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1.
衡水湖岸带重金属潜在生态风险评价及其对道路径流污染物的截留效应 总被引：1，自引：0，他引：1
《湿地科学与管理》2021,(3)
湿地岸带对地表径流污染物具有显著的截留作用。为探讨湿地岸带对道路径流污染物的截留效应以及湿地岸带的潜在生态风险,测定衡水湖四周道路降尘和岸带土壤的重金属含量,并采用多种指数对岸带的潜在生态风险进行评价。结果表明:道路降尘和岸带土壤重金属含量均低于农用地土壤污染风险值。结合单因子指数、内梅罗指数和地质累积指数可知,衡水湖四周道路存在轻微的铅、镉和锌污染,岸带在靠近道路排水渠的表层土壤存在轻微的镉和锌污染。道路和岸带的潜在生态风险指数均小于150,表明衡水湖道路降尘和岸带重金属的潜在生态风险为轻微。岸带表层土壤的铅、镉、锌和铁含量由公路至水面表现出较明显的下降趋势,下层土壤的镉、锌含量显著低于表层土壤,表明岸带在水平方向和垂直方向对重金属都具有较好的截留效应。 相似文献
2.
湿地土壤草根层对铅、镉吸附与解吸的动力学研究 总被引：7，自引：2，他引：7
利用柱实验对向海湿地土壤草根层吸附与解吸铅、镉的动力学特征进行了研究。结果表明，土壤草根层吸附镉的动力学过程符合Elovich吸附速率方程、双常数速率方程、抛物线扩散方程，吸附铅的动力学过程符合双常数速率方程、抛物线扩散方程，说明草根层吸附铅、镉的过程是一个反应速率和扩散因子综合控制的过程；实验条件下，Pb^2 、Cd^2 的吸附动力学特性较好，但解吸动力学特性很差。说明湿地土壤草根层对铅、镉均有较强的吸持能力，可阻挡重金属离子向深层土壤的迁移，减少了深层土壤中重金属的汇集。 相似文献
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破罡湖底泥重金属分布特征及潜在生态危害 总被引：1，自引：0，他引：1
2009年7月,采用Mapinfo专题地图制作技术和Lars Hankson指数模型对破罡湖底泥中铜、铬、锌、镉和铅5种重金属污染的空间分布现状及潜在生态危害进行了研究。结果表明,①破罡湖底泥中铬、铜、锌、镉和铅的含量分别为110～145 mg/kg、51.9～68.1 mg/kg、119～155 mg/kg、1.05～1.41 mg/kg和38.0～62.1 mg/kg;其中,铜和镉的平均含量超过了《土壤环境质量标准》(GB15618-1995)二级标准限值,其他重金属平均含量则在允许范围内。②破罡湖底泥中铜与铬最大含量分布区域都出现在该湖东北部邻枞阳县处;底泥中锌和镉的分布也有一定相似性,最大锌含量和镉含量都出现在湖东北部的小合村以北处,而在湖东南部通江渠附近的锌含量和镉含量都是最小的;铜与铬和锌与镉具有协同毒性,其分布的空间重叠增加了其高含量区域的生态风险。③底泥中铅的高含量区域则出现在湖西湖滨带,汽车尾气排铅是破罡湖底泥中铅的重要来源。④破罡湖底泥中镉含量达到极强生态危害影响水平,其他4种重金属潜在生态危害轻微,由于镉的贡献,导致破罡湖底泥多种重金属潜在生态危害总体上达到很强的水平。 相似文献
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运用典范对应分析（Canonical Correspondence Analysis,CCA）对广西阳朔思的村铅锌矿尾砂坝坍塌后的污染农田土壤酶活性、土壤性质进行研究。结果表明：pH值、全铅和全锌是影响土壤其他因子（碱解氮、有机碳、速效磷、阳离子交换量、蔗糖酶、脲酶和碱性磷酸酶）的重要因素。该区污染土壤尽管经过当地农民长达逾40 a的耕种,但土壤有机质、阳离子交换量、速效磷和碱解氮质量分数仍处于较低的水平,彼此之间的相关系数与其在CCA排序图中的夹角变化规律一致。土壤碱性磷酸酶活性与全锌质量分数呈正相关,因而在CCA排序图中,土壤碱性磷酸酶活性与全锌质量分数的夹角较小。尽管铅-锌污染物与蔗糖酶和脲酶的相关性不显著,但铅-锌污染物的存在造成蔗糖酶和脲酶活性的降低,因而在CCA排序图中,土壤中的铅-锌污染物与蔗糖酶和脲酶基本处于相反的两端,从而弥补相关分析结果信息量不足的弊端。鉴于CCA排序图能够直观展示土壤酶对重金属污染物的敏感强度以及土壤有机碳与养分循环物质之间的相互关系,因此可作为探索土壤因子内在联系的重要工具。 相似文献
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重金属铅和镉对溪荪生理特性的影响 总被引：2，自引：0，他引：2
采用水培法,研究重金属铅和镉及其复合胁迫对溪荪(Iris sanguine)生理特性的影响。结果表明,在500mg/L铅和500mg/L铅+25 mg/L镉复合胁迫下,溪荪的叶绿素a、叶绿素b和类胡萝卜素含量增加,其中,叶绿素a含量增加显著(p<0.05);在25 mg/L镉胁迫下,溪荪的叶绿素a、叶绿素b和类胡萝卜素含量均减少,其中叶绿素a含量减少显著(p<0.05);25 mg/L镉胁迫增大了溪荪地上部分细胞膜的透性,比对照升高了27%,并使丙二醛含量增加到对照的1.19倍;在500mg/L铅胁迫下,丙二醛含量有所上升,但与对照相比差异不显著,说明在该实验浓度下,溪荪对铅的耐性比对镉的耐性强;在500mg/L铅+25 mg/L镉复合胁迫下,无论溪荪地上部分(叶片)还是地下部分(根茎和根)的丙二醛含量都明显增加,说明复合胁迫给溪荪细胞膜带来很大的伤害;铅和镉胁迫对溪荪过氧化物酶(POD)和超氧化物歧化酶(SOD)活性的影响相似,所有污染处理都对溪荪的地下部分酶活性起明显的促进作用,而对溪荪地上部分的酶活性有明显抑制作用。过氧化物酶和超氧化物歧化酶活性在溪荪耐铅和镉胁迫中起到了非常重要的作用。 相似文献
11.
Anna Brooks Rehema M. White David C. Paton 《International Journal of Salt Lake Research》1995,4(2):133-163
The hypermarine southern Coorong is threatened by proposals to drain relatively fresh surface water and groundwater from adjacent agricultural areas into the Coorong. These influent waters carry moderate loads of heavy metals. Acute toxicity of heavy metals toDiacypris compacta, an abundant ostracod in the Coorong, was measured in the laboratory at 18°C in a static system using Coorong water (pH 7.8 salinity 50 ppt). At 4 days (96 h) the mean values of LC50 for copper, zinc, lead and, cadmium respectively were 0.8, 2.1, 3.1 and 4.3 mg L–1, and at 8 days the respective mean LC50
s were 0.4, 0.7, 2.2 and 1.1 mgL–1. The effect of two or three metals on mortality was additive in some cases and synergistic in other cases, but generally less than additive. However, in all cases mortality was greater in the presence of two or three metals than in the presence of a single metal. According to ANZECC (1992) guidelines, maximum acceptable concentrations of heavy metals should be no higher than 0.01 x the lowest LC50 value. Using the lowest LC50 values forDiacypris compacta obtained at 8 days, maximum acceptable concentrations in the Coorong would be 4, 5, 9 and 22 gL–1 for copper, zinc, cadmium and lead respectively, the values for zinc and copper failling below those recommended by ANZECC (1992) for marine waters. Reported concentrations of copper and zinc in surface water and groundwater in areas adjacent to the Coorong sometimes exceed these values, hence drainage of these waters into the Coorong represents a significant hazard to the Coorong biota. 相似文献
12.
Yuehan Lu Philip A. Meyers Brian J. Eadie John A. Robbins 《Journal of Paleolimnology》2010,43(2):261-272
A ~106-cm sediment core from the eastern basin of Lake Erie was examined to investigate biogeochemical processes in this large
lake during its cultural eutrophication over the last century. We measured stable carbon isotopes of total organic carbon
and calcium carbonate (δ13CTOC and
d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} ) as well as the concentrations of total organic carbon (TOC) and calcium carbonate (CaCO3). δ13CTOC and TOC show a strong positive correlation throughout the core and record changes in phytoplankton productivity and nutrient
loading. CaCO3 and TOC concentrations display a negative correlation throughout the core, suggesting that CaCO3 concentrations are controlled primarily by decomposition of TOC in the hypolimnion and the sediments, although temperature
and invasive mussels are also potential controlling factors.
d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values show a positive correlation with δ13CTOC between 1909 and 1969, indicating phytoplankton productivity was the primary control for
d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values during eutrophication. However, a negative correlation between
d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} and δ13CTOC from 1970 to 2002 suggests that these two proxies tracked different aspects of the carbon cycle in the lake in more recent
times. The cause for the negative correlation is not yet known, but it is perhaps associated with temperature variations and
seasonal differences in productivity. 相似文献
13.
We have measured the distribution coefficient (Kd) of210Po and210Pb in laboratory systems and in natural freshwater systems. In the laboratory systems, an inverse relationship was observed between the particle concentration of sand or lake sediment, and the distribution coefficients of210Po and210Pb. The slope of the log-linearK
d
vs particle concentration relation is consistent with existingK
d-particle concentration theories. These laboratory observations are consistent with similar measurements in two lakes. TheK
d values of Po and Pb for the bottom sediment-pore water system with a high particle concentration were 10 to 100 times lower than those for dilute concentrations of particles suspended in the lake water. TheK
d of210Pb in the sediments was >104 so that the diffusive transport of210Pb has only a small influence on the interpretation of210Pb concentration-depth profiles and the210Pb dating of these sediments.This is the second of a series of papers to be published by this journal following the 20th anniversary of the first application of210Pb dating of lake sediments. Dr P. G. Appleby is guest editing. 相似文献
14.
Muhammad Waseem Boot Ghulam Nabi Tanveer Abbas HuiJun Jin Ayesha Yousaf Muhammad Azeem Boota 《寒旱区科学》2018,10(1):55-68
Probable maximum precipitation (PMP) is widely used by hydrologists for appraisal of probable maximum flood (PMF) used for soil and water conservation structures, and design of dam spillways. A number of methods such as empirical, statistical and dynamic are used to estimate PMP, the most favored being statistical and hydro-meteorological. In this paper, PMP estimation in mountainous regions of Pakistan is studied using statistical as well as physically based hydro-meteorological approaches. Daily precipitation, dew point, wind speed and temperature data is processed to estimate PMP for a one-day duration. Maximum precipitation for different return periods is estimated by using statistical approaches such as Gumble and Log-Pearson type-III (LP-III) distribution. Goodness of fit (GOF) test, chi-square test, correlation coefficient and coefficient of determination were applied to Gumble and LP-III distributions. Results reveal that among statistical approaches, Gumble distribution performed the best result compared to LP-III distribution. Isohyetal maps of the study area at different return periods are produced by using the GIS tool, and PMP in mountainous regions varies from 150 to 320 mm at an average value of 230.83 mm. The ratio of PMP for one-day duration to highest observed rainfall (HOR) varied from 1.08 to 1.29 with an average value of 1.18. An appropriate frequency factor (Km) is very important which is a function of mean for observed precipitation and PMP for 1-day duration, and Km values varies from 2.54 to 4.68. The coefficient of variability (Cv) varies from minimum value of 28% to maximum value of 43.35%. It was concluded that the statistical approach gives higher results compared to moisture maximization (MM) approach. In the hydro-meteorological approach, moisture maximization (MM) and wind moisture maximization (WMM) techniques were applied and it was concluded that wind moisture maximization approach gives higher results of PMP as compared to moisture maximization approach as well as for Hershfield technique. Therefore, it is suggested that MM approach is the most favored in the study area for PMP estimation, which leads to acceptable results, compared to WMM and statistical approaches. 相似文献
15.
Ludmila Strokova 《寒旱区科学》2013,5(5):0637-0643
Construction of urban tunnels requires the control of surface subsidence to minimize any disturbance to nearby buildings and services. Past study of surface subsidence has been limited to mainly empiri... 相似文献
16.
Aaron F. Diefendorf William P. Patterson Chris Holmden Henry T. Mullins 《Journal of Paleolimnology》2008,39(1):101-115
A 7.6-m lake sediment core from a marl lake, Lough Inchiquin, records variation in landscape evolution from 16,800 cal yrs
B.P. to 5,540 cal yrs B.P. We observe significant variations (up to 12‰) in δ
13Corg and δ
13Ccalcite values that are interpreted to reflect secular changes in lake water δ
13CDIC values that result from a regional landscape transition from barren limestone bedrock to a forested ecosystem. Lake water
δ
13CDIC values are therefore influenced by two isotopically distinct sources of carbon: terrestrial organic material (−27.1 to −31.2‰VPDB)
via oxidized soil organic matter and weathered limestone bedrock (+3.4‰VPDB). Isotope excursions in lacustrine sediment records
are forced not only by changes in productivity but also by changes in the terrestrial environment. This has profound implications
for the interpretation of paleoclimate records derived from lacustrine sediment and suggests that selection of appropriate
lakes can provide records of terrestrial change where other related records are not available. 相似文献
17.
Influence of soil texture on the binding energies of fine mineral dust particles potentially released by wind erosion 总被引：1，自引：0，他引：1
Stphane C. Alfaro 《Geomorphology》2008,93(3-4):157-167
Models of the two aeolian processes (saltation and sandblasting) that lead to emission of fine dust particles (PM20) by wind erosion in arid and semi-arid areas have been combined to form the so-called ‘Dust Production Model’ (DPM). In this model, the size dependent binding energies of PM20 embedded within the wind-erodible loose soil aggregates or in the soil surface itself are key input parameters. Indeed, their values condition at the same time the intensity of emissions and their initial size distribution. Previous comparisons of vertical mass fluxes measured on-field with the model predictions suggest that these energies might be relatively independent of soil texture and also probably composition. Because this would greatly facilitate application of the DPM at regional or global scale, the objective of this work is to check experimentally the veracity of this result. The strategy that has been designed for this has involved selecting four natural soil samples collected in various source areas of the world and covering a wide range of textures and compositions. Then, these soil samples have been used to perform carefully controlled wind erosion simulations in a wind tunnel. During the experiments, which were carried out at different wind speeds with each soil, the horizontal flux (Fh) of saltating soil aggregates has been monitored. At the same time, number concentrations (Ci) of PM20 released by the sandblasting process were recorded in the 6 size classes of an optical size analyzer. Thus, the efficiency of the sandblasting process (defined as the ratio of Ci to Fh) could be determined for each of these size classes. Analysis of the results obtained in similar saltation conditions shows that for the four tested soils, and within the range of contents in clay and other components favoring aggregation (mostly organic matter and carbonates), the influence of soil composition and texture on binding energies of the PM20 particles within soil aggregates is at best a second order effect that can be neglected in large scale modeling of wind erosion by the DPM. 相似文献
18.
Oxygen isotope analysis of the adult ostracod Eucypris mareotica cultured at controlled temperatures (10, 15, and 19°C) was used to measure isotopic fractionation during shell calcification.
The ostracod shells that precipitated at experimental temperatures are almost in isotopic equilibrium with the culture water
as compared to the oxygen isotope fractionation of inorganic carbonates. Moreover, they had almost constant offsets from equilibrium
based on the oxygen isotope fractionation of inorganic carbonates. The δ18O values of ostracod shells from the 10°C cultures were higher than those of the 15 and 19°C cultures by 1.6 and 2.7‰, respectively.
The observed fractionations are shown by the regression equations:
*20c 10° \textC:d 1 8 \textO\textostracod = 1. 1 7+ 0. 5 7d 1 8 \textO\textwater 1 5° \textC:d 1 8 \textO\textostracod = - 0. 4 8+ 0. 6d 1 8 \textO\textwater 1 9° \textC:d 1 8 \textO\textostracod = - 1. 6+ 0. 6d 1 8 \textO\textwater \begin{array}{*{20}c} { 10^\circ {\text{C}}:\delta^{ 1 8} {\text{O}}_{\text{ostracod}} = 1. 1 7+ 0. 5 7\delta^{ 1 8} {\text{O}}_{\text{water}} } \\ { 1 5^\circ {\text{C}}:\delta^{ 1 8} {\text{O}}_{\text{ostracod}} = - 0. 4 8+ 0. 6\delta^{ 1 8} {\text{O}}_{\text{water}} } \\ { 1 9^\circ {\text{C}}:\delta^{ 1 8} {\text{O}}_{\text{ostracod}} = - 1. 6+ 0. 6\delta^{ 1 8} {\text{O}}_{\text{water}} } \\ \end{array} The fractionation factors (α) are slightly lower for the 15 and 19°C cultures, but slightly higher for the 10°C culture, as compared to inorganic carbonates
(O’Neil et al. in J Chem Phys 51:5547–5558, 1969). The oxygen fractionation factors of E. mareotica are very close to those of synthetic calcite formed in isotopic equilibrium. The ‘vital offsets’ of valve-δ18O for E. mareotica is so small that we can neglect its effect when using the δ18O of E. mareotica living in lake waters with high pH and salinity to reconstruct the paleoenvironment. The paleotemperature or paleoisotopic
composition of lake water interpreted from a core of lacustrine sediment may be closer to the true values when the δ18O data for E. mareotica are used. 相似文献
19.
Bernhard Aichner Heinz Wilkes Ulrike Herzschuh Steffen Mischke Chengjun Zhang 《Journal of Paleolimnology》2010,43(4):873-899
A sediment core from Lake Koucha (eastern Tibetan Plateau) was investigated using organic biomarkers and their stable carbon
isotope signatures. The correlation between TOC content, total amount of aquatic macrophyte-derived n-alkanes (e.g. nC23) and δ13C values of TOC and nC23 indicates that Lake Koucha was macrophyte-dominated before 8 cal ka BP. Shortly after the lake turned from a saline to a
freshwater system at 7.2 cal ka BP, a variety of algal and bacterial markers such as hopanoids and isoprenoids emerged, of
which phytane, pentamethylicosene (PMI), moretene and diploptene are particularly abundant. Phytane and PMI show different
isotopic signals (≈−18 and ≈−28‰, respectively), which indicates that they originated from different sources. Phytane may
have been derived from cyanobacteria, while methanogenic archaea may be the source of PMI. The isotopic depletion of diploptene
and moretene (≈−60‰) indicates the presence of methanotrophs. After 6.1 cal ka BP, the saturated C20 highly branched isoprenoid (HBI) became the dominant constituent of the aliphatic hydrocarbon fraction. Such dominance has
rarely been reported in lacustrine environments, and indicates a strong presence of algae (most likely diatoms) or cyanobacteria.
At 4.7 cal ka BP, the appearance of an unsaturated C25 HBI, which is a specific biomarker for diatoms, was noted. Furthermore, the level of nC17-alkane was observed to increase in abundance in the uppermost two samples. These results suggest that the lake was phytoplankton-dominated
during the last 6.1 ka. Relatively low biomarker concentrations and δ13C values at 6.0, 3.1 and 1.8 cal ka BP indicate the occurrence of cool periods, which is in agreement with inferences from
other locations on the Tibetan Plateau. The δ13C values of nC23 range from −23.5 to −12.6‰, with high values at the peak of macrophyte abundance at ca. 11 cal ka BP and at the phytoplankton
maximum between ca 6.1 and 2.8 cal ka BP. Thus, aquatic macrophyte-derived mid-chain n-alkanes have been found to be excellent indicators of carbon-limiting conditions, which lead to the assimilation of isotopically-enriched
carbon species. The limitation of carbon sources could be a localized phenomenon occurring in dense plant stands (as in the
older section of the core), or it may be induced by high primary productivity (as in the younger section). Since the δ13C value of the inorganic carbon source may vary, the offset between the δ13C values of nC23 and TIC could serve as a more precise proxy for carbon-limiting conditions in lacustrine environments, which could in turn
be interpreted with respect to lacustrine paleo-productivity. 相似文献
20.
Measuring and modeling two-dimensional irrigation infiltration under film-mulched furrows 总被引：1，自引：0，他引：1
Furrow irrigation with film-mulched agricultural beds is being promoted in the arid region of northwest China because it im-proves water utilization. Two-dimensional infiltration patterns under film-mulched furrows can provide guidelines and criteria for irrigation design and operation. Our objective was to investigate soil water dynamics during ponding irrigation infiltration of mulched furrows in a cross-sectional ridge-furrow configuration, using laboratory experiments and mathematical simulations. Six experimental treatments, with two soil types (silt loam and sandy loam), were investigated to monitor the wetting patterns and soil water distribution in a cuboid soil chamber. Irrigation of mulched furrows clearly increased water lateral infiltration on ridge shoulders and ridges, due to enhancement of capillary driving force. Increases to both initial soil water content (SWC) and irrigation water level resulted in increased wetted soil volume. Empirical regression equations accurately estimated the wetted lateral distance (Rl) and downward distance (Rd) with elapsed time in a variably wetted soil medium. Optimization of model parameters followed by the Inverse approach resulted in satisfactory agreement between observed and predicted cumulative infiltration and SWC. On the basis of model calibration, HYDRUS-2D model can accurately simulate two-dimensional soil water dynamics under irrigation of mulched furrows. There were significant differences in wetting patterns between unmulched and mulched furrow irrigation using HYDRUS-2D simulation. The Rd under the mulched furrows was 32.14% less than the unmulched furrows. Therefore, film-mulched furrows are recommended in a furrow irrigation system. 相似文献