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1.
Summary. Magnetic extracts were prepared from samples of Upper Jurassic and Lower Cretaceous pelagic limestones from France and Spain. Thermomagnetic analysis of the magnetic extracts using a microbalance required careful monitoring of base weight changes during heating. Heating in argon gas atmosphere induced production of magnetite during heating while slight oxidation occurred during heating in air. the dominant Curie temperature detected by the thermomagnetic analyses was the 585°C Curie temperature of magnetite. the 680°C Curie temperature of haematite was only detected when isothermal remanent magnetism (IRM) data indicated large concentrations of haematite. Even when IRM data indicated its presence, the thermomagnetic analyses did not detect the Neel temperature of goethite. Although thermomagnetic analyses of magnetic extracts provide more direct identification of the dominant, strongly ferromagnetic minerals, IRM acquisition and subsequent thermal demagnetization is a superior technique in detecting high coercivity, weakly ferromagnetic minerals such as goethite and haematite.  相似文献   

2.
Rock magnetic parameters are often used to recognize variations in the original magnetic mineralogy and for normalizing purposes in palaeointensity studies. Incipient weathering, however, is shown to have a profound but partly reversible influence on the rock magnetic properties of the marls of the Early Pliocene Trubi formation in southern Sicily (Italy). The remanence in the marls resides in single-domain (SD) magnetite grains, but the remanent coercive force (Hcr) shows a strong variation and most values observed are anomalously high ( Hcr) range 36–188 mT).
The enhanced coercivities are attributed to stress in the magnetite grains induced by surface oxidation at low temperature. Upon heating to 150 °C a reduction of coercivities occurs that can be explained by a stress reduction as a result of a reduction of Fe2- gradient due to a higher diffusion rate at elevated temperature. After heating to 150 °C, coercivities are quite uniform throughout the outcrop and the values are characteristic of SD magnetite (Hcr range 30–38 mT). The bulk susceptibility increases by 4–24 per cent, and the isothermal remanent magnetization (IRM) decreases by 5–11 per cent. The increase in anhysteretic remanent magnetization (ARM) is large: 20–242 per cent. The magnitude of the changes is related to the degree of weathering.
Another effect of heating the marl samples to 150 °C is a substantial reduction of the coercivities of the secondary overprint in the natural remanent magnetization. After heating. separation of the secondary and primary components by alternating-field demagnetization is more efficient. The usual difficulties of thermal demagnetization above 300 °C may thus be avoided by a combination of moderate heating to 150 °C and subsequent alternating-field demagnetization.  相似文献   

3.
The time dependence of Isothermal Remanent Magnetization acquisition (tIRM) is a rapid, sensitive and inexpensive way to quantify the presence of ultrafine ferrimagnetic grains straddling the superparamagnetic–single domain grain size boundary, well suited for use in small rock magnetic laboratories. The technique is very selective to the presence of grains with a diameter of approximately 25 nm, and tIRM results correlate well with measurements of frequency dependent susceptibility without the need of correcting for the presence of paramagnetic minerals. A simple IRM acquisition model can be used to obtain quantitative abundance estimates for these ultrafine magnetic grains. Application of tIRM measurements to eleven soil profiles from the Midwestern United States shows that the abundance of ultrafine particles increases with precipitation, as long as the mean annual precipitation is below 850 mm a−1. Sites that developed under more humid conditions show a decrease in tIRM and likely SP abundance, probably caused by increased iron reduction and translocation during more common periods of reducing conditions.  相似文献   

4.
Summary. Titanomagnetites of composition Fe2.4-δAlδTi0.6O4 and Fe2.6-δAlδTi0–4O4(δ=0, 0.1 and 0.2 in both cases) were prepared in the monodomain state by pulverization of sintered synthetic material. In low fields, the thermoremanence (TRM) was found to be linear with inducing field and of high enough intensity to account for typical natural remanent magnetizations of fresh submarine basalts. The higher field TRM acquisition curves follow the Néel model curve for an assemblage of non-interacting identical particles in a general way only, the differences being due to interactions, or the range of particle blocking temperatures and volumes or other features of the samples not included in the model. The unblocking temperatures of low field TRM lie in a narrow range below the Curie point. The low field TRM is very resistant to alternating field demagnetization and provides a very striking illustration of the strength of the TRM mechanism in preserving a stable record of a weak magnetic field. The result of a Lowrie-Fuller test on the material is consistent with the monodomain state.  相似文献   

5.
Palaeomagnetic and geochronological measurements have been carried out on the late Pleistocene basaltic–andesitic unit of Monte Chirica–Costa Rasa, on the island of Lipari (Aeolian Archipelago). The lava flow sequence is about 10  m thick and has been sampled in detail. Magnetic properties are rather uniform; Curie temperatures of 540° to 580 °C, and the saturation IRM reached at applied values of 0.1  T point to titanomagnetite as the main magnetization carrier. Thermal and AF demagnetization have shown the presence of secondary magnetization components. These were removed mostly at 450°–500 °C or 20–30  mT, indicating a highly stable ChRM with directions from transitional to reverse. Where a ChRM could not be isolated by application of the demagnetization techniques, the converging remagnetization circles method gave a mean ChRM value fully comparable with that obtained from other methods. 40Ar/39Ar determinations were performed on two lava flows, in the lower and upper parts of the sequence. The former shows a transitional ChRM direction and a whole-rock age of 157±12  ka, the latter a reverse direction, a whole-rock age of 143±17  ka and a ground-mass age of 128±23  ka. The radiometric data and the reconstructed stratigraphy, which indicate ages of 150±10  ka and 104±3.5  ka, respectively, for the volcanic units at the bottom and top of the Monte Chirica–Costa Rasa unit, suggest that the reverse directions recorded in Lipari are related to the Blake event.  相似文献   

6.
利用采自干旱区高山～新疆阿尔泰山的表层泥炭样品,以K-T曲线为主,结合J-T曲线、磁滞参数以及XRD等相关实验,探讨了应用热磁实验鉴别富含有机质的弱磁性物质磁性特征.结果表明:样品中磁化率的主要贡献者为低矫顽力的强磁性矿物-磁铁矿,磁铁矿的粒径为PSD(准单畴).加热过程中,含铁粘土矿物绿泥石分解生成新的磁铁矿,磁畴转变成MD(多畴),逐步加热的K-T曲线表明,利用K-T曲线分析含有大量有机质成分弱磁性物质的磁性特征具有一定的指导作用,泥炭样品受热生成的磁性矿物的类型与数量不仅受加热的最高温度控制,同时在加热到不同温度时由于有机质对磁性矿物的还原作用表现出差异性,使得泥炭样品加热到不同温度后的转化、改造及最终生成物亦变得异常复杂.  相似文献   

7.
Summary. Remanent acquisition curves, remanent hysteresis curves and alternating field demagnetization curves were determined for a number of artificial rock specimens containing well-defined grain-size fractions between 5 and 250 μm of natural magnetite, titanomagnetite and hematite. From these curves, the remanent acquisition coercive force H 'cr, the remanent coercive force H cr and the median destructive field of IRM H ½I were determined. Theoretically these parameters should be the same for an assembly of non-interacting, homogeneously distributed, randomly oriented single-domain grains. For a given hematite specimen H 'cr, H cr and H ½I have about the same value in spite of the strong grain-size dependence of these parameters. For each specimen of magnetite and titanomagnetite the value of H 'cr is larger than H cr which again is larger than H ½I. However, the ratios H 'cr/ H cr and H ½I/ H cr appear to have a (different) constant value. An interesting relationship which appears to hold for dispersed magnetite, titanomagnetite or hematite grains between 5 and 250 μm, independently of grain-size, quantity and packing density of the magnetic material, is:   相似文献   

8.
Summary. The Cordova gabbro of southern Ontario intrudes 1300 Myr old volcanic rocks of the Hastings Lowlands in the Grenville Structural Province. Three distinct vector magnetizations (A, B and C) have been isolated, using a combination of stable endpoints, subtracted vectors from orthogonal vector plots and converging remagnetization circles. The A magnetization, with mean direction D = 294° I =– 55.5° ( k = 42, α95= 5.5°, N = 18 sites), is a high coercivity, high blocking temperature remanence recorded by 49 samples. The B magnetization was isolated in 33 samples and has a mean direction D = 305.5° I =– 1.5° ( k = 24, α95, N = 11 sites). B has lower coercivities and blocking temperatures than A where the two are superimposed. The A and B palaeopoles, 151°E, 10.5°S ( dp = 6°, dm = 8°) and 165.5°E, 24°N ( dp = 5°, dm = 9.5°), fall on the Grenville Track around 900 and 820 Ma respectively. The A and B magnetizations thus date from uplift and cooling following the Grenvillian orogeny. The third magnetization, the C component, has been isolated in 23 samples. Its mean direction is D = 180° I = 27.5° ( k = 18, α95= 10.5°, N = 12 sites). The C is a low coercivity, low blocking temperature overprint of A and B. Its palaeopole, 102°E, 31°N ( dp = 6.5°, dm = 12°), is unlike post-1300 Precambrian poles for cratonic North America but matches Silurian and late Ordovician poles. 40Ar/39Ar plateau ages of 446 and 447 Ma determined by Lopez-Martinez and York for plagioclases from one of the Cordova samples confirm this age assignment. The C magnetization therefore records a previously unrecognized mild thermal or hydrothermal event that occurred in Palaeozoic time, long after the Grenvillian orogeny.  相似文献   

9.
The Middle and Upper Jurassic Bathonian-Oxfordian shallow-water carbonate rocks from the Paris Basin, France, consist mainly of oolitic and bioclastic limestones that are hydrocarbon reservoirs in the subsurface. Despite a preliminary positive study, these deposits have been considered to be largely remagnetized (Rochette, private communication), and hence not amenable to palaeomagnetic dating. To establish their magnetic mineralogy and test this remagnetization hypothesis, we have used an integrated investigation combining petrographic, geochemical, rock-magnetic and palaeomagnetic measurements on samples extracted from five cores from the Paris Basin and from outcrops in Burgundy. Magnetic minerals in the Bathonian-Oxfordian carbonates include: (1) primary biogenic single-domain magnetite and detrital multi-domain Ti-magnetite and their oxidized form, maghemite; (2) authigenic spheres of magnetite probably related to hydrocarbons; and (3) goethite, either restricted to ferruginous ooid layers or resulting from surficial alteration, notably replacement of pyrite framboids. Rock-magnetic experiments carried out on 68 samples reveal H cr/ H c and M rs/ M s ratios ranging from 1.88 to 5.58 and 0.017 to 0.314, respectively. These values are clearly distinct from diagnostic values for a chemical remagnetization. Pyrrhotite was not identified within these sediments. Moreover, the average H cr/ H c ratio of 3.14 is significantly different from the value of 1.333 for natural pyrrhotite (Dekkers 1988). These results have a direct implication for the preservation of the primary magnetization; consequently, these deposits are selectively amenable for magnetostratigraphic dating and possible regional correlations.  相似文献   

10.
A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe3S4, during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution.  相似文献   

11.
Upper Jurassic red sandstones and red siltstones were collected from 67 layers at 12 localities in the Penglaizhen formation. This formation is in the north of Bazhong county (31.8°N, 106.7°E) in the Sichuan basin, which is located in the northern part of the Yangtze craton. Thermal demagnetization isolated a high-temperature magnetic component with a maximum unblocking temperature of about 690 °C from 45 layers. The primary nature of the magnetization acquisition is ascertained through the presence of magnetostratigraphic sequences with normal and reversed polarities, as well as positive fold and reversal tests at the 95 per cent confidence level. The tilt-corrected mean direction of 36 layers is D = 20.0°, I = 28.8° with α 95 = 5.8°. A Late Jurassic palaeomagentic pole at 64.7°N, 236.0°E with A 95 = 7.0° is calculated from the palaeomagnetic directions of 11 localities. This pole position agrees with the two other Late Jurassic poles from the northern part of the Yangtze craton. A characteristic Late Jurassic pole is calculated from the three poles (68.6°N, 236.0°E with A 95 = 8.0°) for the northern part of the Yangtze craton. This pole position is significantly different from that for the southern part of the Yangtze craton. This suggests that the southern part of the Yangtze craton was subjected to southward extrusion by 1700 ± 1000  km with respect to the northern part. Intracraton deformation occurred within the Yangtze craton.  相似文献   

12.
Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na6[H2W12O40], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.  相似文献   

13.
TRM deviations in anisotropic assemblages of multidomain magnetite   总被引：2，自引：0，他引：2  
Anisotropic assemblages of multidomain magnetite particles develop an anisotropy of magnetic susceptibility (AMS), which in turn induces deviations of thermo-remanent magnetization (TRM) from the field direction. From the theories of multidomain TRM acquisition, it is shown that the TRM anisotropy tensor has its eigenvalue ratios ( T i) related to the principal weak-field susceptibility ratios ( P i) by the order of magnitude T i≃ P 2i. This relation has been experimentally verified on two sets of highly anisotropic rock samples. The exponent has been determined to be 1.94 in the samples from a Peruvian gabbro, and 1.81 in those from the granite of Flamanville (NW France). Accounting for experimental difficulties in determining the TRM anisotropy tensors, these exponents are judged to agree well with the expected one. It is therefore stressed that AMS measurements provide a good means of evaluating the magnetic field direction from deviated TRM directions, providing magnetic carriers are mainly multidomain magnetites.  相似文献   

14.
A paleomagnetic study of the Mull lava succession   总被引：1，自引：0，他引：1  
Summary. A paleomagnetic study has been made of a succession of 139 non-overlapping basaltic lavas, representing 91 per cent of the longest remaining succession of flows associated with the Paleogene Mull volcano. All the lavas have experienced considerable hydrothermal alteration, probably at up to several million years after initial magnetization and frequently with alteration to the opaque minerals and the production of new potentially magnetic phases. The question of whether directional remagnetization has taken place while preserving within-unit directional consistency and discreteness of unit mean direction is discussed. Extensive directional remagnetization is excluded as an explanation for the data. If stable directions obtained by alternating field remanence cleaning coincide with original TRM directions then a mean pole position for all temporally independent lava directions from the British Tertiary igneous province is at 71.9° N, 167.2° E, with k:22 and α95:3.0°. This pole is significantly different from the geographic pole. If the difference in palaeomagnetic and geographic poles is interpreted in terms of absolute plate motion, then 2010 km of northwards motion of the western part of the Eurasian Plate, at 3.7 cm/yr, has taken place over the last 55 Myr. This motion has implications for the geological history of the Arctic and for the complexity of mantle motions.  相似文献   

15.
Summary. The motion of a phase boundary in the Earth caused by temperature and pressure excitations at the Earth's surface is determined under a linear approximation. The solution is found as a sum of convolutions of pressure and temperature Green's functions with the corresponding excitations. The Green's functions are given under the form of Laplace transforms that can be inverted either by numerical evaluation of a branch cut integral or by inversion of a series expansion. This solution is a generalization of a solution previously derived by Gjevik. This latter solution is the first term in the series expansion. The relaxation times associated with the phase boundary motion are of the order of 105–107yr for the olivine—spinel phase transition and of 106–107yr for the basalt—eclogite transition. The linear approximation remains valid for long times only if the phase boundary moves slowly.  相似文献   

16.
Summary. 40Ar-39Ar incremental heating studies have been carried out on samples taken from the Tudor Gabbro, Grenville Province, Ontario. In an earlier K-Ar study, these rocks have yielded an isochron age of ∼700 Ma together with very high initial argon ratios. Age spectrum plots on whole-rock samples, in general, display a saddle-shaped character, with two of them exhibiting minima close to 700 Ma. No clear plateaus are observed for these rocks. A hornblende separate records the time ∼1110 Ma at which the stock finally cooled through the ∼590°C isotherm. The Tudor Gabbro was probably intruded into an area undergoing middle-amphibolite facies meta-morphism about 1180 Ma ago. The age spectra of two whole-rock samples together with that of their plagioclase separates, suggest that the stock cooled to ∼200–250°C at about 720 Ma. Slow cooling, averaging about 1°C Ma−1 is indicated for this section of the Grenville Province for the period 1100–700 Ma. If the age of the Tudor Gabbro's palaeomagnetic pole position is taken to be 720 Ma, the Hadrynian Track Hypothesis leads to very high polar wander rates of > 20cm a−1 for the period 820–720 Ma. If this hypothesis is rejected, the average drift rate for this period would be ∼4 cm a−1, in much better agreement with published values of ∼5 cm a−1 for the period 1400–820 Ma.  相似文献   

17.
Summary. Large, well-characterized single-crystals of titanomagnetite of approximate composition Fe2.4Ti0.6O4 were ground into spheres and orientated along specific crystallographic axes. The field dependences of the thermoremanent magnetization (TRM) and the temperature dependences of the magnetic hysteresis properties were measured and evaluated against the available theoretical models. The models, of necessity simplifications of real materials, were unable to account for many features of the experimental curves. The discrepancies were partly resolved by consideration of the mode of blocking of each individual coercivity fraction. It was deduced that the domain-walls were pinned by both dislocation lines and by inclusions or voids. A fraction of the walls were not thermally blocked. They could however be thought of as being blocked isothermally as the applied field was relaxed. The proportion of remanence blocked in by each process was found to be dependent on the strength of the inducing field through the field dependence of the blocking temperatures. A simplified model, taking these effects into account, was developed. This predicts the main features of the TRM acquisition curve and of the alternating field and thermal demagnetization spectra.  相似文献   

18.
We report on calculations of the on-shore run-up of waves that might be generated by the impact of subkilometre asteroids into the deep ocean. The calculations were done with the COULWAVE code, which models the propagation and shore-interaction of non-linear moderate- to long-wavelength waves  ( kh < π)  using the extended Boussinesq approximation. We carried out run-up calculations for several different situations: (1) laboratory-scale monochromatic wave trains onto simple slopes; (2) 10–100 m monochromatic wave trains onto simple slopes; (3) 10–100 m monochromatic wave trains onto a compound slope representing a typical bathymetric profile of the Pacific coast of North America; (4) time-variable scaled trains generated by the collapse of an impact cavity in deep water onto simple slopes and (5) full-amplitude trains onto the Pacific coast profile. For the last case, we also investigated the effects of bottom friction on the run-up. For all cases, we compare our results with the so-called 'Irribaren scaling': The relative run-up   R / H 0=ξ= s ( H 0/ L 0)−1/2  , where the run-up is   R , H 0  is the deep-water waveheight, L 0 is the deep-water wavelength, s is the slope and ξ is a dimensionless quantity known as the Irribaren number. Our results suggest that Irribaren scaling breaks down for shallow slopes   s ≤ 0.01  when  ξ < 0.1 − 0.2  , below which   R / H 0  is approximately constant. This regime corresponds to steep waves and very shallow slopes, which are the most relevant for impact tsunami, but also the most difficult to access experimentally.  相似文献   

19.
Low-field magnetic susceptibility and its anisotropy (AMS) were measured for a suite of sandstone and siltstone samples. AMS orientations measured on two systems (Bartington and Digico) differed before thermal treatment of the samples but became the same after thermal demagnetization in air to 600 °C. Six position measurement schemes for the Bartington system do not eliminate the effects of specimen inhomogeneity and other errors, whereas 12- and 24-position measurements give good agreement with the Digico anisotropy meter and with the observed petrofabric. Thermal demagnetization from temperatures between 400 and 650 °C had the effect of enhancing both the magnetic susceptibility and AMS. Although the most profound mineralogical change due to heating was the conversion of kaolinite into metakaolin, IRM, XRD, DTA and Mössbauer spectroscopic analysis demonstrate that the changes in magnetic properties were due to the transformation upon heating of trace amounts of sulphides into magnetite and/or maghemite and haematite. Both magnetic susceptibility and the degree of anisotropy decrease with higher-temperature thermal demagnetization due to the oxidation of the newly formed magnetite and/or maghemite into haematite. The magnetic foliation of the newly formed magnetite/maghemite and haematite is parallel to the bedding, possibly following the orientation of the original sulphides.  相似文献   

20.
A detailed record of mineral magnetic properties of a loess–palaeosol profile comprising seven loess horizons, six interbedded palaeosols and recent soil at the top in NE Bulgaria is analysed. A strong contrast between the soil and loess susceptibilities as well as other concentration-dependent hysteresis parameters is present, similar to the well-documented magnetic characteristics of the Chinese loess ( Hus & Han 1992 ; Maher & Thompson 1992 ; Heller & Evans 1995 ; Hunt et al. 1995 ). The magnetic enhancement of the palaeosol units is caused by very fine-grained pedogenic magnetite with superparamagnetic behaviour. Thermomagnetic analyses on bulk material suggest magnetite and maghemite as the main ferrimagnetic carriers in both soil and loess horizons. Their relative proportions are shown to reflect different palaeoclimatic conditions. Chernozem soils, which include recent soil S0 and first and second palaeosols S1 and S2 developed under steppe vegetation, show a high degree of low-temperature oxidation of the pedogenic magnetite to maghemite. This material is characterized by coercive force H c showing even higher values than those of the parent loess material. The older palaeosols (S4 to S6 ) were formed during more humid climatic conditions and therefore probably developed as forest types. Rock magnetic data suggest the existence here of only partly oxidized magnetite grains. The behaviour of the thermomagnetic curves, characterized by a kink at 200 °C, may be due to either a release of internal stress (built up as a result of partial low-temperature oxidation) or interactions between two phases.  相似文献   

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