共查询到20条相似文献，搜索用时 31 毫秒
1.
This paper reports a case study of atmospheric stability effect on dimethyl sulfide(DMS) concentration in the air. Investigation includes model simulation and field measurements over the Pacific Ocean. DMS concentration in surface sea water and in the air were measured during a research cruise from Hawaii to Tahiti. The diurnal variation of air temperature over the sea surface differed from the diurnal cycle of sea surface temperature because of the high heat capacity of sea water. The diurnal cycle of average DMS concentration in the air was studied in relation to the atmospheric stability parameter and surface heat flux. All these parameters had minima at noon and maxima in the early morning. The correlation coefficient of the air DMS concentration with wind speed (at 15 m high) was 0. 64. The observed concentrations of DMS in the equatorial marine surface layer and their diurnal variability agree well with model simulations. The simulated results indicate that the amplitude of the cycle and the mean 相似文献
2.
二甲基硫(CH3SCH3,或DMS)是大气硫化物最主要的天然来源之一,是由海洋浮游植物产生的。其在大气中的氧化产物甲磺酸(MSA)和非海盐硫酸盐(Nss-SO42-)是沿海天然降水中酸性物质的主要贡献者。对大气气溶胶中甲磺酸的采样条件及测定方法进行了探讨,利用离子色谱技术测定了青岛春季大气气溶胶中甲磺酸质量浓度平均为0.376μg/m3,并与文献结果进行了比较。 相似文献
3.
DMS and its oxidation products in the remote marine atmosphere: implications for climate and atmospheric chemistry 总被引：1，自引：0，他引：1
DMS emitted into the atmosphere over the global oceans has a range of effects upon atmospheric composition (mediated through various oxidation products) that may be significant with regard to issues as important as climate regulation, and the trace gas oxidation capacity of the marine atmospheric boundary layer. The roles played by DMS oxidation products within these contexts are diverse and complex, and in many instances are not well understood. Here we summarize what is known, and suspected, about the couplings between the marine atmospheric sulfur cycle, other atmospheric chemical cycles, and the dynamics and microphysics of the marine atmospheric boundary layer. This overview focuses heavily on measurements carried out in clean Southern Ocean air masses in association with the Australian Baseline Air Pollution Station located at Cape Grim (40° 40′ 56″S, 144° 41′ 18″ E), Tasmania. The data confirm that in the remote marine atmosphere, DMS is a central player in a variety of important atmospheric processes, reinforcing the need to understand quantitatively the factors that regulate DMS emissions from the ocean to the atmosphere. 相似文献
4.
5.
This study investigates atmospheric responses to the directions of surface wind over the Kuroshio front in the East China Sea, using wintertime satellite-derived data sets. Composite maps of sea surface temperature, wind speed, precipitation, turbulent heat flux, surface wind divergence, and the curl of wind vectors above the atmospheric boundary layer are depicted based on the classification of intense northeasterly (along the front) and northwesterly (across the front) winds over the East China Sea. When northeasterly winds prevail, considerable precipitation occurs on the offshore side of the Kuroshio front, in contrast to periods when northwesterly winds prevail. First, the northeasterly winds strengthen above the front because of the downward transfer of momentum from the fast-moving air at higher levels and/or an adjustment of sea level pressure over the oceanic front, although the process by which the influence of the Kuroshio penetrates beyond the marine atmospheric boundary layer remains unclear. Second, a cyclonic vortex forms above the marine atmospheric boundary layer (at 850-hPa height) on the offshore side of the front, and thereafter, surface wind convergence via Ekman suction (hence, enhanced precipitation) occurs over the East China Sea shelf breaks. The northeasterly winds blow over the East China Sea when the Aleutian Low retreats to the east and when high sea level pressure covers the northern Sea of Japan. 相似文献
6.
Dimethylsulfide (DMS) was determined in surface seawater and vertical hydrographic profiles in the Atlantic Ocean during two cruises from Hamburg to Montevideo (Uruguay), and from Miami (Florida) into the Sargasso Sea. These data cover most of the ecological zones of the Atlantic. DMS concentrations are related to the levels of marine primary production, in agreement with its release by marine phytoplankton in laboratory cultures. The vertical distribution of DMS in the euphotic zone follows that of primary production, with a maximum at or near the ocean surface and a decrease with depth. Below the level of 1% light penetration, DMS levels decline gradually, but DMS remains detectable even in the bottom waters. The mean DMS concentration in surface water is 84.4, and in deep water 3.2 ng S (DMS) 1?1. No steep gradients of DMS exist near the sea surface on scales of centimeters to tenths of millimeters. At a drift station, DMS was observed to be diurnally variable, with an increase in concentration in the euphotic zone throughout the day. DMS is actively turned over in the surface ocean with a residence time of a few days, but it is apparently very stable in the deep sea. DMS is the major volatile sulfur compound in the ocean, and its transfer across the air-sea interface contributes significantly to the atmospheric sulfur budget. 相似文献
7.
8.
二甲基硫的海洋化学研究 总被引：2，自引：1，他引：1
二甲基硫（ＤＭＳ） 是海洋排放到大气中的最主要的生源硫化物。作者综述了ＤＭＳ在海洋中的分布特征、影响ＤＭＳ转化的因素、ＤＭＳ的海空扩散及其对环境的影响等。ＤＭＳ在海洋中存在很大程度的时空变化,这一变化不仅与海洋初级生产力水平有关,而且还与浮游植物的种类组成密切相关。微生物的降解、光化学的氧化以及海空扩散是ＤＭＳ在海洋中迁移变化的三个最重要的途径。ＤＭＳ的海－ 空扩散也存在较大的时空变化。ＤＭＳ的释放会对全球的气候变化和酸雨的形成产生重要的影响。本文同时就国内外的研究现状和今后的研究方向进行了分析和总结。 相似文献
9.
10.
船舶尾气排放是造成海洋污染的主要排放源之一。自 2016 年设立船舶大气污染物排放控制区以来,船舶硫氧化物、氮氧化物和颗粒物排放显著减少。为了对环渤海湾水域排放控制区的大气 SO2 减排效果进行分析,选取了 Aura 卫星搭载的
OMI 传感器痕量数据产品 OMSO2 进行大气 SO2数据反演。选择 2017 年各月的 OMI Level-2 痕量数据,对大气边界层 SO2 柱量值进行提取,采用空间分析方法,对其时空变化进行分析,以监测排放控制区的减排效果。结果表明：春季和冬季 SO2 量值明显高于其他季节,年际变化比较明显,自 2016 年以来,SO2 柱总量峰值逐年降低,并且高值区域逐渐减少,证明排放控制区的设立对大气质量保护具有积极作用。 相似文献
11.
V. N. Kudryavtsev 《Physical Oceanography》1996,7(2):99-125
This paper discusses a simplified model for the evolution of the atmospheric planetary boundary layer overlying a thermal
front in the sea. The model provides local values of the friction/heat transfer geostrophic coefficients and the direction
of surface wind stress, as well as the wind/temperature profiles at any point on the front. With the running over a warm front,
the baroclinicity of the internal boundary layer leads to the generation of a near-surface current of air directed down the
front. The model can be used to interpret radar imagery of the sea surface with the purpose of determining its mesoscale variability.
Translated by Vladimir A. Puchkin. 相似文献
12.
High winds in a typhoon over the ocean can produce substantial amounts of spray in the lower part of the atmospheric boundary layer, which can modify the transfer of momentum, heat, and moisture across the air-sea interface. However, the consequent effects on the boundary layer structure and the evolution of the typhoon are largely unknown. The focus of this paper is on the role of sea spray on the storm intensity and the structure of the atmospheric boundary layer. The case study is Typhoon Imbudo in July 2003. The results show that sea spray tends to intensify storms by increasing the sea surface heat fluxes. Moreover, the effects of sea spray are mainly felt in boundary layer. Spray evaporation causes the atmospheric boundary layer to experience cooling and moistening. Sea spray can cause significant effects on the structure of boundary layer. The boundary-layer height over the eyewall area east to the center of Typhoon Imbudo was increased with a maximum up to about 550 m due to sea spray, which is closely related with the enhancements of the heat fluxes, upward motions, and horizontal winds in this region due to sea spray. 相似文献
13.
Ｅｆｆｅｃｔ ｏｆ ａｉｒ－ｓｅａ ｔｅｍｐｅｒａｔｕｒｅ ｄｉｆｆｅｒｅｎｃｅ ｏｎ ｔｈｅ ｍｏｍｅｎｔｕｍ ｅｘｃｈａｎｇｅ ｂｅｔｗｅｅｎ ａｉｒ ａｎｄ ｓｅａ ｆｏｒ ｆｅｔｃｈ－ｌｉｍｉｔｅｄ ｃａｓｅｓＣｈｅｎｇＺｈａｎａｎｄＷｕＳｈ... 相似文献
14.
15.
《Marine Chemistry》2001,76(3):137-153
Laboratory experiments, along with in situ investigation in Funka Bay, Japan, were conducted to determine the enrichment factor (EF) of dimethylsulfide (DMS) in the sea surface microlayer, as well as its the production and consumption rates. The EF of DMS in the microlayer was largely affected by various factors including sampling methods, sampling thickness, temperature, salinity, and DMS concentration in bulk water. In all cases but the sealed system, a part of DMS in the microlayer was always unavoidably lost during sampling. High temperature, great wind speed, and slow sampling would increase the extent of loss of DMS due to volatilization. In the field, the screen-collected samples usually exhibited greater microlayer enrichment for DMS than the plate-collected samples, showing that the screen sampler might be more effective for collecting the in situ microlayer DMS. The production and consumption rates of DMS in the surface microlayer were higher than those in the bulk water and these two rates were significantly correlated with the microlayer DMS concentrations. Moreover, the EF of DMS appeared to be related to the microlayer production rate of DMS, providing evidence supporting the observed DMS enrichment in the microlayer. The DMS production and consumption rates were not directly related to its concentrations in the bulk water, suggesting that the processes of production and consumption of DMS were very complex. In the surface microlayer, the biological turnover time of DMS varied from 0.4 to 1.9 days, with an average of 0.9 days, which was about 540-fold greater than the mean DMS sea–air turnover time (2.4 min). Thus, the biological process occurring within the microlayer can be neglected when we consider the sea–air exchange of DMS. Considering the microlayer production rate of DMS (an average of 9.7 nM day−1) to be too small to counteract the sea-to-air removal of DMS, the main source of DMS in the microlayer appears to be through vertical transport by turbulent diffusion from the underlying water. 相似文献
16.
The surroundings of the Bay of Bengal (BoB) suffer a lot from the extreme rainfall events during Indian summer monsoon (ISM). Previous studies have proved that the sea-air interaction is an important factor for the monsoonal precipitation. Using the 6th Coupled Modol Inter-comparison Project (CMIP6) models, this study examined the biases of surface heat flux, which is the main connection between atmosphere and ocean. Results show that although CMIP6 have a better simulation of intraseasonal sea surface temperature (SST) anomalies over BoB than the previous ones, the “atmospheric blockage” still delays the response of latent heat flux to the oceanic forcing. Specifically, during the increment of positive latent heat flux in CMIP6, the negative contribution from wind effects covers most of the positive contribution from humidity effects, due to the underestimate of humidity effects. Further diagnostic analysis denote that the surface air humidity has a quarter of a phase ahead of warm SST in observation, but gets wet along with the warm SST accordingly in most CMIP6 models. As a result, the simulated transfer of intraseasonal moisture flux is hindered between ocean and atmosphere. Therefore, as a bridge between both sides, the atmospheric boundary layer is essential for a better sea-air coupled simulation, especially when the atmospheric and the oceanic variabilities involved in a climate model becomes increasingly sophisticated. The surface air humidity and boundary layer processes require more attention as well as better simulations. 相似文献
17.
《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(26):2918-2927
Atmospheric trace gas measurements were conducted during SEEDS-II. Atmospheric dimethylsulfide (DMS) was continuously measured by GC-MS during the R/V Hakuho cruise. Further, ambient air was sampled into canisters (42 samples) and analyzed by GC-MS and GC-FID for various biogenic and anthropogenic volatile organic compounds (VOCs) after the cruise. CO, O3, SO2, and NOx were monitored continuously aboard the ship.A fertilization experiment was conducted in a high-nitrate, low-chlorophyll (HNLC) region (48°N, 165°E). The atmospheric concentrations inside a patch (fertilized area) were compared with those outside it (natural area); however, clear differences were not observed for biogenic trace gasses (DMS, CH3Cl, CH3I, isoprene, and alkenes) in the atmosphere. However, a high DMS concentration was observed over the northwestern Pacific Ocean. The fertilized area was also observed by R/V Kilo Moana, and DMS was measured by GC-FPD. A good agreement was observed between the results of the measurements made aboard the two independent ships by different measurement methods.The atmospheric SO2 concentration was compared with the atmospheric DMS concentration. The SO2 concentration was found to vary with the atmospheric DMS concentration. A diurnal variation of the atmospheric DMS concentration was observed around the fertilized region. The DMS content tends to increase during the night and decrease during the day. A box model calculation was conducted to explain the diurnal variation of the atmospheric DMS. Since there was no diurnal variation of the wind speed, a constant DMS flux from the ocean surface was assumed. Further, the atmospheric OH radical concentration was assumed to be dependent on sunlight. The box model can roughly reproduce the atmospheric DMS diurnal variation mainly caused by its removal reaction with OH radicals. 相似文献
18.
海—气相互作用与海流、风暴潮 总被引：3，自引：4，他引：3
从方法论上说,除潮汐以外,通常在处理海洋动力学问题时,大多撇开海洋对大气的影响,强调大气对海洋的主导作用,把大气运动当作诱发海水运动的唯一原动力,视海面风场为给定条件,而后用经验或半经验公式算出海面风应力场,作为施加于海水的强迫力。因此,一个成功的海浪、海流或风暴潮的预报,除了具备反映海水运动的主要物理性能的数学模型外,还必须以客观的、准确的海面风场的数值计算和预报为前提。由于问题的复杂性,迄今为止似乎还不能说在实用上已经提供了海面风的一种足够精确的估算或预报方法。海上气象观测资料,尤其是测风资料的稀少,给海面风应力的实际计算带来不少困难。 相似文献
19.
Ang Li Xueming Zhu Yunfei Zhang Shihe Ren Miaoyin Zhang Ziqing Zu Hui Wang 《海洋学报(英文版)》2021,40(11):87-103
In order to satisfy the increasing demand for the marine forecasting capacity, the Bohai Sea, the Yellow Sea and the East China Sea Operational Oceanography Forecasting System (BYEOFS) has been upgraded and improved to Version 2.0. Based on the Regional Ocean Modeling System (ROMS), a series of comparative experiments were conducted during the improvement process, including correcting topography, changing sea surface atmospheric forcing mode, adjusting open boundary conditions, and considering atmospheric pressure correction. (1) After the topography correction, the volume transport and meridional velocity maximum of Yellow Sea Warm Current increase obviously and the unreasonable bending of its axis around 36.1°N, 123.5°E disappears. (2) After the change of sea surface forcing mode, an effective negative feedback mechanism is formed between predicted sea surface temperature (SST) by the ocean model and sea surface radiation fluxes fields. The simulation errors of SST decreased significantly, and the annual average of root-mean-square error (RMSE) decreased by about 18％. (3) The change of the eastern lateral boundary condition of baroclinic velocity from mixed Radiation-Nudging to Clamped makes the unreasonable westward current in Tsushima Strait disappear. (4) The adding of mean sea level pressure correction option which forms the mean sea level gradient from the Bohai Sea and the Yellow Sea to the western Pacific in winter and autumn is helpful to increasing the fluctuation of SLA and outflow of the Yellow Sea when the cold high air pressure system controls the Yellow Sea area. 相似文献
20.
黄、渤海二甲基硫化物的浓度分布与迁移转化速率研究 总被引：2，自引：1，他引：1
于2015年8-9月对黄、渤海海域进行现场调查,研究了海水中二甲基硫（DMS）、β-二甲巯基丙酸内盐（DMSP）、二甲亚砜（DMSO）的浓度分布、相互关系及影响因素,测定了DMS的生物生产与消耗、光化学氧化和海-气扩散速率,对DMS的迁移转化速率进行综合评价。结果表明:表层海水中DMS、溶解态DMSP（DMSPd）、颗粒态DMSP（DMSPp）、溶解态DMSO（DMSOd）和颗粒态DMSO（DMSOp）浓度的平均值分别为（6.12±3.01）nmol/L、（6.03±3.45）nmol/L、（19.47±9.15）nmol/L、（16.85±8.34）nmol/L和（14.37±7.47）nmol/L,整体呈现近岸高远海低,表层高底层低的趋势。DMS、DMSPd和DMSOp浓度与叶绿素（Chl a）浓度存在显著的相关性。表层海水中DMS光氧化速率顺序为:kUVA > kUVB > k可见,其中UVA波段占光氧化的70.8%。夏季黄、渤海微生物消耗、光氧化及海-气扩散对DMS去除的贡献率分别为32.4%、34.5%和33.1%,表明3种去除途径作用相当。黄、渤海DMS海-气通量变化范围为0.79~48.45 μmol/（m2·d）,平均值为（11.87±11.35）μmol/（m2·d）。 相似文献