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1.
The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

2.
Shale gas has currently attracted much attention during oil and gas exploration and development. Fractures in shale have an important influence on the enrichment and preservation of shale gas. This work studied the developmental period and formation mechanism of tectonic fractures in the Longmaxi Formation shale in the Dingshan area of ??southeastern Sichuan Basin based on extensive observations of outcrops and cores, rock acoustic emission (Kaiser) experiments, homogenization temperature of fracture fill inclusions, apatite fission track, thermal burial history. The research shows that the fracture types of the Longmaxi Formation include tectonic fractures, diagenetic fractures and horizontal slip fractures. The main types are tectonic high-angle shear and horizontal slip fractures, with small openings, large spacing, low densities, and high degrees of filling. Six dominant directions of the fractures after correction by plane included NWW, nearly SN, NNW, NEE, nearly EW and NW. The analysis of field fracture stage and fracture system of the borehole suggests that the fractures in the Longmaxi Formation could be paired with two sets of plane X-shaped conjugate shear fractures, i.e., profile X-shaped conjugate shear fractures and extension fractures. The combination of qualitative geological analysis and quantitative experimental testing techniques indicates that the tectonic fractures in the Longmaxi Formation have undergone three periods of tectonic movement, namely mid-late Yanshanian movement (82–71.1 Ma), late Yanshanian and middle Himalaya movements (71.1–22.3 Ma), and the late Himalayan movement (22.3–0 Ma). The middle-late period of the Yanshanian movement and end of the Yanshanian movement-middle period of the Himalayan movement were the main fracture-forming periods. The fractures were mostly filled with minerals, such as calcite and siliceous. The homogenization temperature of fracture fill inclusions was high, and the paleo-stress value was large; the tectonic movement from the late to present period was mainly a slight transformation and superposition of existing fractures and tectonic systems. Based on the principle of tectonic analysis and theory of geomechanics, we clarified the mechanism of the fractures in the Longmaxi Formation, and established the genetic model of the Longmaxi Formation. The research on the qualitative and quantitative techniques of the fracture-phase study could be effectively used to analyze the causes of the marine shale gas fractures in the Sichuan Basin. The research findings and results provide important references and technical support for further exploration and development of marine shale gas in South China.  相似文献   

3.
The marine primary producers assimilate the atmospheric CO2 to form the organic carbon in surface water. The organic carbon then settles down through the water column and is removed from the oceans by final preservation in sediments in the form of petroleum or nature gases. The reconstruction of paleoproductlvity will thus improve our understanding of the biological processes in the formation of fossil energy resource and help to locate new sites for future exploration. In this study, biorelated elements P, Cd, Al, Ba, as well as redox sensitive element Mo, were analyzed in the 448 rock samples collected from Permian strata at the Shangsi (上寺) Section, Guangyuan (广元), Northeast Sichuan (四川) in China. On the basis of the Ti content, the nondetrital contents of P, Ca, and Al, denoted as Pxs, Cdxs, and Alxs, were calculated and found to coincide with the TOC content throughout the whole section, with some enrichment intervals being found in the middle part of Chihsia Formation, topmost Maokou (茅口) Formation, and Dalong (大隆) Formation. This suggests that the biorelated elements could be used as proxies for the paleoproductivity here in this section. Baxs, a paleoproductivity indicator widely used in the paleoceanography, shows insignificant correlation with TOC, Pxs, Cdxs, and Alxs, probably arising from the loss of biological barium in anoxic conditions. Compiled with the data of TOC content and Pxs Cdxs, and Alxs, three episodes of enhanced paleoproductivity were identified in Permian strata including the middle part of Chihsla Formation, topmost Maokou Formation, and Dalong Formation.  相似文献   

4.
Early Paleozoic black organic sediments and bentonites occur widely in the craton basin within the Yangtze block and are generally believed to be genetically related to a specific tectonic setting on the cratonic boundary. However, the intimate relationship between their origins and the dynamic mechanisms are unclear, as exemplified by the genesis of the black shale series and bentonites from the Wufeng Formation during the Ordovician–Silurian transition (OST). In order to reveal the relationship between the Wufeng Formation and the convergence of the Yangtze and Cathaysia blocks (i.e., the intracontinental Kwangsian Orogeny), two stratigraphic sections respectively in Zhaotong area (Northeast Yunnan) and Puyi area (Northwestern Guizhou) that were located in the semi-restricted inner Yangtze Sea during the OST were systematically studied, on the basis of whole-rock geochemical composition, pyrite δ34S (δ34Spy), total organic carbon (TOC), stable Sr isotope, pyrite framboid size distribution and zircon U-Pb age, trace elements. The evidence shows that the paleo-oceanic environment changed significantly at the turn of the early–late Katian and formed the black shale series in the Wufeng Formation. These acritarch assemblages were formed in the transition process of the Upper Yangtze Basin from passive continental margin basin to foreland basin during this interval. Based on previous research on the genetic relationship between black shale series and plate tectonic movement, a basin-mountain evolution model suitable for South China in the Late Ordovician is presented. The two bentonites in the Wufeng Formation with U-Pb ages of 445.5 ± 0.8 Ma and 441.9 ± 2.4 Ma primarily originated from the intermediate–acid volcanic eruption during the collision and convergence between the Yangtze and Cathaysia blocks in the Late Ordovician, the provenance region probably being located in the Jiangnan orogenic belt. Thus, we believe that the appearance of the black shale series and bentonite in the Wufeng Formation at the turn of the early–late Katian may represent the initiation of basin-mountain transformation and the Kwangsian Orogeny in South China, which provides important evidence for the collision and convergence of the Yangtze and Cathaysia blocks in the Late Ordovician.  相似文献   

5.
The mechanism of sedimentary transition from the Cretaceous black shales to the oceanic red beds is a new and important direction of Cretaceous research. Chemical sequential extraction is applied to study the burial records of reactive phosphorus in the black shale of the Gyabula Formation and oceanic red beds of the Chuangde Formation, Southern Tibet. Results indicate that the principal reactive phosphorus species is the authigenic and carbonate-associated phosphorus (CaP) in the Gyabula Formation and iron oxides-associated phosphorus (FeP) in the Chuangde Formation which accounts for more than half of their own total phosphorus content. While the authigenic and carbonate-associated phosphorus (CaP) is almost equal in the two Formations; the iron oxides-associated phosphorus is about 1.6 times higher in the Chuangde Formation than that in the Gyabula Formation resulting in a higher content of the total phosphorus in the Chuangde Formation. According to the observations on the marine phosphorus cycle in Modern Ocean, it is found that preferential burial and regeneration of reactive phosphorus corresponds to highly oxic and reducing conditions, respectively, leading to the different distribution of phosphorus in these two distinct type of marine sediments. It is the redox-sensitive behavior of phosphorus cycle to the different redox conditions in the ocean and the controlling effects of phosphorus to the marine production that stimulate the local sedimentary transition from the Cretaceous black shale to the oceanic red beds.  相似文献   

6.
The Qom Formation comprises Oligo-Miocene deposits from a marine succession distributed in the Central Basin of Iran. It is composed of five members designated as A-F. Little previous work exists on the sequence stratigraphy. Based on an integrated study of sequence stratigraphy with outcrop data, wells and regional seismic profiles, the Qom Formation is interpreted as a carbonate succession deposited in a mid-Tertiary back-arc basin. There are two second-order sequences (designated as SS1 and SS2) and five third-order sequences (designated as S1-S5). Five distinct systems tracts including transgressive, highstand, forced regressive, slope margin and lowstand have been recognized. The relationship between the sequences and lithologic sub-units has been collated and defined (S1 to S5 individually corresponding to A-C1, C2-C4, D-E, the lower and upper portions of F); a relative sea level change curve and the sequence stratigraphic framework have been established and described in detail. The coincidence of relative sea level change between that of the determined back-arc basin and the world indicates that the sedimentary cycles of the Qom Formation are mainly controlled by eustatic cycles. The variable combination of the systems tracts and special tectonic-depositional setting causally underpin multiple sequence stratigraphic framework styles seen in the carbonates of the back-arc basin revealing: (1) a continental margin basin that developed some form of barrier, characterized by the development of multiple cycles of carbonate-evaporites; (2) a flat carbonate ramp, which occurred on the southern shelf formed by the lack of clastic supply from nearby magmatic islands plus mixed siliciclastics and carbonates that occurred on the northern shelf due to a sufficient clastics supply from the land; and (3) a forced regressive stratigraphic stacking pattern that occured on the southern shelf and in basin lows due to the uplifting of the southern shelf. Thick and widespread aggradational framework limestone usually occurs in the initial sequences (S1 and S3) of the supersequence, which led to preferential oil reservoir deposition but a lack of source and cap rocks, whereas the retrogradational and progradational framework limestone usually occurs in the later sequences (S2 and S4-S5) of the supersequence, which results in two perfect sets of source, reservoir and cap rock assemblies, so that the limestone in sub-member C2-C4 and the F-Member can be predicted as important objects for oil exploration.  相似文献   

7.
<正>Objective At present,there is controversy regarding the existence of marine-terrestrial transitional facies that can act as a source of shale gas.This detailed study of CarboniferousPermian age geological data from the northern Shaanxi area(China)provides new insight for this type of shale gas.In addition,a new deposition and accumulation pattern for this type of shale gas is established.Thus,the objectives of this study were to identify high quality gasbearing shale intervals in the lithological column of the  相似文献   

8.
The common microscale to nanoscale pore types were introduced and divided into organic and inorganic pores to estimate their contributions to porosity in the Lower Silurian Longmaxi Formation shale of southeast Chongqing. Following the material balance principle, the organic porosity values, which changed with formation subsidence and thermal evolution, were calculated using chemical kinetics methods and corrected via the organic porosity correction coefficient, which was obtained from field emission scanning electron microscopy. Grain density values were determined using the contents and true densities of compositions in the shale samples. The total porosity was calculated based on the grain and bulk densities. The inorganic porosity was determined from the difference between the total porosity and organic porosity at the same depth. The results show that inorganic pores mainly contain microfractures, microchannels, clay intergranular pores, intercrystalline pores and intracrystalline pores in the Lower Silurian Longmaxi Formation shale of southeast Chongqing. Organic pores mainly include organopore and fossil pore. The total porosity, organic porosity and inorganic porosity of organic-rich shale samples can be quantitatively evaluated using this method. The total porosity, organic porosity and inorganic porosity values of the Longmaxi Formation shale samples from the well Py1 in southeast Chongqing lie in 2.75%–6.14%, 0.08%–2.52% and 1.41%–4.92% with average values of 4.34%, 0.95% and 3.39%, respectively. The contributions of the inorganic pores to the total porosity are significantly greater than those of the organic pores.  相似文献   

9.
The successful exploration and production of shale-gas resources in the United States and Canada sets a new possible solution towards the energy crisis presently affecting most countries of Asia. This study focuses on the use of well log and 2D seismic data for the characterization of the shale oil/gas potential of a Paleocene–Eocene succession — the Meyal area in the Potwar Basin of Pakistan. Two shaly plays are identified in Paleocene–Eocene strata in well logs using ΔLogR and modified ΔLogR cross-plot techniques. The results indicate that Paleocene shale(the Patala Formation) and the lower shaly part of Eocene limestone(Sakesar Formation) can be potentially mature source rocks. However, the thermal maturity modelling proves that only the Paleocene shale is mature. Our results also suggest that the maturity responses on ΔLogR models for the lower shaly part of the Eocene limestone are due to trapped hydrocarbons in the intra-formational fractures. Petroelastic/petrophysical analysis of the Patala Formation reveals two potential shale oil/gas zones on the basis of Young's modulus, Poisson's ratio, Brittleness index and Total Organic Content at an exploitation depth of 3980–3988 m. This work can provide valuable insight for estimating shale oil/gas potential in highly deformed basins not only in Asia but in other parts of the world.  相似文献   

10.
Abstract: This study is based on the sedimentation conditions, organic geochemistry, storage spaces, physical properties, lithology and gas content of the shale gas reservoirs in Longmaxi Formation of the Jiaoshiba area and the gas accumulation mode is summarized and then compared with that in northern America. The shale gas reservoirs in the Longmaxi Formation in Jiaoshiba have good geological conditions, great thickness of quality shales, high organic content, high gas content, good physical properties, suitable depth, good preservation conditions and good reservoir types. The quality shales at the bottom of the deep shelf are the main target interval for shale gas exploration and development. Shale gas in the Longmaxi Formation has undergone three main reservoiring stages: the early stage of hydrocarbon generation and compaction when shale gas reservoirs were first formed; the middle stage of deep burial and large-scale hydrocarbon generation, which caused the enrichment of reservoirs with shale gas; the late stage of uplift, erosion and fracture development when shale gas reservoirs were finally formed.  相似文献   

11.
The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains: (1) sapropelic I organic matter; (2) a 40-m thick bedded sequence where total organic carbon (TOC) content is > 2%; (3) a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and (4) a mean methane adsorption capacity of 1.80 cm3/g (7 MPa pressure). A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.  相似文献   

12.
With the aid of geophysical measurements, including seventeen two-dimensional(2 D) seismic lines and the well logging curves of well FGY1, the structure and reservoir characteristics of the Upper Ordovician–Lower Silurian strata in the Fenggang block, northern Guizhou Province, were analyzed thoroughly to identify desert areas and favorable intervals. The results show that Longmaxi-Wufeng is the most prospect-rich formation, consisting of a thick succession of overmature black shale, this formation remaining partially in the Suiyang, Fenggang and Jianchaxi synclines. The Longmaxi-Wufeng shale, especially the lower member, was deposited in a reducing low-energy environment with relatively high U content and a low Th/U value. In this shale, the organic matter type(sapropelic and humic-sapropelic), total organic carbon(TOC) content, gas content, gas adsorption capacity, vitrinite reflectance and brittle mineral content are profitable for shale gas preservation and development. The fractures of this shale were closed because of its high overburden pressure. The gas adsorption capacity of this shale increases with increasing TOC content and Ro. In the Longmaxi-Wufeng Formation at well FGY1, the most favorable intervals are in the depth ranges of 2312.4–2325.1 m and 2325.8–2331.1 m.  相似文献   

13.
In this study, organic geochemical and petrological analyses were conducted on 111 shale samples from a well to understand the retention, intraformational migration and segmented accumulation(shale oil enrichment in different intervals is unconnected) features of shale oil within the organic-rich shale in the Qingshankou Formation of the Gulong Sag. Our study shows that retained petroleum characteristics in the investigated succession are mainly influenced by three factors: organic richness, int...  相似文献   

14.
To enable the lithostratigraphic and biostratigraphic study of the Gurpi Formation,within the ‘Dezak’ or Globigerina Marl,a stratigraphic section at Booraki,located to the NNW of Shiraz,SW Iran,through the late Cretaceous was examined.The formation consists of shale and greenish-gray marls interbedded with cream limestone,brown sandstones and siltstones with an exposed thickness of 160 m in the studied section.Samples were taken at regular intervals in all yielding 14 genera and 16 different species of benthic and planktic foraminifera that allowed determination of the age of the beds as Maastrichtian.To examine the paleoecology of the formation,some important ecological factors including water level,salinity,and oxygen regime change during the depositional courses of the formation were analyzed.The density of foraminiferans decreases from the base to top of the Gurpi Formation whereas the ratio of planktic to benthic Foraminifera(i.e.,P/B) and proportion of shallow-water fauna increase.These foraminiferal changes indicate an increase and decrease in depth,temperature,salinity and oxygen,respectively,at the base and top of the Formation.  相似文献   

15.
Geochemical analysis of sandstones from the Sardar Formation (from two stratigraphic successions) in east-central Iran were used for identification of geochemical characterization of sandstones, provenance and tectonic setting. Sandstones in the two lithostratigraphic successions have similar chemical compositions suggesting a common provenance. Bulk-rock geochemistry analysis of Carboniferous sandstones from Sardar Formation indicates that they are mainly quartz dominated and are classified as quartzarenites, sublitharenites and subarkoses, derived from acid igneous to intermediate igneous rocks. Discrimination function analysis indicates that the sandstones of Sardar Formation were derived from quartzose sedimentary provenance in a recycled orogenic setting. Also, major and trace elements in sandstones of Sardar Formation (e.g., K2O/Na2O vs. SiO2) indicate deposition in a stable passive continental margin (PM). Chemical index of alteration (CIA) for these rocks (> 65%) suggests a moderate to relatively high degree of weathering in the source area.  相似文献   

16.
Auriferous quartz veins in the Bankuan gold deposit occur in the interlayer broken zone of the basal conglomerate of the Tietonggou Formation or at the unconformity between the Tietonggou Formation and the crystalline basement.The composition of fluid inclusions in the minerals indicates that the nature and composition of ore-forming hydrothermal solutions show a drastical change soon after the solutions reached the Tietonggou Formation from the crystalline basement,resulting in gold precipitation.So the Bankuan gold deposit can be assigned to the conglomerate stata-bound-type deposits.137 thermometric data are concentrated in the three ranges 400-340℃,330-220℃ and 180-160℃,representing three episodes of metalogenesis,Oxygen isotope studies demonstrate the evolution of ore-forming hydrothermal solutions from early metamorphic to late meteoric,Diversity of ore-forming materials dominated by deep-source material is supported by sulphur and lead isotope data.From the above discussions it may be concluded that the deposit formed by metamorphism induced as a result of Mesozoic northward intracontinental subduction along the Machaoying fault.  相似文献   

17.
Early Cambrian shale is an important petroleum source rock around the world. Because of little drilling data and poor seismic data, until recently, organic matter enrichment of the Lower Cambrian Yuertusi and Xishanbulake formations shale is still an enigma in the Tarim Basin, northwestern China. Total organic carbon (TOC), major and trace element data of Cambrian shale samples from five boreholes have been analyzed to decipher the mechanism of the organic matter enrichment. The results show that the shales deposited in the western restricted intraplatform have much higher TOC contents (3.2%–19.8%, on average 11.0%) than those from the eastern basin (2.2%–10.2%, on average 4.5%). The paleoproductivity proxies (Ba, Ba/Al, P/Al) in the western restricted platform are much higher than those in the eastern basin. The trace element indicators such as V/Cr, Ni/Co, Mo–TOC and MoEF–UEF suggest an anoxic environment across the basin, but a more restricted environment in the western intraplatform. The paleoproductivity rather than anoxic condition and hydrothermal activity are concluded to have resulted in the differentiation of the organic matter enrichment from the western intraplatform to eastern basin in the early Cambrian shales; the restricted environment was favorable for paleoproductivity and preservation of organic matter.  相似文献   

18.
In the Lower CretaceousMcMurray-Clearwater succession of the intracontinental Alberta Foreland Basin,Canada,detrital zircon U-Pb geochronology samples(referred to herein as DZ samples)have been used to interpret the strata as representing a paleo-continental-scale drainage system.However,the majority of DZ samples are relatively small(n≈90–100),and syndepositional DZ(i.e.,crystallization age<5 Ma older than depositional age)are rare.This has forced a reliance on dinocysts with long stratigraphic ranges to chronostratigraphically subdivide the McMurray-Clearwater succession rather than employing maximum depositional ages(MDAs)derived from DZ samples.Herein,43 DZ samples(taken from20 subsurface cores)are assigned to 1 of 5 stratigraphic intervals,and in each stratigraphic interval all associated DZ samples are combined to produce a grouped DZ sample.Analysis and comparison of individual and grouped DZ samples are used to(1)assess variability in provenance through time and space,and(2)assess the accuracy of chronostratigraphically subdividing the succession using MDAs.Along the main paleo-drainage axis,a comparison of dissimilarity between DZ samples from the same stratigraphic interval,as well as between stratigraphic intervals,reveals increasing average dissimilarity between individual DZ samples and their respective grouped DZ samplewith increasing spatial separation of samples.These data indicate that in the McMurray Depocenter some sediment is sourced from local tributaries,leading to geographical provenance variability.CalculatedMDAs for all 43 DZ samples and groupedMDAs(gMDAs)for the 5 grouped DZ samples are compared to an ash-derived absolute age and existing biostratigraphy.In theMcMurray Formation,comparison of MDAs to gMDAs shows that in basins with rare syndepositional DZ,the gMDA method improved depositional age estimates by transforming low-confidence MDAs(e.g.,youngest single grains)into high-confidence(multi-grain)gMDAs.In the Clearwater Formationwhere syndepositional DZ are plentiful(i.e.,>5%of the total DZ population),calculating maximumlikelihood ages fromgrouped DZ samples avoids negatively biased(i.e.,too young)MDAs.We suggest grouped DZ samples and the gMDA method be used in systems with multiple DZ samples from a well-defined stratigraphic interval as a means of assessing variability in provenancewithin a depositional system and for improving estimates of depositional ages using DZ.  相似文献   

19.
From a fresh field investigation, it has been ascertained that the Late Palaeozoic Yu'erhong (Yuernhung) flora from Yu'erhong, Yumen, Gansu, northwestern China, studied by Bohlin in 1971 includes plants from the Westphalian Yangfukou Formation and the Stephanian to Sakmarian Taiyuan Formation. The Yu'erhong flora from the Yanghukou Formation is dominated by Euramerican elements with a few elements of the Cathaysian flora. No Angarian elements have be found in this section for lack of Late Permian strata. The specimens studied by Bohlin might possibly come from the upper part of the Upper Permian at tne southeastern corner . of the Yu'erhong basin. Those fossils from different horizons and localities might be mixed with each other during collection ;so they fail to reflect the exact horizon of certain plant fossils.  相似文献   

20.
A new genus with one new species and five new species of genus Amblomma of fossil ommatids are described and illustrated: Euryomma tylodes gen. et sp. nov., Amblomma cyclodonta sp. nov., Amblomma miniscula sp. nov., Amblomma porrecta sp. nov., Amblomma eumeura sp. nov., and Amblomma protensa sp. nov. All of them were collected from the Upper Jurassic or Lower Cretaceous Yixian Formation of western Liaoning, China. A key to the species of Amblomma is given. The wide epipleural space shows that Euryomma may be a primitive genus in Ommatidae. Many different species of Amblomma occurred within the same sedimentary horizon in this area could be environmental changes caused by frequent volcanic activities during the deposition of the Yixian Formation.  相似文献   

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