Precambrian tholeiites. This first phase of partial melting resulted in the slightly fractionated REE pattern of these amphibolites. Derivation of the younger granitic unit from the trondhjemites can be ruled out on the basis of REE data alone. REE data suggest partial melting of metasediments to be the origin of these rocks. It is also possible that deeply buried volcanic rocks, similar to calc-alkaline components of greenstone belts, are the parent for this component.  相似文献   

8.
Early Pliocene (Zanclean) basalts in the Dien Bien Phu pull-apart basin in NW Vietnam, associated with the presently sinistral Dien Bien Phu Fault Zone, have been dated by the K–Ar method at 4.4–4.9 and 5.4–5.2 Ma. Rapid migration of basaltic magma to the surface in the Dien Bien Phu Fault Zone may be due to Pliocene transtension of the crust in this region, resulting from asthenospheric upwelling induced by lateral displacement of the mantle. The basalts are moderately phyric ( < 10%) and consist of olivine (hyalosiderite), plagioclase (bytownite–labradorite) and orthopyroxene (bytownite–labradorite) phenocrysts, and a fine-grained crystalline matrix (olivine–hortonolite, plagioclase–labradorite, clinopyroxene–pigeonite and augite, K-feldspar). The presence of Fe-rich olivine and orthopyroxene phenocrysts indicates that the basalts are SiO2-saturated/oversaturated olivine tholeiites which formed under water-undersaturated conditions. The Dien Bien Phu basalts contain both mantle-derived (pyroxenites, dunites, gabbros) and crustal (sillimanite/mullite + Mg–Fe spinel), wallrock xenoliths, indicative of crustal contamination during the ascent of the basaltic magma. The basalts show selective enrichment in some mobile elements (K, Rb, Sr and Th), a feature considered to be a result of metasomatism. These rocks, classified on the basis of their normative composition as quartz tholeiites, could represent primary olivine tholeiites/basalts, in which the geochemical signatures were modified by the processes of contamination.  相似文献   

9.
A total of 17 alkali basalts (alkali olivine basalt, limburgite, olivine nephelinite) and quartz tholeiites, and of 10 peridotite xenoliths (or their clinopyroxenes) were analyzed for Nd and Sr isotopes. 143Nd/144Nd ratios and 87Sr/86Sr ratios of all basalts and of the majority of ultramafic xenoliths plot below the mantle array with a large variation in Nd isotopes and a smaller variation in Sr isotopes. The tholeiites were less radiogenic in Nd than the alkali basalts. Volcanics from the Eifel and Massif Central regions contain Nd and Sr, which is more radiogenic than that of the basalts from the Hessian Depression. Nd and Sr isotopic compositions of all rocks from the latter area, with the exception of one tholeiite and one peridotite plot in the same field of isotope ratios as the Ronda ultramafic tectonite (SW Spain), which ranges in composition from garnet to plagioclase peridotite. The alkali basaltic rocks are products of smaller degrees of partial melting of depleted peridotite, which has undergone a larger metasomatic alteration compared with the source rock of tholeiitic magmas. For the peridotite xenoliths such metasomatic alteration is indicated by the correlation of their K contents and isotopic compositions. We assume that the upper mantle locally can acquire isotopic signatures low in radiogenic Nd and Sr from the introduction of delaminated crust. Such granulites low in radiogenic Nd and Sr are products of early REE fractionation and granite (Rb) separation.  相似文献   

10.
A comparison of new and published geochemical characteristics of magmatism in the western and eastern Indian Ocean at the initial and recent stages of its evolution revealed several important differences between the mantle sources of basaltic melts from this ocean.
  1. The sources of basalts, from ancient rises and from flanks of the modern Central Indian Ridge within the western Indian Ocean contain an enriched component similar in composition to the source of the Réunion basalts (with radiogenic Pb and Sr and unradiogenic Nd), except for basalts from the Comores Islands, which exhibit a contribution from an enriched HIMU-like component.
  2. The modern rift lavas of spreading ridges display generally similar geochemical compositions. Several local isotopic anomalies are characterized by the presence of an EM2-like component. However, two anomalous areas with distinctly different enriched mantle sources were recognized in the westernmost part of the Southwestern Indian Ridge (SWIR). The enriched mantle source of the western SWIR tholeiites in the vicinity of the Bouvet Triple Junction has the isotopic ratios indicating a mixture of HIMU + EM2 in the source. The rift anomaly distinguished at 40° E displays the EM1 signature in the mantle source, which is characterized by relatively low 206Pb/204Pb (up to 17.0) and high 207Pb/204Pb, 208Pb/204Pb and 87Sr/86Sr. This source may be due to mixing with material from the continental lithosphere of the ancient continent Gondwana. The material from this source can be distinguished in magmas related to the Mesozoic plume activity in Antarctica, as well as in basalts from the eastern Indian Ocean rises, which were formed by the Kerguelen plume at 100–90 Ma.
  3. The geochemical heterogeneities identified in the ancient and present-day magmatic products from the western and eastern Indian Ocean are thought to reflect the geodynamic evolution of the region. In the eastern part of the ocean, the interaction of the evolving Kerguelen plume with the rift zones produced magmas with specific geochemical characteristics during the early opening of the ocean; such a dispersion of magma composition was not recognized in the western part of the ocean.
  相似文献   

11.
Mafic tholeiitic basalts from the Nejapa and Granada (NG) cindercone alignments provide new insights into the origin and evolutionof magmas at convergent plate margins. In comparison to otherbasalts from the Central American volcanic front, these marietholeiitic basalts are high in MgO and CaO and low in Al2Op,K2O1, Ba and Sr. They also differ from other Central Americanbasalts, in having clinopyroxene phenocrysts with higher MgO,CaO and Cr2O3 concentrations and olivine phenocrysts with higherMgO contents. Except for significantly higher concentrationsof Ba, Sr and 87Sr/86Sr, most of the tholeiites are indistinguishable in compositionfrom mid-ocean ridge basalts. In general, phenocryst mineralcompositions are also very similar between NG tholeiites andmid-ocean ridge basalts. The basalts as a whole can be dividedinto two groups based on relative TiO2-K2O concentrations. Thehigh-Ti basalts always have the lowest K2O and Ba and usuallyhave the highest Ni and Cr. All of the basalts have experienced some fractional crystallizationof olivine, plagioclase and clinopyroxene. Relative to otherCentral American basalts, the Nejapa-Granada basalts appearto have fractionated at low PT and PH2O. The source of primarymagmas for these basalts is the mantle wedge. Fluids and/ormelts may have been added to the mantle wedge from hydrothermally-altered,subducting oceanic crust in order to enrich the mantle in Sr,Ba and 87Sr/86Sr, but not in K and Rb. The role of lower crustaicontamination in causing the observed enrichments in Sr, Baand 87Sr/86Sr of NG basalts in comparison to mid-ocean ridgebasalts, however, is unclear. Rutile or a similar high-Ti accessoryphase may have been stable in the mantle source of the low-TiNG basalts, but not in that of the high-Ti basalts. Mafic tholeiiticbasalts, similar to those from Nejapa and Granada, may representmagmatic compositions parental to high-Al basalts, the mostmafic basalts at most Central American volcanoes. The characterof the residual high-Al basalts after this fractionation stepdepends critically on PH2O Both high and low-Ti andesites are also present at Nejapa. Likethe high-Ti basalts, the high-Ti andesites have lower K2O andBa and higher Ni and Cr in comparison to the low-Ti group. Thehigh-Ti andesites appear to be unrelated to any of the otherrocks and their exact origin is unknown. The low-Ti andesitesare the products of fractional crystallization of plagioclase,clinopyroxene, olivine (or orthopyroxene) and magnetite fromthe low-Ti basalts. The eruption that deposited a lapilli sectionat Cuesta del Plomo involved the explosive mixing of 3 components:high-Ti basaltic magma, low-Ti andesitic magma and high-Ti andesiticlava.  相似文献   

12.
Plagioclase separates from the Layered Series (LS), Upper Border Series (UBS), and Marginal Border Series (MBS) of the Skaergaard intrusion were analyzed to examine major and trace element variations. In general, plagioclase from the LS, UBS, and MBS show similar trends in major elements vs. crystallization: SiO2, Na2O, and K2O progressively increase, and CaO and MgO progressively decrease with fractionation. No abrupt changes in the trends of major components of Skaergaard plagioclase during the differentiation of the intrusion are observed. Trace elements in plagioclase reflect changes in the Skaergaard magma and changes in plagioclase distribution coefficients with differentiation. Sr, Ga, and probably Ba are included elements in Skaergaard plagioclase, but were excluded from the other cumulus phases, and as a result systematically increased in the magma and plagioclase during differentiation. Be, Cs, Hf, Rb, Ta, U, and Zr, and the transition metals Co, Cr, Cu, Ni, Sc, V, and Zn were excluded elements in Skaergaard plagioclase, and remained low in plagioclase during differentiation. Changes in the abundances of these elements in plagioclase during differentiation reflect changes in their abundance in the magma. With the exception of the lower zone, which is enriched in the light rare earth elements, rare earth elements in LS plagioclase, in general, increase with differentiation of the Skaergaard intrusion, but decrease dramatically at the UZa/UZb boundary where abundant apatite first appears. Rare earth elements in UBS plagioclase followed a similar trend to LS plagioclase, except during the initial and final stages of differentiation. UBS plagioclase is much more enriched in rare earth elements during the final 20% of crystallization, except for Eu, which is similar in plagioclase from the two series. The observed trends suggest that the floor and roof sequences became isolated from each other and that the floor sequence may have been more reducing and the roof sequence more oxidizing during the final 20% of crystallization. As the Skaergaard magma ceased convection, or convected as isolated cells, during the final stages of differentiation, volatile elements may have accumulated in the UBS magma, resulting in an increase in ƒO2, and a decrease in Eu/Sm in UBS plagioclase. The observed trends of rare earth elements in plagioclase from the LS and UBS fit well with theoretical calculations that assume closed-system crystallization, and would be difficult to reconcile with any model requiring significant discharge of magma from the chamber during the final 20% of crystallization. The enrichment of light rare earth elements in plagioclase, suggests that the lower part of the intrusion re-equilibrated with a late, light rare earth element-rich fluid or melt. The recharge model proposed by earlier workers to explain anomalous Sr and Nd isotopes appears unlikely in light of the two to fourfold enrichment of light rare earth elements in these samples. Received: 1 October 1999 / Accepted: 14 May 2000  相似文献   

13.
Before the Pan-African Orogeny, the Palæoproterozoic basement and its Neoproterozoic cover (limestones and quartzites) of the Zenaga Inlier were cross-cut by a swarm of doleritic dykes. They are more or less altered. The primary mineral assemblage consists of plagioclase, clinopyroxene, very rare orthopyroxene, ilmenite, apatite, micropegmatite and sometimes hornblende and biotite. Mineralogical and geochemical studies indicate that the dolerites are continental tholeiites. Two groups of dykes have been distinguished. Accordingly, rare earth elements, P2O5, Zr, Th, Ba and Sr contents are higher in group I than in group II, which is richer in V. Group I comprises the north-south and northwest-southeast swarms, while group II corresponds to northeast-southwest and east-west swarms, which were emplaced later. These geochemical variations may be explained by a higher degree of melting of the mantle source for the later group II. Doleritic dykes of Zenaga had been emplaced during an extensional episode, prior to Pan-African folding.  相似文献   

14.
A critical study of 311 published WR chemical analyses, isotopic and mineral chemistry of anorthosites and associated rocks from eight Proterozoic massif anorthosite complexes of India, North America and Norway indicates marked similarities in mineralogy and chemistry among similar rock types. The anorthosite and mafic-leucomafic rocks (e.g., leuconorite, leucogabbro, leucotroctolite, anorthositic gabbro, gabbroic anorthosite, etc.) constituting the major part of the massifs are characterized by higher Na2O + K2O, Al2O3, SiO2, Mg# and Sr contents, low in plagioclase incompatible elements and REE with positive Eu anomalies. Their δ 18O‰ (5.7–7.5), initial 87Sr/86Sr (0.7034–0.7066) and ɛ Nd values (+1.14 to +5.5) suggest a depleted mantle origin. The Fe-rich dioritic rocks occurring at the margin of massifs have isotopic, chemical and mineral composition more close to anorthosite-mafic-leucomafic rocks. However, there is a gradual decrease in plagioclase content, An content of plagioclase and XMg of orthopyroxene, and an increase in mafic silicates, oxide minerals content, plagioclase incompatible elements and REE from anorthosite-mafic-leucomafic rocks to Fe-rich dioritic rocks. The Fe-rich dioritic rocks are interpreted as residual melt from mantle derived high-Al gabbro melt, which produced the anorthosite and mafic-leucomafic rocks. Mineralogically and chemically, the K-rich felsic rocks are distinct from anorthosite-mafic-leucomafic-Fe-rich dioritic suite. They have higher δ 18O values (6.8–10.8‰) and initial 87Sr/86Sr (0.7067–0.7104). By contrast, the K-rich felsic suites are products of melting of crustal precursors.  相似文献   

15.
Rare-earth-element, radiogenic and oxygen isotope, and mineral chemical data are presented for tholeiitic and alkaline Quaternary volcanism from Karasu Valley (Hatay, southeastern Turkey). Karasu Valley is the northern segment of the Dead Sea transform fault and is filled with flood-basalt type volcanics of Quaternary age. This valley is an active fault zone that is known as “Karasu fault,” extending in a NE-SW direction. The Karasu Valley basaltic volcanics (KVBV) are subaphyric to porphyritic, with variable amounts of olivine, clinopyroxene, and plagioclase phenocrysts. Alkali basalts are generally characterized by high contents of olivine, clinopyroxene, and plagioclase phenocrysts. Their groundmass contains olivine, clinopyroxene, plagioclase, and Fe-Ti oxides. Tholeiitic basalts are subaphyric to porphyritic (high contents of olivine, clinopyroxene, and plagioclase). Their groundmass is similar to that of alkali basalts. The range of olivine phenocryst and microlite compositions for all analyzed samples is Fo81 to Fo43. Plagioclase compositions in both tholeiitic and alkali basalts range from andesine, An38 to bytownite, An72. Clinopyroxene compositions range from diopside to calcic augite. Most of the olivine, plagioclase, and clinopyroxene phenocrysts are normally zoned and/or unzoned. Fe-Ti oxides in both series are titanomagnetite and ilmenite.

Based on normative and geochemical data, the Karasu Valley basaltic volcanics are mostly olivine and quartz-tholeiites, and relatively lesser amount of alkali olivine-basalts. KVBV have low K2O/Na2O ratios, typically between 0.25 and 0.45. Olivine- and quartz-tholeiites are older than alkali olivine-basalts. Olivine tholeiites have Zr/Nb and Y/Nb ratios similar to alkaline rocks, but their Ba/Nb, Ba/La, and La/Nb ratios are slightly higher than alkali olivine-basalts. In contrast, quartz-tholeiites have the highest Ba/Nb, Ba/La, Zr/Nb, and Y/Nb and the lowest Nb/La ratios among the KVBV. Alkali basalts have 87Sr/86Sr and 143Nd/144Nd ratios ranging from 0.703353 to 0.704410 and 0.512860 to 0.512910, respectively. In contrast, quartz-tholeiites have higher 87Sr/86Sr and lower 143Nd/144Nd ratios, which vary from 0.704410 to 0.705490 and 0.512628 to 0.512640, respectively. Olivine tholeiites have intermediate isotopic compositions ranging from 0.703490 to 0.704780 and 0.512699 to 0.512780, respectively. 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb isotopic ratios of KVBV range from 18.817 to 19.325, 15.640 to 15.718, and 39.054 to 39.223, respectively. The range of O isotope values is between +5.84 and +7.97‰. The higher O and Sr isotopes in olivine- and quartz-tholeiites relative to alkali olivine-basalts can be explained by contamination of magmas by crustal materials.

The KVBV have intraplate chemistry similar to that of other tholeiitic and alkaline basalts in other within-plate environments, and isotopes range from isotopically depleted mantle to enriched isotope compositions similar to some enriched ocean islands. Trace-element and isotope data indicate that the KVBV are derived from a common OIB-like asthenospheric mantle source, but they have experienced different degrees of crustal contamination during their ascent to the surface, contemporaneous with little fractional crystallization. Although quartz-tholeiites display significant effects of crustal contamination, alkali olivine-basalts appear to have negligible or no crustal contamination in their geesis.  相似文献   

16.
Mineral chemistry, major and trace elements, and 87Sr/86Sr ratios are presented for 29 igneous rocks dredged from the northern portion of the Izu-Ogasawara arc. These rocks are compositionally bimodal. Basement gabbro and trondhjemite from the arc are extremely poor in K2O (0.05–0.19%) and Rb (0.48–0.62 ppm), and their REE patterns and Sr isotope ratios indicate that there are island arc tholeiites. Quaternary volcanic rocks from the present volcanic front (Shichito Ridge; active arc), back-arc seamounts (east side; inactive arc) and Torishima knoll between the two back-arc depressions (incipient back-arc basins) behind the active arc have the same geochemical characteristics as the above plutonic rocks though they are not as depleted in K and Rb. Rhyolite pumice from the backarc depression is also the depleted island arc tholeiite, whereas basalts from the depression have compositions that are transitional between MORB and island arc tholeiites in trace element (Ti, Ni, Cr, V, Y and Zr) and mineral chemistries. The back-arc depression basalts have relatively high BaN/CeN(0.66–1.24), Cen/YbN(1.1–1.9) and K/Ba(45–105) and low 87Sr/86Sr (0.70302–0.70332) and Ba/Sr (0.1–0.2), which are similar to other back-arc basin basalts and E-type MORB, but are quite unlike the depleted island arc tholeiites. The diverse trace element and Sr isotope compositions of basalt-andesite from the back-arc depressions imply the interplay between E-type MORB and island arc tholeiite. These chemical characteristics and the relationships of (Ce/Yb)N vs (Ba/Ce)N and (Ce/Yb)N vs 87Sr/86Sr suggest that the back-arc depression magmas are generated by mixing of E-type MORB and depleted island arc tholeiite magmas. Geochemical characters of the associated rhyolite from the depression are compatible with partial melting of lower crust.  相似文献   

17.
On Rhum, Eigg, Canna and Muck Tertiary volcanics rest upon a Mesozoic or Pre-Mesozoic basement. Aphyric, olivine-phyric, and plagioclase-phyric basalts are recognized. The aphyric basalts are mildly alkaline or transitional types with either a few percent normative nepheline or normative hypersthene. They have anomalously low concentrations of Rb, Sr and K2O compared to Tertiary tholeiites from the same province.Aphyric hawaiites, and mugearties are found on all the islands, but are particularly abundant on Rhum. The volcanics from Bloodstone Hill, Rhum, originally described as mugearites are anomalous in that they are quartz normative and contain both augite and hypersthene, in contrast to the normal one-pyroxene rocks of the alkali basalt-trachyte association (Muir and Tilley, 1961). These volcanics have closer affinities to the icelandites, the presence of basic plagioclase xenocrysts suggesting an hybrid origin.Olivine and plagioclase are involved in the low-pressure fractionation of the transitional basalts, whereas pyroxene and titanomagnetie play only minor roles. Consequently, the suppression of titanomagnetite crystallization results in an initial trend towards iron enrichment. The presence of both oversaturated and undersaturated derivitives following the hawaiite stage of differentiation, reflects variation in the amount of extracted pyroxene and titanomagnetite.Felsites and pitchstones intrude the volcanic pile on Eigg. The felsites carry corroded quartz crystals and rare alkali feldspar. The more crystal rich pitchstones generally contain augite, hypersthene, zoned plagioclase and titanomagnetite. One from Rudh an Tancaird contains alkali feldspar, titanomagnetite and ferrohedenbergite.Whole rock analyses and microprobe analyses of feldspars and pyroxenes indicate that the acid volcanics are not genetically related to the basalt-hawaiite-mugearite lineage. The felsites appear to have been derived from Torridonian arkose by partial melting, but the pitchstones could only be derived by anatexis of Lewisian gneiss basement (see Dunham, 1968) substantially more basic than that outcropping on Rhum.It is suggested that the low concentrations of Rb, Sr, and K2O in the alkaline and transitional basalts, mitigates against extensive pre-eruptive differentiation. Possibly the basalts could have been derived by partial melting of a mantle depleted in these elements.  相似文献   

18.
Chemical and structural zoning in plagioclase can develop in response to a number of different magmatic processes. We examine plagioclase zonation formed during the transfer of plagioclase from a granodioritic host to a monzodioritic enclave to understand the development of different zonation patterns caused by this relatively simple magma mixing process. The transferred plagioclase records two stages of evolution: crystallization of oscillatory plagioclase in the host granodioritic magma and crystallization of high An zones and low An rims in the hybrid enclave magma. High An zones (up to An72) are formed only in the hybrid enclaves after plagioclase transfer. Plagioclase from a primitive enclave, showing no or only minimal interaction with the host, is An30–43. The implication is that high An zones crystallize only from the hybrid magma and not from the primitive one, probably because of an increase in water content in the hybrid magma. Complex interactions between the two magmas are also recorded in Sr content in plagioclase, which indicates an initial increase in Sr concentration in the melt upon transfer. This is contrary to what is expected from the mixing of low Sr enclave magma with a high Sr granodiorite one. Such Sr distribution in the plagioclase implies that the transfer of the plagioclase took place before the onset of plagioclase crystallization in the enclave magma. Therefore, the mixing between high Sr granodiorite magma and low Sr enclave magma was recorded only in plagioclase rims and not in the high An zones.  相似文献   

19.
Major, trace-element, and Sr-, Nd-and Pbisotope data are presented for volcanics from 12 active or recently active volcanoes from the islands of Flores, Adonara, Lembata and Batu Tara in the eastern Sunda are. The volcanics vary in composition from low-K tholeiite, through medium-and high-K calcalkaline types to the K-rich leucite basanites of Batu Tara. From the tholeiites to the leucite basanites there are marked increases in the concentrations of LILE (K, Rb, Ba, Sr), LREE and La/Yb, and all the volcanics have high Ba/ Nb, La/Nb and Ba/La compared with mid-ocean ridge and intraplate eruptives. K/Cs values are generally lower than OIB values, and overlap those of other arc volcanics and northeast Indian Ocean sediments. The volcanics exhibit a broad range of 87Sr/86Sr (0.70468–0.70706), 143Nd/144Nd (0.512946–0.512447), and a moderate range in 206Pb/204Pb (18.825–19.143), 207Pb/ 204Pb (15.643–15.760) and 208Pb/204Pb (38.97–39.51). Trace-element and isotopic data suggest that the mantle beneath the eastern Sunda arc is a complex heterogeneous mixture of 3 or 4 major source components: MORB-source or depleted MORB-source, OIB-source and subducted Indian Ocean sediment. The low-K tholeiites were probably formed by relatively large degrees of melting of depleted MORB-source mantle, modified by subduction-related fluids, whereas the trace-element and isotopic characteristics of the K-rich volcanics suggest that they were derived from an OIB source which and been modified by a subduction-related melt component. The source components of the medium-to high-K calcalkaline rocks are more difficult to determine, and probably include mixtures of MORB-source or OIB-source, and melt/fluid derived from subducted oceanic sediment. Minor-and trace-element modelling calculations indicate substantial difficulties in producing the relatively low Ti-contents of arc volcanics by melting OIB-source mantle. Where OIB mantle is considered to be an important component of arc magmas it is suggested that the HFSE are buffered to relatively low concentration by a residual Ti-rich accessory phase.  相似文献   

20.
《Precambrian Research》1987,37(3):173-189
The Proterozoic Giles Complex, central Australia contains an almost complete range of anorthosite types from minor or major layers in gabbronorite intrusions to large anorthosite-troctolite bodies to small orthopyroxene anorthosite massifs; each type has a distinctive Sr isotopic signature. Anorthosite-dominated masses have a regular relationship between ferromagnesian mineralogy, initial 87Sr/86Sr and anorthite contents in plagioclase: anorthosite-troctolite bodies have significant olivine, relatively low initial 87Sr/86Sr (0.7038–0.7043) and An50–69; orthopyroxene-dominant anorthosites have relatively high 87Sr/86Sr (0.7045–0.7063) and An45−60. The pattern is found worldwide. Detailed study of one intrusion demonstrates that contamination by wall-rock granulite produces the higher 87Sr/86Sr values, anti-correlation between 87Sr/86Sr and An, and determines olivine/orthopyroxene proportions. Olivine-bearing anorthosites form from a primary aluminous tholeiite magma with plagioclase dominating the liquidus; progressive contamination of this parent magma produces a gradation to orthopyroxene anorthosites.  相似文献   

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