共查询到20条相似文献,搜索用时 15 毫秒
1.
《Applied Geochemistry》2003,18(11):1705-1721
Armoring of limestone is a common cause of failure in limestone-based acid-mine drainage (AMD) treatment systems. Limestone is the least expensive material available for acid neutralization, but is not typically recommended for highly acidic, Fe-rich waters due to armoring with Fe(III) oxyhydroxide coatings. A new AMD treatment technology that uses CO2 in a pulsed limestone bed reactor minimizes armor formation and enhances limestone reaction with AMD. Limestone was characterized before and after treatment with constant flow and with the new pulsed limestone bed process using AMD from an inactive coal mine in Pennsylvania (pH=2.9, Fe =150 mg/l, acidity =1000 mg/l CaCO3). In constant flow experiments, limestone is completely armored with reddish-colored ochre within 48 h of contact in a fluidized bed reactor. Effluent pH initially increased from the inflow pH of 2.9 to over 7, but then decreased to <4 during the 48 h of contact. Limestone grains developed a rind of gypsum encapsulated by a 10- to 30-μm thick, Fe-Al hydroxysulfate coating. Armoring slowed the reaction and prevented the limestone from generating any additional alkalinity in the system. With the pulsed flow limestone bed process, armor formation is largely suppressed and most limestone grains completely dissolve resulting in an effluent pH of >6 during operation. Limestone removed from a pulsed bed pilot plant is a mixture of unarmored, rounded and etched limestone grains and partially armored limestone and refractory mineral grains (dolomite, pyrite). The ∼30% of the residual grains in the pulsed flow reactor that are armored have thicker (50- to 100-μm), more aluminous coatings and lack the gypsum rind that develops in the constant flow experiment. Aluminium-rich zones developed in the interior parts of armor rims in both the constant flow and pulsed limestone bed experiments in response to pH changes at the solid/solution interface. 相似文献
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Fluvial bedrock erosion rates due to impacting sediment particles are thought to be proportional to the energy delivered to the bedrock. When sediment particles cover the bed, they reduce the energy transmitted to the bed by an impacting particle. We measured the decline of energy transferred through sediment cover of increasing thickness in laboratory experiments. The energy arriving at the bed is a function both of the cover thickness and the grain size of the covering sediment. Using a simple stochastic model of cover distribution, the experimental results were upscaled to the reach scale. Although cover thickness influences energy delivery heavily at a given point, when averaging over the whole bed, cover-free areas dominate total energy delivery, making partial energy transfer through the cover negligible when a small or intermediate fraction of the bed is covered by sediment. Partial energy delivery through the bed cover is not negligible when a large fraction or the complete bed is already covered, but in this situation, an erosion threshold may become important. On grounds of the presented data, we expect that the areal distribution of sediment in a bedrock channel dominates total energy delivery and that partial energy delivery to the bed through a sediment layer can be neglected for most modelling purposes. 相似文献
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Direct numerical simulation of bedload transport using a local, dynamic boundary condition 总被引:3,自引:0,他引:3
ABSTRACT Temporally and spatially averaged models of bedload transport are inadequate to describe the highly variable nature of particle motion at low transport stages. The primary sources of this variability are the resisting forces to downstream motion resulting from the geometrical relation (pocket friction angle) of a bed grain to the grains that it rests upon, variability of the near‐bed turbulent velocity field and the local modification of this velocity field by upstream, protruding grains. A model of bedload transport is presented that captures these sources of variability by directly integrating the equations of motion of each particle of a simulated mixed grain‐size sediment bed. Experimental data from the velocity field downstream and below the tops of upstream, protruding grains are presented. From these data, an empirical relation for the velocity modification resulting from upstream grains is provided to the bedload model. The temporal variability of near‐bed turbulence is provided by a measured near‐bed time series of velocity over a gravel bed. The distribution of pocket friction angles results as a consequence of directly calculating the initiation and cessation of motion of each particle as a result of the combination of fluid forcing and interaction with other particles. Calculations of bedload flux in a uniform boundary and simulated pocket friction angles agree favourably with previous studies. 相似文献
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The variability of critical shear stress, friction angle, and grain protrusion in water-worked sediments 总被引:3,自引:0,他引:3
JAMES W. KIRCHNER WILLIAM E. DIETRICH† FUJIKO ISEYA‡ HIROSHI IKEDA‡ 《Sedimentology》1990,37(4):647-672
The erodibility of a grain on a rough bed is controlled by, among other factors, its relative projection above the mean bed, its exposure relative to upstream grains, and its friction angle. Here we report direct measurements of friction angles, grain projection and exposure, and small-scale topographic structure on a variety of water-worked mixed-grain sediment surfaces. Using a simple analytical model of the force balance on individual grains, we calculate the distribution of critical shear stress for idealized spherical grains on the measured bed topography. The friction angle, projection, and exposure of single grain sizes vary widely from point to point within a given bed surface; the variability within a single surface often exceeds the difference between the mean values of disparate surfaces. As a result, the critical shear stress for a given grain size on a sediment surface is characterized by a probability distribution, rather than a single value. On a given bed, the crtitical shear stress distributions of different grain sizes have similar lower bounds, but above their lower tails they diverge rapidly, with smaller grains having substantially higher median critical shear stresses. Large numbers of fines, trapp.ed within pockets on the bed or shielded by upstream grains, are effectively lost to the flow. Our calculations suggest that critical shear stress, as conventionally measured, is defined by the most erodible grains, entrained during transient shear stress excursions associated with the turbulent flow; this implies a physical basis for the indeterminacy of initial motion. These observations suggest that transport rate/shear stress relationships may be controlled, in part, by the increasing numbers of grains that become available for entrainment as mean shear stress increases. They also suggest that bed textures and grain size distributions may be controlled, within the constraints of an imposed shear stress and sediment supply regime, by the influence of each size fraction on the erodibility of other grain sizes present on the bed. 相似文献
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JAMES R. STEIDTMANN 《Sedimentology》1982,29(6):877-883
It is well known that sediment sorting according to size, shape and density occurs, but the exact mechanisms involved are poorly understood. To assess the effects of size and density, sand-size spheres of two densities were transported and deposited under controlled flume conditions. Observations on the motion of discrete particles show that grains smaller than bed-roughness grains move continuously and have the same transport velocities regardless of density. For grains near and slightly larger than the roughness, movement is intermittent and, for a given size, heavy particles move more slowly than lights. For grains much larger than bed roughness grains, movement is continuous over the rough surface and light and heavy grains have nearly the same transport velocities. Analyses of bulk sediment deposited from plane-bed transport, show that the size and proportion of heavies decreases and that of lights increases with distance transported. For ripple bed transport, however, the size relations between associated light and heavy grains remains essentially unchanged with transport distance and the proportion of light and heavy grains is extremely variable. These results suggest that size-density sorting in plane-bed transport is a function of the transportabilities identified in the discrete grain studies but that sorting in ripple-bed transport is related to deposition on, and recycling through, the bed forms. Application of these findings to the concept of hydraulic equivalence implies that some indication of bed configuration may be necessary for the concept to be useful. 相似文献
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Zsolt Schléder János L. Urai Sofie Nollet Christoph Hilgers 《International Journal of Earth Sciences》2008,97(5):1045-1056
Zechstein (Z1) rocksalt from the Fulda basin, from the immediate vicinity of the Hessen potash bed is folded into tight to
isoclinal folds which are cut by an undeformed, 1 cm thick, coarse-grained halite vein. Microstructures were investigated
in etched, gamma-irradiated thin sections from both the wall rock and the vein. The lack of synsedimentary dissolution structures
and the widespread occurrence of plate-shaped and hopper grains in the wall-rock suggests that the sedimentary environment
was perennial lake. Deformation microstructures are in good agreement with solution-precipitation creep process, and salt
flow under very low differential stress. Strength contrast between anhydrite-rich and anhydrite-poor layers caused the small
scale folding in the halite beds. The vein is completely sealed and composed mainly of euhedral to subhedral halite grains,
which often overgrow the wall-rock grains. Those microstructures, together with the presence of occasional fluid inclusion
bands, suggest that the crystals grew into a solution-filled open space. Based on considerations on the maximum value of in-situ
differential stress, the dilatancy criteria, the amount of released fluids from the potash bed during metamorphism and the
volume change, it is proposed that the crack was generated by hydrofracturing of the rocksalt due to the presence of the salt-metamorphic
fluid at near-lithostatic pressure. 相似文献
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Existing formulations for bed sediment entrainment under steady flow are incapable of explaining two well-documented observational facts: (i) water flow requires considerably higher dimensionless shear stresses to move the bed grains than air flow; and (ii) under open channel flow, steep granular beds are more stable than beds with milder slopes. These two facts, together with recent direct measurements of forces acting on bed grains giving time-mean negative drags ( Schmeeckle et al. , 2007 ), question the conventional models of forces used so far. Here, fluid forces acting on bed particles are treated in a new way in order to take into consideration the fundamental interference effects, thus obtaining appropriate magnitude estimates that exhibit good agreement with direct force measurements by Schmeeckle et al. (2007) . Impulsive pressure fluctuations generated by turbulence are shown to be capable of dislodging the bed grains by saltation under air flow, whereas they can only produce a rocking effect under water flow, thus explaining the first anomaly. On the other hand, previous work by the authors allows a direct estimate of space averaged time-mean drag and lift forces exerted on bed grains. Both components have the same order of magnitude but, contrary to the common belief, the mean lift is downward, which provides an explanation for the second anomaly. Finally, spatial disturbances of pressure, both positive and negative, appear to generate maximum, persistent, local forces considerably greater than mean forces, thus allowing an explanation for the observed negative time-mean drag. A new formula for predicting incipient motion of sediment under open channel flow is derived, which incorporates all dynamically significant effects and gives very good agreement with observation for the entire range of bed slopes. 相似文献
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An experimental study of multiple grain-size ejecta produced by collisions of saltating grains with a flat bed 总被引:11,自引:0,他引:11
Collision data are presented from coloured high-speed films of three size fractions of sand grains saltating over a bed of the total grain population. Each fraction was colour tagged and the proportion of each size ejected by grains colliding with the surface was recorded on a number of films taken as the bed was progressively eroded. The results confirm earlier findings that V3/V1?0.5–0.6, Vn/V1?.08 and the rebound angle increases with decreasing grain size. Ejected grains are examined in relation to their size, the impactor size, ejection speed and angle and the number of ejecta per collision. In addition, changes in grain parameters are observed with time. For fine impactors, ejection speeds generally increase with a decrease in ejecta size, but the fine fraction does not follow this trend for the coarse and medium impactors. Ejection angles are typically between 40° and 60°, with coarse grains having shallower mean angles than fine ejecta. The number of ejections per collision increases with a decrease in particle size for each impactor size. The general tendency for coarse particles to be ejected at lower speeds and shallower angles than fine particles will lead to sorting of the grain sizes. There is poor correlation between the forward momentum loss of the saltating grams at collision and both the forward momentum of the ejected grains and the number of ejected grains. Much of the forward momentum of the saltating grains is transfered to creeping grains. The composition and geometry of the bed are considered to be important factors in the evolution of the saltation cloud. 相似文献
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For more than a century, studies of sedimentology and sediment transport have measured bed-sediment grain size by collecting samples and transporting them back to the laboratory for grain-size analysis. This process is slow and expensive. Moreover, most sampling systems are not selective enough to sample only the surficial grains that interact with the flow; samples typically include sediment from at least a few centimeters beneath the bed surface. New hardware and software are available for in situ measurement of grain size. The new technology permits rapid measurement of surficial bed sediment. Here we describe several systems we have deployed by boat, by hand, and by tripod in rivers, oceans, and on beaches. 相似文献
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为了解析底部高含沙层特征,研究了物理影响机制和时均含沙量剖面。采用波流边界层1DV泥沙数学模型,结合试验资料,通过设置不同的计算工况进行了影响因素敏感性分析;在此基础上,提出波浪相关的时均泥沙扩散系数分布,考虑主要影响机制,推导了基于边界层物理过程的波浪作用下时均含沙量剖面表达式。结果表明,底部高含沙层与波浪边界层密切相关,是受水动力和床面形态综合影响的结果。仅建立高含沙层与水动力或床面形态的单一关系是有局限性的。含沙量层化效应和制约沉速对底部高含沙层具有重要影响。提出的平底床面含沙量剖面表达式为幂函数-Rouse-指数分布,漩涡沙波床面为指数-幂函数-Rouse分布。预期可应用于二维和三维泥沙数值模拟。 相似文献
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Experiments are described in which the threshold conditions for sediment entrainment are measured for uniform and mixed sand beds beneath both steady and combined steady/oscillatory flows. Derived critical shear stresses are compared with the mixed bed entrainment model of Wiberg & Smith (1987). As predicted by the model, coarser grains within a sand mixture are entrained at lower bed shear stresses than progressively finer grains. Entrainment occurs generally at lower shear stresses than predicted by the model, especially under unidirectional flows. This may be the result of grains resting in unusually unstable positions during the experiments because the beds are ‘unworked’ at the start of the experiments. The model of Wiberg and Smith predicts threshold conditions more accurately for the mixed beds if the bed pivoting angle is correctly defined. The pivoting angles of the beds used here are measured using a new technique designed specifically for comparison with the threshold data. The measured angles repeat the finding that the coarse grains are more mobile than the finer fractions of a mixture. The results are poorly described by the pivoting angle model presented by Wiberg & Smith (1987) and are better represented by a model of the form Φ = αDγ(Di/D50)β (after 21 ), where α, γ and β are empirical constants. The threshold model is found to be more effective using the improved pivoting relationship. The entrainment of grains is found to be easier beneath unidirectional flows than combined flows, in accordance with previous authors’ findings. A suggestion that this result is caused by a change in the erosion mechanism beneath wave flows is made. Wave boundary layers may act as an extended laminar sublayer over bed grains and reduce the erosive efficiency of the overlying current flow. The results of the experiment have implications for the natural sorting mechanisms of sediment beds being deposited in near-threshold flows. 相似文献
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在我国西部山区地震、地质活跃带,泥石流灾害对位于泥石流沟道、沟口等位置处的桥墩构成重大威胁。如何量化描述泥石流冲击桥墩的动力过程,是泥石流减灾领域拟要解决的一个重要科学问题。以泥石流灾害威胁成兰铁路沿线桥墩的工程背景为基础,依托大型泥石流模拟系统,进行多组室内大比例泥石流冲击桥墩物理模型试验。研究泥石流流速、流深以及流体特征参数与泥石流冲击压力的相关性。试验结果表明:冲击过程主要受到弗汝德数Fr和雷诺数Re两个无量纲数控制,稀性泥石流冲击压力主要控制参数为Fr,而对于黏性泥石流则同时有Fr和Re的影响;不论是对于峰值冲击力还是冲击功率谱,不同类型泥石流差别显著;在相同重度等条件下,稀性泥石流具有更大的冲击能量;此外,各种类型泥石流通过临界Fr线得到了本质上的区分。研究成果将为桥墩抗泥石流冲击结构设计提供技术支持及科学依据。 相似文献
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阶梯-深潭系统是山区河流广泛分布的控制性河床结构,泥沙输移过程中大颗粒碰撞阶梯关键石块,使其发生位移,强烈影响阶梯-深潭的稳定性。以单个阶梯-深潭的关键石块为研究对象,重点考虑碰撞对阶梯-深潭的影响,量化来沙中大颗粒碰撞作用并改进稳定性理论模型,利用新模型分析阶梯-深潭的临界条件和破坏机制。来沙颗粒对关键石块的碰撞作用受自身粒径、运动速度和阶梯下游冲刷程度影响且皆为正相关关系。颗粒撞击减小阶梯失稳临界流量,且参与碰撞的石块粒径越大,减小作用越明显。当η> 0.55时(η=D1/D,D1为碰撞石块粒径,D为关键石块粒径),临界流量下降幅度达到50%以上,表明来沙中卵石漂石对阶梯-深潭稳定性发挥主要影响。山区河流发生低频率洪水或滑坡泥石流,向下游河道输运大粒径石块并与阶梯碰撞,显著增大转动合力矩并降低失稳临界流量,使得单个阶梯-深潭更易达到临界条件发生破坏。 相似文献
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A new method for analysing observed aeolian sand transport rate profiles of the kind obtained by Williams is presented. The method involves a mathematical model of aeolian saltation. Detailed information about the saltation process can be calculated from the transport rate profile by means of this model. The method is used to perform a re-analysis of Williams' trap data. Among the main findings of this analysis is that the grain borne shear stress appears to be a smaller fraction of the total shear stress than assumed by Bagnold & Owen in their theories of aeolian saltation. Other findings are that the probability distribution of the jump height of the grains does not depend much on the wind speed once the saltation is established, and that the vertical component of the mean launch velocity decreases with the grain size. It is approximately inversely proportional to the grain diameter. Our estimates of the landing angles indicate that estimates of the impact angles obtained from photographically recorded trajectories are too small due to biased sampling. The influence of grain shape on the transport characteristics is mainly due to changes in the grains' ability to jump when hitting the bed. It is found that angular grains have a lower mean jump height than spherical grains. 相似文献
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准噶尔盆地南缘的郝家沟剖面三叠系—侏罗系连续发育,是研究三叠系—侏罗系界线及相关地质问题的重要剖面。孢粉分析发现,上三叠统郝家沟组以气候适应范围较宽的裸子植物花粉占优势,而在下侏罗统八道湾组下部主要适应温暖湿润气候的蕨类植物孢子含量明显增高,在组合中常占据优势地位,说明研究区早侏罗世气候比晚三叠世更为潮湿。沉积岩有机碳同位素分析结果显示,在剖面八道湾组下部的δ13C值总体低于-24.5‰,形成两次明显的负向偏移,同时采集的丝炭样品的分析结果也证明δ13C在八道湾组下部具有明显负向偏移。根据现代湖泊沉积有机质碳同位素与气候关系的研究成果,沉积有机质稳定碳同位素负偏是气候温暖潮湿化的反应,支持了孢粉研究的结果。以上表明,研究区侏罗纪之初的气候比晚三叠世更加炎热潮湿。 相似文献
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Outcrops of the Early Jurassic Navajo Sandstone in southern Utah and northern Arizona, south-western USA are being actively eroded by sand-laden, south-westerly winds. Small-scale stepped topography with risers facing into the wind develops even on steep canyon walls when wind-swept grains strike the rock at a low angle. Photosynthetic, endolithic microbes directly underlie most outcrop surfaces; the crusts formed by these organisms are essential to formation of the small-scale steps. Wind erosion of highlands also forms troughs and pits that are tens of metres across. The pits have deeply scalloped, overhanging walls, and contain central domes surrounded by 'moats' filled with dune sand. Wind erosion of aeolian sandstone is favoured by a positive feedback mechanism in which grains that are liberated from outcrops by impacting particles become a fresh supply of pre-sorted abrasive particles for further attack. 相似文献