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1.
长江中游湖泊CDOM光学特性及其空间分布对比 总被引：4，自引：1，他引：3
根据2007年秋季洪湖、东湖和梁子湖的调查结果,分析了长江中游3个典型湖泊CDOM光学特性及其空间分布差异.结果表明:(1)CDOM吸收系数在洪湖最高,梁子湖最低;(2)在洪湖,CDOM吸收系数受陆源影响较大,与悬浮泥沙浓度呈现较好正相关关系,而在梁子湖,CDOM吸收系数主要受到浮游植物降解贡献,与叶绿素浓度具有显著的正相关关系;(3)洪湖与东湖指数函数斜率S值变化不大;梁子湖CDOM吸收系数空间分布差异较大,指数函数斜率S值与400nm波段CDOM吸收系数ag(400)显著负相关.在建立梁子湖CDOM遥感反演模型时,应引入上述指数甬数斜率S值与400nm波段CDOM吸收系数之间的线性函数,对CDOM吸收系数的指数模型进行优化. 相似文献
2.
淀山湖有色可溶性有机物的光谱吸收特性 总被引：3，自引：2，他引：1
探讨了淀山湖水体中有色可溶性有机物(CDOM)的光谱吸收特性,CDOM与叶绿素a、浊度和COD等水质参数的关系,以及不同波段范围内CDOM光谱吸收形状(指数函数斜率S值)的变化.结果表明:淀山湖CDOM吸收系数不高,在355 nm波长处的吸收系数变化范围是6.95-10.28 m-1,而且湖南区高于湖北区;CDOM吸收系数和叶绿素a、浊度、COD等水质参数的相关性都不高,证明湖中的CDOM主要来自于城镇生活污水和工业废水的排放;CDOM吸收系数在300-500 nm范围内随着波长的增加呈指数递减,超过500 nm之后呈线性递减,在300-500 nm波段范围内指数函数的曲线斜率S为11.7-14.8 μm-1,在501-750 nm波段范围内波长每增1 nm,CDOM的吸收系数减小0.0021 m-1. 相似文献
3.
暴雨事件对千岛湖CDOM及颗粒物吸收光谱特征的影响 总被引：1，自引：1，他引：0
为了研究暴雨事件对千岛湖有色可溶性有机物(CDOM)和颗粒物吸收光谱的影响,利用2016年暴雨前(3月1-6日)和暴雨后(4月6-11日)采集的水样,对暴雨前、后千岛湖水体CDOM、浮游藻类和非藻类颗粒物的吸收光谱特征进行分析,探讨暴雨事件对其造成的影响.结果表明:千岛湖作为典型的深水型内陆湖泊,其CDOM、浮游藻类颗粒物和非藻类颗粒物的吸收强度较太湖等浅水型湖泊弱.暴雨前,CDOM光谱吸收系数aCDOM(λ)值在0~0.6 m-1范围内变化,其光谱拟合系数SCDOM的均值为0.0158±0.00145 nm-1.暴雨前浮游藻类光谱吸收在总颗粒物中占主导,aph(λ)在0~0.35m-1范围内变化,非藻类颗粒物光谱吸收系数aNAP(λ)在0~0.15 m-1范围内变化,其光谱拟合系数SNAP均值为5.62±0.57μm-1;暴雨后CDOM光谱吸收系数aCDOM(λ)值在0~1.6 m-1范围内变化,其光谱拟合系数SCDOM的均值为0.0157±0.00101 nm-1.暴雨后浮游藻类光谱吸收系数aph(λ)在0~2.5 m-1范围内变化,非藻类颗粒物光谱吸收在部分区域已占据主导地位,aNAP(λ)在0~0.8 m-1范围内变化,其光谱拟合系数SNAP均值为5.72±0.68μm-1.由CDOM吸收特征值相对分子质量M值得出,暴雨前、后千岛湖不同区域CDOM组成都以富里酸为主,且暴雨前M值分布较均匀,暴雨后M值呈现从新安江向缓冲区、东南区递增的趋势,这说明西北区随暴雨输入的腐殖酸增加了CDOM的相对分子质量.暴雨对SNAP值影响较大的区域为西北区、西南区、东北区,对西南区影响最小.本研究为使用光学手段深入探讨暴雨事件对千岛湖水环境的影响提供重要依据. 相似文献
4.
东太湖CDOM吸收光谱的影响因素与参数确定 总被引：19，自引：7，他引：12
CDOM吸收特性是湖泊水色遥感的重要研究内容之一,影响着水体的遥感反射率;吸收光谱的形状一般符合波长的负指数关系,但不同水体的形态因子即S值是不同的.实地采集东太湖水样,实验室测量叶绿素、悬浮物质以及黄色物质的组份含量,室内测试计算水样的CDOM吸收光谱,根据光谱曲线形状,把样点分为三组,分别进行考察,结果发现对东太湖春季水体而言,浮游植物的降解对CDOM吸收具有重要甚至主导作用;水体中有机悬浮颗粒占有一定的比例,在测试或计算东太湖总的吸收或散射系数时,必须充分考虑有机悬浮颗粒的吸收与散射特性,否则会带来较大的误差;以500nm为分界点,把300—700nm的波段范围分为两个部分即300—500nm和500—700nm,分别定义CDOM吸收光谱的曲线斜率即S值,可以提高CDOM吸收光谱的估测精度,把S值定义为随波长线性变化的函数,可以进一步提高CDOM吸收光谱的估测精度,对东太湖春季水体而言,当:300≤λ<500nm时,S(μm-1)=-0.0193×λ 20.821,当500≤λ≤700nm时,S(μm-1)=-0.0121×λ 16.003. 相似文献
5.
云南高原湖泊有色可溶性有机物和颗粒物光谱吸收特性 总被引：9，自引：6，他引：3
云南高原湖泊是我国湖泊分布最密集的五大湖群之一,不但湖泊数量众多而且类型多样.由于湖泊所处位置海拔较高,容易受只益增强UV-B辐射影响.通过对云南高原34个湖泊有色可溶性有机物和颗粒物吸收测定,分析其光谱吸收特性及对总吸收的贡献,有利于深刻理解紫外辐射在高原湖泊内衰减.不同湖泊间CDOM吸收差异明显,其大小与水体营养盐状况相关,CDOM吸收系数与水体总氮存在显著正相关.增加背景项的指数函数模型能最好模拟CDOM光谱吸收.除在浮游植物浓度非常高的杞麓湖、听湖、星云湖,颗粒物吸收系数在675nm附近存在一个吸收蜂外,其它湖泊总颗粒物光谱吸收大致随波长的增加吸收系数逐渐降低,呈现非色素颗粒物光谱吸收特征,整体上颗粒物吸收以非色素颗粒物为主.CDOM对总吸收的贡献主要集中在600nm以下波长,尤其是400nm以下的紫外波段,其在紫外波段(350-400nm)的贡献明显要大于光合有效辐射波段(400-700nm)(ANOVA,P<0.001).特别对于透明度SD≥1.0的清澈型湖泊,CDOM吸收对紫外辐射衰减的贡献更大,其吸收很大程度上决定了紫外辐射的影响深度. 相似文献
6.
兴凯湖春季水体悬浮颗粒物和CDOM吸收特性 总被引：1，自引：0，他引：1
为了分析兴凯湖水体光学活性物质的吸收特性、来源和空间分布以及对400~700 nm范围内总吸收的贡献,于2013年5月对该水体进行野外实验,对水体中浮游藻类、非藻类颗粒物和有色可溶性有机物的吸收特性和水质参数进行测定.结果表明:总悬浮颗粒物的吸收光谱与非藻类颗粒物相似,色素颗粒物含量较少且单一,非藻类颗粒物在总悬浮颗粒物吸收中占主导地位,其贡献率始终在50%以上.CDOM吸收曲线的拟合函数斜率值Sg均高于其它水体.440 nm处总悬浮颗粒物和非藻类颗粒物的吸收系数ap(440)、ad(440)与总悬浮颗粒物、无机悬浮颗粒物和有机悬浮颗粒物浓度相关性均较好,与叶绿素a(Chl.a)浓度的相关性较差.兴凯湖与其它Ⅱ类水体的差异性表现在440 nm处CDOM吸收系数ag(440)与Chl.a浓度、溶解性有机碳(DOC)浓度均无显著相关性,说明DOC以无色部分为主.总体上,大兴凯湖各吸收系数和水质参数均值均低于小兴凯湖,后者水质受农耕区退水及周围渔业、旅游业的影响较大. 相似文献
7.
8.
淮河流域周村水库夏季CDOM吸收光谱特征、空间分布及其来源分析 总被引：6，自引：0，他引：6
基于2015年8月采集的24个淮河流域以周村水源水库为代表的表层水样的有色溶解性有机物(CDOM)吸收系数数据,研究了CDOM吸收光谱的空间分布特征,考察了CDOM的吸收系数与水质参数的相关关系,同时探讨了周村水库夏季CDOM的潜在来源.结果显示:依据CDOM的吸收光谱空间分布特性及采样点分布特征,周村水库分为入库口、过渡区和主库区3个特征水域;CDOM的吸收系数沿入库口到主库区依次递减,S值呈现相反的趋势;分析发现S240~500与a(355)和a*(355)呈极显著负相关(R~2=0.98、0.88);CDOM吸收系数a(355)与溶解性有机碳(DOC)浓度具有良好的线性相关,有利于建立DOC遥感反演模型;同时,CDOM吸收系数a(355)与a_(ph)(440)存在极显著正线性相关,表明浮游植物的新陈代谢及其降解产物是夏季周村水库CDOM的潜在来源.综上,通过对夏季周村水库水体CDOM的研究,丰富了关于水源水体CDOM的调查资料,可为日后水库的管理提供技术支撑. 相似文献
9.
基于三维荧光和平行因子分析法的太湖水体CDOM组分光学特征 总被引：11，自引：1，他引：10
基于2008年11月份太湖全湖69个样点的CDOM三维荧光光谱数据,将平行因子分析法与现有荧光基团相结合,确定CDOM的组成成分及其荧光光谱特征,进一步分析其动力学机制.太湖CDOM荧光基团主要是类腐殖质,其类蛋白质组分可能主要来源于太湖水体生物残骸;同时,类腐殖质荧光发射波长随着荧光强度的增加向长波方向移动,存在"红移"效应.利用平行因子分析法可以将三维荧光矩阵分解为6个主成分,这6种成分可以解释92.48%的变量,平均贡献率分别是PCI占19.709%,PC2占18.685%,PC3占16.914%、PC4占16.62%、PC5占15.514%、PC6占12.558%.275nm处的吸收系数肩值除去受陆源类腐殖质影响外,影响其大小的主要是峰N,其次是峰M;而影响该肩值形状的主要是峰A和N,其次是峰T和M.根据荧光基团的类别,太湖CDOM源类型可以分为四类:①陆源主导类型;②偏陆源主导类型;③偏海源主导类型;④海源主导类型. 相似文献
10.
有色溶解性有机物(CDOM)广泛存在于水体中,占溶解有机碳(DOC)10%～90%,其浓度影响水环境碳循环过程、污染物质迁移以及水生生物群落的结构和功能。为分析东北地区水库DOC碳循环情况,本文于2015—2020年对第二松花江流域典型水库白山水库和丰满水库进行5次现场观测和室内实验,在分析CDOM吸收特性的基础上,基于Landsat系列卫星利用波段比值法建立CDOM浓度反演模型(R2=0.82),根据实测值CDOM与DOC的强相关性(R2=0.78),进而估算水库DOC浓度。结果表明：(1)利用野外实测数据和Landsat系列卫星能够对东北内陆水库CDOM浓度进行良好反演,(2)2000—2020年白山水库和丰满水库年际CDOM和DOC浓度变化不大,在2010年之后表现出轻微上升趋势,CDOM浓度从支流和干流的汇入到主库区呈现逐渐减少趋势,(3)白山水库和丰满水库M值(CDOM在250和365 nm处吸收系数比值)和S275～295(CDOM在275～295 nm波段处的吸收光谱的斜率)较小、SUVA254<... 相似文献
11.
官厅水库秋季悬浮颗粒物和CDOM吸收特性 总被引：2，自引：0，他引：2
利用2012年9月5日在官厅水库采集的水体吸收系数数据,对总悬浮颗粒物、浮游植物色素颗粒物、非色素颗粒物和有色可溶性有机物的吸收特性进行研究.结果表明:秋季官厅水库的颗粒物吸收以浮游植物色素吸收为主,总颗粒物吸收光谱与浮游藻类吸收光谱相似;非色素颗粒物和有色可溶性有机物的吸收系数随波长的增大接近指数规律衰减;ad(440)、ad(675)与CChl.a呈显著相关,表明官厅水库秋季的非色素颗粒物主要来源于浮游藻类降解产物,陆源性输入较少;a ph(440)、a ph(675)与CChl.a存在显著线性关系,但其比吸收系数较为恒定,与CChl.a基本无关;不同采样点的不同组分吸收系数对总吸收系数的贡献不同,大致有4种表现类型.在富营养程度较高的妫库区,浮游植物色素是水体光谱吸收的主导因子;在富营养程度较低的中库区,颗粒物与有色可溶性有机物共同主导水体光谱吸收. 相似文献
12.
The optical properties and spatial distribution of chromophoric dissolved organic matter (CDOM) in Meiliang Bay of Lake Taihu were evaluated and compared to the results in literature. Concentrations of dissolved organic carbon (DOC) ranged from 8.75 to 20.19 mg L?1 with an average of (13.10 ± 3.51) mg L?1. CDOM absorption coefficients a(λ) at 280 nm, 355 nm, and 440 nm were in the range 11.28...33.46 m?1 (average (20.95 ± 5.52) m?1), 2.42...7.90 m?1 (average (4.92 ± 1.29) m?1), and 0.65...2.44 m?1 (average (1.46 ± 0.44) m?1), respectively. In general, CDOM absorption coefficient and DOC concentration were found to decrease away from the river inflow to Meiliang Bay towards the lake center. The values of the DOC‐specific absorption coefficients a*(λ), given as absorption coefficient related to mass concentration of organic carbon (C) ranged from 0.28 to 0.47 L mg?1 m?1 at 355 nm. The determination coefficients between CDOM absorption and DOC concentration decreased with the increase of wavelength from 280 to 550 nm. The linear regression relationship between CDOM absorption at 280 nm and DOC concentration was following: a(280 nm) = 1.507 L mg?1 m?1 · DOC + 1.215 m?1. The spectral slope S values were dependent on the wavelength range used in the regression. The estimated S values decreased with increasing wavelength range used. A significant negative linear relationship was found between CDOM absorption coefficients, DOC‐specific absorption coefficients and estimated S values especially in longer wavelength range. The linear regression relationship between DOC‐specific absorption coefficients at 440 nm and estimated S values during the wavelength range from 280 to 500 nm was following: a*(440 nm) = (–0.021 μm · S + 0.424) L mg?1 m?1. 相似文献
13.
Distribution and photoreactivity of chromophoric dissolved organic matter in northern Gulf of Mexico shelf waters 总被引：1，自引：0，他引：1
The distribution and photoreactivity of chromophoric dissolved organic matter (CDOM) in the northern Gulf of Mexico along the Louisiana coastal shelf were examined during three cruises in summer 2007, fall 2007, and summer 2008. The influence of the Mississippi River plume was clearly evident as CDOM levels (defined as a305) and dissolved organic carbon (DOC) concentrations were well-correlated with salinity during all cruises. Elevated CDOM and CDOM:DOC ratios of surface samples collected offshore of Atchafalaya Bay and the Breton-Chandeleur Sound complex indicated emanations of organic-rich waters from coastal wetlands are also an important source to nearshore shelf waters. Generally, CDOM and DOC levels were highest in surface waters and decreased with depth, but during summer 2007 and summer 2008, CDOM levels in near-bottom samples were occasionally higher than at mid-depths without concomitant increases in DOC. CDOM photobleaching was measured during 24 irradiations using a SunTest XLS+ solar simulator with photobleaching rate coefficients (k305) ranging from 0.011 to 0.32 h−1. For fall 2007 and summer 2008, higher k305 values were generally observed in samples with higher initial CDOM levels. However, samples collected during summer 2007 did not exhibit a similar pattern nor were there differences in photobleaching rates between surface and bottom samples. Spectral slope coefficients (S275-295 or S350-400) and DOC levels were largely unchanged after 24 h irradiations. Modeled CDOM photobleaching for northern Gulf of Mexico mid-shelf waters predicts that during the summer when solar irradiance is high and the water column becomes stratified, nearly 90% of the CDOM in the upper 1 m may be lost to photobleaching, with losses up to 20% possible even at 10 m depth. 相似文献
14.
Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m−1 at Barataria in June 2008 to 11.225 m−1 at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m−1 at Mississippi in May 2008 and 0.0261 m−1 at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L−1 and POM was between 0.3 and 49.6 mg L−1. 相似文献
15.
太湖沿岸水体CDOM吸收光谱特性 总被引：17，自引：7，他引：10
有色可溶性有机物(CDOM)吸收光谱特性研究对于水色定量遥感反演具有重要作用.通过2007年6月10日至6月18日太湖沿岸68个CDOM吸收光谱曲线和水质参数实测数据,分析了CDOM吸收光谱曲线特征以及ag(440)、Sg值及其相关关系等,结果表明:太湖沿岸水体CDOM吸收光谱曲线表现为两种类型,贡湖湾CDOM吸收系数明显高于太湖其他沿岸水域,ag(440)最高值即出现在贡湖湾;同时,梅梁湾、贡湖湾、镇湖湾、光富湾等ag(440)高于沿岸水体平均值,而南部3个湖湾皆低于平均值.另外,贡湖湾Sg值较小,且与ag(440)呈现出较好的关系;而沿岸其它水体Sg值与ag(440)虽然呈现负相关,但关系不明显.这对于了解太湖水体CDOM特件以及定量反演有一定的意义和作用. 相似文献
16.
水体中藻类颗粒物、非藻类颗粒物、CDOM的光谱吸收特性的变化是整个水体对光吸收特性变化的源．本文针对梅梁湾水体中介质的吸收系数,分析了总悬浮颗粒物、藻类颗粒物、非藻类颗粒物和CDOM的标准化谱吸收数的变化．结果表明:藻类颗粒物、非藻类颗粒物组成比例的空间分布不同,是造成该区域总悬浮颗粒物标准化谱吸收系数空间变化的原因．且标准化谱吸收系数的变化主要集中在400-425 nm及600-690 nm两个波段;就谱形而言,总悬浮颗粒物的谱吸收特性主要表现为非藻类颗粒物的吸收特点,即在该区域的水体中,非藻类颗粒物是总悬浮颗粒物吸收特性的主要贡献者;藻类颗粒物、非藻类颗粒物和CDOM的吸收系数的空间变化主要是由各自的浓度变化造成的,即在采样时间内,梅梁湾的水体中,藻类颗粒物中的各种组成色素、非藻类颗粒物及CDOM中的腐殖酸和棕黄酸的组成比例在空间上基本没有太大的变化．另针对藻类颗粒物的吸收特性,本文还对比分析了用甲醇浸泡法和光谱标准分离法分离的藻类颗粒物的吸收特性,发现相对光谱标准分离法来说,甲醇浸泡法会造成藻类颗粒物吸收系数的较大波动． 相似文献
17.
Luca Bracchini Antonio Tognazzi Arduino Massimo Dattilo Franco Decembrini Claudio Rossi Steven Arthur Loiselle 《Aquatic Sciences - Research Across Boundaries》2010,72(4):485-498
In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been
extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture
of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified
and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope
of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis
of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral
slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study
the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution.
We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating
that consistent values may be determined, with a typical uncertainty of ±0.0004 nm−1 when absorption at 300 nm was greater then 0.1 m−1 (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution,
we show differences between measurements that were significantly different. These values allow us to distinguish possible
sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds
into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or
near deep chlorophyll maximum. 相似文献