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1.
采用GIS和地统计学研究土壤有机质（SOM）的空间分布、影响因素和预测是指导农业生产、环境治理和土壤碳储计量的重要手段。基于广西马山县北部岩溶区表层土壤 (0~20 cm)的441个SOM数据,建立普通克里格(OK)、回归克里格（RK）,以及结合辅助变量的地理加权回归克里格(GWRK)、残差均值（MM_OK）和中值（MC_OK）均一化克里格的5种模型,并比较其预测精度,旨在探讨岩溶区SOM制图中地统计学方法的适用性。结果表明:（1）SOM的变异系数为37.30%,属于中等空间变异;（2）岩溶区SOM空间变异受土地利用方式、土壤类型和地形因子等因素共同影响,SOM高值区分布在西北部、西部和东部等石灰土分布的岩溶区和水田,低值区位于北部红水河沿岸的冲积土地带;（3）RK、GWRK、MM_OK和 MC_OK对SOM解释能力均较优,可用于岩溶区SOM预测制图。结合辅助变量因子的GWRK预测模型能有效消除空间变异因素的影响,克服岩溶区SOM含量的空间非平稳性,从而提高SOM含量模型的稳定性和精度,同时MC_OK模型能提高预测的准确度。 相似文献
2.
定义了土壤变异中的块段效应,提出了考虑块段效应的RBF神经网络空间插值模型(RBFBE法),以期提高土壤水分和养分的插值精度;并以江苏省扬州市区北部某试区为例,通过A、B两种训练方案,将RBFBE法对土壤含水率与有机质含量的插值结果与常规的RBF神经网络(RBFANN法)空间插值结果及普通克里金法(OK法)插值结果进行了对比分析。结果表明:与OK法相比,RBFBE法能使土壤特性的均方误差Mse缩小19.0%~62.2%,预测吻合度G提高8.9%~28.8%;与输入信息相同的RBFANN法相比,RBFBE法亦能使土壤特性的均方误差Mse缩小10.0%~48.8%,预测吻合度G提高3.4%~22.0%;此外,研究也表明RBFBE法具有较强的泛化能力。考虑块段效应的RBF神经网络方法有利于拓展人工神经网络方法在土壤特性空间插值中的应用范围,具有一定的应用前景。 相似文献
3.
等值线图是研究地基土层发育分布规律的最主要方法,但是通过地质钻孔进行地基土空间插值的精度研究并不多见。本文以天津滨海新区全新统中组第Ⅰ海相层为例,对地基土层埋深及厚度进行了空间插值对比研究;采用验证法对普通克里格法、距离倒数权重法和薄板张力样条函数法的插值精度、插值效果进行了分析评价,重点探讨了空间尺度变化、钻孔数量变化对插值效果的影响,确定了滨海新区地基土层空间插值的最佳钻孔间距、钻孔数量。在2000 m×2000 m及原始数据尺度下,采用普通克里格法对不同工程地质分区内的地基土层埋深及厚度各等级分布面积进行了统计,分析了地基土层埋深和厚度的空间插值变化情况。研究结果表明:滨海新区地基土层埋深及厚度的空间插值总体以2000 m×2000 m空间尺度下的OK法插值效果最好,能准确地揭示出地基土层的空间发育分布规律。 相似文献
4.
元素空间分布插值方法的对比研究:以铜陵地区土壤中的重金属元素为例 总被引：7，自引：0，他引：7
文中以铜陵地区As、Cd、Cu、Pb、Tl、Zn等6种土壤污染元素为例,选取常用且具有代表性的反距离加权法、径向基函数法、普通克里格法、多维分形法4种空间插值方法,进行土壤元素空间插值,并对其结果进行验证分析和评价。各方法均选取最优参数进行插值对比,土壤样本数共372个,其中337个用于插值计算,35个不参与插值计算而用于验证插值结果。对比研究显示,普通克里格法对刻画区域土壤元素的空间分布趋势效果最佳,但其半变异函数模型及参数的优选仍有待进一步研究;多维分形法对刻画土壤元素局部异常和污染效果最佳,但其对土壤元素分布普遍特征的反映仍需深入研究;反距离加权法和径向基函数法对土壤元素分布的空间插值精度一般,但其简单易用、插值最优参数易于选择。 相似文献
5.
土壤碳储量计算中不同插值方法对比研究——以吉林省大安市为例 总被引：1，自引：0，他引：1
土壤碳储量问题是大气温室效应和全球变化研究的热点问题。本文采用“单位土壤碳量”方法,计算了吉林省大安市表层土壤有机碳总储量和平均土壤有机碳储量,以为全球碳循环研究提供精确的基础数据。分析和比较了反距离加权、全局多项式、局部多项式、径向基函数和普通克里格等不同插值模型对表层单位土壤有机碳储量空间插值结果的影响,结果表明全局多项式插值的均差最小,径向基函数中张力样条法的平均绝对误差最小,普通克里格法的标准差最小。综合分析来看,普通克里格的有理二次方程式模型插值精度最高。 相似文献
6.
《物探化探计算技术》2015,(3)
西藏甲玛铜多金属矿矿区元素分布复杂,传统的地质统计学方法对其进行储量估算时忽略了多金属的相互影响,因此为了反映出不同金属元素的空间变异情况,采用协同克里格法对该矿区的金属元素储量进行估算。这里首先介绍了协同克里格算法的相关理论和相关技术,然后以此为基础,对不同方向上的空间变差函数进行结构套合的优化,并对协同克里格方程组进行降维处理。最后以2012年甲玛矿区勘探工程的数据为例,以Cu为主区域化变量,以Ag为协同区域化变量,计算了各自的实验变差函数和交差实验变差函数,分别进行协同克里格法插值和普通克里格法插值。交叉验证结果表明,协同克里格估值的标准差为0.6477,在储量计算上面精度更高,并能广泛应用于西藏甲玛铜多金属矿的地质属性、储量估算等空间数据建模。 相似文献
7.
基于空间散乱点插值的曲面重构 总被引：3，自引：1，他引：2
采用最近邻点法、距离反比加权法和克里格法等空间插值方法,基于IDL语言实现插值算法,对我国西部某金属矿山坑道内,利用大功率充电法测得的163个电位数据进行曲面重构,结果表明,克里格插值方法更能够真实地反映空间数据变量(场)的分布特性,具有广泛的实用价值。 相似文献
8.
在克里格计算或其它地质统计学研究中,变异函数模型选取的适当性直接影响渗透系数的结构分析与插值结果的合理性。分别基于高斯模型、球状模型、指数模型对同一沉积相介质的渗透系数进行结构分析,并采用普通克里格法进行插值,结果分析表明:变异函数模型对渗透系数克里格插值的影响主要体现在变程值的不同;变程值过小,搜索邻域内各数据点之间的相关性降低甚至消失,克里格法退化为简单的算术平均;随着变程值增大,参与克里格计算的实测点增多,插值结果趋近于平稳;当变程值与实际值较为吻合时,克里格插值精度达到最大。 相似文献
9.
合肥义城地区土壤重金属污染评价中典型插值方法的对比 总被引：5，自引：0，他引：5
空间插值对于土壤中重金属元素的空间分布及污染评价具有重要意义。对合肥义城地区土壤中的Cu、Pb、Zn、Cd、As、Hg等污染重金属元素,以常用且具有代表性的反距离加权法、径向基函数法、普通克里格法,进行了空间插值的对比验证分析和评价。通过对各种元素的空间插值各种误差进行综合比较的结果表明：Cu、Pb、As元素采用普通克里格法进行插值结果最优,而Zn元素采用反距离加权法最优,对于Cd、Hg元素则径向基函数插值法最优。 相似文献
10.
长期地下煤炭开采在地表产生了大面积的塌陷塘,并造成了不同程度的水域污染。为研究塌陷塘重金属的分布特征及成因,选择了8种对环境影响较大的重金属元素（Fe,Mn,Zn,Cu,Cr,Cd,Pb,Ni）为研究对象,以淮南潘集一矿塌陷塘为研究区域,利用ArcGIS地统计模块中的协同克里格算法,通过水体实测光谱反射率作为协变量来估算水体中的重金属含量空间分布特征。结果表明:水体实测光谱与重金属含量有较好的关系,以水体光谱为协变量的协同克里格插值与单变量的普通克里格插值相比,8种重金属元素的预测值与实际值之间的均方根误差明显减少,证明水体实测光谱适合作为协变量来估计水体重金属的空间分布情况。综合分析发现,水体中的Cd,Pb,Cu,Ni主要来自水域西北部的煤矸石堆山,且Cd,Cu,Pb含量均超过了当地的背景值,对环境影响较大;Cr主要来自农业肥料、成土母质和周边道路旁的煤泥灰厂及煤矸石堆;Zn的来源主要是煤矸石、上游生活污水、农业肥料、土壤母质,由于其含量较低,对水环境质量的影响不大。 相似文献
11.
Philip J. Potts Peter C. Webb Michael Thompson 《Geostandards and Geoanalytical Research》2013,37(4):403-416
Data reported by laboratories contributing to the GeoPT proficiency testing programme for geochemical laboratories over the period from 2001 to 2011 have been assessed to identify the elements and concentration ranges over which analytical performance can be considered satisfactory. Criteria developed in the paper indicated that performance in the content determination of the elements/constituents SiO2, Al2O3, MnO, Cs, Dy, Er, Eu, Ga, Hf, Ho, Lu, Nd, Pr, Sm, Sr, Tb, Tl, Tm, U, Y, Yb and Zn was satisfactory over the full concentration range assessed. The elements/constituents TiO2, Fe2O3(T), MgO, CaO, Na2O, K2O, P2O5, Ba, Be, Cd, Ce, Co, Gd, La, Li, Nb, Rb, Sb, Sc, Sn, Ta, Th, V and Zr showed some degradation in performance at lower concentration levels (approaching the detection limit of some techniques). Performance in determining LOI, As, Bi, Cr, Cu, Ge, Mo, Ni, Pb and W was in general unsatisfactory over the full concentration range assessed. Other elements (especially Fe(II)O, H2O+, CO2, Ag, Au, B, Br, Cl, F, Hg, I, In, Ir, N, Os, Pd, Pt, Re, Rh, S, Se, Te) could not be evaluated as they were not routinely reported by laboratories participating in the GeoPT programme, often because they are present in silicate rocks at sufficiently low concentrations to require a pre‐concentration stage. Some suggestions are made for the causes of unsatisfactory performance, but further progress will require a detailed assessment of the methods used by participating laboratories, which will form the subject of a further paper. 相似文献
12.
Christopher J. Duffin Jane P. Davidson 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(1):7-15
The diabolical and supernatural folklore traditions of geology are examined systematically for the first time. The following have all been suggested explanations for fossil remains: Devil's footprints, bones, toenails, fingers, thumbs, buttons, money and ninepins; Hobgoblin's claws; Fairy's fingers, heads, faces, hearts, beads, causeways, saltcellars, bottles, weights, money and loaves; elf arrows; witches’ beads and tongues. Twinned staurolite crystals have been called Fairy crosses. 相似文献
13.
The Ilgin lignite field can be subdivided into the Haramiköy and Kurugöl areas which are separated by an area of basement and a fault. The lignite-bearing sequence consists mainly of fluvial and lacustrine Neogene deposits. The Ilgin lignite, averaging 8 m (up to 25 m) thick, is blackish brown and dark brown in colour. The lignite contains abundant brown wood, plant remains and white gastropod shells. Samples have an average of 38.9% moisture on an as-received basis and a mean of 3.9% total sulphur on an air-dried basis. Geochemical analysis, using an ICP-MS, was undertaken. Thirteen lignite core samples from three boreholes drilled in the Kurugöl area were ashed at 750°C. The average trace element contents of the lignite show a higher concentration of U (average 43 ppm) when compared to the range for most coals in the world, while the others (Ti, P, Sc, Be, Mn, Co, Cu, Zn, Ga, As, Rb, Sr, Zr, Nb, Mo, Cs, Ba, Y, Ta, W, Tl, Pb, Bi, Th, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu) agree with the global ranges. The Ilgin lignite is identified as of Middle Miocene (Middle Serravallian) age and occurs within lacustrine sediments deposited under subtropical climatic conditions. 相似文献
14.
Tectono-geochemical samples were systematically collected from 5 drillcores along the No. 304 explora-tion line and at the -310 m level under the pit in the mining area, totalling 705 samples from the metamorphic rocks, granites, altered rocks and orebodies, and were determined for their contents of 20 kinds of elements including Au, Ag, As, Sb, Hg, Cu,,Pb, Zn, Sn, Bi, Mo, Co, Ni, Mn, Cr, V, Ti, Ba, Rb, Sr, etc. By using the Surfer software the geochemical exploration line profile maps for the 20 kinds of elements and the curves for the element geochemical contents of individual ore vein groups were established. In conbination with the geochemical map analytical method and Gregorian’s zoning index calculation method, the vertical, longitudinal and lateral zonation sequences of the elements were ascertained and the geochemical three-dimentional zonation model of the primary halos was estab-lished on the basis of the analysis of metallogenic structures and alteration zonation. Coupled with the results of analysis of the geology and geochemistry data, it may be concluded that the process of alteration of granites in the mining area is also accompanied with the process of gold enrichment and mineralization. With the intensification of alteration of granites from granite →potash feldspathization granite →sericite-quartz alteration granite, seric-ite-quartz rocks →beresitized granite, pyrite sericite-quartz rock, silicified granite →gold ore, the contents of thio-phile ore-forming elements such as Au, Ag, As, Cu, Bi, Mo, Pb, Sb, Hg, and Sn tended to increase. Factor analysis of trace elements indicated: factor F2 (Au, Ag, Cu, Sn, As) represents the element association brought in at the main stage of hydrothermal metallogenesis; factor F4 (Bi, Sb) and factor F5 (Pb, Zn) represent the ore-forming element association supperposed during the late stage of Au-bearing sulfides. By using the Gregorian’s zoning index and map analysis method we have ascertained the primary halo axial zonation sequence (form frontal halo →tail halo): Pb, Zn, Mn, Ba, Sr, Rb, As, Sb, Ag, Cu, Sn, Mo, Au, Bi, Hg, Ti, Cr, V, Ni, and Co. The geochemical anomalies in the mining area display a tendency of lateral plunging to WS, which is consistent with the lateral plunging of orebodies and mineralization alteration zone. Comprehensive analysis of the results of investigations on ore-controlling structures, mineralization-alteration zonation and geochemical zonation of the primary halos indicates that the gold orebodies in this area are still of greater extension. 相似文献
15.
Bhaskar Chandra ACHARYA Prasanta Kumar PANIGRAHY Binod Bihari NAYAK Rama Krishna SAHOO 《Resource Geology》1998,48(2):125-136
Abstract: Ilmenite, hematite, garnet, monazite, zircon, rutile, magnetite, sillimanite, pyroxene and amphibole from the beach sands of Ekakula, Gahiramatha coast, Orissa, India are reported here for the first time. Their total concentration varies from 26. 4 to 100%. Ilmenite, monazite and zircon are between 100 and 300 um in size and are well rounded in shape. Ilmenite-hematite intergrowth is common. Ilmenite has 50. 02–54. 73% TiO2 , 42. 42–46. 90% FeO (total Fe) and small amounts of Al, Mn, Mg, Ca, Ba, Si, V, Cr, and Zn. The bulk samples contain 10. 63–41. 42 % TiO2 , 6. 15–26. 07 % FeO, 5. 86–16. 75 % Fe2 O3 , 7. 41–61. 74 % SiO2 , 1. 39–12. 83% A12 O3 , 0. 32–4. 97% CaO, 0. 53–4. 24% P2 O5 , 0. 17–3. 27% MgO, 0. 15–2. 97% Na2 O, 0. 07–2. 34% K2 O, and 0. 05–0. 71% V2 O5 together with appreciable amounts of La, Ce, Pr, Nd, Sm, Eu, Y, U, Th, Zr, and trace amounts of Pb, Zn, Cu, Ni, Co, and Cr. Khondalite, charnockite, calc-silicate granulite, leptynite, migmatite, gneiss, basic granulite and pegmatite of the Eastern Ghats appear to be the major source for the above heavy mineral assemblages. The samples are amenable to gravity and magnetic methods of beneficiation. 相似文献
16.
贵阳花溪下三叠统大冶组中富产遗迹化石,产出18个遗迹属:Beaconichnus,Circulichnis,Cosmorhaphe,Dendrohaphe,Glockerichnus,Gyrochorte,Gordia,Maeandropolydora,Micatuba,Mammillichnis,Megagrapton,Planolites,Palaeophycus,Phycodes,Phycosiphon,Rhizocorallium,Thalassinoides和Undichna。自下而上可识别出三个遗迹组构,分别为Phycodes、Phycosiphon Mammillichnis和Thalassinoidess遗迹组构。根据遗迹化石各属种分布,大冶组自下而上出现四个遗迹相:Cruziana遗迹相、Zoophycoss遗迹相、Nereites遗迹相和Cruziana遗迹相。结合遗迹组构,对大冶组的沉积环境进行了讨论,Phycodes组构属于Cruziana相,指示浅水环境;Phycosiphon Mammillichnis组构属于Zoophycos遗迹相—Nereites遗迹相,代表台缘下斜坡半深海低能环境;Thalassinoides组构属于Cruziana相,指示早三叠世印度期末的浅水高能环境。 相似文献
17.
Concentrations of some heavy metals and trace elements such as Cr, Ga, Ni, Zn, Mo, Cu, Pb, Yb, Y, Nb, Ti, Sr, Ba, Mn, Sc, Co, V, Zr, Fe, Al, W, Se, Bi, Sb, As, Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated. The distribution of the elements in the shells is categorized into four groups. Of these, concentrations of 12 elements （As, Bi, Cd, Co, Ga, Mo, Nb, Sb, Se, Sc, W and Yb） are below zero [（0.053-0.79）×10^-6]; concentrations of seven elements （Cr, Ni, Pb, V, Y, Zr and Cu） are （1.0-6.0）×10^-6; concentrations of four elements （Ti, Mn, Ba and Zn） are 10- 20×10^-6; and concentrations of five elements （Si, Al, Fe, Mg and Sr） are （47.44-268.11）×10^-6. The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina （Linn6）, Pitar rudis （Poli）, Nassarius reticulatus （Linn6）, Venerupis senescens （Coocconi）, Mytilus galloprovincialis （Lamarck）, Mytilaster lineatus （Gemelin in Linne） and Chlamys glabra. It was found that, in mollusk taxonomy, the elements have unique values. In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks. In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment. Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment. 相似文献
18.
Saday Azadoglu ALIYEV Ali SARI Bahadir KTEN Ankara University Faculty of Engineering Department of Geological Engineering Tandogan Ankara Turkey 《《地质学报》英文版》2008,82(6)
Concentrations of some heavy metals and trace elements such as Cr,Ga,Ni,Zn,Mo,Cu, Pb,Yb,Y,Nb,Ti,Sr,Ba,Mn,Sc,Co,V,Zr,Fe,Al,W,Se,Bi,Sb,As,Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated.The distribution of the elements in the shells is categorized into four groups.Of these,concentrations of 12 elements(As,Bi,Cd,Co,Ga,Mo,Nb, Sb,Se,Sc,W and Yb)are below zero [(0.053-0.79)×10~(-6)];concentrations of seven elements(Cr,Ni, Pb,V,Y,Zr and Cu)are(1.0-6.0)×10~(-6);concentrations of four elements(Ti,Mn,Ba and Zn)are 10- 20×10~(-6);and concentrations of five elements(Si,Al,Fe,Mg and Sr)are(47.44-268.11)×10~(-6).The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina(Linné),Pitar-rudis(Poll),Nassarius reticulatus(Linné),Venerupis senescens (Coocconi),Mytilus galloprovincialis(Lamarck),Mytilaster lineatus(Gemelin in Linné)and Chlamys glabra.It was found that,in mollusk taxonomy,the elements have unique values.In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks.In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment.Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment. 相似文献
19.
K. Christanis A. Georgakopoulos J. L. Fernndez-Turiel A. Bouzinos 《International Journal of Coal Geology》1998,36(3-4)
Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins. 相似文献
20.
中国煤中的九种金属元素 总被引：6，自引：0，他引：6
在煤的加工利用过程中,煤中金属元素进入大气、水体和土壤,以致污染环境,这是人们关心的事。本文将介绍镉、钴、铬、铜、锰、钼、镍、铅、锌等九种元素在我国煤中的分布和赋存情况。 相似文献