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1.
PHREEQC在地下水溶质反应-运移模拟中的应用 总被引：7，自引：2，他引：7
由于地下水污染的加剧,对地下水中污染物运移规律的研究日益受到重视。地下水中的溶质在运移过程中伴随着溶质组分间的化学反应,因此需要建立地下水溶质运移与化学反应的耦合模型。PHREEQC是近年来发展起来的描述局部平衡反应、动态生物化学反应的水文地球化学模拟软件。本文利用该模拟软件对一维地下水流动过程中溶质离子交换反应和动态氧化还原反应进行了模拟。结果表明,PHREEQC能够成功地进行溶质运移情况下复杂水化学反应模拟,但对于复杂地下水流和溶质运动的情况,有必要耦合其它的地下水流动和溶质运移软件来共同完成。 相似文献
2.
2007年7月在上海崇明东滩盐沼内部采用复合测量手段进行了现场观测,对取得的盐沼水动力过程数据进行了较系统的分析。崇明东滩盐沼内部的观测及分析结果表明:(1)潮沟及盐沼表面对潮波产生严重阻尼作用,潮波传播至盐沼内部时,潮沟水位波动明显异于外海,水位上升极快,而下降慢。当潮沟有退水时,涨潮初期的当地水位上升并不是潮水进入潮沟的结果,而是流向相反的潮沟进口涨潮水和潮沟内退潮水形成的水位壅高;(2)潮波进入盐沼内部时,风具有一定作用,向岸风可抬高潮沟及盐沼内部水位,离岸风反之;(3)潮沟水流流速与潮沟水位变化率、外海潮位变化率都不存在相关关系;(4)潮沟水位低时,过流断面较小,涨潮水进入潮沟时,潮沟水一旦改变流向,就具备很高的流速并伴随流速峰值的出现。潮沟水向盐沼表面漫溢时,过流断面突变,潮沟流速出现峰值。由于潮沟退潮水位变化慢,盐沼表面水归槽时并没有产生潮沟流速峰值。根据崇明东滩观测结果,概括了盐沼水动力过程的影响因素,指出了以后研究应重视的问题。 相似文献
3.
为了探究潮上带盐沼系统地层盐分分布规律及其形成机制,本研究以江苏盐城近岸盐沼湿地为例,采用电阻率测量和土壤样品分析的方法,得出土壤孔隙水盐度空间分布,并分析其与生态地貌类型的关系。结果表明,盐沼平台10 m深度以下地下水盐分较高且空间分布均匀,5 m深度以上浅层孔隙水存在显著淡化,其程度与条带状生态地貌特征相关;近潮沟区域浅层土壤孔隙水盐度接近海水,而螃蟹孔洞和互花米草区域下方地层均存在低盐区,且前者规模更大;短期潮汐过程仅影响近潮沟区域的局部地层盐分,螃蟹孔洞明显促进了降水的下渗和脱盐作用,并有助于地表蒸发和盐分集结,增大了浅层土壤水盐度的垂向差异,而植被生长引起的根系优势流和蒸发抑制作用,有效降低了表层土壤的盐度水平。 相似文献
4.
昆明市地热田越流含水系统中地下热水的数值模拟 总被引：7，自引：0，他引：7
深层基岩地下（热）水水化学污染问题日趋严重,急需定量而仿真地模拟和预报天然状态和各种人为工程经济活动下地下（热）水流动及溶质（或污染物）的运移。在充分认识地质、水文地质条件的基础上,建立了考虑温压变化和越流条件的昆明市地热田深层基岩地下热水系统中水流和溶质运移的准三维非稳定流数学模型。模型用于开采条件下地热田地下热水水位及 F－、Cl－浓度的模拟,模拟结果具有较高的仿真性,拟合误差一般小于 2％～5％,表明模型合理、可靠。应用所建模型预测了开采条件下昆明市地热田II块段地下热水流场和溶质浓度动态的变化趋势,并提出了控制地下热水环境进一步恶化的措施。 相似文献
5.
岩溶区地下水数值模拟研究进展 总被引：2，自引：2，他引：0
岩溶含水介质的不均一性导致岩溶地下水流动、溶质运移和热量迁移的数学模拟研究成为地下水模拟的难点。本文综述了岩溶区地下水流模拟的几种方法,重点阐述了等效多孔介质法、双重连续介质法和三重介质法的定义、发展过程和适用范围,并回顾了这几种方法的研究成果。从等效多孔介质法到三重介质法,模拟精度不断提高,适用范围也逐渐由大区域实际问题向小区域理论研究过渡。介绍了溶质运移模拟和热迁移模拟的研究方法及实例。溶质运移模拟以对流弥散方程为基础,其中尺度效应是溶质运移模拟的重点研究问题;热量迁移模拟应考虑地下热水密度变化对地下热水运动的影响。溶质运移模拟和热量迁移模拟往往是将迁移模型和已经调试成功的地下水流动模型相耦合,从而达到模拟溶质及热量迁移的目的。由于溶质运移和热量迁移的复杂性,现阶段水流模型多数处于等效多孔介质模型阶段。综合理论及实际应用,指出精确刻画裂隙及管道和注重基础数学算法是岩溶水数值模拟进步的关键。 相似文献
6.
《岩土力学》2018,(Z2)
填埋场底部黏土垫层特性对其长期防渗隔污服役性能的有效发挥具有极其重要的作用。针对实际堆场中黏土屏障呈现出的高饱和状态,将液相(孔隙水)与气相(闭塞气泡)视为混合流体,通过分别建立土体应力平衡方程、混合流体质量守恒方程及溶质质量守恒方程,综合考虑土颗粒-孔隙流体-溶质间的相互作用机制,推导得到了高饱和度条件下,溶质在黏土防渗层中运移的水-力-化全耦合模型,能够实现多物理场耦合作用时土层变形量、混合流体压力及溶质溶度随时空分布的直接精确求解。采用多场耦合有限元分析软件COMSOL对所建模型开展数值模拟,结果表明,模型结果与Peters所得结果吻合较好;黏土垫层中可压缩性气体的存在延缓了超孔隙流体压力的消散,加大了土层的沉降量,对溶质在防渗黏土层中的运移进程起到了显著的阻滞效果。 相似文献
7.
波浪会促进海水中溶质向海底沉积物运移,但已有研究大多未考虑海床（海底沉积物）变形效应的影响。为揭示波浪作用下海床土变形对溶质运移过程的影响机制,构建了考虑海床土变形影响的溶质运移计算模型,对波浪作用下溶质向砂质海底沉积物中的运移过程进行模拟。结果表明:海床土变形会增大孔隙水流速,进而增大溶质纵向水动力弥散系数,增强溶质运移的机械弥散作用,促进溶质向沉积物中运移;考虑海床变形时的溶质最大纵向水动力弥散系数可达不考虑海床变形时的8.5倍,约为分子扩散系数的545倍;海床土剪切模量越小,土体变形效应越明显,对溶质运移过程的影响越大;海床土饱和度的降低,会进一步加速波浪作用下溶质向海底沉积物的运移过程。 相似文献
8.
迄今为止,注入时间和静水压力对溶质在深层承压地热水中的运移规律影响研究少有报道。通过模拟35℃的低温地热环境,开展了注入时间1,2,3,4,5 h以及静水压力0,6,9 MPa条件下Cl-的运移柱模拟试验。采用CXTFIT 2.1软件进行数值模拟,探讨了孔隙型热储砂土中Cl-的运移规律和影响因素。结果表明：在模拟的低温孔隙型热储层中,不同注入时间和静水压力下,Cl-的运移曲线均呈正态对称分布,一维对流弥散(CDE)模型也可较好地表征其穿透曲线,因此溶质扩散过程符合菲克定律。注入时间的不同,会引起Cl-的穿透曲线、运移参数发生变化,这与不同注入时间条件下溶质注入总量、柱内溶质浓度差以及分子扩散能力不同有关。在不同静水压力条件下,弥散系数从0 MPa的25.22 cm2/h增加到9MPa的36.13 cm2/h,分子扩散系数、机械弥散系数以及弥散度也随之增大,因此溶质的弥散作用随静水压力的增大而增强。研究结果对于丰富地下水的溶质运移理论具有重要意义。 相似文献
9.
盐渍土壤中的物理化学作用对溶质运移具有重要影响.吸附和离子交换作用是土壤中常见的反应.利用室内土柱出流实验对这两种作用下的单组分和多组分溶质运移进行了探讨,用CXTFIT软件模拟了只考虑对流-弥散的常规溶质运移;用水文地球化学模拟软件PHREEQC进行了耦合吸附和离子交换反应的模拟.结果表明,土壤质地对单组分溶质的运移具有重要影响,而在多组分溶质运移中,组分之间的相互作用对溶质运移具有更为重要的影响,并且耦合物理化学作用的模拟精度更高. 相似文献
10.
基于CFP的岩溶管道流溶质运移数值模拟研究 总被引：2，自引：0，他引：2
多重岩溶含水介质的复杂性导致岩溶地下水流动及溶质运移的数学模拟成为地下水研究难点之一。为了探讨岩溶多重含水介质中地下水流溶质运移特征,文章构建了管道流CFP水流模型和MT3DMS溶质运移三维耦合数值模型。在阐述管道流CFP和MT3DMS基本原理的基础上,通过建立水文地质概念模型算例（1个落水洞、4个直管道）,探讨岩溶管道水流及溶质运移规律,分析讨论不同水文地质参数对浓度穿透曲线的影响。研究结果表明:管道流CFP模型能够刻画岩溶管道与基岩裂隙水流交换特征,MT3DMS模型能够模拟穿透曲线的拖尾现象,符合实际岩溶区特征。随着水力梯度、管道直径及管道渗透系数增大,孔隙度减小,浓度曲线峰值越大,峰值到达时间越快,浓度穿透曲线越对称。得出结论:耦合CFP水流模型和MT3DMS溶质运移模型能够刻画岩溶管道流溶质运移规律,为研究岩溶复杂介质污染物运移特征提供一种思路和途径。 相似文献
11.
Ditching and Ditch-Plugging in New England Salt Marshes: Effects on Hydrology, Elevation, and Soil Characteristics 总被引：1，自引：0，他引：1
Anthropogenic activities in New England salt marshes have altered hydrologic flows in various ways, but unintended consequences from some types of habitat modifications have received little attention. Specifically, ditches have existed on salt marshes for decades, but the effects of these hydrologic alterations are only poorly understood. Ditch-plugging is a more recent methodology used for salt marsh habitat enhancement and mosquito control, but the long-term effects from this management practice are also unclear. The interactions involving marsh surface elevation, soil characteristics, and hydrologic regimes result in feedbacks that regulate the salt marsh self-maintenance process, and these interactions vary with hydrologic modification. Using natural tidal creeks and pools as controls, we examined the effects of ditching and plugging, respectively, on hydrology, surface elevations, and soils. Results showed the most apparent effects of altered hydrology from ditching are prolonged pore-water retention in the rooting zone and significantly lower soil bulk density and mineral content when compared with natural creek habitat. From a management perspective, the important question is whether the combined alterations to physical and biological processes will hinder the marsh’s ability to keep pace with increasing rates of sea level rise, especially in more heavily ditched marshes. In contrast, ditch-plugging results in the decoupling of feedback processes that promote salt marsh self-maintenance and in doing so, threatens marsh stability and resilience to climate change. High surface water levels, permanently saturated soils, marsh subsidence, and significantly lower bulk density, carbon storage, soil strength, and redox levels associated with hydrologic alterations from ditch-plugging all support this conclusion. 相似文献
12.
Janet M. Fischer Tara Reed-Andersen Jennifer L. Klug Alice G. Chalmers 《Estuaries and Coasts》2000,23(4):565-571
Geomorphology may be an important predictor of vegetation pattern in systems where suceptibility to disturbance is unevenly
distributed across the landscape. Salt marsh communities exhibit spatial pattern in vegetation at a variety of spatial scales.
In coastal Georgia, the low marsh is a virtual monoculture ofSpartina alterniflora interspersed with patches of species that are more typical of the high marsh. These localized disturbances are most likely
created by wrack mats, mats of dead vegetation which can compact and smother underlying vegetation creating bare patches for
colonization by high marsh species. We investigated the spatial pattern of disturbed patches along a 2 km section of Dean
Creek, a tidal creek at the southwestern end of Sapelo Island, Georgia, U.S. We used a discriminant model to explore the relationship
between tidal creek morphology (e.g., the presence of drainage channels and creek bends) and the spatial distribution of disturbed
patches. The model predicted vegetation pattern along the creek with relatively high accuracy (>70%). Areas where water movement
is slowed or multidirectional (e.g., along creek bends and near drainage channels) were most susceptible to disturbance. Our
findings suggest an important functional linkage between geomorphology and vegetation pattern in salt marsh communities. 相似文献
13.
Surface films on marsh creeks form water-air interfaces of high biological activity. The development, movement, deposition, and breakup of the tidal creek surface film in a naturalSpartima alterniflora-dominated salt marsh in Delaware were followed seasonally over tidal cycles. The metabolic activity, i.e., photosynthesis and respiration, of the surface film and underlying water were determined in the field at the time of peak film formation, just prior to high tide, and the particulate material and chlorophylla were quantified over the tidal cycles. The quantities of organic and inorganic components of the particulate material were all significantly higher in the surface film than in the underlying water (on a volume basis). Numbers of algal cells and quantities of chlorophyll were orders of magnitude greater in the surface film than in the water column. Photosynthesis and respiration were significantly higher in the surface film than in the underlying water. The spectrum of fatty acids was more diverse and their total content was significantly greater in the surface film than in the water column, indicating a concentrated food source contributed by the film as well as a biological richness of the film. When water in the creek flooded the marsh plain at high tide, film deposition was greatest on simulated creek bankS. alterniflora stems, compared to stems along rivulets in the marsh and those in the marsh plain. Using surface film dry weight measurements on an areal basis and film velocity in the creek, both measured throughout a tidal cycle during the summer, it was determined that approximately 12 kg (dry weight) of particulate material moved on the creek surface (2 m wide) past a given point on the flood tide, and 14 kg moved in the opposite direction on the ebb tide. The biological and physical data collected in this study illuminate the contribution of the surface film to the biological (food web) and physical (sediment transport and deposition) functions of a salt marsh. 相似文献
14.
Flow paths of water and sediment in a tidal marsh: Relations with marsh developmental stage and tidal inundation height 总被引：1，自引：0，他引：1
This study provides new insights in the relative role of tidal creeks and the marsh edge in supplying water and sediments to and from tidal marshes for a wide range of tidal inundation cycles with different high water levels and for marsh zones of different developmental stage. Net import or export of water and its constituents (sediments, nutrients, pollutants) to or from tidal marshes has been traditionally estimated based on discharge measurements through a tidal creek. Complementary to this traditional calculation of water and sediment balances based on creek fluxes, we present novel methods to calculate water balances based on digital elevation modeling and sediment balances based on spatial modeling of surface sedimentation measurements. In contrast with spatial interpolation, the presented approach of spatial modeling accounts for the spatial scales at which sedimentation rates vary within tidal marshes. This study shows that for an old, high marsh platform, dissected by a well-developed creek network with adjoining levees and basins, flow paths are different for tidal inundation cycles with different high water levels: during shallow inundation cycles (high water level <0.2 m above the creek banks) almost all water is supplied via the creek system, while during higher inundation cycles (high water level >0.2 m) the percentage of water directly supplied via the marsh edge increases with increasing high water level. This flow pattern is in accordance with the observed decrease in sedimentation rates with increasing distance from creeks and from the marsh edge. On a young, low marsh, characterized by a gently seaward sloping topography, material exchange does not take place predominantly via creeks but the marsh is progressively flooded starting from the marsh edge. As a consequence, the spatial sedimentation pattern is most related to elevation differences and distance from the marsh edge. Our results imply that the traditional measurement of tidal creek fluxes may lead in many cases to incorrect estimations of net sediment or nutrient budgets. 相似文献
15.
Field experiments were completed to determine patterns of evapotranspirative water loss from salt and tidal freshwater marshes in Virginia. Water losses from “Mariotte systems” attached to open-water lysimeters and lysimeters vegetated by dominant marsh macrophytes were used to calculate hourly rates of open-water evaporation (Eo) and evapotranspiration (ET), respectively, during low tide. In the tidal freshwater marsh, ET was significantly greater than Eo (p=0.002, n=6); in the salt marsh, there were no differences between mean rates of ET and Eo (p=0.200, n=3). The ratio ET:Eo was highly correlated with leaf area index (LAI) (r2=0.82). In the tidal freshwater marsh, the amount of water loss due to plant transpiration was partitioned from total evapotranspiration by covering the water surface of the lysimeters with styrofoam beads. Measured transpiration rates in the tidal freshwater marsh were strongly correlated with leaf area index according to the following linear regression equation: T=0.355(LAI)?0.084 (r2=0.797, n=10). Because LAI was shown to be a good predictor of the relative increase in ET over Eo, it is likely that in vegetated tidal freshwater marshes with high leaf densities most atmospheric water loss comes from plants, not from the surface of the marsh. In salt marshes, low plant densities do not contribute substantially to atmospheric water loss, suggesting that paths of water transport and patterns of solute concentration in the subsurface environment are different compard to the tidal freshwater marsh. 相似文献
16.
Mummichog,Fundulus heteroclitus, were collected weekly from a southern New Jersey high-salinity salt marsh from October 1988 to June 1989 and from September 1989 to June 1990 to determine the overwintering habitat. Major habitat types sampled within the salt marsh were subtidal creek, intertidal creeks, and salt-marsh pools. Few individuals were collected in the intertidal creek or the subtidal creek from the end of October through the beginning of May for both years, when creek water temperatures were low. Both young-of-the-year and adults of both sexes were abundant in the salt-marsh pools (total lengths ranged from 29 mm to 125 mm) throughout the winter. In the spring, catch per unit effort (CPUE) within the tidal creek increased with increasing water temperature, while CPUE in marsh pools decreased with increases in estuarine water temperature. These collection patterns indicate that the majority ofF. heteroclitus may move from subtidal and intertidal creeks into salt-marsh pools in the late fall and leave in the spring. This seasonal movement could explain how fish survive winter environmental conditions because daily average water temperatures of salt-marsh pools were warmer than subtidal creek temperatures for much of the winter. 相似文献
17.
Evelyn B. Haines 《Estuaries and Coasts》1979,2(1):34-39
The amount of nitrogen present as ammonia, nitrate, nitrite, dissolved organic nitrogen, and particulate nitrogen was determined for nearshore Georgia shelf waters and for tidal water inundating a 0.5 hectare dikedSpartina alterniflora salt marsh in the adjacent estuary. Concentrations of ammonia, nitrate, and nitrite were comparatively low in offshore water (<2.2 μg-at N/1), and in high tide water in the marsh (<9.9 μg-at N/1). High concentrations of ammonia, up to 73.4 μg-at N/1, were measured in low tide water draining from marsh. The largest pools of nitrogen in offshore water and in high tide water in the marsh creek were dissolved organic nitrogen (DON) (2.5 to 20.4 μg-at N/1) and particulate nitrogen (PN) (0.1 to 30.0 μg-at N/1). Concentrations in marsh creek water at low tide were higher, ranging from 4.4 to 38.0 μg-at N/1 for DON and from 13.0 to 239.0 μg-at N/1 for PN. Comparisons of the average concentrations of dissolved and particulate forms of nitrogen in the marsh tidal creek during flood and during ebb tide suggested no net movement of the inorganic nitrogen nutrients, a net influx of PN to the marsh, and a net outflux of DON from the marsh. 相似文献
18.
J. Blake Clark Wen Long Maria Tzortziou Patrick J. Neale Raleigh R. Hood 《Estuaries and Coasts》2018,41(3):708-723
Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River. 相似文献
19.
In October of 2004, a 3-d observational program to measure flow and sediment resuspension within a coastal intertidal salt
marsh was conducted in the North Inlet/Winyah Bay National Estuarine Research Reserve located near Georgetown, South Carolina.
Current and acoustic backscatter profiles were obtained from a moored acoustic Doppler current profiler (ADCP) deployed in
a shallow tidal channel during the spring phase of the tidal cycle under high discharge conditions. The channel serves as
a conduit between Winyah Bay, a large brackish estuary, and North Inlet, a saline intertidal coastal salt marsh with little
freshwater input. Salinity measurements indicate that the water column is vertically well mixed during flood, but becomes
vertically stratified during early ebb. The stratification results from brackish (15 psu) Winyah Bay water entering North
Inlet via the tidal channel, suggesting an exchange mechanism that permits North Inlet to receive a fraction of the poor water
quality and high discharge flow from upland rivers. Although maximum flood currents exceed maximum ebb currents by 0.2 m s−1, suspended sediment concentrations are highest during the latter ebb phase and persist for a longer fraction of the ebb cycle.
Even though the channel is flood-dominated, the higher concentrations occurring over a longer fraction of the ebb phase indicate
net particulate transport from Winyah Bay to North Inlet during spring tide accompanied by high discharge. Our evidence suggests
that the higher concentrations during ebb result from increased bed friction caused by flow asymmetries and variations in
water depth in which the highest stresses occur near the end of ebb near low water despite stronger maximum currents during
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