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1.
陕西镇安二台子金铜矿床表生地球化学异常特征   总被引：4，自引：0，他引：4  
为查明二台子金铜矿床的表生地球化学异常特征，采用土壤地球化学综合剖面的研究方法，对其进行了详细的分析研究。结果表明，区域上二台子金铜矿床的表生地球化学异常元素组合为Au-As-Sb-Hg-Cu，并表现出与原生异常在组合，含量等特征上的一致性。矿区内金、铜等成矿及指示元素在土壤中的不同层位产生了一定程度的富集。土壤和岩石样品的Au，As，Hg，Cu均密切相关。该矿床上覆的土壤及氧化矿石中的金主要以自然金相，水溶相和硫化物相形式存在，金的这种赋存相态特征可以作为寻找掩埋和隐伏金矿床的标志。  相似文献   

2.
Some comparative marine chemistries of rhenium, gold, silver and molybdenum   总被引：1，自引：0，他引：1  
Four metals, Re, Au, Ag and Mo, whose dissolved forms in seawater can potentially be reduced to insoluble states, have been measured in a variety of solids depositing under anoxic conditions: hydrothermal sulfides; coastal sediments; and phosphorites. For comparative purposes these elements have also been determined in ferromanganese minerals and pelagic sediments which have accumulated under oxidizing conditions. Rhenium appears to be a unique sentinel for identifying reducing depositional environments, where enrichments of greater than three orders of magnitude above crustal concentrations are found. Molybdenum follows Re in these sediments but Mo is enriched also in those that accumulate under oxidizing conditions. The reported Mo crustal concentrations appear low in comparison to our measured sedimentary values. Gold and Ag are concentrated in hydrothermal deposits and sulfides appear to be involved in the precipitation of these elements. Coastal sediments adjacent to a domestic outfall of Los Angeles, California contain extraordinary high accumulations of anthropogenic Au, Ag and Pt. The study seeks an understanding of the mobilities and sinks of these metals in the marine environment during the major weathering cycle. Further, anthropogenic contributions to their sedimentary concentrations are identified.  相似文献   

3.
The investigation was conducted within highly and moderately separated highlands and high plateaus where glaciers, stone streams, solifluction, and glacial and fluvio-glacial deposits are widely developed. A capping of Miocene basalts remains in the divides over the Au ore deposits and their oxidation zones. Young water-filled fractures traverse the ore-bearing structures and control the direction of the glacial and river valleys, as well as the location of the lakes, springs, and icings.Gold occurs in small- to average-sized sulphide-Au-quartz veins and in a sulphidized black shale series of Precambrian and Paleozoic age. Both mechanical and hydromorphic dispersion of Au are exhibited clearly in the highlands. The latter is due to the processes of modern oxidation of the Au-bearing sulphide minerals. The anomalies of Au in streams and small lakes are related to supra- and sub-ice waters. In the water of streams Au is present in three forms; colloidal, dissolved, and sorbed. Gold in colloidal form comprises the most ample and contrasty anomalies. The truly dissolved Au is more local and manifests itself close to the source of the stream. Gold sorbed on suspended matter is evident because of a significant removal from the source into the solution. Migration of Au and formation of long (up to 2.5 km) and contrasty dispersions in waters of low dissolved solids is favoured by the presence of organic matter and argillaceous and ferruginous suspensions as well as other sorbents. The anomalies of Au in water either coincide with anomalies in stream sediments over mineralized zones or indicate new mineralized areas not reflected in stream sediments.  相似文献   

4.
纳米地球化学:穿透覆盖层的地球化学勘查   总被引：5，自引：0，他引：5       下载免费PDF全文
盖层下方隐伏矿成矿及伴生元素如何穿透覆盖层到达地表,是深穿透地球化学迁移机理研究的热点。笔者以隐伏铜镍矿和金矿为例,同时采集地气、土壤、矿石样品,使用透射电子显微镜(TEM),对样品中微粒物质的粒径、形貌、成分、结构进行了观测,发现微粒具有下列特点:(1)广泛观测到的微粒成分是铜及铜合金,金只在金矿上方土壤孔隙气体中能被观测到;(2)单个金属微粒粒径主体为几十nm,也有个别小到几个nm,大到上百个nm,微粒大多呈团聚体;(3)微粒晶形完整,内部原子呈有序晶体排列;(4)迁移柱实验表明纳米微粒具有快速迁移能力。在地气、土壤和矿石中同时观测到纳米级金属微粒,粒径大小、微粒形态、元素组合都非常相同或相近,表明两者具有来源一致性并具有序晶体结构,表明形成于内生作用。这是首次同时观测到矿石、土壤、气体介质中具有继承性关系的纳米金属微粒。矿石中纳米级金属微粒通过与微气泡表面相结合,以地气流为载体,或纳米微粒本身具有类气体性质,可以克服重力影响,穿透厚覆盖层迁移至地表,到达地表后一部分纳米颗粒仍然滞留在气体里,另一部分被土壤地球化学障(粘土、胶体、氧化物等)所捕获。这为深穿透地球化学从描述性或推测性模型走向实证性科学迈出了重要一步,为利用土壤作为采样介质、精确分离含矿信息用于寻找外来盖层下的隐伏矿提供了纳米地球化学技术。  相似文献   

5.
The paper presents the results of our investigations carried out to examine the behavior of native gold in the southern West Siberia during the fluvial transport of an auriferous terrigenous material at the mountain-to-plain transition geomorphological zone. The piedmont alluvium accumulates the small- and, to a lesser extent, fine-grained gold transported from the denudation zones by the main mountain-lowland rivers. The background Au content varies from n to 10n mg/m3. High contents (100n mg/m3 to n g/m3) are recorded in some sectors in the upper zones of channel alluvium (spit and shoal facies). Flatness coefficient of particles is an important characteristic of allochthonous native gold in the piedmont alluvium. This property shows direct correlation with the lateral dimension of particles. Composition is an essential typomorphic property of the small- and fine-grained gold in the studied sediments. This statement is primarily valid for the degree of fineness commonly related to the Ag content in gold. In some cases, a significant indicator role can be played by traces of Hg and Cu. For example, Hg is an important indicator for the gold-mercury mineralization, whereas Cu is an essential indicator in the case of gold mineralization associated with rhodingites and high-temperature Cu-Au mineralization. Abundance of the allochthonous native gold in different-age terrigenous sediments testifies to its high stability during the continental sedimentation.  相似文献   

6.
《Applied Geochemistry》2000,15(5):629-646
Stream waters and sediments draining a gossan tailings pile at the Murray Brook massive sulphide deposit were collected to investigate Au mobility. Weathering of the massive sulphides at Murray Brook during the Late Tertiary period resulted in the concentration of Au in the gossan cap overlying the supergene Cu and unoxidized massive sulphide zones of the deposit. The gossan was mined between 1989 and 1992, and Au and Ag were extracted using a cyanide vat leach process. Although stream sediments prior to mining had Au<5 ppb (the detection limit), sediments collected in 1997 had Au contents ranging up to 256 ppm with values up to 6 ppm more than 3 km downstream from the deposit. Dissolved Au contents were similarly anomalous, up to 19 μg/L and in excess of 3 μg/L 3 km downstream. The elevated Au contents in the waters and sediments are interpreted to reflect complexation of Au (as Au(CN)2−) by cyanide hosted within the gossan tailings pile. Precipitation recharges through the tailings pile with groundwater flow exiting to Gossan Creek. Degradation of cyanide along the flow path and within Gossan Creek allows colloidal Au to form via reduction of Au(I) by Fe2+, consistent with SEM observations of Au as <1 μm subrounded particles. In the surface waters, the majority of the Au must be in a form <0.45 μm in size to account for the similarity in Au contents between the <0.45 μm and unfiltered samples. The very elevated stream sediment Au values close to the headwaters of Gossan Creek near the tailings indicate that upon exiting to the surface environment, Au(CN)2− complexes are rapidly destroyed and Au removed from solution. However, the high Au<0.004 μm/Autotal in the headwaters and the extended Au dispersion in Gossan Creek waters and sediments suggest that Au(CN)2− complexes persist for the full length of Gossan Creek. The decrease in aqueous Au which is less than 0.004 μm indicates that Au is converted from a complexed form to a colloidal form with increasing distance downstream, consistent with dissolved NO3− contents which decrease from 5210 μg/L near the headwaters to 1350 μg/L at the lower end of the stream.  相似文献   

7.
近20年来,越来越多的大型金属矿床在盆地内部及其边缘被发现。传统的勘查地球化学方法对盆地及盆山边缘覆盖区无能为力,深穿透地球化学探测技术为解决盆地及其边缘覆盖区找矿难题提供了一种行之有效的手段。文章通过对沉积砂岩盆地铀矿、火山岩盆地银多金属矿、变质岩盖层铜镍矿和沉积盖层金矿开展探测试验,得出:(1)砂岩型铀矿中活动性铀主要以铀酰络阳离子的形式存在,铀酰络阳离子很容易受地下水运动及蒸发蒸腾作用而发生迁移,迁移通道包括砂岩的孔隙、构造裂隙等,到达地表后,铀酰络阳离子易与土壤中带负电的黏土矿物结合而赋存其中,使用微细粒分离和活动态提取两种方法均能圈定矿致异常;(2)火山岩盆地中,与火山岩近乎同期形成的矿床,矿床形成过程中含矿流体携带成矿元素银、金、铜等沿构造裂隙运移,迁移到地表后被土壤中的黏土矿物所吸附,使用土壤活动态测量和微细粒分离测量均能有效圈定已知矿体,异常直接位于矿体上方;(3)变质岩盆地超基性岩体在侵位过程中,岩体与变质岩接触带将产生大量的构造裂隙,因此当流体通过岩体与围岩接触带时,将携带矿体中铜、镍向上迁移至地表,形成环状异常;(4)洛宁盆地金矿成矿过程中,成矿元素金、银等以络合物、纳米级单质或合金等形式通过流体携带顺着构造破碎带向上迁移,地表岩石风化发生成矿元素解离,后期被黄土覆盖,矿体或岩石解离的化合物或纳米颗粒可以穿过黄土孔隙向上迁移至地表,并赋存于表层黄土的细粒级黏土中,因此采用土壤微细粒分离测量可圈出矿致异常。本文根据深穿透地球化学方法应用效果,异常的形态,并结合盖层的特点,成矿元素的存在形式、迁移方式以及在地表的赋存状态,初步建立了盆地金属矿深穿透地球化学勘查模型,为盆地盖层区地球化学勘查提供了理论与技术支撑。  相似文献   

8.
Despite its potential economic and environmental importance, the study of trace metals in supergene (secondary) Cu-sulfides has been seriously overlooked in the past decades. In this study, the concentration and mineralogical form of “invisible” precious metals (Ag, Au) and metalloids (As, Sb, Se, Te) in supergene digenite (Cu1.8S) from various Cu deposits in the Atacama Desert of northern Chile, the world’s premier Cu province, were determined in detail using a combination of microanalytical techniques. Secondary ion mass spectrometry (SIMS) and electron microprobe analyzer (EMPA) measurements reveal that, apart from hosting up to ∼11,000 ppm Ag, supergene digenite can incorporate up to part-per-million contents of Au (∼6 ppm) and associated metalloids such as As (∼300 ppm), Sb (∼60 ppm), Se (∼96 ppm) and Te (∼18 ppm). SIMS analyses of trace metals show that Ag and Au concentrations strongly correlate with As in supergene digenite, defining wedge-shaped zones in Ag-As and Au-As log-log spaces. SIMS depth profiling and high-resolution transmission electron microscopy (HRTEM) observations reveal that samples with anomalously high Ag/As (>∼30) and Au/As (>∼0.03) ratios plot above the wedge zones and contain nanoparticles of metallic Ag and Au, while samples with lower ratios contain Ag and Au that is structurally bound to the Cu-sulfide matrix. The Ag-Au-As relations reported in this study strongly suggest that the incorporation of precious metals in Cu-sulfides formed under supergene, low-temperature conditions respond to the incorporation of a minor component, in this case As. Therefore, As might play a significant role by increasing the solubility of Ag and Au in supergene digenite and controlling the formation and occurrence of Ag and Au nanoparticles. Considering the fact that processes of supergene enrichment in Cu deposits can be active from tens of millions of years (e.g. Atacama Desert), we conclude that supergene digenite may play a previously unforeseen role in scavenging precious metals from undersaturated (or locally slightly supersaturated) solutions in near-surface environments.  相似文献   

9.
斑岩型钼矿床的形成机制与地球化学过程   总被引：1，自引：1，他引：0  
斑岩型钼矿床是世界钼矿床中最重要的种类,其中90%以上的钼矿床都和斑岩有关。斑岩型钼矿床主要分布于环太平洋成矿带和特提斯成矿带上,主要与板块俯冲过程有关,可以分为斑岩铜钼矿床、高氟型斑岩钼矿床和低氟型斑岩钼矿床。我们通过对全球斑岩型钼矿床的时空分布与钼元素地球化学性质分析,认为斑岩型钼矿床的物质来源是钼元素通过表生地球化学作用进行初始富集后形成的富钼沉积物。新元古代晚期(750～542Ma)大气氧再次升高之后,富钼的黑色页岩等才大量出现,因此斑岩型钼矿床主要形成于500Ma之后。富钼黑色页岩等沉积物在板块俯冲过程中脱水,形成富含Mo和Re的变质流体,同时两者发生分异。这种变质流体交代上覆地幔楔使Mo和Re留存在其中。随着俯冲洋壳的部分熔融,形成富Cu(Au)的岩浆,穿过富含Re(Mo)的上覆地幔楔,形成斑岩型铜钼矿床,因此这类矿床的辉钼矿Re含量更高。而随后出现的板块后撤,使软流圈上涌,板片上大量多硅白云母分解,形成了富含F的岩浆,穿过富含Mo的上覆地幔楔,进而形成高氟型斑岩矿床。低氟型钼矿床很可能与俯冲关系较小,富钼沉积物通过造山过程被深埋,在适当的条件下形成低氟型斑岩钼矿床。  相似文献   

10.
Ground-water, alluvium, and bedrock samples were collected from drill holes near the Chimney Creek, Preble, Summer Camp, and Rabbit Creek disseminated gold deposits in northern Nevada to determine if Au and ore-related metals, such as As, Sb, and W, are being hydromorphically mobilized from buried mineralized rock, and, if they are, to determine whether the metal-enriched ground water is reacting with the alluvial material to produce a geochemical anomaly within the overburden.Results of chemical analyses of drill-hole water samples show the presence of hydromorphic dispersion anomalies of Au, As, Sb, and W in the local ground-water systems associated with these deposits. Background concentrations for Au in the ground water up-gradient from the buried deposits was less than 1 nanogram per liter (ng/L), near the deposits the Au values ranged from 1 to 140 ng/ L, and in drill holes penetrating mineralized rock, concentrations of Au in the ground water were as high as 4700 ng/L. Highest concentrations of Au were found in ground-water samples where the measured Eh and the distribution of arsenic species, arsenite [As(III)] and arsenate [As(V)], indicated oxidizing redox potentials. Similarly, As, Sb, and W concentrations in the ground water near the deposits were significantly enriched relative to concentrations in the ground water up-gradient from the deposits. In general, however, the highest concentrations of As, Sb, and W occurred in ground-water samples where the measured Eh and the distribution of arsenic species indicated reducing conditions. Arsenic concentrations ranged from 9 to 710 micrograms per liter (μg/L); Sb, from less than 0.1 to 250 μg/L; and W, from 1 to 260 μg/L.In addition, analysis of sequential dissolution and extraction solutions of drill cuttings of alluvium and bedrock indicate geochemical anomalies of gold and ore-related metals in the overburden at depths corresponding to the location of the present-day water table. This relationship suggests that water-rock reactions around these buried deposits are active and that this information could be very useful in exploration programs for concealed disseminated gold deposits.  相似文献   

11.
The outer sector of the Neoproterozoic Katangan Orogen of Central Africa is characterised by nappes thrust northwards, toward the foreland region, the major part of which occurs in the Democratic Republic of Congo (DRC). The rocks called R.A.T. (‘Roches Argilo-Talqueuses’) are terrigenous clastics traditionally considered as the oldest stratigraphical interval of these allochthonous units. They are correlated with the terrigenous clastic sediments at the base of the autochthonous Katangan succession in Zambia to the south, which were deposited at the opening stage of the Katangan Rift Basin. The lower interval of the R.A.T. represents red beds, whereas the upper one was deposited in anoxic conditions. Therefore, they are called red and grey R.A.T., respectively. This paper presents stratigraphic, structural and geochemical arguments against the traditional stratigraphical view and demonstrates that the R.A.T. rocks are younger than previously considered. They are interpreted here as synorogenic sediments of the Katangan foreland basin.Olistostromes with R.A.T. olistoliths, which occur either interbedded within ‘normal’ R.A.T. sediments or overlie angular unconformities, testify to pronounced tectonic movements and palæotopography of the basin in which the R.A.T. sediments were deposited. The provenance of other olistoliths implies that, contrary to the previous views, the R.A.T. olistostromes are younger than the overlying rock complexes and the contact between the two is tectonic. Clastic dykes of the incompetent R.A.T. lithologies injected into the overlying competent units suggest that the former were partly unconsolidated sediments over-ridden by the Katangan nappes. Plots of the geochemical compositions point to two distinct tectonosedimentary cycles and two types of sources, each related to a different stage of orogen evolution. The terrigenous materials of the Katangan autochthonous strata (Roan and Kundelungu Groups) and correlative allochthonous units are derived from basement granitic and metamorphic rocks eroded during the opening of the Katagan rift basin. By contrast, the R.A.T. rocks are related to the closure of the basin. Their provenance is from the orogenic source-the Katangan nappes advancing towards the foreland region in the north.The autochthonous Roan Group rocks in Zambia and their allochthonous correlatives in DRC contain one of the richest Cu-Co deposits known. In accord with the previous correlation, the CuCo mineralisation in the grey R.A.T. rocks was considered of the same age as the Zambian deposits. However, the results presented in this paper imply that the grey R.A.T. deposits represent a second generation of mineralisation in the Katangan belt, younger than the Roan Group orebodies. The R.A.T. Cu-Co mineralisation is related to the anoxic stage of the foreland basin, and the advancing nappes containing Roan-correlative orebodies acted as the sources of the metals. In conclusion, points pertaining to the revision of stratigraphical classification of the Katangan Supergroup are proposed.  相似文献   

12.
The recently discovered gold deposit in the Lubin-Sieroszowice district lies 0.0 to 1.5?m below the stratabound copper-silver orebody, mainly in the Polkowice-west mine. The deposit extends over 60?km2, has a thickness of 20–80?cm and a conservative estimate of the average grade of 1.5?g/t gold, 0.3?g/t Pd and 0.2?g/t Pt. It contains gold and electrum in association with minor amounts (up to 0.4?vol%) of hematite, chalcocite, digenite, djurlite, bornite, chalcopyrite, pyrite, gersdorffite, rammelsbergite and clausthalite. The gold-bearing zone lies mainly in the Weissliegendes sandstone, but locally transgresses the stratigraphy into the overlying Kupferschiefer shale and Werra Dolomite of the Zechstein evaporite sequence. It lies within a transition zone between the oxidized, hematite-stained Rote Fäule facies and the overlying reduced organic carbon-bearing sediments. At the Polkowice-west mine, but only where gold is present, this zone is characterized by hematite-stained `patches' within grey to maroon sediment that contains little or no hematite or organic carbon. These textures were caused by downwelling reducing sulfur-rich solutions, flowing through previously oxidized sediments, and by gravitational instability between the reducing and oxidizing fluids. The oxidizing fluid originated within the Rote Fäule facies, whereas the reducing fluid originated in the overlying Zechstein sequence from which it was expelled downward during gypsum dehydration accompanying burial. Gold transport as the chloride complex in the oxidizing fluid is unlikely at the low temperature (?<100?°C) prevailing during mineralization. Some gold was probably transported as the bisulfide and, to a lesser extent, the polysulfide complexes, in the descending reducing fluid. However, the potential source rocks do not contain enough gold to account for the known deposit. Most of the gold was probably transported as the thiosulfate complex during replacement of reduced sediments by the Rote Fäule facies. Parts of the district where reduced fluids penetrated deeply into the Weissliegendes, and where the Rote Fäule facies transgressed the greatest volume of reduced sediments, should be evaluated for the presence of gold. We propose that the Polkowice-West mine represents a new class of gold deposit.  相似文献   

13.
The presented overview of hypergene metallogeny of the Urals is largely based on original data of the author. All bauxite, Co–Ni oxide–silicate, and high-grade ferromanganese our deposits, gold, platinum, and diamond placers, as well as brown coal, kaoline, refractory, and other economic-grade mineral deposits, currently mined in the Urals are hosted in hypergene zones and related hypergene blankets of different ages. Prospects for diverse mineral deposits are estimated with a special emphasis on thermal hypergene deposits (Ni, Au, and others) that are atypical for the Urals but favorable for mining under conditions of the market economy owing to the presence of high-grade ore bodies.  相似文献   

14.
藏南查拉普金矿床载金矿物特征与金的赋存状态   总被引：1，自引：0，他引：1  
黄铁矿和毒砂是卡林型和造山型金矿床重要的载金矿物。文章通过电子探针(EPMA)分析研究了藏南查拉普金矿床不同类型黄铁矿和毒砂中Au、As、S、Fe等元素的含量变化和分布规律,发现不同阶段的黄铁矿具有不同的结构特征和元素组成特点。沉积成岩期黄铁矿(Py1)主要呈草莓状、胶状,常构成环带状黄铁矿的核心,其中金的含量最高,显示了金在沉积成岩期的大量富集。热液期早阶段黄铁矿(Py2)主要呈自形-半自形的立方体,与Py1元素(S、Fe、As)组成相近,显示了一定的继承演化关系。热液期主阶段黄铁矿(Py3)与毒砂共生,多呈自形-半自形的五角十二面体、立方体,常包裹早期的黄铁矿形成环带结构。Py3中As的含量明显升高,其增加量近似等于S的减少量,说明As主要进入黄铁矿晶格替代了S的位置。各个阶段的黄铁矿和毒砂中Au的分布在EPMA微束的分辨率下均显示是不均匀的,Au在Py1和大部分Py2中主要以纳米级自然金(Au0)的形式存在;而在Py3中主要以(Au+)的形式存在,少部分以纳米级自然金(Au0)形式存在。Py1的结构及元素组成与典型卡林型金矿和造山型金矿沉积成岩期黄铁矿的特点相似,而Py3的大量发育则符合卡林型金矿的特征。  相似文献   

15.
The «Selektor-C» software package and standard thermodynamic functions of ternary Ag–Au–Hg solid solutions were used for developing physicochemical models in natural processes with participation of gold, silver and mercury. On the example of the Kyuchyus Au–Sb–Hg deposit we have worked out hypogene and hypergene models of formation of native gold, including mercuric gold. We obtained thermodynamic evidence that the Kyuchyus deposit ores formed with the origin of electrum at the early main productive quartz–sulfide stage and ternary Au–Ag–Hg solid solutions at the late non-substantive Au-bearing stages.  相似文献   

16.
Abstract

The Yilgarn Craton of Western Australia hosts a number of Cenozoic paleochannels, which have been incised into the underlying Paleozoic and Precambrian rocks, filled with sediments and subsequently weathered. The paleochannels are of particular interest in mineral exploration as they may not only host placer-type deposits but also overlie significant supergene and primary mineralisation. Paleochannels also pose particular challenges during exploration as they mask underlying geochemical anomalies, including gold and pathfinder elements. This study investigates a method of distinguishing transported overburden from residual regolith utilising a combination of field and laboratory-based techniques. At the Minotaur deposit, the residual regolith and transported overburden are mineralogically similar, although the presence of biotite, chlorite and muscovite is more characteristic of the residual regolith. Geochemically, Zr, Ti, Co and Sc ratios form distinct groupings allowing more confident discrimination of transported overburden from the underlying residual regolith units. The presence of a distinct gold depletion zone at the redox front was also identified to be a feature of the Minotaur deposit, with Au enrichment occurring above (within transported overburden) and below (within saprolite) the redox front, similar to other gold deposits on Lake Lefroy. The lithological, stratigraphic and Au-enrichment characteristics at Minotaur have also been compared with regional studies and suggest the long-lived impact of paleovalleys on the depositional systems and Au distribution of Lake Lefroy. This work provides a basis for future studies of the region in particular the variation of depositional sequences within regional paleochannel networks.  相似文献   

17.
隐伏金属矿床上升气流微粒特征、形成及迁移   总被引：3，自引：0，他引：3  
曹建劲 《地学前缘》2012,19(3):113-119
结合地球化学和纳米科学技术的理论和研究方法,研究隐伏金属矿床有关微粒的形成、迁移和特征。对十多个金属矿床的研究表明,隐伏金属矿体地表沉积物中上升气流微粒样品有单个微粒和微粒聚合体,单个微粒形态有球状、近球状、不规则状、规则多边形、长柱状,微粒有晶质、非晶质和部分晶质。聚合体形态一般是不规则状、球状和近球状。它们的矿物成分主要有自然Au、自然Cu、氯化物、氧化物、硫酸盐、氢氧化物等。成矿元素Au、Cu可以自然金属或自然合金形式存在,Cu、Pb、Zn等成矿元素可以氧化物或硫酸盐等形式存在,也可以存在于氧化物、氢氧化物、氯化物、硫酸盐等微粒中作为杂质元素,这些是隐伏金属矿体的指示微粒。成矿期后,与隐伏金属矿体有关微粒主要形成于断层作用、氧化作用和生物作用。在上升气流中,微粒呈“布朗运动”。  相似文献   

18.
张永强  谈乐  李小明 《中国地质》2019,46(S1):46-54
首次汇集了陕西石泉-旬阳金矿带整装勘查区内7个图幅1：50 000水系沉积物测量18种元素（Au、Cu、Zn、As、Sb、Hg、Bi、Ti、V、Ag、Sn、Pb、W、Mo、Ni、Co、Cr、Cd）的测试数据,共包含数据点13 169个,数据180 944个,第一次建立了该勘查区的地球化学数据库。在此基础上,编制了233张各类地球化学系列图件,并建立了空间数据库。通过本数据集在区内共圈定各类单元素异常2 083处,其中金元素异常304处;圈定金找矿靶区10处,金成矿远景区12处;经过后期矿产综合检查,整装勘查区内共发现金矿产（点）53处,其中,中型规模金矿床8处,小型规模金矿床18处,金元素异常与金矿床（点）对应程度较好,矿致异常达189处,显示1：50 000水系沉积物测量是勘查区内较好的找矿手段之一。  相似文献   

19.
包村和朝山金矿床位于安徽铜陵狮子山矿田，属于夕卡型岩金矿床，侵入岩体分别为包村石英闪长岩体和白芒山辉石闪长岩体。通过矿相鉴定和电子探针分析，对矿床中的自然金进行了详细的观察和研究。结果表明，在两个矿床中，金矿物均以独立的自然金颗粒形式产出，且常具有“银边结构”，但在自然金的嵌布方式、载体矿物、形态、大小、金银含量变化和成色等方面表现出显著差别。根据自然金的不同特征，对金矿床的成因进行分类，包村金矿床属于Cu-Au共生，而朝山矿床为Cu-Pb-Zn-Au共生型金矿床。不同矿床不同的金产状主要是由于金的运移、络合物种类、温度、pH和金银络合物活度比值等因素赞成的。此外，包村矿床和朝山矿床在地表均遭受氧化作用形成表生矿床，其表生金成色均明显高于原生金，且成分均一。  相似文献   

20.
As a result of over-erosion of soils, the fine particles, which contain the majority of nutrients, are easily washed away from soils, which become deficient in a host of components, accumulating in lakes. On one hand, the accumulation of nutrients-rich sediments are a problem, as they affect the quality of the overlying water and decrease the water storage capacity of the system; on the other hand, sediments may constitute an important resource, as they are often extremely rich in organic and inorganic nutrients in readily available forms. In the framework of an extensive work on the use of rock related materials to enhance the fertility of impoverish soils, this study aimed to evaluate the role on the nutrients cycle, of particles recycling processes from the watershed to the bottom of a large dam reservoir, at a wet tropical region under high weathering conditions. The study focus on the mineralogical transformations that clay particles undergo from the soils of the drainage basin to their final deposition within the reservoir and their influence in terms of the geochemical characteristics of sediments. We studied the bottom sediments that accumulate in two distinct seasonal periods in Tucuruí reservoir, located in the Amazonian Basin, Brazil, and soils from its drainage basin. The surface layers of sediments in twenty sampling points with variable depths, are representative of the different morphological sections of the reservoir. Nineteen soil samples, representing the main soil classes, were collected near the margins of the reservoir. Sediments and soils were subjected to the same array of physical, mineralogical and geochemical analyses: (1) texture, (2) characterization and semi-quantification of the clay fraction mineralogy and (3) geochemical analysis of the total concentration of major elements, organic compounds (organic C and nitrogen), soluble fractions of nutrients (P and K), exchangeable fractions (cation exchange capacity, exchangeable bases and acidity) and pH(H2O).There is a remarkable homogeneity in the sedimentary distribution along the reservoir in terms of the texture and mineralogy of the clay fraction and of the chemistry of the total, soluble and exchangeable phases. These observations contrast with the physical, morphological and chemical heterogeneity of the soils and the setting lithology. Most of the sediments has a higher contribution of fine-grained material and the mineralogy of the clay fraction is dominated by kaolinite in soils and kaolinite and illite in sediments, followed by lesser amounts of gibbsite, goethite, and metahaloisite and by small/vestigial contents of chlorite and smectite. The sediments are mainly inherited from the watershed but there exist marked differences between the accumulated sediments and their parent materials. These differences mainly come from the selective erosion of fine-grained particles and the extreme climatic conditions which enhance complex transformations of mineralogical and chemical nature. Compared with the parental soils, the reservoir sediments show the following differences: (1) enrichment in fine-grained and less dense inorganic particles, (2) aggradative mineralogical transformations, including enrichment in clay minerals with higher cationic adsorption and exchange capacity, (3) degradation of the crystalline structure of Fe- and Al-oxides (goethite, gibbsite), (4) increase in easily leached elements (Mg, Ca, P, K, Na) and decrease in chemically less mobile elements (Si, Fe) and (5) higher contents of organic carbon, nitrogen, and soluble forms of P and K, mainly concentrated in the clay fraction. These transformations are extremely important in the nutrients cycle, denoting that sediments represent an efficient sink for nutrients from the over-erosion of soils. Mineral and organic compounds can permanently or temporarily sequester these nutrients, recycling them and enhancing their availability through the slow release of components from relatively loose crystal structures. These processes can easily explain the enrichment in soluble and exchangeable forms of elements such as P, K, Ca or Mg. This study conclude that the particles recycling in a large tropical dam reservoir which receives high fluxes of allochthonous nutrients, has an important role in the good quality of sediments for agricultural use and in the profitable use of this technology to recover depleted soils in remediation projects in regions near large hydroelectric plants.  相似文献   

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