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1.
研究南四湖消落带底泥有机磷赋存形态及分布特征,有利于全面揭示湖区各形态磷迁移转化规律,对南四湖富营养化防控及南水北调东线调水水质保障具有重要的科学意义。以南四湖消落带底泥为研究对象,采用改进Hedley连续分级提取法测定底泥中各形态有机磷含量,通过紫外可见分光光谱与三维荧光光谱技术表征底泥有机分子结构特征及稳定性,反映消落带有机磷结构及稳定性差异,运用Pearson相关性分析及主成分分析解析底泥各形态磷与其他理化指标的相关性。研究结果表明,南四湖消落带底泥总磷含量均值为679.90 mg/kg,其中有机磷(OP)占比20.03%~45.69%。各赋存形态有机磷含量及相对比例大小依次为:残渣态有机磷(67.58%)＞钙结合态有机磷(16.61%)＞铁/铝结合态有机磷(7.62%)＞碳酸氢钠提取态有机磷(5.97%)＞水提取态有机磷(2.22%)。南四湖消落带底泥OP含量及形态主要受内源影响,主要来自内源性微生物代谢。南四湖消落带西岸底泥磷释放风险高于东岸和南岸消落带。相关性分析发现,消落带底泥pH与磷含量显著负相关,表明随着底泥碱性的增强可能导致底泥磷向水体中释放的风险更高;底泥有机质与OP显著正相关,表明有机质可能是OP的重要载体;主成分分析发现底泥各形态磷呈正相关性,表明消落带底泥各形态磷具有同源性。研究结果可为南四湖湖区内源磷释放控制及富营养化风险防控提供科学依据。 相似文献
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以自主研发的煅烧改性净水厂污泥（C-WTPS）作为污染底泥活性覆盖材料,室内静态模拟实验研究C-WTPS覆盖强度对控制底泥磷释放效果的影响,分析C-WTPS和底泥中不同形态磷含量变化,探讨C-WTPS薄层覆盖对上覆水体中pH、DO和ORP的影响.结果表明,实验历时40天,在底泥TP释放强度为6.25~10.87 mg/（m2·d）时,覆盖强度为0.25、0.50、1.00、1.50和2.00 kg/m2的C-WTPS对TP平均削减率分别为59.68%、75.71%、88.75%、92.42%和96.28%,可见覆盖强度为1.00 kg/m2以上的C-WTPS能控制底泥中90%以上TP释放.C-WTPS吸附的磷主要以无机磷（IP）中的铁铝结合态磷（NAIP）形式存在,有机磷（OP）和钙磷（AP）形式较少.C-WTPS促进了底泥中易释放形态磷迁移到C-WTPS中,并转化较为稳定的形态磷,可见C-WTP覆盖不仅控制了底泥磷释放,而且也削减了底泥磷释放风险.C-WTPS覆盖后,上覆水体中pH开始呈现下降趋势,最终维持在pH=7范围波动;C-WTPS覆盖强度越大,上覆水体pH下降也明显;C-WTPS覆盖改善上覆水体中DO和ORP环境的效果不明显. 相似文献
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为探究大规模调水输入背景下南四湖生态环境演变特征,采用多种非参数统计方法综合分析2010—2020年南四湖藻密度、总氮（TN）、总磷（TP）、氨氮、叶绿素a（Chl.a）、五日生化需氧量（BOD5）、高锰酸盐指数（CODMn）年际年内变化规律和影响因素.结果表明：2010—2020年南四湖上、下级湖水质综合污染指数年均值范围分别为0.759~0.945、0.719~0.926,水质总体逐渐改善,但TN单项污染指数存在超标现象,主要可能与入湖河流中高浓度氮输入有关.受南水北调东线工程运行初期与严峻旱情的影响,南四湖藻密度、TP、氨氮、Chl.a在2013—2015年发生突变,随后均呈增加趋势.南水北调东线工程的运行对南四湖藻密度的年内波动影响强烈,调水工程运行后每年10月份出现峰值,其中2016年上级湖藻密度高达520.0×104 cells/L.湖区藻密度不仅与氮磷质量比（TN/TP）、TP、CODMn、Chl.a呈显著相关,还与降雨、水温密切相关.在南四湖生态环境保护治理过程中,应强化关键水质指标的污染监管与治理,完善调水方案和水生态危机应急管理办法. 相似文献
5.
鄱阳湖沉积物中磷的赋存形态及分布特征 总被引：11，自引：2，他引：9
利用分级提取法对鄱阳湖沉积物进行了磷形态的分级提取和测定,系统研究了沉积物中磷的赋存形态及分布特征.结果表明,鄱阳湖表层沉积物中磷的赋存形态主要包括铁磷(Fe-P)、钙磷(Ca-P)、铝磷(Al-P)、可溶性磷(DP)等无机磷(IP)及有机磷(OP),各形态磷的空间分布基本具有从河口地区监测点向湖区监测点方向升高的趋势,垂向分布上总磷及各形态磷含量随深度增加而降低.表层沉积物(0-2cm)中总磷含量为578.36-813.55mg/kg,主要由无机磷组成,无机磷中以Fe-P含量最高,最大值达350.24mg/kg,占总磷的40%以上,Ca-P、Al-P含量相当,约占总磷含量的20%左右,而以DP的含量最低,含量在5%以下.有机磷含量约占总磷含量的15%左右.另外,沉积物中TP含量与Fe-P、Al-P、Ca-P及OP均具有较好的相关性,且OP含量与Fe-P、Al-P也具有较好的正相关关系,而与Ca-P的相关性较弱. 相似文献
6.
苦草(Vallisneria natans)和黑藻(Hydrilla verticillata)对沉积物各形态磷垂直分布的影响 总被引：2，自引：2，他引：0
采用沉水植物苦草(V.natans)和黑藻(H.verticillata)作为研究对象,在其旺盛生长期测定群落内外上覆水及沉积物各形态磷的含量,以探究不同根系特点的沉水植物对沉积物中各形态磷垂直分布的影响.结果表明:实验进行30 d后苦草和黑藻组沉积物总磷(TP)、无机磷(IP)和氢氧化钠提取磷(NaOH-P)含量在垂直方向均呈现不同程度的降低.苦草和黑藻组沉积物TP的含量在4.5 cm深度处降低幅度最大,较对照组分别下降了58.91和36.46 mg/kg;IP含量分别在沉积物6.0和3.0 cm深度处降低幅度最大,较对照组分别降低了85.41和57.41 mg/kg.总体来看,沉水植物苦草对沉积物各形态磷含量降低的影响大于黑藻. 相似文献
7.
三峡澎溪河高阳平湖高水位期间磷-藻生态模型研究 总被引：1，自引：0，他引：1
通过在前期建立的总磷模型基础上建立磷-藻模型.从正磷酸盐所代表的无机磷和藻类生物量所代表的有机磷入手,分析蓄水期所累积的磷在高水位时期各种形态转化和循环机制,以期从定性和定量两方面说明冬季末水华暴发所消耗磷的来源.研究表明:高水位蓄水期、稳定期和水华期这3个阶段中各磷库磷通量各不相同.淹没消落带磷释放是该时期高阳平湖溶解性正磷酸盐的主要来源(占总输入通量的72.69%),其释放量与被淹没消落带面积和消落带水土界面磷交换速率有关,淹没消落带面积越多,磷交换速率越高,磷释放量越大,对整个磷循环的贡献越大.但水华期间藻磷的合成率最大仅为14.4%,藻类对冬季高水位期间所积累磷的利用量依然相对较低. 相似文献
8.
三峡澎溪河回水区高水位期间高阳平湖总磷模型 总被引：2，自引：1，他引：1
三峡水库"蓄清排浑"的调度运行方式使得冬季高水位期间近岸消落带受淹.消落带氮、磷等营养物受淹后向水体中释放与积累对冬末初春的水华将可能具有重要贡献.构建高水位时期澎溪河高阳平湖总磷收支模型,定量分析高水位期间总磷的收支途径、累积量以及累积磷的主要来源.结果表明:蓄水期,由于蓄水水位升高和顶托而导致大量磷积累;稳定期,磷收支变幅较小,总体趋于平缓;水华期,前期积累的磷被大量消耗,形成水华.淹没消落带磷释放是冬季高水位时期高阳平湖总磷的主要来源,蓄水期所淹没大量消落带所释放的磷为冬季末水华暴发提供条件.研究结果为后续定量分析磷形态的转化和分配奠定重要基础. 相似文献
9.
白洋淀沉积物氮磷赋存特征及其内源负荷 总被引：11，自引：2，他引：9
白洋淀环境整治对区域生态文明建设具有重要意义,然而,目前对加剧白洋淀富营养化的内源氮、磷污染负荷依然缺乏系统的研究.本研究以野外调研和室内培养实验相结合形式,在白洋淀主要水域内采集原位柱状沉积物样品,详细地研究了白洋淀沉积物中氮、磷赋存形态、间隙水中氮、磷剖面特征以及沉积物-水界面氮、磷交换特征.结果表明,白洋淀沉积物总氮、总磷含量分别为1230.8~9559.0 mg/kg（均值2379.5 mg/kg）和344.4~915.4 mg/kg（均值608.4 mg/kg）,氮、磷累积污染量大.沉积物中铵态氮赋存量大（3.2~175.8 mg/kg）,由此导致间隙水中铵态氮浓度较高,最高达到28.8 mg/L.沉积物磷形态以Ca-P和Fe-P为主,分别占总量的38.3%~76.1%和3.98%~18.0%,间隙水中磷酸盐浓度已接近甚至高于国内外典型富营养湖区.间隙水中高浓度的铵态氮和磷酸盐导致沉积物-水界面氮、磷交换通量较高,铵态氮平均释放和扩散通量分别为106.37和12.42 mg/（m2·d）;磷酸盐平均释放和扩散通量分别为15.06和2.33 mg/（m2·d）,沉积物内源氮、磷污染负荷较高,已严重威胁到白洋淀水环境质量,迫切需要整治.其中,北部河口区域以及中部府河入湖区和人口密集活动区沉积物氮、磷内源负荷尤为突出,应成为白洋淀沉积物内源污染整治的关键区域. 相似文献
10.
浅水湖泊沉积物磷释放的波浪水槽试验研究 总被引：15，自引：1，他引：15
为探索浅水湖泊水动力扰动作用对沉积物内源营养盐释放的规律,采用波浪水槽试验研究了波浪扰动对太湖和巢湖沉积物悬浮和磷释放的作用.试验结果显示在强波浪扰动下,底泥大规模悬浮,使得水体中悬浮固体(SS)、总磷(TP)和溶解性总磷(DTP)含量显著升高,太湖和巢湖底泥水槽试验中上覆水体TP含量分别升高了6倍和3倍,DTP分别升高了1倍和70％,太湖底泥试验中溶解性活性磷(SRP)含量亦升高了25％.掀沙过程中,不但表层底泥间隙水中的溶解性磷释放到上覆水体当中,沉积物颗粒所吸附的磷也大量转化为SRP而解吸释放.然而,强波浪掀沙一段时间后,溶解态磷的释放逐渐受到限制.随着波浪扰动作用的持续,悬浮物的中值粒径减小,细颗粒组分的百分含量明显增加,使得悬浮物对溶解态磷的吸附能力增强;波浪扰动显著提高了水体的溶解氧浓度,也会促进水体铁锰物质的氧化,增大其对磷酸根离子的吸附能力.这些变化可能是波浪掀沙后期限制水体SRP浓度进一步升高的主要原因.太湖底泥波浪水槽试验的结果与太湖梅梁湾中心区域常见风浪扰动下底泥的悬浮起动情况相吻合,底泥起动的临界切应力也基本相同,强波浪掀沙的切应力条件及水体SS,TP及SRP浓度变化的特点也一致,表明本实验的结果接近太湖的实际状况.本研究说明太湖的水动力扰动能显著提高水体TP及SRP浓度,大波掀沙初期对底泥磷释放的影响最大,后期的影响强度则有所下降. 相似文献
11.
采用沉水植物苦草(Vallisneria natans)为研究对象,在其衰亡期测定群落内、外上覆水及沉积物各形态磷的含量,以探究沉水植物在其衰亡期对上覆水和沉积物中各形态磷的影响.结果表明:苦草衰亡过程中上覆水中总磷、可溶性总磷、溶解性活性磷、颗粒磷、可溶性有机磷浓度的变化相对平稳,与对照组相比无显著差异;沉积物中各形态磷含量均呈小幅度上升趋势,在实验结束时,苦草组沉积物中总磷含量为719.27 mg/kg,和初始值比增加了14.68 mg/kg,无机磷和有机磷含量分别增加了12.06和2.20 mg/kg,氢氧化钠提取磷和盐酸提取磷含量分别增加了7.05和4.29 mg/kg.总体来看,沉水植物苦草在其衰亡过程中分解速率较慢,对水-沉积物之间各形态磷含量无显著影响. 相似文献
12.
Forms of phosphorus in sediments from 25 lakes in the middle and lower reaches of Yangtze River were analyzed by the sequential extraction procedure. Contents and spatial distrubution of algal available phosphorus (AAP) in sediments of Lake Taihu, the third largest freshwater lake of China, were also studied. Relationships between phosphorus forms in sediment and macrophytes coverage in sample sites, as well as phosphorus forms in sediments and chlorophyal contents in lake water were discussed. Exchangeable form of phosphorus (Ex-P) in surface sediments was significantly positive correlative to total phosphorus (TP), dissolved total phosphorus (DTP) and soluble reactive phosphorus (SRP) contents in the lake water. Bioavailable phosphorus (Bio-P) contents in sediments from macrophytes dominant sites were significantly lower than that in no macrophyte sites. In Lake Taihu, Ex-P content in top 3 cm sediment was highest. However, content of ferric fraction phosphorus (Fe-P) was highest in 4–10 cm. Bioavalilble phosphorus (Bio-P) contents in surface sediments positively correlated to Chlorophyll a contents in water of Lake Taihu with significant difference. Therefore, contents of Bio-P and AAP could be acted as the indicators of risks of internal release of phosphorus in the shallow lakes. It was estimated that there were 268.6 ton AAP in top 1 cm sediments in Lake Taihu. Sediment suspension caused by strong wind-induced wave disturbance could carry plenty of AAP into water in large shallow lakes like Lake Taihu. 相似文献
13.
Phosphorus forms and bioavailability of lake sediments in the middle and lower reaches of Yangtze River 总被引：5，自引：2，他引：5
Forms of phosphorus in sediments from 25 lakes in the middle and lower reaches of Yangtze River were analyzed by the sequential extraction procedure. Contents and spatial distrubution of algal available phosphorus (AAP) in sediments of Lake Taihu, the third largest freshwater lake of China, were also studied. Relationships between phosphorus forms in sediment and macrophytes coverage in sample sites, as well as phosphorus forms in sediments and chlorophyal contents in lake water were discussed. Exchangeable form of phosphorus (Ex-P) in surface sediments was significantly positive correlative to total phosphorus (IP), dissolved total phosphorus (DTP) and soluble reactive phosphorus (SRP) contents in the lake water. Bioavailable phosphorus (Bio-P) contents in sediments from macrophytes dominant sites were significantly lower than that in no macrophyte sites. In Lake Taihu, Ex-P content in top 3 cm sediment was highest. However, content of ferric fraction phosphorus (Fe-P) was highest in 4 - 10 cm. Bioavalilble phosphorus (Bio-P) contents in surface sediments positively correlated to Chlorophyll a contents in water of Lake Taihu with significant difference. Therefore, contents of Bio-P and AAP could be acted as the indicators of risks of internal release of phosphorus in the shallow lakes. It was estimated that there were 268.6 ton AAP in top 1 cm sediments in Lake Taihu. Sediment suspension caused by strong wind-induced wave disturbance could carry plenty of AAP into water in large shallow lakes like Lake Taihu. 相似文献
14.
Experimental study on phosphorus release from sediments of shallow lake in wave flume 总被引：2，自引：2，他引：2
Influence of wave on sediment resuspension and nutrients release from sediments, collected from Lake Taihu and Lake Chaohu, was studied in flume experiments. Under strong-wave conditions, concentrations of suspended solids (SS), total phosphorus (TP) and dissolved total phosphorus (DTP) in overlying water were increased significantly following the sediments re-suspension. During the experiments on sediments of Lake Taihu and Lake Chaohu, TP concentrations increased 6 times and 3 times, and DTP concentration increased 100% and 70% more than it in presuspension, respectively. Concentration of soluble reactive phosphorus (SRP) of experiment on sediment of Lake Taihu increased 25%. During the massive sediment suspension, the dissolved phosphorus in pore water and much of the phosphorus adsorbed by the sediment particles were released into overlying water. The phenomena in this wave flume experiment are quite similar to the situation observed in situ of Lake Taihu. The critical wave stresses of sediment re-suspension are nearly equal. The change of concentrations of SS, TP, and SRP was the same as that in situ situation. This study showed that concentrations of TP and SRP in lake water could be increased significantly by wave disturbance. Phosphorus release was significantly enhanced by wave disturbance at the beginning of massive sediment re-suspension, but decreased later. 相似文献
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疏浚对巢湖重污染入湖河流沉积物中污染物赋存及释放的影响 总被引：3，自引：1，他引：2
以巢湖重污染入湖河流双桥河为研究对象,研究了底泥疏浚对水质以及沉积物中总氮、总磷和有机质的短期影响及长期效应.结果表明,双桥河水质的季节变化显著,受上游城市污水及周边面源污染的影响,疏浚对水质改善作用不明显.表层沉积物中总氮、总磷及有机质含量在疏浚结束后1个月有所降低,但是2年后分别回复到疏浚前的189.77%、111.62%和152.87%.疏浚结束2年后,沉积物中磷主要以钙磷和有机磷的形式存在,铝磷和铁磷的含量较少,弱结合态磷的含量最低;但是表层沉积物中的弱结合态磷、铝磷和铁磷结合态磷含量较疏浚前分别升高了728.32%、13.52%和37.73%,并呈现出表层富集现象,存在较高的污染物释放风险.这可能是由沉积环境改变、外源污染未得到有效控制引起的.因此,为了维持疏浚的长期效果,应该对外源污染源进行有效控制. 相似文献
16.
Influence of wave on sediment resuspension and nutrients release from sediments, collected from Lake Taihu and Lake Chaohu, was studied in flume experiments. Under strong-wave conditions, concentrations of suspended solids (SS), total phosphorus (TP) and dissolved total phosphorus (DTP) in overlying water were increased significantly following the sediments re-suspension. During the experiments on sediments of Lake Taihu and Lake Chaohu, TP concentrations increased 6 times and 3 times, and DTP concentration increased 100% and 70% more than it in presuspension, respectively. Concentration of soluble reactive phosphorus (SRP) of experiment on sediment of Lake Taihu increased 25%. During the massive sediment suspension, the dissolved phosphorus in pore water and much of the phosphorus adsorbed by the sediment particles were released into overlying water. The phenomena in this wave flume experiment are quite similar to the situation observed in situ of Lake Taihu. The critical wave stresses of sediment re-suspension are nearly equal. The change of concentrations of SS, TP, and SRP was the same as that in situ situation. This study showed that concentrations of TP and SRP in lake water could be increased significantly by wave disturbance. Phosphorus release was significantly enhanced by wave disturbance at the beginning of massive sediment re-suspension, but decreased later. 相似文献