共查询到20条相似文献，搜索用时 265 毫秒
1.
黔北大方地区二叠纪及三叠纪地层发育,在二叠系—三叠系界线处发现12~14cm厚的界线粘土,在界线粘土层之上还发现3~4层5~18cm厚的火山事件粘土层。二叠系—三叠系界线粘土、事件粘土及松子坎段底部火山事件粘土岩(绿豆岩)均具有高的K_2O和MgO含量;二叠系—三叠系界线粘土的稀土元素特征与关岭组松子坎段底部绿豆岩相似,与沙堡湾段事件粘土岩的稀土元素特征也十分相似,Eu异常较明显,说明界线粘土及事件粘土成因均与火山活动有密切关系。界线粘土比事件粘土具更明显的Eu异常,部分界线粘土还具有Ce异常。二叠系—三叠界线粘土、事件粘土及关岭组绿豆岩的源区均属于活动大陆边缘的长英质火山岩区,为酸性的长英质火山岩喷发(火山灰)沉积的产物,而沙堡湾段及九级滩段正常沉积泥岩的源区属于被动大陆边缘的长石砂岩岩区。界线粘土中,大部分微量元素与事件粘土及关岭组绿豆岩中对应微量元素的含量相近,但其中的Th、Y、Nb、Cd、Ga、In、Ta明显高于与火山活动有关的事件粘土及绿豆岩,推测事件粘土与少量宇宙事件外来物质的加入有关。 相似文献
2.
纳米科技与粘土矿物学研究的思考 总被引：2，自引：0，他引：2
纳米科技已在地学领域取得了重要研究成果。粘土矿物学在材料科学中占有重要的地位,有必要建立“纳米粘土矿物学”这一学科,其研究手段与纳米科技一致,研究内容主要包括：纳米粘土矿物微粒矿物学、纳米粘土矿物体系物理学、纳米粘土矿物化学、纳米粘土矿物材料学和纳米粘土矿物加工学。本文进一步对纳米粘土矿物的检测方法和检测标准、聚合物／纳米粘土矿物复合材料的产业化提出了思考。 相似文献
3.
论高岭石粘土和铝土矿研究的新进展 总被引：4，自引：0，他引：4
过去我国地质界向前苏联学习,把球粘土(Ballclay)作为高岭土或耐火粘土的一个变种,使我们找矿走入误区,以致后来从美国进口球粘土。其实球粘土的结晶性质这个内在因素与高岭土或耐火粘土常不相同,则派生的性能更不一样,应成为独立的矿种,还可与国际接轨。又过去国内外学者认为高岭石高度有序为热液型的,而沉积型的为无序高岭石。但笔者等的研究,我国高岭石高度有序而规模大且均匀稳定的,应算沉积型的紫矸(古生代高岭石软质粘土),可以作流动性好的造纸涂料。又我国硬水铝石岩溶铝土矿,应属于生物有机质成矿作用的沉积型铝土矿。 相似文献
4.
5.
关于粘土岩崩解，泥化机理的讨论 总被引：28，自引：5，他引：28
分析研究了水利，采矿，地下等工程中常见的粘土岩，泥岩等的泥化，及开挖暴露后的吸水崩解现象，讨论了粘土岩等泥化及崩解的物理化学和力学作用机理，特别是对含胀缩性蒙脱石矿物的粘土岩，还从粘土岩的力学强度特性讨论了他们的泥化崩解问题，系统深入地阐述了粘土岩等泥化，崩解机制。 相似文献
6.
简述了某软土基坑复合土钉支护结构失稳过程,分析失稳原因,介绍工程治理措施.文中还对软土基坑与残积土基坑破坏机理进行探讨,提出了软土基坑按地层可分为双层软土基坑、三层软土基坑.三层软土基坑比双层软土基坑采用复合土钉支护结构能较优控制变形和提高稳定性.可供工程技术人员参考. 相似文献
7.
为评价污泥灰改性黏土作为填埋场衬垫防渗材料的可行性,分析污泥灰改性黏土强度特性及孔隙结构,针对受垃圾渗沥液腐蚀的纯黏土与污泥灰掺量为1%～5%的改性黏土,采用直接剪切试验分析其抗剪强度变化规律,采用低温氮气吸附试验分析剪切变形后试样的孔隙结构组成。结果表明,改性黏土属于VI型等温线,并存在H3型滞后环,且2～6 nm介孔的数量占比较大。受垃圾渗沥液腐蚀后,黏土抗剪强度大幅下降,黏聚力与内摩擦角分别下降60.12%和19.17%;黏土的最大氮气吸附量降低16.19%,且孔隙分布双肩峰发育不完全;随污泥灰添加量的增加,改性黏土抗剪强度增大,且孔隙分布逐渐恢复双肩峰形式,总孔容增大。 相似文献
8.
非饱和红粘土和膨胀土抗剪强度的比较研究 总被引：24，自引：4，他引：20
红粘土是对环境湿热变化敏感的塑性粘土,具有一般膨胀土吸水膨胀失水收缩的特性。与普通粘性土相比,红粘土与膨胀土的强度特性更为复杂。它既是土体抵抗剪切破坏能力的表征,也是计算路堑、渠道、路堤、土坝等斜坡稳定性以及支挡构筑物土压力的重要参数。通过试验研究讨论了红粘土与膨胀土的强度特性以及与一般粘性土的差别及其各种影响因素,并探讨了非饱和红粘土与膨胀土的抗剪强度指标与含水量之间的相关关系。试验结果表明,红粘土与一般膨胀土的吸水膨胀规律完全相同。其试验结果可为红粘土与膨胀土地区工程设计与建设提供参考依据。 相似文献
9.
Adsorption, desorption and oxidation of arsenic affected by clay minerals and aging process 总被引：20，自引：0，他引：20
Adsorption/desorption and oxidation/reduction of arsenic at clay surfaces are very important to the natural attenuation of
arsenic in the subsurface environment. Although numerous studies have concluded that iron oxides have high affinities for
the adsorption of As(V), very little experimental work has addressed the arsenic attenuation capacities of different clay
minerals and aging process affecting the transformation of arsenic. The abundance of clay minerals in a variety of geochemical
environments and their influence on adsorption of contaminants suggests a need for more experimental work to characterize
the adsorption desorption, and oxidation of arsenic on clay minerals. In this investigation three types of clay mineral were
studied: the 1 : 1 layer clays [halloysite (IN), sedimentary M-kaolinite, and weathered EPK-kaolinite]; the 2 : 1 layer clays
[illite (MT) and illite/montmorillonite (MT)]; the 2 :>: 1 layer clay [chlorite (CA)]. The halloysite and the chlorite had
much greater As(V) adsorption (25–35 folds) than the other clay minerals. The clay minerals had lower As(III) adsorption than
As(V) adsorption, and the adsorption was affected by pH. Desorption of arsenic from the clay minerals was significantly influenced
by the aging process. The quantities of extractable As(III) and As(V) decreased with increasing aging time. The results demonstrated
that oxidation of As(III) to As(V) occurred on the clay surfaces, whereas reduction of As(V) to As(III) was not found in any
of the clay minerals studied. The oxidation of As(III) was affected by the types of clay and aging time.
Received: 22 March 1999 · Accepted: 15 April 1999 相似文献
10.
Provenance of iron,bauxite and clay deposits of the Carboniferous Benxi Formation in southern margin of North China Craton: An example from Da'an bauxite and clay deposit of Sanmenxia area,Henan Province 
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下载免费PDF全文 Liu Xue-Fei Wang Qing-Fei Ma Yao Li Zhong-Ming Zhao Li-Hua Zhou Zhi-Hui Liu Bai-Shun Ma Xin-Li 《古地理学报》1999,22(5):965-976
During the Middle Ordovician to Late Carboniferous period,the North China Craton(NCC)was exposed and experienced prolonged weathering that resulted in the formation of large-scale iron,clay and bauxite deposits. The source of ore-forming material has always been a research focus,in particular,whether the sources of the iron ore and the Fe-bearing clay at the bottom of Benxi Formation are the same as the upper bauxite and clay deposit is still unclear. In this study,the Da'an bauxite and clay deposit at the southern margin of the NCC was chosen to carry out a detailed analysis of the micro-region mineral composition and elemental geochemical characteristics for further exploring the sources of iron,bauxite and clay deposits. The composition of the ore-bearing rocks in the Da'an bauxite deposit from the bottom to top includes Fe-bearing clay(locally iron ore),bauxite,and bauxitic clay;locally,in karstic uplift,bauxitic clay layer is directly overlying on the Fe-bearing clay. The Fe-bearing clay is dominated by siderite,pyrite,and illite in the karstic depression,and hematite,illite,and kaolinite in the uplift. Bauxite is mainly composed of diaspore,illite,and anatase,while bauxitic clay is mainly composed of illite. Mineral microanalysis revealed the development of large amounts of moissanite and small amounts of natural silica,silicalite,and chromite at the bottom of bauxitic clay layer. Regional comparison and correlation reveal that the ophiolite in the Shangdan suture zone and Erlangping Group in the North Qinling orogenic belt(NQOB)likely provides source materials for bauxite and clay deposits. The obvious differences in immobile element ratios (e.g., Zr/TiO2,Hf/TiO2,Nb/TiO2,Ta/TiO2)between the bottom Fe-bearing clay layer and the upper bauxite and clay layer in Da'an deposit,revealing that they are from different sources. The bottom Fe-bearing clay and iron ore layers are the products of in-situ weathering of underlying carbonates,while the top bauxite and clay are allochthonous. The regional uplift of the NQOB during the Late Carboniferous period provided important ore-forming materials for the formation of the NCC bauxite and clay deposits. 相似文献
11.
华北克拉通在中奥陶世至晚石炭世期间一直出露地表,经历了长期的风化作用,形成大规模的铁-铝黏土矿,其成矿物源一直是研究的热点,尤其是本溪组底部铁矿和铁质黏土矿与上部铝黏土矿是否为同一来源尚未查清。本研究选取克拉通南缘大安铝黏土矿床作为研究对象,展开微区矿物及元素地球化学组成分析,进一步探讨铁-铝黏土矿物质来源。大安矿床内含矿岩系自下而上包括铁质黏土岩、铝土矿、铝质黏土矿;局部喀斯特高地缺失铝土矿,铝质黏土矿直接覆盖于铁质黏土岩之上。铁质黏土岩在洼地以菱铁矿、黄铁矿和伊利石为主,在隆起区以赤铁矿、伊利石和高岭石为主。铝土矿以硬水铝石、伊利石和锐钛矿为主;铝质黏土矿主要矿物为伊利石。矿物微区分析在黏土矿底部发现大量的碳化硅和少量自然硅、硅铁矿、铬铁矿;区域对比揭示北秦岭造山带内商丹缝合带和二郎坪群中的蛇绿岩为铝黏土矿形成提供了成矿物质。本溪组底部铁质黏土与上部铝黏土矿稳定元素比率(例如Zr/TiO2、Hf/TiO2、Nb/TiO2、Ta/TiO2)存在明显差异,揭示二者为不同来源: 底部铁质黏土岩和铁矿层为底板碳酸盐岩原地风化的产物;而上部铝黏土矿是异地搬运物,北秦岭造山带在晚石炭世的整体抬升为华北铝黏土矿形成提供了重要的成矿物质。 相似文献
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13.
Pliocene and Holocene siltstones and silts in outcrops from the Boso Peninsula, Japan and in cores from the East China were studied to determine distinctive characteristics of the turbiditic (Bouma E-Division) and hemipelagic siltstones and silts. Weathering characteristics, colour, grain size, and organic carbon-organic nitrogen ratio, plus clay fabric proved valuable in characterizing each unit. Clay and non-clay mineral content was uniform throughout. Clay fabric differences are pronounced. Random clay flake orientation prevails in the turbiditic interval while the hemipelagic unit has more preferred orientation. The fabric reflects different conditions of sedimentation. The turbiditic clay was deposited more rapidly in the flocculated state while the interturbidite hemipelagic clay may have formed from more slowly sedimented dominantly dispersed clay. Results suggest that clay fabric may be useful in combination with other sedimentary features in the study of mud-turbidite sedimentation. 相似文献
14.
Accumulation and Post-Sedimentary Diagenesis of Tonsteins 总被引：2，自引：0，他引：2
The work is devoted to specific features of sedimentogenesis and multistage alterations of eolian volcanic ash and epiclastic clay in paleopeat bogs and their transformation into ortho- and paratonsteins, respectively. The hydrolysis of aluminosilicate minerals and volcanic glass and their alteration into monotonous submonomineral clay, which is compositionally similar to epiclastic clay, is associated with the diagenesis stage. During the catagenesis, submonomineral clay is lithified and transformed into tonsteins, which undergo recrystallization as the temperature increases. Clay minerals are replaced by illite and chlorite, while tonsteins are transformed into metatonsteins. Paragenetic relationships of clay minerals are discussed. 相似文献
15.
Research on the longevity of potential bentonite-based barrier materials is an important part of the Canadian Nuclear Fuel Waste Management Program. Valuable information on the longterm effectiveness of bentonitic barriers can be obtained by examining the properties of unprocessed bentonites from natural deposits. This study compares the swelling capacity (Ps) and hydraulic conductivity (K) of an unprocessed (clay that has not been ground and dried by the supplier) and a processed bentonite from south-central Saskatchewan, Canada. The clay deposit is 75 to 85 Ma old. At a given clay density, the processed bentonite exhibits a greater P3 and a lower K than the unprocessed clay. This can be at least partially attributed to the partial cementation of the unprocessed bentonite particles; this cementation is likely ruptured when the clay is ground during processing. Even though K for the unprocessed clay is higher than that of the processed clay, it is still low enough (< 1011m/s) to meet the permeability requirements of a barrier material in a nuclear fuel waste disposal vault. The unprocessed clay also has the has the ability to self seal: exposure to water, the normalized flow rate of water through some samples was as high as 10-5 m3/s, but the rate rapidly decreased to < 10-10m3/s the clay absorbed water and swelled. The data indicate that the unprocessed bentonite clay maintains anacceptably high swelling capacity and low permeability millions of years after deposition. 相似文献
16.
Centrifuge tests were carried out to confirm and determine the effect of different pure alcohols, methyl t-butyl ether (MTBE) and mixtures of alcohols with gasoline and diesel on a thin disc of consolidated clay. The evolution of changes in the clay hydraulic conductivity with time was investigated and other structural changes due to chemical attack were monitored. The findings presented here demonstrate that the hydraulic conductivity of the clay appear to be generally related to the polarity of the chemicals and the dielectric constant. The cracking effect of butanol and MTBE on consolidated clay at low flow rate and low stress level was observed. The addition of ethanol or MTBE to diesel increased the clay permeability and the migration of organic chemical. The addition of ethanol to gasoline also caused an increase in the clay hydraulic conductivity. The effect of the association of alcohols with gasoline or diesel on the clay hydraulic conductivity is discussed, with a view to improving current pollution remediation techniques. 相似文献
17.
El-Zein Abbas Airey David Yu Bowei Esgandani Golnaz Alipour Proust Gwénaëlle Dias-da-Costa Daniel Gao Yifei Gan Yixiang Chen Shunzhi 《Acta Geotechnica》2021,16(12):3741-3760
Clay minerals and clayey soils have been extensively researched over the last century leading to a rich and still evolving corpus of knowledge on clay chemistry, microstructure and macroscopic behaviour. Clay has the ability, under certain conditions, to spontaneously repair its cracks. However, despite ample evidence, clay self-repair remains understudied and under-theorised. For example, the majority of experimental studies discussing clay self-repair infer its existence from changes to macroscopic properties assumed to be caused by self-repair, and only a small number of studies have attempted to observe self-repair directly. This paper reviews the literature on clay self-repair. First, it situates clay self-repair within the broader context of self-repairing material. Next, autogenous self-repair of clay, under wet-dry cycles, freeze–thaw cycles and deep-ground consolidation, is presented focusing on evidence, driving mechanisms and key variables of influence. Next, theories of clay self-repair proposed in the literature are discussed, highlighting their scope and limitations, as well as the extent to which they have been validated by experimental observations. Key gaps in current knowledge of clay self-repair are highlighted and ways in which they can be addressed in future research are proposed. Finally, a nomenclature distinguishing between different kinds of clay self-repair is proposed based on eight different attributes.
相似文献18.
滇西北红粘土的工程地质特性及其灾害效应 总被引：1，自引：0，他引：1
在野外地质调查的基础上,结合室内土工试验,系统分析了滇西北红粘土的物质组成、物性特征和工程地质特性,并以此为基础探讨了其地质灾害效应。研究结果表明：滇西北红粘土粒度组成主要以粘粒为主,粘土矿物成分比较复杂,在丽江以南其矿物成分主要以高岭石（K）为主,在丽江以北则以伊利石/蒙脱石（I/S）混层矿物为主。此外,滇西北红粘土具有含水量高、重度低、塑性高、膨胀性弱等物性特征,在天然状态下比较稳定,但是随着含水量的增加其土体强度大大降低,易引发滑坡、水土流失等地质灾害。 相似文献
19.
红粘土的成因及其对工程性质的影响 总被引：21，自引：3，他引：18
姜洪涛 《水文地质工程地质》2000,27(3):33-37
根据国内外的文献资料,通过对广西贵县和柳州龙船山地区红粘土的研究,本文分析了红粘土的成因及演化过程,认为红土化过程实质是一个物理化学改变的过程,并探讨了红粘土中特殊的矿物成分,结构连接方式以及其演化过程对其工程地质性质的影响。 相似文献
20.
粘土矿物保存海洋沉积有机质研究进展及其碳循环意义 总被引：3，自引：0，他引：3
海洋沉积物吸附有机质的量和有机质循环周期与粘土矿物类型和吸附方式密切相关,并在全球碳循环中扮演着不同的角色。粘土吸附有机质有物理吸附和化学吸附之分,前者主要存在于粘土的微孔隙中,参与年、十年或百年尺度的循环;后者主要存在于粘土矿物层间和外表面,稳定性较好,有机质易于保存,可参与百万年或更长时间的循环,这种不同时间尺度内的碳循环,将会改写海洋沉积物有机碳“源”、“汇”的关系。不同类型粘土矿物的性质存在差异,决定了吸附有机质量的多寡,蒙脱石的吸附量远大于伊利石的吸附量,这可能是造成全球不同海域中有机碳“源”、“汇”变化的原因。海洋沉积物处于水圈、生物圈和岩石圈的交汇地带,有机碳的差异和变化,都会对全球碳循环及气候变化产生重要的影响。 相似文献