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1.
We have elaborated an evolutionary turbulent model of the subnebula of Saturn derived from that of Dubrulle (1993, Icarus106, 59-76) for the solar nebula, which is valid for a geometrically thin disk. We demonstrate that if carbon and nitrogen were in the form of CO and N2, respectively, in the early subnebula, these molecules were not subsequently converted into CH4 and NH3 during the evolution of the disk, contrary to the current scenario initially proposed by Prinn and Fegley (1981, Astrophys. J., 249, 308-317). However, if the early subnebula contained some CH4 and NH3, these gases were not subsequently converted into CO and N2. We argue that Titan must have been formed from planetesimals migrating from the outer part of the subnebula to the present orbit of the satellite. These planetesimals were relics of those embedded in the feeding zone of Saturn prior to the completion of the planet and contained hydrates of NH3 and clathrate hydrates of CH4. It is shown that, for plausible abundances of CH4 and NH3 in the solar nebula at 10 AU, the masses of methane and nitrogen trapped in Titan were higher than the estimate of masses of these components in the primitive atmosphere of the satellite. If our scenario is valid and if our turbulent model properly describes the structure and the evolution of the actual subnebula of Saturn, the Xe/C ratio should be six times higher in Titan's atmosphere today than in the Sun, while the current scenario would probably result in a quasi solar Xe/C ratio. The mass spectrometer and gas chromatograph instrument aboard the Huygens Titan probe of the Cassini mission has the capability of measuring this ratio in 2004, thus permitting us to discriminate between the current scenario and the one proposed in this report. 相似文献
2.
Fischer-Tropsch catalysis, which converts CO and H2 into CH4 on the surface of iron catalyst, has been proposed to produce the CH4 on Titan during its formation process in a circum-planetary subnebula. However, Fischer-Tropsch reaction rate under the conditions of subnebula have not been measured quantitatively yet. In this study, we conduct laboratory experiments to determine CH4 formation rate and also conduct theoretical calculation of clathrate formation to clarify the significance of Fischer-Tropsch catalysis in a subnebula. Our experimental result indicates that the range of conditions where Fischer-Tropsch catalysis proceeds efficiently is narrow (T∼500-600 K) in a subnebula because the catalysts are poisoned at temperatures above 600 K under the condition of subnebula (i.e., H2/CO = 1000). This suggests that an entire subnebula may not become rich in CH4 but rather that only limited region of a subnebula may enriched in CH4 (i.e., CH4-rich band formation). Our experimental result also suggests that both CO and CO2 are converted into CH4 within time significantly shorter than the lifetime of the solar nebula at the optimal temperatures around 550 K. The calculation result of clathration shows that CO2-rich satellitesimals are formed in the catalytically inactive outer region of subnebula. In the catalytically active inner region, CH4-rich satellitesimals are formed. The resulting CH4-rich satellitesimals formed in this region play an important role in the origin of CH4 on Titan. When our experimental data are applied to a high-pressure model for subnebula evolution, it would predict that there should be CO2 underneath the Iapetus subsurface and no thick CO2 ice layer on Titan's icy crust. Such surface and subsurface composition, which may be observed by Cassini-Huygens mission, would provide crucial information on the origin of icy satellites. 相似文献
3.
Previous modeling by Banaszkiewicz et al. (2000a,b) showed that the CH4 thermospheric mixing ratio on Titan could vary as much as 35-40% due to ion-neutral chemical reactions. A new vertical methane profile has been computed by simultaneously modifying the stratospheric methane mixing ratio and the K(z) previously considered by Lara et al. (1996) and Banaszkiewicz et al. (2000a,b). A satisfactory fit of the methane thermospheric abundance and stratospheric mixing ratio of other minor constituents is achieved by placing the homopause at ∼1000 km and increasing the methane stratospheric mixing ratio (qCH4) up to 3.8%. The new proposed eddy diffusion coefficient steadily rises from 1×107 cm2 s−1 at 700 km to 1×1010 cm2 s−1 at 1500 km, whereas the stratospheric values are in the range (4-20)×103 cm2 s−1. Other likely ionization sources that can influence the methane distribution are (i) a metallic ion layer produced by micrometeoroid infall and (ii) frequent X-rays solar flares. Analysis of the effects of these ionization sources on the methane distribution indicates that, unlike previously assumed, CH4 can suffer considerable variations. These variations, although proved in this work, must be cautiously regarded since several assumptions have to be made on the rate of N2 and CH4 ionization by the processes previously mentioned. Hence, these results are only indicative of methane sensitivity to ionospheric chemistry. 相似文献
4.
High spectral resolution observations from the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297] are analysed to derive new estimates for the mole fractions of CH4, CH3D and 13CH4 of (4.7±0.2)×10−3, (3.0±0.2)×10−7 and (5.1±0.2)×10−5 respectively. The mole fractions show no hemispherical asymmetries or latitudinal variability. The analysis combines data from the far-IR methane rotational lines and the mid-IR features of methane and its isotopologues, using both the correlated-k retrieval algorithm of Irwin et al. [Irwin, P., and 9 colleagues, 2008. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150] and a line-by-line approach to evaluate the reliability of the retrieved quantities. C/H was found to be enhanced by 10.9±0.5 times the solar composition of Grevesse et al. [Grevesse, N., Asplund, M., Sauval, A., 2007. Space Sci. Rev. 130 (1), 105-114], 2.25±0.55 times larger than the enrichment on Jupiter, and supporting the increasing fractional core mass with distance from the Sun predicted by the core accretion model of planetary formation. A comparison of the jovian and saturnian C/N, C/S and C/P ratios suggests different reservoirs of the trapped volatiles in a primordial solar nebula whose composition varies with distance from the Sun. This is supported by our derived D/H ratio in methane of (1.6±0.2)×10−5, which appears to be smaller than the jovian value of Lellouch et al. [Lellouch, E., Bézard, B., Fouchet, T., Feuchtgruber, H., Encrenaz, T., de Graauw, T., 2001. Astron. Astrophys. 370, 610-622]. Mid-IR emission features provided an estimate of , which is consistent with both the terrestrial ratio and jovian ratio, suggesting that carbon was accreted from a shared reservoir for all of the planets. 相似文献
5.
Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO2, CH4, NH3 and H2S may have been trapped as solids in the feeding zone of the planet. CH4 and H2S may have been in the form of clathrate hydrates while CO2 presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH3. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH4 clathrate and CO2 ice (and maybe as organics) while nitrogen was in the form of NH3 hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the 14N/15N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo. 相似文献
6.
Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH4 bands, the CH4 3ν3 band, and the (3-0) and (4-0) quadrupole bands of H2. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10?5 < D/H < 3.1 × 10?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive. 相似文献
7.
In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH4, NH3, and H2S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6RJ from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system. 相似文献
8.
Bruno Bézard Emmanuel LellouchDarrell Strobel Jean-Pierre Maillard Pierre Drossart 《Icarus》2002,159(1):95-111
Thirteen lines of the CO band near 4.7 μm have been observed on a jovian hot spot at a resolution of 0.045 cm−1. The measured line profiles indicate that the CO mole fraction is 1.0±0.2 ppb around the 6-bar level and is larger in the upper troposphere and/or stratosphere. An external source of CO providing an abundance of 4+3−2×1016 molecules cm−2 is implied by the observations in addition to the amount deposited at high altitude by the Shoemaker-Levy 9 collision. From a simple diffusion model, we estimate that the CO production rate is (1.5-10)×106 molecules cm−2 s−1 assuming an eddy diffusion coefficient around the tropopause between 300 and 1500 cm2 s−1. Precipitation of oxygen atoms from the jovian magnetosphere or photochemistry of water vapor from meteoroidal material can only provide a negligible contribution to this amount. A significant fraction of the CO in Jupiter's upper atmosphere may be formed by shock chemistry due to the infall of kilometer- to subkilometer-size Jupiter family comets. Using the impact rate from Levison et al. (2000, Icarus143, 415-420) rescaled by Bottke et al. (2002, Icarus156, 399-433), this source can provide the observed stratospheric CO only if the eddy diffusion coefficient around the tropopause is 100-300 cm2 s−1. Higher values, ∼700 cm2 s−1, would require an impact rate larger by a factor of 5-10, which cannot be excluded considering uncertainties in the distribution of Jupiter family comets. Such a large rate is indeed consistent with the observed cratering record of the Galilean satellites (Zahnle et al. 1998, Icarus136, 202-222). On the other hand, the ∼1 ppb concentration in the lower troposphere requires an internal source. Revisiting the disequilibrium chemistry of CO in Jupiter, we conclude that rapid vertical mixing can provide the required amount of CO at ∼6 bar for a global oxygen abundance of 0.2-9 times the solar value considering the uncertainties in the convective mixing rate and in the chemical constants. 相似文献
9.
We model the subnebulae of Jupiter and Saturn wherein satellite accretion took place. We expect each giant planet subnebula to be composed of an optically thick (given gaseous opacity) inner region inside of the planet’s centrifugal radius (where the specific angular momentum of the collapsing giant planet gaseous envelope achieves centrifugal balance, located at rCJ ∼ 15RJ for Jupiter and rCS ∼ 22RS for Saturn) and an optically thin, extended outer disk out to a fraction of the planet’s Roche-lobe (RH), which we choose to be ∼RH/5 (located at ∼150 RJ near the inner irregular satellites for Jupiter, and ∼200RS near Phoebe for Saturn). This places Titan and Ganymede in the inner disk, Callisto and Iapetus in the outer disk, and Hyperion in the transition region. The inner disk is the leftover of the gas accreted by the protoplanet. The outer disk may result from the nebula gas flowing into the protoplanet during the time of giant planet gap-opening (or cessation of gas accretion). For the sake of specificity, we use a solar composition “minimum mass” model to constrain the gas densities of the inner and outer disks of Jupiter and Saturn (and also Uranus). Our model has Ganymede at a subnebula temperature of ∼250 K and Titan at ∼100 K. The outer disks of Jupiter and Saturn have constant temperatures of 130 and 90 K, respectively.Our model has Callisto forming in a time scale ∼106 years, Iapetus in 106-107 years, Ganymede in 103-104 years, and Titan in 104-105 years. Callisto takes much longer to form than Ganymede because it draws materials from the extended, low density portion of the disk; its accretion time scale is set by the inward drift times of satellitesimals with sizes 300-500 km from distances ∼100RJ. This accretion history may be consistent with a partially differentiated Callisto with a ∼300-km clean ice outer shell overlying a mixed ice and rock-metal interior as suggested by Anderson et al. (2001), which may explain the Ganymede-Callisto dichotomy without resorting to fine-tuning poorly known model parameters. It is also possible that particulate matter coupled to the high specific angular momentum gas flowing through the gap after giant planet gap-opening, capture of heliocentric planetesimals by the extended gas disk, or ablation of planetesimals passing through the disk contributes to the solid content of the disk and lengthens the time scale for Callisto’s formation. Furthermore, this model has Hyperion forming just outside Saturn’s centrifugal radius, captured into resonance by proto-Titan in the presence of a strong gas density gradient as proposed by Lee and Peale (2000). While Titan may have taken significantly longer to form than Ganymede, it still formed fast enough that we would expect it to be fully differentiated. In this sense, it is more like Ganymede than like Callisto (Saturn’s analog of Callisto, we expect, is Iapetus). An alternative starved disk model whose satellite accretion time scale for all the regular satellites is set by the feeding of planetesimals or gas from the planet’s Roche-lobe after gap-opening is likely to imply a long accretion time scale for Titan with small quantities of NH3 present, leading to a partially differentiated (Callisto-like) Titan. The Cassini mission may resolve this issue conclusively. We briefly discuss the retention of elements more volatile than H2O as well as other issues that may help to test our model. 相似文献
10.
We propose an interpretation of the composition of volatiles observed in comets based on their trapping in the form of clathrate hydrates in the solar nebula. The formation of clathrates is calculated from the statistical thermodynamics of Lunine and Stevenson (1985, Astrophys. J. Suppl. 58, 493-531), and occurs in an evolutionary turbulent solar nebula described by the model of Hersant et al. (2001, Astrophys. J. 554, 391-407). It is assumed that clathrate hydrates were incorporated into the icy grains that formed cometesimals. The strong depletion of the N2 molecule with respect to CO observed in some comets is explained by the fact that CO forms clathrate hydrates much more easily than does N2. The efficiency of this depletion, as well as the amount of trapped CO, depends upon the amount of water ice available in the region where the clathration took place. This might explain the diversity of CO abundances observed in comets. The same theory, applied to the trapping of volatiles around 5 AU, explains the enrichments in Ar, Kr, Xe, C, and N with respect to the solar abundance measured in the deep troposphere of Jupiter
[Gautier et al 2001a] and [Gautier et al 2001b]. 相似文献
11.
Updated Galileo probe mass spectrometer measurements of carbon, oxygen, nitrogen, and sulfur on Jupiter 总被引：1，自引：0，他引：1
The in situ measurements of the Galileo Probe Mass Spectrometer (GPMS) were expected to constrain the abundances of the cloud-forming condensible volatile gases: H2O, H2S, and NH3. However, since the probe entry site (PES) was an unusually dry meteorological system—a 5-μm hotspot—the measured condensible volatile abundances did not follow the canonical condensation-limited vertical profiles of equilibrium cloud condensation models (ECCMs) such as Weidenschilling and Lewis (1973, Icarus 20, 465-476). Instead, the mixing ratios of H2S and NH3 increased with depth, finally reaching well-mixed equilibration levels at pressures far greater than the lifting condensation levels, whereas the mixing ratio of H2O in the deep well-mixed atmosphere could not be measured. The deep NH3 mixing ratio (with respect to H2) of (6.64±2.54)×10−4 from 8.9-11.7 bar GPMS data is consistent with the NH3 profile from probe-to-orbiter signal attenuation (Folkner et al., 1998, J. Geophys. Res. 103, 22847-22856), which had an equilibration level of about 8 bar. The GPMS deep atmosphere H2S mixing ratio of (8.9±2.1)×10−5 is the only measurement of Jupiter's sulfur abundance, with a PES equilibration level somewhere between 12 and 15.5 bar. The deepest water mixing ratio measurement is (4.9±1.6)×10−4 (corresponding to only about 30% of the solar abundance) at 17.6-20.9 bar, a value that is probably much smaller than Jupiter's bulk water abundance. The 15N/14N ratio in jovian NH3 was measured at (2.3±0.3)×10−3 and may provide the best estimate of the protosolar nitrogen isotopic ratio. The GPMS methane mixing ratio is (2.37±0.57)×10−3; although methane does not condense on Jupiter, we include its updated analysis in this report because like the condensible volatiles, it was presumably brought to Jupiter in icy planetesimals. Our detailed discussion of calibration and error analysis supplements previously reported GPMS measurements of condensible volatile mixing ratios (Niemann et al., 1998, J. Geophys. Res. 103, 22831-22846; Atreya et al., 1999, Planet. Space Sci. 47, 1243-1262; Atreya et al., 2003, Planet. Space Sci. 51, 105-112) and the nitrogen isotopic ratio (Owen et al., 2001b, Astrophys. J. Lett. 553, L77-L79). The approximately three times solar abundance of NH3 (along with CH4 and H2S) is consistent with enrichment of Jupiter's atmosphere by icy planetesimals formed at temperatures <40 K (Owen et al., 1999, Nature 402 (6759), 269-270), but would imply that H2O should be at least 3×solar as well. An alternate model, using clathrate hydrates to deliver the nitrogen component to Jupiter, predicts O/H?9×solar (Gautier et al., 2001, Astrophys. J. 550 (2), L227-L230). Finally we show that the measured condensible volatile vertical profiles in the PES are consistent with column-stretching or entraining downdraft scenarios only if the basic state (the pre-stretched column or the entrainment source region) is described by condensible volatile vertical profiles that are drier than those in the equilibrium cloud condensation models. This dryness is supported by numerous remote sensing results but seems to disagree with observations of widespread clouds on Jupiter at pressure levels predicted by equilibrium cloud condensation models for ammonia and H2S. 相似文献
12.
We have analyzed Titan observations performed by the Infrared Space Observatory (ISO) in the range 7-30 μm. The spectra obtained by three of the instruments on board the mission (the short wavelength spectrometer, the photometer, and the camera) were combined to provide new and more precise thermal and compositional knowledge of Titan’s stratosphere. With the high spectral resolution achieved by the SWS (much higher than that of the Voyager 1 IRIS spectrometer), we were able to detect and separate the contributions of most of the atmospheric gases present on Titan and to determine disk-averaged mole fractions. We have also tested existing vertical distributions for C2H2, HCN, C2H6, and CO2 and inferred some information on the abundance of the first species as a function of altitude. From the CH3D band at 1161 cm−1 and for a CH4 mole fraction assumed to be 1.9% in Titan’s stratosphere, we have obtained the monodeuterated methane-averaged abundance and retrieved a D/H isotopic ratio of 8.7−1.9+3.2 × 10−5. We discuss the implications of this value with respect to current evolutionary scenarios for Titan. The ν5 band of HC3N at 663 cm−1 was observed for the first time in a disk-averaged spectrum. We have also obtained a first tentative detection of benzene at 674 cm−1, where the fit of the ISO/SWS spectrum at R = 1980 is significantly improved when a constant mean mole fraction of 4 × 10−10 of C6H6 is incorporated into the atmospheric model. This corresponds to a column density of ∼ 2 × 1015 molecules cm−2 above the 30-mbar level. We have also tested available vertical profiles for HC3N and C6H6 and adjusted them to fit the data. Finally, we have inferred upper limits of a few 10−10 for a number of molecules proposed as likely candidates on Titan (such as allene, acetonitrile, propionitrile, and other more complex gases). 相似文献
13.
The photochemical flow reactor (D.W. Clarke et al., 2000, Icarus 147, 282-291) has been modified to minimize the incorporation of oxygen and other impurities in the photoproducts. A mixture of gases that approximate their mixing ratios on Titan (N2, CH4, H2, C2H2, C2H4, and HC3N) (0.98, 0.018, 0.002, 3.5 × 10−4, 3 × 10−4, 1.7 × 10−5, respectively) was irradiated in the flow photochemical reactor using a 185-nm source to give a Titan haze analog as a solid product. X-ray photoelectron spectroscopy (XPS) gave a composition of 93.3% C, 5.3% N, and 1.4% O. Of the 93.3% carbon, high-resolution XPS revealed that 81.2% was present as CH, CC, and CC groups, 12.1% may be CO, CN, CN, CN, and/or CN groups, 5.3% as a CN group. The peak for N was symmetrical and was assigned to the CN while that for oxygen was assigned to the CO and/or the CO group. Some of these assignments were confirmed by FTIR spectroscopy. The polymeric product had a C:N ratio of 17.6, which is significantly greater than that for Titan haze analogs prepared in discharge reactions. When the polymer was exposed to air for seven days the oxygen content increased by 6% along with an increase in the infrared absorption at 1710 cm−1 assigned to the CO group of a ketone. The oxidation is attributed to the reaction of oxygen with free radicals trapped in the polymer matrix. It is proposed that the photochemical initiation of Titan haze formation from compounds formed from starting materials formed high in Titan’s atmosphere is a more plausible model than haze formed in reactions initiated by solely by discharges. These data will be helpful in the interpretation of the data returned from the Huygens probe of the Cassini mission. 相似文献
14.
Using spectra taken with NIRSPEC (Near Infrared Spectrometer) and adaptive optics on the Keck II telescope, we resolved the latitudinal variation of the 3ν2 band of CH3D at 1.56 μm. As CH3D is less abundant than CH4 by a factor of 50±10×10-5, these CH3D lines do not saturate in Titan’s atmosphere, and are well characterized by laboratory measurements. Thus they do not suffer from the large uncertainties of the CH4 lines that are weak enough to be unsaturated in Titan. Our measurements of the methane abundance are confined to the latitude range of 32°S-18°N and longitudes sampled by a 0.04″ slit centered at ∼195°W. The methane abundance below 10 km is constant to within 20% in the tropical atmosphere sampled by our observations, consistent with the low surface insolation and lack of surface methane [Griffith, C.A., McKay, C.P., Ferri, F., 2008. Astrophys. J. 687, L41-L44]. 相似文献
15.
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10−4, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν5 + 3ν6 and 2ν3 + 2ν6 bands of CH3D. 相似文献
16.
Yasuhito Sekine Hiroshi Imanaka Takafumi Matsui Emma L.O. Bakes Christopher P. McKay 《Icarus》2008,194(1):186-200
In Titan's atmosphere consisting of N2 and CH4, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N2 and CH4 gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×10−3×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry. 相似文献
17.
Ever since their discovery the regular satellites of Jupiter and Saturn have held out the promise of providing an independent set of observations with which to test theories of planet formation. Yet elucidating their origins has proven elusive. Here we show that Iapetus can serve to discriminate between satellite formation models. Its accretion history can be understood in terms of a two-component gaseous subnebula, with a relatively dense inner region, and an extended tail out to the location of the irregular satellites, as in the SEMM model of Mosqueira and Estrada (2003a,b) (Mosqueira, I., Estrada, P.R. [2003a]. Icarus 163, 198-231; Mosqueira, I., Estrada, P.R. [2003b]. Icarus 163, 232-255). Following giant planet formation, planetesimals in the feeding zone of Jupiter and Saturn become dynamically excited, and undergo a collisional cascade. Ablation and capture of planetesimal fragments crossing the gaseous circumplanetary disks delivers enough collisional rubble to account for the mass budgets of the regular satellites of Jupiter and Saturn. This process can result in rock/ice fractionation as long as the make up of the population of disk crossers is non-homogeneous, thus offering a natural explanation for the marked compositional differences between outer solar nebula objects and those that accreted in the subnebulae of the giant planets. For a given size, icy objects are easier to capture and to ablate, likely resulting in an overall enrichment of ice in the subnebula. Furthermore, capture and ablation of rocky fragments become inefficient far from the planet for two reasons: the gas surface density of the subnebula is taken to drop outside the centrifugal radius, and the velocity of interlopers decreases with distance from the planet. Thus, rocky objects crossing the outer disks of Jupiter and Saturn never reach a temperature high enough to ablate either due to melting or vaporization, and capture is also greatly diminished there. In contrast, icy objects crossing the outer disks of each planet ablate due to the melting and vaporization of water-ice. Consequently, our model leads to an enhancement of the ice content of Iapetus, and to a lesser degree those of Titan, Callisto and Ganymede, and accounts for the (non-stochastic) compositions of these large, low-porosity outer regular satellites of Jupiter and Saturn. For this to work, the primordial population of planetesimals in the Jupiter-Saturn region must be partially differentiated, so that the ensuing collisional cascade produces an icy population of ?1 m size fragments to be ablated during subnebula crossing. We argue this is likely because the first generation of solar nebula ∼10 km planetesimals in the Jupiter-Saturn region incorporated significant quantities of 26Al. This is the first study successfully to provide a direct connection between nebula planetesimals and subnebulae mixtures with quantifiable and observable consequences for the bulk properties of the regular satellites of Jupiter and Saturn, and the only explanation presently available for Iapetus’ low density and ice-rich composition. 相似文献
18.
The 8.6-μm emission feature of Titan's infrared spectrum was analyzed using the Voyager temperature-pressure profile. Although both C3H8 and CH3D have bands at that wavelength, we show that CH3D dominates the observed emission on Titan. We derived a CH3D/CH4 mixing ratio using this band and the strong CH4 band at 7.7 μm. The corresponding D/H ratio is 4.2?1.5+2 × 10?4, neglecting deuterium fractionation with other molecules. The main uncertainty in this value comes from the continuum emission characteristics. The D/H ratio is apparently significantly enhanced on Titan with respect to published values for Saturn. 相似文献
19.
Evidence for a marginal detection of the Titan ionosphere has been obtained from a new analysis of the dual-frequency Doppler data recorded during theVoyager 1occultation in 1980. The original report by Lindalet al.(1983,Icarus53,348–363) gave only upper bounds on the peak electron density of 3000 cm−3during ingress (evening terminator) and 5000 cm−3during egress (morning terminator). The dual-frequency ingress data imply a maximum electron density of 2400 ± 1100 cm−3for Titan's upper ionosphere at an altitude of 1180 ± 150 km. The egress data were determined to be of limited use for this analysis because the X-band signal was received for only a few seconds. Nevertheless, a distinct ionospheric peak is revealed in the S-band data for both ingress and egress. The height and peak density of this ionized layer are in good agreement with expectations from numerical models that invoke photoionization and energetic electron impacts. 相似文献
20.
Fifteen organic and three inorganic compounds were tested for methane (CH4) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m−2; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO3, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH4 g−1 h−1, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH4 cm−2 h−1. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH4 cm−2 h−1 (16.5 nmol m−2 h−1) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m2) is likely to create a significant source of terrestrial methane contamination during the early part of the mission. 相似文献