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1.
A one-dimensional, time-dependent model of the neutral and ion composition of the middle atmosphere is used to study the processes controlling the production and loss of odd nitrogen species during particle ionization events. From consideration of the cross-sections for the relevant ionization and dissociation reactions we conclude that between 1.3 and 1.6 odd nitrogen atoms per ion pair are produced in the middle atmosphere. The value in the thermosphere is larger due to the role of atomic oxygen. The time-dependent mutual destruction of odd nitrogen by the reaction N(4S) +NO→ N2+O must be included and the assumption of a nitric oxide production normalized to the ionization rate is invalid. A simulation of the 1972 August solar proton event is presented. The calculated ozone depletion occurring during the event due to the increase in odd nitrogen agrees well with the measured ozone changes.  相似文献   

2.
A one dimensional time-dependent model of the neutral and ion chemistry of the middle atmosphere has been used to examine the production of odd hydrogen (H, OH, and HO2) during charged particle precipitation. At altitudes above about 65 km, odd hydrogen production depends on the ionization rate, and the atomic oxygen and water vapor densities. Odd hydrogen production is shown to exhibit diurnal and other time dependent variations during such an event at these altitudes, and the assumption that two odd hydrogen particles are always produced per ionization is reexamined.  相似文献   

3.
A time-dependent two-dimensional numerical model of the minor neutral constituents of the thermosphere NO, N(2D), and N(4S) is used to examine the effects of winds in transporting these constituents from their production region in auroral arcs. The calculations show that thermospheric winds flowing through regions of enhanced local auroral production produce downwind plumes of enhanced minor neutral constituent densities and that the densities depend upon the wind velocity. Below about 200 km N(2D) is in photochemical equilibrium and is not transported. Above 200 km N(2D) is transported by the wind and since quenching of N(2D) by O is small and the radiational lifetime is long, a downwind plume of emission at 5200 Å develops from the particle source region. We present data from a rocket flight in the vicinity of the magnetospheric cusp and data from the Atmosphere Explorer-D (AE-D) satellite that both show enhanced 5200 Å emission rates in a general downwind direction from a region of direct particle precipitation. The general wind speed and direction are obtained from predictions made by the NCAR thermospheric general circulation model. The results suggest that transport of N(2D) by the wind system is more important than the convection of O+ ions by electric fields in causing the enhanced 5200 Å emission rate in regions outside but in the vicinity of direct particle precipitation.  相似文献   

4.
The nitrogen isotope ratio of middle atmosphere nitrogen oxide is predicted as a function of altitude. Nitrogen oxides originate photochemically either from stratospheric nitrous oxide reacting with O(1D) or in the mesosphere and thermosphere from direct dissociation of N2 and ionization-initiated reactions involving O2 and N2. During its formation process, N2O acquires a nitrogen isotopic composition of N isotopes different than N2. Photodissociation within the stratosphere also modifies the proportion of isotopes. Reaction of stratospheric NO with O3 produces NO2, which when photodissociated yields NO depleted in 15N relative to NO2 in laboratory air. The value of δ15NO in the stratosphere is −100‰. In the altitude region between 50 and 65 km, NO is transformed into NO2 and then returned to NO by reaction of NO2 with O and by NO2 photodissociation. These reactions determine the isotopic makeup of NO. Above 65 km, nitric oxide is produced by local ionization processes and gas phase photochemical reactions involving N2 and excited O2. These processes determine the isotopic composition of NO in the upper mesosphere and thermosphere. Here δ15NO is 0‰. Air transported into the mesosphere above 65 km will reflect the NO isotopic values of the region below, while mesospheric NO transported below 65 km will not be distinguishable from NO originating in the stratosphere.  相似文献   

5.
The effects of a typical auroral electron precipitation substorm sequence on odd nitrogen species in the thermosphere have been investigated. The analysis makes use of the time dependent model of the aurora developed by Roble and Rees (1977), which couples the thermal properties to the ionospheric chemistry and transport self-consistently and includes diffusive transport of NO, N(2D) and N(4S). A substantial increase in the E-region density of NO or of N(4S) is predicted, with the result depending on the production ratio of N(2D) to N(4S) in the aurorally dominant source mechanism, electron impact dissociation of N2. A production ratio that favors N(2D) by a factor of one half or larger leads to enhancement of NO, while a ratio of 14N(2D)+34N(4S) results in a buildup of N(4S). The cyclical behaviour of the substorm, i.e. alternate intervals of electron precipitation and quiet periods, accentuates the scavenging effect of the initially dominant odd nitrogen species upon the less abundant one.  相似文献   

6.
A review is given of the stratospheric budgets of odd oxygen, odd nitrogen, nitrous oxide, methane and carbonyl sulfide. The stratospheric column production rate of NO by the reaction N2O + O(1D) → 2 NO is 1.1–1.9 × 108 molecules cm?2 s?1. The stratospheric loss rates for N2O, CH4 and COS are equal to 0.9–1.4 × 109, 1 × 1010 and 0.5 × 107 molecules cm?2 s?1, respectively. From currently available information on the global distributions of N2O and CH4 there are some indications of about two times smaller OH concentrations below 35 km than those which are calculated based on the latest compilation of kinetic data.Most significantly, however, it is shown that photochemical models and available ozone observations cannot be reconciled and that there may be particularly severe problems in the 25–35 km region. This issue is thoroughly discussed.Volcanic emissions of SO2 to the stratosphere may locally lead to much enhanced ozone concentrations and heating rates. These may influence the dynamic behaviour of volcanic plumes before their dispersion over large volumes of the stratosphere.  相似文献   

7.
A. Bar-nun 《Icarus》1980,42(3):338-342
The effects of the newly discovered thunderstorms on Venus upon the nitrogen and carbon species in its atmosphere were calculated. An Earth-like lightning frequency of 100 sec?1 was used for Venus, in accord with recent optical measurements by Pioneer-Venus (W. J. Borucki, J. W. Dyer, G. Z. Thomas, J. C. Jordon, and D. A. Comstock, submitted for publication). The rate of NO production by thunder shock waves, 2.5 × 1011 g year?1, is about an order of magnitude smaller than on the Earth. But on Venus, in the absence of precipitation, which is the major removal mechanism of odd nitrogen from the Earth's atmosphere, the mixing ratios of odd nitrogen species might be considerably higher. The global CO production is governed by CO2 photolysis rather than by CO2 pyrolysis by lightning. However, thunderstorms produce about 2.5 × 1011 g year?1 of CO in the cloud layer, far from the high altitude CO2 photolysis region.  相似文献   

8.
The nitric oxide density profile between the altitudes 72 and 120 km was obtained by means of the airglow γ(1, 0) band measured with a rocket-borne radiometer flown at Syowa Station (69°S, 40°E). The NO density was found to have two peaks with a value of 1.5× 108cm?3 at 90 and 110 km, and is much larger than those in the middle and low latitudes. Because of a long lifetime of NO in the mesosphere, the observed NO enhancement may be due to the after-effect of the particle precipitation event which occurred within the half day before, despite no polar disturbance during the rocket flight.  相似文献   

9.
A self-consistent, time-dependent numerical model of the aurora and high-latitude ionos-phere has been developed. It is used to study the response of ionospheric and atmospheric properties in regions subjected to electron bombardment. The time history of precipitation events is arbitrarily specified and computations are made for a variety of electron spectral energy distributions and flux magnitudes. These include soft electron precipitation, such as might occur on the poleward edge of the auroral oval and within the magnetospheric cleft, and harder spectra representative of particle precipitation commonly observed within and on the equatorward edge of the auroral oval. Both daytime and night-time aurorae are considered. The results of the calculations show that the response of various ionospheric and atmospheric parameters depends upon the spectral energy distribution and flux magnitudes of the precipitating electrons during the auroral event. Various properties respond with different time constants that are influenced by coupling processes described by the interactive model. The soft spectrum aurora affects mainly the ionospheric F region, where it causes increases in the electron density, electron temperature and the 6300 Å red line intensity from normal quiet background levels during both daytime and night-time aurora. The fractional variation is greater for the night-time aurora. The hard spectrum aurorae, in general, do not greatly affect the F-2 region of the ionosphere; however, in the F-1 and E regions, large increases from background conditions are shown to occur in the electron and ion temperatures, electron and ion densities, airglow emission rates and minor neutral constituent densities during the build-up phase of the auroral event. During the decay phase of the aurora, most of these properties decrease at nearly the same rate as the specified particle precipitation flux. However, some ionospheric and atmospheric species have a long memory of the auroral event. The odd nitrogen species N(4S) and NO probably do not ever reach steady-state densities between auroral storms.  相似文献   

10.
Nonmethane hydrocarbon breakdown in the atmosphere produces aldehydes of which a fraction are transferred into peroxyacetyl nitrates (PAN) in the presence of NO and NO2. Since ethane is destroyed photochemically primarily above 1 km, PAN can be introduced into the upper troposphere and lower stratosphere without the need to be transported from the boundary layer where most hydrocarbons are destroyed and where PAN may be lost due to thermal decomposition and heterogeneous loss. Mixing ratios of ethane in the lower troposphere increase by a factor of 4–8 from equatorial to northern mid-latitudes. This difference is directly translatable into a PAN latitude gradient. At mid-latitudes the concentration of PAN below 20 km is 0.1 ppb comparable to and in some instances larger than predicted HO2NO2 mixing ratios. Like HO2NO2 and HNO3, PAN serves as a reservoir for odd nitrogen.  相似文献   

11.
Recently, modelers have expressed a concern that the currently known chemistry of atmospheric NOy is deficient. It is therefore necessary to explore possible sources and sinks of atmospheric NOx that may have been overlooked. In this context, it is noteworthy that the experimentally observed, four-center, Woodward-Hoffman forbidden, reaction 02(B 3Σ) + N2 → NO(X) + NO (X) is atmospherically significant. In the 20 to 30 km region NOx production from this reaction may potentially exceed the production from the “classical” N20 + O(1D) reaction, and may provide a new mechanism to couple the solar UV variability and stratospheric ozone. The avoidance of the non-conservation of the orbital symmetry via the production of one NO in the excited electronic state being endothermic, it appears that the interaction of 02(B 3Σ) with the adjoining 1Λ, 3Λ and 3Σu+ states might be responsible for the reaction. Experimental studies of the reaction as a function of the vibrational levels of the B-state, temperature and pressure are needed for reliable atmospheric applications of this reaction. At altitudes greater than about 50 km the production of NO from 02(B) begins to decrease rapidly. The NO production from 02 (A 3Σ++) + N2 → NO + NO reaction may become important here, if the reaction is confirmed by experiments. These new sources of NOx call for new sinks of this species. In the upper stratosphere and mesosphere the chemical acceleration of NO dissociation via the reactions of electronically and vibrationally excited NO with 02 may help. In the lower atmosphere there is a possibility of the annihilation of NO, N02pair leading to the recreation of a stable NN bond. This might happen if N203 from NO and N02 recombination may photodissociate as N20 + 02. Unfortunately the requirements are stringent, and only experiments can tell whether or not this mechanism operates in the atmosphere.  相似文献   

12.
A new method is developed to determine the concentration profiles of chemical species from satellite measurements. The method takes into account the interaction of photochemical and radiative processes in the stratosphere and is applied for chemical species (nitric oxide and nitrogen dioxide) experiencing large diurnal changes. It is found that if the interaction of the photochemical and radiative processes is neglected, that is if the temporal and spatial variations of NO and NO2 are not considered in the radiative transfer calculations, the resulting errors for the concentration profiles for altitudes less than 20 km reach 100 and 5% respectively, for both sunset and sunrise. A photochemical scheme is developed capable of providing the mixing ratio profiles of NO and NO2 for different latitudes, altitudes and seasons and a retrieval code combining an iterative inversion algorithm, working from top of the atmosphere downwards, and a parameterization of the variability of NO and NO2 is also constructed. The method is used to examine the accuracy of the retrieval of the vertical concentration profiles and the new results show that the recovered profiles are in good agreement (error 5–15%) with measured profiles (WMO, 1985) and reflect the trends of NO and NO2 at sunset and sunrise.  相似文献   

13.
In the mesosphere, water vapor photolysis is the major source of odd hydrogen (H, OH and HO2) under normal conditions. The odd hydrogen produced may then be converted to H2 by the reaction H + HO2→ H2 + O2. This process is responsible for the calculated decrease in the H2O mixing ratio and accompanying increase in the H2 mixing ratio with altitude in the upper mesosphere and lower thermosphere. Charged particle precipitation events are calculated to produce the same effect, particularly in the 70–85 km region, thus temporarily resulting in enhanced conversion of H2O to H2 following such an event. Since odd hydrogen is produced predominantly by water vapor photolysis at these altitudes, decreased odd hydrogen concentrations are also anticipated. Odd hydrogen processes dominate ozone destruction in this region, and so an increase in ozone may occur if odd hydrogen concentrations decrease. We have examined the calculated time behavior of these processes in a numerical model using the August 1972 solar proton event as an example, and we present calculations indicating what might be observed in future events.  相似文献   

14.
In an updating of energy characteristics of lightnings on Venus obtained from Venera-9 and -10 optical observations, the flash energy is given as 8 × 108 J and the mean energy release of lightnings is 1 erg cm?2 s which is 25 times as high as that on the Earth. Lightnings were observed in the cloud layer. The stroke rate in the near-surface atmosphere is less than 5 s?1 over the entire planet if the light energy of the stroke exceeds 4 × 105 J and less than 15 s?1 for (1–4) × 105 J.The average NO production due to lightnings equals 5 × 108 cm?2 s?1, the atomic nitrogen production is equal to 7 × 109 cm?2s?1,the N flux toward the nightside is 3.2 × 109 cm?2s?1, the number densities [N] = 3 × 107cm?3 and [NO] = 1.8 × 106cm?3 at 135 km. Almost all NO molecules in the upper atmosphere vanish interacting with N and the resulting NO flux at 90-80 km equals 5 × 105cm?2s?1, which is negligibly small as compared with lightning production. If the predissociation at 80–90 km is regarded as the single sink of NO, its mixing ratio, fNO, is 4 × 10?8, for the case of a surface sink fNO = 0.8 × 10?9 at 50 km. Excess amounts, fNO ? 4 × 10?8, may exist in the thunderstorm region.  相似文献   

15.
Models are developed for the photochemistry of a CO2H2ON2 atmosphere on Mars and estimates are given for the concentrations of N, NO, NO2, NO3, N2O5, HNO2, HNO3, and N2O as a function of altitude. Nitric oxide is the most abundant form of odd nitrogen, present with a mixing ratio relative to CO2 of order 10?8. Deposition rates for nitrite and nitrate minerals could be as large as 3× 105 N equivalent atoms cm?2 sec?1 under present conditions and may have been higher in the past.  相似文献   

16.
A model for diurnal variations of neutral and ionic nitrogen compounds in the thermosphere is reconstructed on the basis of a new photochemical aspect on N(2D), together with new observations of the NO density. The NO density so far measured must be reduced by a factor 2, due to a revision of the fluorescence coefficient for the NO γ-band airglow. Incorporating the quenching reaction of N(2D) with O in the model calculation results in a reduction of the NO density at heights as low as 100 km. These two effects are combined to lead to an evaluation that the N(2D) quantum yield for various possible reactions is as large as 0.9. A smaller rate coefficient for the quenching reaction than that measured in the laboratory, i.e. 1.0 × 10?12cm3sec?1 is favourable for the recent NO observation in the early morning, as well as the observed emission rates of the 5200 A airglow from N(2D) The present model predicts a significant day-to-night variation of N and NO densities at heights above 100 km. Below 100 km, the NO density is fairly stable because of its long chemical time constant. Since the rate coefficient for the conversion of N(4S) to NO is highly temperature dependent, the relative population of N(4S) and NO is very sensitive to the thermospheric temperature variation. Large variations of both N(4S) and NO densities due to the temperature change could occur especially at night. The model is in good agreement with the NO observations so far available in low and middle latitudes, as well as the N observation by the use of a rocket in the twilight.  相似文献   

17.
A simplified D-region model consisting of O2+, NO+ and their respective cluster ions grouped as Zo2+ and ZNO+ is used to reproduce the available rocket data on positive ion relative composition and effective clustering rates for the height range 70–90 km. The results of this analysis for a winter anomalous day (Sardinia, 40°N) are in good agreement with the presently known ideas on NO densities, O2+ production rates, mesospheric temperature, negative ion to electron density ratio and effective loss coefficient for electrons. Mesospheric nitric oxide density and temperature profiles from this study are in excellent agreement with the findings of Zbinden et al. (1975) and Hidalgo (1977) for the anomalous day at Sardinia.  相似文献   

18.
Two density profiles of the thermospheric nitric oxide were obtained by means of the γ(1,0) band airglow measured with rocket-home radiometers flown from Uchinoura, Japan (31°N) at around autumnal equinoxes in 1982 and 1983. The peak densities were found at altitudes of 105–110 km and are 9 × 107 and 7 × 107 cm−3, respectively. They are well reproduced by the variation of solar activity in terms of a one-dimensional photochemical-diffusive model, but the densities above 140 km under moderate solar activity differ considerably from the model prediction. A similar discrepancy has already been found in the NO density profile obtained by our previous experiment at solar maximum. These discrepancies infer a possibility either that our understanding of thermospheric nitrogen chemisty includes a serious error, or that the meridional circulation affects considerably the NO density profile even at altitudes above 140 km and at low latitudes.  相似文献   

19.
Time variations in the solar flux between 1000 and 4000 Å induce changes in the concentrations of minor constituents in the upper stratosphere and mesosphere. The response of mesospheric ozone to variations in the Lyman α line over the course of several solar rotations may be of measurable magnitude. Large Lyman α fluxes lead to small O3 densities above 65 km due to the enhanced dissociation of H2O and resultant destruction of odd oxygen by odd hydrogen. An increase in continuum and Lyman α fluxes causes a slight enhancement in both the odd oxygen and hydrogen concentrations in the upper stratosphere.  相似文献   

20.
Nitric oxide is formed in the atmosphere through the ionization and dissociation of molecular nitrogen by galactic cosmic rays. One NO molecule is formed for each ion pair produced by cosmic ray ionization.The height-integrated input (day and night) to the lower stratosphere is of the order of 6 × 107 NO molecules cm?2/sec in the auroral zone (geomagnetic latitude Φ ? 60°) during the minimum of the sunspot cycle and 4 × 107 NO molecules cm?2/sec in the subauroral belt and auroral region (Φ? 45°) at the maximum of solar activity. The tropical production is less than 10?7 NO molecules cm?2/sec above 17 km and at the equator the production is only 3 × 106NO molecules cm?2/sec.  相似文献   

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