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1.
A so-called megaregolith layer that is considered to be produced by continuous impacts in Mercury's early stages is integrated into the thermal evolution models...  相似文献   

2.
Because of their short cosmic ray exposure ages, chondritic meteorites are more likely to have been broken off from parent bodies in Earth-crossing orbits than from parent bodies in the asteroid belt. The radii of the objects now in the vicinity of the Earth (Apollo and Amor objects) are too small to be unfragmented asteroids of the theory for the origin of gas-rich meteorites of Anders. Because of the abundant evidence for very heavy shock and reheating among L- and H-chondrites, I conclude that the asteroidal origin for the ordinary chondrites is still the most likely. A cometary origin for the CI chondrites is examined. Regolith and megaregolith do not necessarily have to be formed by impacts on the cometary nucleus. The short-period comet Encke receives about 1/10 the solar-wind flux of a belt asteroid at 2.5 AU in its present orbit. The thickness of the megaregolith (C1 chondrites) is estimated between 0.1 and 0.3 km. Stirring of the megaregolith without substantial loss of dust from the comet might occur when the comet is transitional between “active” and “dead.” The consolidation of C1- “dust” into rock is somewhat problematic, but if liquid water and water vapor have played a role, then a crust rich in solar gases might form in the outer regions of a comet. A testable alternative explanation is suggested, namely that the solar gases in the C1 chondrites do not come from the Sun.  相似文献   

3.
We model the cratering of the Moon and terrestrial planets from the present knowledge of the orbital and size distribution of asteroids and comets in the inner Solar System, in order to refine the crater chronology method. Impact occurrences, locations, velocities and incidence angles are calculated semi-analytically, and scaling laws are used to convert impactor sizes into crater sizes. Our approach is generalizable to other moons or planets. The lunar cratering rate varies with both latitude and longitude: with respect to the global average, it is about 25% lower at (±65°N, 90°E) and larger by the same amount at the apex of motion (0°N, 90°W) for the present Earth-Moon separation. The measured size-frequency distributions of lunar craters are reconciled with the observed population of near-Earth objects under the assumption that craters smaller than a few kilometers in diameter form in a porous megaregolith. Varying depths of this megaregolith between the mare and highlands is a plausible partial explanation for differences in previously reported measured size-frequency distributions. We give a revised analytical relationship between the number of craters and the age of a lunar surface. For the inner planets, expected size-frequency crater distributions are calculated that account for differences in impact conditions, and the age of a few key geologic units is given. We estimate the Orientale and Caloris basins to be 3.73 Ga old, and the surface of Venus to be 240 Ma old. The terrestrial cratering record is consistent with the revised chronology and a constant impact rate over the last 400 Ma. Better knowledge of the orbital dynamics, crater scaling laws and megaregolith properties are needed to confidently assess the net uncertainty of the model ages that result from the combination of numerous steps, from the observation of asteroids to the formation of craters. Our model may be inaccurate for periods prior to 3.5 Ga because of a different impactor population, or for craters smaller than a few kilometers on Mars and Mercury, due to the presence of subsurface ice and to the abundance of large secondaries, respectively. Standard parameter values allow for the first time to naturally reproduce both the size distribution and absolute number of lunar craters up to 3.5 Ga ago, and give self-consistent estimates of the planetary cratering rates relative to the Moon.  相似文献   

4.
Abstract— The hypothesis of a lunar cataclysmic cratering episode between 3.8 and 3.9 Gyr ago lacks proof. Its strongest form proposes no cratering before about 4.0 Gyr, followed by catastrophic formation of most lunar craters and basins in >200 Myr. The premise that “zero impact melts implies zero impacts” is disproved by data from asteroids, on which early collisions clearly occurred, but from which early impact melts are scarce. Plausible cataclysm models imply that any cataclysm should have affected the whole inner solar system, but among available lunar and asteroid impact melt and impact age resetting data, a narrow, strong 3.8–3.9 Gyr spike in ages is seen only in the region sampled by Apollo/Luna. Reported lunar meteorite data do not show the spike. Asteroid data show a broader, milder peak, spreading from about 4.2 to 3.5 Gyr. These data suggest either that the spike in Apollo impact melt ages is associated with unique lunar front side events, or that the lunar meteorites data represent different kinds of events than the Apollo/Luna data. Here, we develop an alternate “megaregolith evolution” hypothesis to explain these data. In this hypothesis, early impact melts are absent not because there were no impacts, but because the high rate of early impacts led to their pulverization. The model estimates survival halflives of most lunar impact melts prior to 4.1 Gyr at >100 Myr. After a certain time, Tcritical ?4.0 Gyr, impact melts began to survive to the present. The age distribution differences among impact melts and plutonic rocks are controlled by, and hold clues to, the history of regolith evolution and the relative depths of sequestration of impact melts versus plutonic rocks, both among lunar and asteroidal samples. Both the “zero cratering, then cataclysm” hypothesis and the “megaregolith evolution” hypothesis require further testing, especially with lunar meteorite impact melt studies.  相似文献   

5.
Radar, infrared, and photogeologic properties of lunar craters have been studied to determine whether there is a systematic difference in blocky craters between the maria and terrae and whether this difference may be due to a deep megaregolith of pulverized material forming the terra surface, as opposed to a layer of semi-coherent basalt flows forming the mare surface. Some 1310 craters from about 4 to 100 km diameter have been catalogued as radar and/or infrared anomalies. In addition, a study of Apollo Orbital Photography confirmed that the radar and infrared anomalies are correlated with blocky rubble around the crater.Analysis of the radar and infrared data indicated systematic terra—mare differences. Fresh terra craters smaller than 12 km were less likely to be infrared and radar anomalies than comparable mare craters: but terra and mare craters larger than 12 km had similar infrared and radar signatures. Also, there are many terra craters which are radar bright but not infrared anomalies.Our interpretation of these data is that while the maria are rock layers (basaltic flow units) where craters eject boulder fields, the terrae are covered by relatively pulverized megaregolith at least 2 km deep, where craters eject less rocky rubble. Blocky rubble, either in the form of actual rocks or partly consolidated blocks, contributes to the radar and infrared signatures of the crater. However, aging by impacts rapidly destroys these effects, possibly through burial by secondary debris or by disintegration of the blocks themselves, especially in terra regions.PSI Contribution No. 110.  相似文献   

6.
This work identifies and describes features of the changing seasonal frost-covered surface of Mars based on HiRISE images, and analyses the possibility that ephemeral liquid brine formation produces them. Because some of these dark features show flow-like appearance, and salts on Mars are present, liquid brines might be also present, possibly accounting for the changing droplet-like features on the Phoenix lander.We observed in-situ darkening and movement of dark features (or movement of the darkening front) on seasonal frost-covered polar dunes. Darkening and brightening may happen within several meters from each other during local spring. Darkening always starts from the bottom and moves up, while brightening progresses from top and moves toward the bottom between the small dune ripples. Brightening occurs during the springtime warming on time scales of several days close to the sites of darkening; therefore, dark material falling from the air, and refreezing of bright ice on it, does not adequately explain the observations. Interpreting the observations as brine-related melting or refreezing also poses problems, but because brine may engulf salt grains or ice blocks, phase changes here could be influenced by factors other than temperature values, and could produce the observations.Analysis of absolute albedo changes indicates that the flow-like features are the darkest at their lower frontal end, sometimes darker than the dark spot from which they originate. A bright halo (white collar) also forms around these spots, possibly due to refreezing. Inside the observed larger spots an outer gray area surrounds the central darkest cores, which is about 10 cm lower than the surrounding bright CO2 ice. At those places, most or all of the CO2 ice deposited earlier has disappeared, and H2O ice is present. Observations of dark flow features moving on the top of this H2O rich layer suggest even if the flow features start as dry dune avalanches of rolling grains, their dark material heated by solar insolation is in contact with H2O ice and may produce brines.  相似文献   

7.
Megaregolith accumulation can have important thermal consequences for bodies that lose heat by conduction, as vacuous porosity of the kind observed in the lunar megaregolith lowers thermal conductivity by a factor of 10. I have modeled global average ejecta accumulation as a function of the largest impact size, with no explicit modeling of time. In conjunction with an assumed cratering size‐distribution exponent b, the largest crater constrains the sizes of all other craters that significantly contribute to a megaregolith. The largest impactor mass ratio is a major fraction of the catastrophic‐disruption mass ratio, and in general the largest crater’s diameter is close to the target’s diameter. Total accumulation is roughly 1–5% of (and proportional to) the target’s radius. Global accumulations estimated by this approach are higher than in the classic Housen et al. (1979) study by a factor of roughly 10. This revision is caused mainly by higher (typical) largest crater size. For b ～ 2, the single largest crater typically contributes close to 50% of the total of new (nonrecycled) ejecta. Megaregolith can be destroyed by sintering, a process whose pressure sensitivity makes it effective at lower temperature on larger bodies. Planetesimals ～100 km in diameter may be surprisingly well suited (about as well suited as bodies two to three times larger in diameter) for attaining temperatures conducive to widespread melting. A water‐rich composition may be a significant disadvantage in terms of planetesimal heating, as the shallow interior may be densified by aqueous metamorphism, and will have a low sintering temperature.  相似文献   

8.
Impact crater Dantu not only exhibits a very complex geological history but also shows an exceptional heterogeneity of its surface composition. Because of its location within a low‐lying region named Vendimia Planitia, which has been proposed to represent an ancient impact basin, Dantu possibly offers a window into the composition of Ceres’s deeper crust, which apparently is enriched in ammonia. Local concentration of carbonates within Dantu or its ejecta blanket may be either exposed or their emplacement induced by the Dantu impact event. Because carbonates can be seen along Dantu's crater walls, exposed due to recent slumping, but also as fresh spots or clusters of spots scattered across the surface, the deposition/formation of carbonates took place over a long time period. The association of several bright spots enriched in carbonates with sets of fractures on Dantu's floor might be accidental. Nevertheless, its morphological and compositional similarity to the faculae in Ceres’s prominent impact crater Occator including its hydrated state does not exclude a cryo‐volcanic origin, i.e., upwelling of carbonate‐enriched brines influenced by H2O ice in the subsurface. Indeed, an isolated H2O ice spot can be identified near Dantu, which shows that ice still exists in Ceres’s subsurface at midlatitudes and that it can exist on the surface for a longer period of time.  相似文献   

9.
Mare ridges of the Hesperia Planum area form linear, reticular and circular structures. The main factors effective in mare ridge formation have been (i) a large areal, or maybe even global, shortening and compression, (ii) major crustal tectonics, and (iii) the moderation of tectonic movements by the megaregolith discontinuity layer(s) between surface lavas and the bedrock leaving the compressional thrust to dominate over other fault movements in surface tectonics.  相似文献   

10.
A single fragment from an Apollo 16 soil appears to be a soil agglutinate that has experienced thermal metamorphism. Its texture is similar to that observed in many of the samples of recrystallized polymict breccias collected in the lunar highlands. Debris blankets, consisting largely of mineral and lithic clasts and derived from highland bedrock by major impacts, are less likely than agglutinate-rich soil from the highland megaregolith to be the progenitor of this class of recrystallized rocks.  相似文献   

11.
Abstract— Characteristics of the regolith of Cayley plains as sampled at the Apollo 16 lunar landing site are reviewed and new compositional data are presented for samples of <1 mm fines (“soils”) and 1–2 mm regolith particles. As a means of determining which of the many primary (igneous) and secondary (crystalline breccias) lithologic components that have been identified in the soil are volumetrically important and providing an estimate of their relative abundances, more than 3 × 106 combinations of components representing nearly every lithology that has been observed in the Apollo 16 regolith were systematically tested to determine which combinations best account for the composition of the soils. Conclusions drawn from the modeling include the following. At the site, mature soil from the Cayley plains consists of 64.5% ± 2.7% components representing “prebasin” materials: anorthosites, feldspathic breccias, and a small amount (2.6% ± 1.5% of total soil) of nonmare, mafic plutonic rocks, mostly gabbronorites. On average, these components are highly feldspathic, with average concentrations of 31–32% Al2O3 and 2–3% FeO and a molar Mg/(Mg + Fe) ratio of 0.68. The remaining 36% of the regolith is syn- and postbasin material: 28.8% ± 2.4% mafic impact-melt breccias (MIMBs, i.e., “LKFM” and “VHA basalts”) created at the time of basin formation, 6.0% ± 1.4% mare-derived material (impact and volcanic glass, crystalline basalt) with an average TiO2 concentration of 2.4%, and 1% postbasin meteoritic material. The MIMBs are the principal (80–90%) carrier of incompatible trace elements (rare earths, Th, etc.) and the carrier of about one-half of the siderophile elements and elements associated with mafic mineral phases (Fe, Mg, Mn, Cr, Sc). Most (71%) of the Fe in the present regolith derives from syn- and postbasin sources (MIMBs, mare-derived material, and meteorites). Thus, although the bulk composition of the Apollo 16 regolith is nominally that of noritic anorthosite, the noritic part (the MIMBs) and the anorthositic part (the prebasin components) are largely unrelated. There is compositional evidence that 3–4% of the soil is Th-rich material such as that occurring at the Apollo 14 site, and one fragment of this type was found among the small regolith particles studied here. If regolith such as that represented by the Apollo 16 ancient regolith breccias was a protolith of the present regolith, such regolith cannot exceed ～71% of the present regolith; the rest must be material added or redistributed since closure of the ancient regolith breccias. The postclosure material includes the mare-derived material and the Apollo-14-like component. Compositions of all mature surface soils from Apollo 16, even those collected 4 km apart on the Cayley plains, are very similar, which is in stark contrast to the wide compositional range of the lithologies of which the soil is composed. This uniformity indicates that the ratio of MIMBs to feldspathic prebasin components is not highly variable in the megaregolith over distances of a few kilometers, that there are no large, subsurface concentrations of “pure” mafic impact-melt breccia, and that the intimate mixing is inherent to the Cayley plains at a gross scale. Thus, the mixing of mafic impact-melt breccias and feldspathic prebasin components must have occurred during formation and deposition of the Cayley plains; such uniformity could not have been achieved by small postdeposition impacts into a stratified megaregolith. Using this conclusion as one constraint, and the known distribution of Th on the lunar surface as another, and the assumption that the Imbrium impact is primarily responsible for formation of the Cayley plains, arguments are presented that the Apollo 16 MIMBs derive from the Imbrium region, and, consequently, that one-fourth of the Apollo 16 regolith is primary Imbrium ejecta in the form of mafic impact-melt breccias.  相似文献   

12.
We report on laboratory experiments in which we allowed an SNC-derived mineral mix to react with pure water under a simulated Mars atmosphere for 7 months. These experiments were performed at one bar and at three different temperatures in order to simulate the subsurface conditions that most likely exist where liquid water and rock interact on Mars today. The dominant cations dissolved in the solutions we produced, which may be characterized as dilute brines, are Ca2+, Mg2+, Al3+, and Na+, while the major anions are dissolved C, F−, SO2−4 and Cl−. Typical solution pH was in the range of 4.2-6.0. Abundance patterns of elements in our synthetic sulfate-chloride brines are distinctly unlike those of terrestrial ocean water or continental waters, however, they are quite similar to those measured in the martian fines at the Mars Pathfinder and Viking 1 and 2 Landing sites. This suggests that salts present in the martian regolith may have formed over time as a result of the interaction of surface or subsurface liquid water with basalts in the presence of a martian atmosphere similar in composition to that of today. If most of the mobile surface layer was formed during the Noachian when erosion rates were much higher than at present, and if this layer is homogeneous in salt composition, the total amount of salt in the martian fines is approximately the same as in the Earth's oceans. The minimum quantity of circulating water necessary to deposit this amount of salt is approximately equivalent to a global layer 625 m deep.  相似文献   

13.
It is shown that viscous liquid film flow (VLF-flow) on the surfaces of slopes of martian dunes can be a low-temperature rheological phenomenon active today on high latitudes. A quantitative model indicates that the VLF-flows are consistent with the flow of liquid brines similar to that observed by imaging at the Phoenix landing site. VLF-flows depend on the viscosity, dynamics, and energetics of temporary darkened liquid brines. The darkening of the flowing brine is possibly, at least partially, attributed to non-volatile ingredients of the liquid brines. Evidence of previous VLF-flows can also be seen on the dunes, suggesting that it is an ongoing process that also occurred in the recent past.  相似文献   

14.
Abstract— The lunar surface is marked by at least 43 large and ancient impact basins, each of which ejected a large amount of material that modified the areas surrounding each basin. We present an analysis of the effects of basin formation on the entire lunar surface using a previously defined basin ejecta model. Our modeling includes several simplifying assumptions in order to quantify two aspects of basin formation across the entire lunar surface: 1) the cumulative amount of material distributed across the surface, and 2) the depth to which that basin material created a well‐mixed megaregolith. We find that the asymmetric distribution of large basins across the Moon creates a considerable nearside‐farside dichotomy in both the cumulative amount of basin ejecta and the depth of the megaregolith. Basins significantly modified a large portion of the nearside while the farside experienced relatively small degrees of basin modification following the formation of the large South Pole‐Aitken basin. The regions of the Moon with differing degrees of modification by basins correspond to regions thought to contain geochemical signatures remnant of early lunar crustal processes, indicating that the degree of basin modification of the surface directly influenced the distribution of the geochemical terranes observed today. Additionally, the modification of the lunar surface by basins suggests that the provenance of lunar highland samples currently in research collections is not representative of the entire lunar crust. Identifying locations on the lunar surface with unique modification histories will aid in selecting locations for future sample collection.  相似文献   

15.
Abstract— Carbonates in Martian meteorite Allan Hills 84001 occur as grains on pyroxene grain boundaries, in crushed zones, and as disks, veins, and irregularly shaped grains in healed pyroxene fractures. Some carbonate disks have tapered Mg-rich edges and are accompanied by smaller, thinner and relatively homogeneous, magnesite microdisks. Except for the microdisks, all types of carbonate grains show the same unique chemical zoning pattern on MgCO3-FeCO3-CaCO3 plots. This chemical characteristic and the close spatial association of diverse carbonate types show that all carbonates formed by a similar process. The heterogeneous distribution of carbonates in fractures, tapered shapes of some disks, and the localized occurrence of Mg-rich microdisks appear to be incompatible with growth from an externally derived CO2-rich fluid that changed in composition over time. These features suggest instead that the fractures were closed as carbonates grew from an internally derived fluid and that the microdisks formed from a residual Mg-rich fluid that was squeezed along fractures. Carbonate in pyroxene fractures is most abundant near grains of plagioclase glass that are located on pyroxene grain boundaries and commonly contain major or minor amounts of carbonate. We infer that carbonates in fractures formed from grain boundary carbonates associated with plagioclase that were melted by impact and dispersed into the surrounding fractured pyroxene. Carbonates in fractures, which include those studied by McKay et al. (1996), could not have formed at low temperatures and preserved mineralogical evidence for Martian organisms.  相似文献   

16.
The presence of sulfate salts and limited subsurface water (ice) on Mars suggests that any liquid water on Mars today will occur as (magnesium) sulfate-rich brines in regions containing sources of magnesium and sulfur. The Basque Lakes of British Columbia, Canada, represent a hypersaline terrestrial analogue site, which possesses chemical and physical properties similar to those observed on Mars. The Basque Lakes also contain diverse halophilic organisms representing all three Kingdoms of life, growing in surface and near-subsurface environments. Of interest from an astrobiological perspective, crushed magnesium sulfate samples that were analyzed using a modified Lowry protein assay contained biomass in every crystal inspected, with biomass values from 0.078 to 4.21 mgbiomass/gsalt; average=0.74±0.7 mgbiomass/gsalt. Bacteria and Archaea cells were easily observed even in low-biomass samples using light microscopy, and bacteria trapped within magnesium sulfate crystals were observed using confocal microscopy. Regions within the salt also contained bacterial pigments, e.g., carotenoids, which were separate from the cells, indicating that cell lysis might have occurred during entrapment within the salt matrix. These biosignatures, cells, and any ‘soluble’ organic constituents were primarily found trapped within fluid inclusions or fluid-filled void spaces between intergrown crystals. Diffuse reflectance infrared Fourier transform spectroscopy (reflectance IR) analysis of enrichment cultures, containing cyanobacteria, Archaea, or dissimilatory sulfate-reducing bacteria, highlighted molecular biosignature features between 550-1650 and 2400-3000 cm−1. Spectra from natural salts demonstrated that we can detect biomass within salt crystals using the most sensitive biosignatures, which are the 1530-1570 cm−1, C-N, N-H, -COOH absorptions and the 1030-1050 cm−1 C-OH, C-N, PO43− bond features. The lowest detection limit for a biosignature absorption feature using reflectance IR was with a natural sample that possessed 0.78 mgbiomass/gsalt. In a model cell, i.e., a 0.5 by 1 μm bacillus, this biomass value corresponds to approximately 7.8×108 cells/gsalt. Based on its ability to detect biomass entrapped within natural sulfate salts, reflectance IR may make an effective remote-sensing tool for finding enrichments of organic carbon within outcrops and surficial sedimentary deposits on Mars.  相似文献   

17.
Abstract— Zag and Monahans (1998) are H‐chondrite regolith breccias comprised mainly of light‐colored metamorphosed clasts, dark clasts that exhibit extensive silicate darkening, and a halite‐bearing clastic matrix. These meteorites reflect a complex set of modification processes that occurred on the H‐chondrite parent body. The light‐colored clasts are thermally metamorphosed H5 and H6 rocks that were fragmented and deposited in the regolith. The dark clasts formed from light‐colored clasts during shock events that melted and mobilized a significant fraction of their metallic Fe‐Ni and troilite grains. The clastic matrices of these meteorites are rich in solar‐wind gases. Parent‐body water was required to cause leaching of chondritic minerals and chondrule glass; the fluids became enriched in Na, K, Cl, Br, Al, Ca, Mg and Fe. Evaporation of the fluids caused them to become brines as halides and alkalies became supersaturated; grains of halite (and, in the case of Monahans (1998), halite with sylvite inclusions) precipitated at low temperatures (≤100 °C) in the porous regolith. In both meteorites fluid inclusions were trapped inside the halite crystals. Primary fluid inclusions were trapped in the growing crystals; secondary inclusions formed subsequently from fluid trapped within healed fractures.  相似文献   

18.
Abstract— We have analyzed nine highland lunar meteorites (lunaites) using mainly INAA. Several of these rocks are difficult to classify. Dhofar 081 is basically a fragmental breccia, but much of its groundmass features a glassy‐fluidized texture that is indicative of localized shock melting. Also, much of the matrix glass is swirly‐brown, suggesting a possible regolith derivation. We interpret Dar al Gani (DaG) 400 as an extremely immature regolith breccia consisting mainly of impact‐melt breccia clasts; we interpret Dhofar 026 as an unusually complex anorthositic impact‐melt breccia with scattered ovoid globules that formed as clasts of mafic, subophitic impact melt. The presence of mafic crystalline globules in a lunar material, even one so clearly impact‐heated, suggests that it may have originated as a regolith. Our new data and a synthesis of literature data suggest a contrast in Al2O3‐incompatible element systematics between impact melts from the central nearside highlands, where Apollo sampling occurred, and those from the general highland surface of the Moon. Impact melts from the general highland surface tend to have systematically lower incompatible element concentration at any given Al2O3 concentration than those from Apollo 16. In the case of Dhofar 026, both the bulk rock and a comparatively Al‐poor composition (14 wt% Al2O3, 7 μg/g Sm) extrapolated for the globules, manifest incompatible element contents well below the Apollo 16 trend. Impact melts from Luna 20 (57°E) distribute more along the general highland trend than along the Apollo 16 trend. Siderophile elements also show a distinctive composition for Apollo 16 impact melts: Ni/Ir averaging ?1.8x chondritic. In contrast, lunaite impact‐melt breccias have consistently chondritic Ni/Ir. Impact melts from Luna 20 and other Apollo sites show average Ni/Ir almost as high as those from Apollo 16. The prevalence of this distinctive Ni/Ir ratio at such widely separated nearside sites suggests that debris from one extraordinarily large impact may dominate the megaregolith siderophile component of a nearside region 2300 km or more across. Highland polymict breccia lunaites and other KREEP‐poor highland regolith samples manifest a strong anticorrelation between Al2O3 and mg. The magnesian component probably represents the chemical signature of the Mg‐suite of pristine nonmare rocks in its most “pure” form, unaltered by the major KREEP‐assimilation that is so common among Apollo Mg‐suite samples. The average composition of the ferroan anorthositic component is now well constrained at Al2O3 ?29–30 wt% (implying about 17–19 wt% modal mafic silicates), in good agreement with the composition predicted for flotation crust over a “ferroan” magma ocean (Warren 1990).  相似文献   

19.
F.P. Fanale 《Icarus》1976,28(2):179-202
Observations of Mars and cosmochemical considerations imply that the total inventory of degassed volatiles on Mars is 102 to 103 times that present in Mars' atmosphere and polar caps. The degassed volatiles have been physically and chemically incorporated into a layer of unconsolidated surface rubble (a “megaregolith”) up to 2km thick. Tentative lines of evidence suggest a high concentration (～5g/cm2) of 40 Ar in the atmosphere of Mars. If correct, this would be consistent with a degassing model for Mars in which the Martian “surface” volatile inventory is presumed identical to that of Earth but scaled to Mars' smaller mass and surface area. The implied inventory would be: (40Ar) = 4g/cm2, (H2O) = 1 × 105g/cm2, (CO2) = 7 × 103g/cm2, (N2) = 3 × 102g/cm2, (Cl) = 2 × 103g/cm2, and (S) = 2 × 102g/cm2. Such a model is useful for testing, but differences in composition and planetary energy history may be anticipated between Mars and Earth on theoretical grounds. Also, the model demands huge regolith sinks for the volatiles listed.If the regolith were in physical equilibrium with the atmosphere, as much as 2 × 104g/cm2 of H2O could be stored in it as hard-frozen permafrost, or 5 × 104g/cm2 if equilibrium with the atmosphere were inhibited. Spectral measurements of Martian regolith material and laboratory measurement of weathering kinetics on simulated regolith material suggest large amounts of hydrated iron oxides and clay minerals exist in the regolith; the amount of chemically bound H2O could be from 1 × 104 to 4 × 104g/cm2. In an Earth-analogous model, a 2 km mixed regolith must contain the following concentrations of other volatile-containing compounds by weight: carbonates = 1.5%, nitrates = 0·3%, chlorides = 0.6%, and sulfates = 0.1%. Such concentrations would be undetectable by current Earth-based spectral reflectance measurements, and (except the nitrates) formation of the “required” amounts of these compounds could result from interaction of adsorbed H2O and ice with primary silicates expected on Mars. Most of the CO2 could be physically adsorbed on the regolith.Thus, maximum amounts of H2O and other volatiles which could be stored in the Mars regolith are marginally compatible with those required by an Earth-analogous model, although a lower atmospheric 40Ar concentration and regolith volatile inventory would be easier to reconcile with observational constraints. Differences in the ratios of H2O and other volatiles to 40Ar between surface volatiles on the real Mars and on an Earth-analogous Mars could result from and reflect differences in bulk composition and time history of degassing between Mars and Earth. Models relating Viking-observable parameters, e.g., (40Ar) and (36Ar), to the time history and overall intensity of Mars degassing are given.  相似文献   

20.
We model the chemical evolution of Titan, wherein primordial NH3 reacts with sulfate-rich brines leached from the silicate core during its hydration. The resulting differentiated body consists of a serpentinite core overlain by a high-pressure ice VI mantle, a liquid layer of aqueous ammonium sulfate, and a heterogeneous shell of methane clathrate, low-pressure ice Ih and solid ammonium sulfate. Cooling of the subsurface ocean results in underplating of the outer shell with ice Ih; this gravitationally unstable system can produce compositional plumes as ice Ih ascends buoyantly. Ice plumes may aid in advection of melt pockets through the shell and, in combination with surface topography, provide the necessary hydraulic pressure gradients to drive such melts to the surface. Moreover, contact between the magma and wall rock (methane clathrate) will allow some methane to dissolve in the magma, as well as eroding fragments of wall rock that can be transported as xenoliths. Upon rising to the clathrate decomposition depth (∼2 MPa, or 1700 m), the entrained xenoliths will break down to ice + methane gas, powering highly explosive eruptions with lava fountains up to several kilometers high. Hence we predict that Titan is being resurfaced by cryoclastic ash consisting of ice and ammonium sulfate (or its tetrahydrate), providing an abundance of sedimentary grains, a potential source of bedload for fluvial transport and erosion, and of sand-sized material for aeolian transport and dune-building. The infrared reflectance spectrum of ammonium sulfate makes it a plausible candidate for the 5 μm-bright material on Titan's surface.  相似文献   

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