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1.
Water mass distributions, upwelling and filament formation are of complex significance for biological and chemical processes.
Temperature and salinity are routinely used to characterize these hydrographic conditions. In situ profiles and sample analyses
from the cruise So119 of RV Sonne in May 1997 into the Arabian Sea indicate that optical parameters such as the fluorescence of phytoplankton pigments, gelbstoff
and proteins reflect hydrographic processes as well, and are useful to describe and explain biochemical processes. The dependence
of bio-optical parameters to DOC and chlorophyll a concentrations is examined. While the relation between extracted chlorophyll and chlorophyll fluorescence is quite reasonable,
DOC and gelbstoff fluorescence do not show a functional dependency. This is mainly due to sunlight-induced degradation of
fluorophores in the surface layer. Enhanced gelbstoff signals in intermediate and deep waters are related to Persian Gulf
Water. The optical data reveal a relation between the depth of the chlorophyll maximum, the depth of 1% surface light and
the geographical latitude. In the context of remote sensing of phytoplankton biomass from ocean colour images, the depth of
the chlorophyll maximum is a crucial parameter. Thus, the revealed dependency on latitude is useful for the evaluation of
primary production with satellite remote sensing.
Received: 22 May 2002 / Accepted: 18 February 2003
Responsible Editor: Andreas Oschlies
Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the framework of the
JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. Special thanks are given to the chief scientist of the cruise, Pr. V. Ittekkot, for helpful discussions.
We are indebted to Mr. Rüdiger Heuermann and Mr. Nils Bürckel for their participation in the cruise and their support in the
data analysis. 相似文献
2.
3.
N. Iwagami T. Shibaki T. Suzuki H. Sekiguchi N. Takegawa W. H. Morrow 《Journal of Atmospheric and Solar》2003,65(16-18):1349-1360
Atomic oxygen density and airglow volume emission rate profiles measured in the rocket experiment S-310-29 carried out as a part of the Waves in Airglow Structures Experiment over Kagoshima in 2000 (WAVE2000) campaign are presented, and the excitation processes of the atomic oxygen 557.7 nm line and the molecular oxygen atmospheric band airglow emissions are discussed. The volume emission rate profiles calculated from the measured atomic oxygen densities using the methods and parameters proposed by the ETON campaign (EATON model) are found to well represent the shapes of measured twin-peak emission rate profiles seen during this campaign suggesting that the EATON model is valid for a perturbed atmosphere. There is some discrepancy in the modeled absolute values for the emissions. Applying the model to the current O density measurements results in predicted emission rates that are a factor of 3.2 and 1.5 too high for the 557.7 nm line and Atmospheric band, respectively. This suggests either that the atomic oxygen densities of the present campaign are too large by a factor of 1.2 (=1.51/2) to 1.5 (=3.21/3), or that those of the ETON campaign were too small by the same factor or that the combined errors in both campaigns can account for the discrepancy (the modeled volume emission rates of the 557.7 nm line and atmospheric band are roughly in proportion to [O]3 and [O]2, respectively). Our present data findings do not favor the 2-step more than the 1-step excitation process for the atmospheric band because a calculation of the quantum efficiency based on the observed O density does not show a steep gradient around 100 km. 相似文献
4.
The results of a comparison between chemical water quality determinants and river water fluorescence on the River Tyne, NE England, demonstrate that tryptophan‐like fluorescence intensity shows statistically significant relationships between nitrate, phosphate, ammonia, biochemical oxygen demand (BOD) and dissolved oxygen. Tryptophan‐like fluorescence intensity at the 280 nm excitation/350 nm emission wavelength fluorescence centre correlates with both phosphate (r = 0·80) and nitrate (r = 0·87), whereas tryptophan‐like fluorescence intensity at the 220 nm excitation/350 nm emission wavelength centre correlates with BOD (r = 0·85), ammonia (r = 0·70) and dissolved oxygen (r = ?0·65). The strongest correlations are between tryptophan‐like fluorescence intensity and nitrate and phosphate, which in the Tyne catchment derive predominantly from point and diffuse source sewage inputs. The correlation between BOD and the tryptophan‐like fluorescence intensity suggests that this fluorescence centre is related to the bioavailable or labile dissolved organic matter pool. The weakest correlations are observed between tryptophan‐like fluorescence intensity and ammonia concentration and dissolved oxygen. The weaker correlation with ammonia is due to removal of the ammonia signal by wastewater treatment, and that with dissolved oxygen due to the natural aeration of the river such that this is not a good indicator of water quality. The observed correlations only hold true when treated sewage, sewerage overflows or cross connections, or agricultural organic pollutants dominate the water quality—this is not true for two sites where airport deicer (propylene glycol, which is non‐fluorescent) or landfill leachate (which contains high concentrations of humic and fulvic‐like fluorescent DOM) dominate the dissolved organic matter in the river. Mean annual tryptophan‐like fluorescence intensity agrees well with the General Water Quality Assessment as determined by the England and Wales environmental regulators, the Environment Agency. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
5.
6.
The optical properties and spatial distribution of chromophoric dissolved organic matter (CDOM) in Meiliang Bay of Lake Taihu were evaluated and compared to the results in literature. Concentrations of dissolved organic carbon (DOC) ranged from 8.75 to 20.19 mg L?1 with an average of (13.10 ± 3.51) mg L?1. CDOM absorption coefficients a(λ) at 280 nm, 355 nm, and 440 nm were in the range 11.28...33.46 m?1 (average (20.95 ± 5.52) m?1), 2.42...7.90 m?1 (average (4.92 ± 1.29) m?1), and 0.65...2.44 m?1 (average (1.46 ± 0.44) m?1), respectively. In general, CDOM absorption coefficient and DOC concentration were found to decrease away from the river inflow to Meiliang Bay towards the lake center. The values of the DOC‐specific absorption coefficients a*(λ), given as absorption coefficient related to mass concentration of organic carbon (C) ranged from 0.28 to 0.47 L mg?1 m?1 at 355 nm. The determination coefficients between CDOM absorption and DOC concentration decreased with the increase of wavelength from 280 to 550 nm. The linear regression relationship between CDOM absorption at 280 nm and DOC concentration was following: a(280 nm) = 1.507 L mg?1 m?1 · DOC + 1.215 m?1. The spectral slope S values were dependent on the wavelength range used in the regression. The estimated S values decreased with increasing wavelength range used. A significant negative linear relationship was found between CDOM absorption coefficients, DOC‐specific absorption coefficients and estimated S values especially in longer wavelength range. The linear regression relationship between DOC‐specific absorption coefficients at 440 nm and estimated S values during the wavelength range from 280 to 500 nm was following: a*(440 nm) = (–0.021 μm · S + 0.424) L mg?1 m?1. 相似文献
7.
C. H. A. von Savigny I. C. McDade G. G. Shepherd Y. Rochon 《Annales Geophysicae》1999,17(11):1439-1446
Vertical profiles of nitric oxide in the altitude range 90 to 105 km are derived from 553 nm nightglow continuum measurements made with the Wind Imaging Interferometer (WINDII) on the Upper Atmosphere Research Satellite (UARS). The profiles are derived under the assumption that the continuum emission is due entirely to the NO+O air afterglow reaction. Vertical profiles of the atomic oxygen density, which are required to determine the nitric oxide concentrations, are derived from coordinated WINDII measurements of the atomic oxygen OI 557.7 nm nightglow emission. Data coverage for local solar times ranging from 20 h to 04 h, and latitudes ranging from 42°S to 42°N, is achieved by zonally averaging and binning data obtained on 18 nights during a two-month period extending from mid-November 1992 until mid-January 1993. The derived nitric oxide concentrations are significantly smaller than those obtained from rocket measurements of the airglow continuum but they do compare well with model expectations and nitric oxide densities measured using the resonance fluorescence technique on the Solar Mesosphere Explorer satellite. The near-global coverage of the WINDII observations and the similarities to the nitric oxide global morphology established from other satellite measurements strongly suggests that the NO+O reaction is the major source of the continuum near 553 nm and that there is no compelling reason to invoke additional sources of continuum emission in this immediate spectral region. 相似文献
8.
Based on observations of mesopause emissions, namely, emissions of hydroxyl (band (6-2)) and molecular oxygen (band (0-1)
of the atmospheric system), their systematic nighttime and seasonal variations are determined at Zvenigorod Observatory in
2000–2008. It is shown that the intensity of hydroxyl emission decreases during the entire night or first half-night, probably
due to the influence of the chemical sink of atomic oxygen on the nighttime behavior of hydroxyl emission. The nighttime behavior
of the intensity of molecular oxygen emission is explained by the action of atmospheric tides. The seasonal behavior of emissions
is characterized by two minima, in April–May and December; it is caused by the annual behavior of the atomic oxygen content,
temperature, and atmospheric density in the emitting layer. Based on the emission data, we determined the seasonal variations
of atomic oxygen at heights of ∼87 km (maximum of hydroxyl emission) and ∼95 km (maximum of molecular oxygen emission). 相似文献
9.
The optical observations on Heiss Island (Φ′ = 75.0°) have been used to study the characteristics of auroras in the near-noon
MLT sector after abrupt increases in the solar wind dynamic pressure at negative and positive polarity of the IMF B
z
component. It has been found out that the 427.8 and 557.7 nm emission intensities considerably increased at B
z
< 0 both equatorward of the dayside red luminosity band and within this band. The value of the emission intensities at a
red luminosity maximum (I
6300/I
5577 ∼ 0.5) indicates that energetic electron precipitation is of the magnetospheric origin. At B
z
> 0, fluxes of harder (E > 1 keV) precipitating electrons were superimposed on the soft spectrum of precipitating particles in the equatorial part
of the red luminosity band. This red band part was hypothetically caused by the low-latitude boundary layer (LLBL) on closed
lines of the geomagnetic field, the estimated thickness of which is ∼3 R
e
. The 557.7 nm emission intensity increased during 3–5 min after SC/SI and was accompanied by the displacement of the red
band equatorward boundary toward lower latitudes. The displacement value was ∼150–200 km when the dynamic pressure abruptly
increased by a factor of 3–5. After SC/SI, the 630.0 nm emission intensity continued increasing during 16–18 min. It is assumed
that the time of an increase in the red line intensity corresponds to the time of saturation of the magnetospheric boundary
layers with magnetosheath particles after an abrupt increase in their density. 相似文献
10.
Temporal and spatial variability in the Guadalquivir estuary: a challenge for real-time telemetry 总被引：1，自引：1，他引：0
Gabriel Navarro Francisco Javier Gutiérrez Manuel Díez-Minguito Miguel Angel Losada Javier Ruiz 《Ocean Dynamics》2011,61(6):753-765
Meteorological, hydrological, and hydrodynamic data for 3 years (2008–2010) have been used to document and explain the temporal
and spatial variability of the physical–biogeochemical interactions in the Guadalquivir River Estuary. A real-time, remote
monitoring network has been deployed along the course of the river between its mouth and Seville to study a broad range of
temporal scales (semidiurnal, diurnal, fortnightly, and seasonal). This network consists of eight hydrological monitoring
stations capable of measuring temperature, conductivity, dissolved oxygen, turbidity, and chlorophyll fluorescence at four
depths. In addition, six stations have been deployed to study hydrodynamics, obtaining 20-cell water column current profiles,
and there is a meteorological station at the river mouth providing data for understanding atmospheric interactions. Completing
this data-gathering network, there are several moorings (tide gauges, current/wave sensors, and a thermistor chain) deployed
in the estuary and river mouth. Various sources of physical forcing, such as wind, tide-associated currents, and river discharge,
are responsible for the particular temporal and spatial patterns of turbidity and salinity found in the estuary. These variables
force the distribution of biogeochemical variables, such as dissolved oxygen and chlorophyll fluorescence. In particular,
episodes of elevated turbidity (when suspended particle matter concentration >3,000 mg/l) have been detected by the network,
together with episodes of declining values of salinity and dissolved oxygen. All these patterns are related to river discharge
and tidal dynamics (spring/neap and high/low tide). 相似文献
11.
12.
Estimate of seasonal changes in the intensity of the infrared atmospheric system of molecular oxygen
A. I. Semenov V. I. Perminov K. V. Lipatov V. Yu. Khomich 《Geomagnetism and Aeronomy》2011,51(3):415-420
On the basis of measurements of the intensity of 1.58-μm emissions of the Infrared Atmospheric System of molecular oxygen
(IRAO2) conducted at the Zvenigorod scientific station of the Institute of Atmospheric Physics of the Russian Academy of Sciences
(φ = 55.7°N, λ = 36.8°E), seasonal variations are estimated for various solar zenith angles. Their amplitude has the maximum
value at the solar zenith angles χ
S
∼ 105–110°. It decreases at χ
S
∼ 125–130° and tends to zero at χ
S
∼ 80–85°. The comparison of currently measured values of the 1.58-μm emission intensity of the Infrared Atmospheric System
of molecular oxygen with published data on the intensity of this emission obtained in 1961–1966 reveals their decrease over
approximately 50 years. This fact is in good agreement with similar behavior of the emission intensity of atomic oxygen (557.7
nm) over the period considered. 相似文献
13.
Nozomi Ytow Motoo Utsumi Humitake Seki 《Aquatic Sciences - Research Across Boundaries》1996,58(2):91-102
Ultraviolet (UV) spectra were measured to characterize the dissolved and particulate organic matter in a bog and to investigate the seasonal fluctuation of this organic matter. The optical density spectra in the UV region of dissolved organic matter (DOM) were proportional to
–4, where is the wavelength of incident light. There was also small absorption on the
–4 spectra. The optical density at a wavelength of 280 nm was proportional to the concentration of dissolved organic carbon (DOC). The spectra and the dependency of optical density on DOC did not vary throughout the investigation period. The UV spectra of acid extractions of particulate organic matter (POM) showed two absorption peaks at the wavelengths of 220 nm and 335 nm. These peaks are well represented by the sum of two Lorentz functions. The ratio of the absorbances,A
280/A
335, was dependent on the nitrogen/carbon ratio of POM and the chlorophyll fraction in particulate organic carbon (POC), and not dependent on POC itself. The dependency of POC absorption at 280 nm varied with this ratio which fluctuated seasonally. 相似文献
14.
有色溶解性有机物(CDOM)广泛存在于水体中,占溶解有机碳(DOC)10%～90%,其浓度影响水环境碳循环过程、污染物质迁移以及水生生物群落的结构和功能。为分析东北地区水库DOC碳循环情况,本文于2015—2020年对第二松花江流域典型水库白山水库和丰满水库进行5次现场观测和室内实验,在分析CDOM吸收特性的基础上,基于Landsat系列卫星利用波段比值法建立CDOM浓度反演模型(R2=0.82),根据实测值CDOM与DOC的强相关性(R2=0.78),进而估算水库DOC浓度。结果表明：(1)利用野外实测数据和Landsat系列卫星能够对东北内陆水库CDOM浓度进行良好反演,(2)2000—2020年白山水库和丰满水库年际CDOM和DOC浓度变化不大,在2010年之后表现出轻微上升趋势,CDOM浓度从支流和干流的汇入到主库区呈现逐渐减少趋势,(3)白山水库和丰满水库M值(CDOM在250和365 nm处吸收系数比值)和S275～295(CDOM在275～295 nm波段处的吸收光谱的斜率)较小、SUVA254<... 相似文献
15.
M.-J. GonsalvesA.L. Paropkari C.E.G. FernandesP.A. Loka Bharathi L. KrishnakumariV. Fernando G.E. Nampoothiri 《Continental Shelf Research》2011,31(11):1224-1235
The presence of a delicately poised mid-depth oxygen minimum zone (OMZ) makes the Arabian Sea a unique and important ecosystem. So far, various aspects responsible for its formation have been studied. However, the contributions from bacterial groups mediating its formation and maintaining its intensity are described for the first time in this study. Thus, we hypothesize that the bacterial dynamics along with organic carbon loading result in bringing about differences in the intensity of OMZ between two stations in the Eastern Arabian Sea (EAS). Water column from 2 stations, one from offshore and another from slope, in the EAS were examined for phytoplankton diversity and pertinent groups of culturable bacteria. Vertical profiles of dissolved oxygen, productivity, chlorophyll a, total organic carbon and different physiological groups of bacteria showed well-defined stratified patterns in tandem with physical and chemical stratifications of the water column. The phytoplankton diversity was higher at the slope station (SS) and was dominated by the heterotrophic dinoflagellates. The offshore station (OS) on the other hand, showed lower diversity dominated by diatoms (p<0.05). This observation could imply relatively higher autotrophy at the OS. Our results show that OMZ from these ‘oligotrophic’ regions is dominated by anaerobic bacteria. We believe that these bacteria contribute to intensify the OMZ in the EAS. Further, a higher abundance of viable anaerobic bacteria (TVCanaero) and other anaerobic groups at the SS than the OS suggest that the OMZ is relatively much more intense near the slope. Besides, total organic carbon (TOC) load is three-fold higher at the SS than at OS implying its higher accumulation and lower degradability in slope waters. Settling of this more preserved organic carbon in mid-slope sediments in contact with OMZ results in one of the highest enrichments of sedimentary TOC in the world oceans. 相似文献
16.
The spatial and diurnal tidal variability of dissolved organic carbon (DOC) concentrations and the composition of dissolved
organic matter (DOM), as evaluated by high-temperature catalytic oxidation and excitation–emission matrix combined with parallel
factor analysis (EEM–PARAFAC), respectively, were determined in Liverpool Bay. EEM–PARAFAC modeling resulted in six fluorescent
components characterized as terrestrial humic-like (two), microbial humic-like (two), and protein-like (two). The spatial
distributions of DOC and the four humic-like components were negatively correlated with salinity in the high-salinity waters
observed in this study (30.41–33.75), suggesting that terrestrial DOM was conservatively distributed. The spatial patterns
of protein-like components were largely different from those of DOC, humic-like components, and chlorophyll a, suggesting that these distributions were the combined result of production and degradation in the bay in addition to river
inputs. These findings suggest that the DOM dynamics in Liverpool Bay are strongly controlled by river-dominated allochthonous
DOM inputs with some less significant contributions of autochthonous DOM within the bay. In addition, the temporal variations
of DOM associated with the diurnal tidal cycles were determined at one inshore (31.34–32.24 salinity) and one offshore (33.64–33.75
salinity) station in the bay. Negative linear relationships between salinity and DOM characteristics, i.e., DOC, humic-like,
and protein-like components, were observed at the inshore station. In contrast, no relationship was observed at the offshore
station, suggesting that the export of DOM through rivers and possibly tidal flats have a noticeable influence on DOM concentration
and composition up to a relatively elevated salinity of around 33 in Liverpool Bay. 相似文献
17.
David P. Hamilton Katherine R. O’Brien Michele A. Burford Justin D. Brookes Chris G. McBride 《Aquatic Sciences - Research Across Boundaries》2010,72(3):295-307
The factors affecting vertical distributions of chlorophyll fluorescence were examined in four temperate, warm monomictic
lakes. Each of the lakes (maximum depth >80 m) was sampled over 2 years at intervals from monthly to seasonal. Profiles were
taken of chlorophyll fluorescence (as a proxy for algal biomass), temperature and irradiance, as well as integrated samples
from the surface mixed layer for chlorophyll a (chl a) and nutrient concentrations in each lake. Depth profiles of chlorophyll fluorescence were also made along transects of the
longest axis of each lake. Chlorophyll fluorescence maxima occurred at depths closely correlated with euphotic depth (r
2 = 0.67, P < 0.01), which varied with nutrient status of the lakes. While seasonal thermal density stratification is a prerequisite
for the existence of a deep chlorophyll maximum (DCM), our study provides evidence that the depth of light penetration largely
dictates the DCM depth during stratification. Reduction in water clarity through eutrophication can cause a shift in phytoplankton
distributions from a DCM in spring or summer to a surface chlorophyll maximum within the surface mixed layer when the depth
of the euphotic zone (z
eu) is consistently shallower than the depth of the surface mixed layer (z
SML). Trophic status has a key role in determining vertical distributions of chlorophyll in the four lakes, but does not appear
to disrupt the annual cycle of maximum chlorophyll in winter. 相似文献
18.
Seasonal and year-to-year variability in the intensity of the 557.7 nm line of atomic oxygen atmospheric emission and its
dependence on solar activity in the 23rd solar cycle is considered. The experimental data of the 557.7 nm emission observations
in Eastern Siberia obtained in 1997–2008 and the NRLMSIS-00 atmospheric model are used. For particular considered characteristics
of the 557.7 nm emission, differences between the experimental data and model approximations for the 23rd solar cycle are
noted. Possible causes of the discovered discrepancies are discussed. 相似文献
19.
Fluorescence and UV‐VIS techniques were employed for the investigation of natural organic matter (NOM) of a tropical lake. The relationships of absorbance/dissolved organic carbon (A/DOC), fluorescence intensity/dissolved organic carbon (FI/DOC), fluorescence ratio (FR), and peak wavelength with the highest intensity (PW) were used to distinguish the pedogenic or aquagenic origin of NOM. The values of FR, PW and A285/DOC of high waters (HW) or flooded period samples and of low waters (LW) period samples of the dry season, except for September 2002, confirm the predominance of pedogenic material. The spectra of water were similar to the standard fulvic acid (FA), and the spectra of FA from the lake were similar to the nearby soils, indicative of pedogenic predominance. The results confirm that the dissolved NOM of Patos Lagoon – MS (Brazil), in all sampling periods, predominantly consisted of humic substances (FA) of pedogenic origin. 相似文献
20.
A method for the rapid detection of cyanobacteria (blue‐green algae) and their differentiation from eukaryotic algae in natural phytoplankton assemblages is presented. Fluorescence emission of photosynthetic pigments at 670 nm was measured using a microplate fluorescence reader when excited at two different wavelengths – 485 nm and 590 nm. The ratio of fluorescence excited at these wavelengths (590 nm/485 nm) was proportional to the ratio of cyanobacteria and eukaryotic algae, which was determined by the in situ spectrofluorometer for the phytoplankton quantification. The fluorescence intensity was equal to the total chlorophyll‐a content. These two fluorescence values can provide the first warning on a development of potentially toxic cyanobacteria in water. 相似文献