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1.
Abstract– Eight saponite‐rich micrometeorites with very similar mineralogy were found from the recent surface snow in Antarctica. They might have come to Earth as a larger meteoroid and broke up into pieces on Earth, because they were recovered from the same layer and the same location of the snow. Synchrotron X‐ray diffraction (XRD) analysis indicates that saponite, Mg‐Fe carbonate, and pyrrhotite are major phases and serpentine, magnetite, and pentlandite are minor phases. Anhydrous silicates are entirely absent from all micrometeorites, suggesting that their parental object has undergone heavy aqueous alteration. Saponite/serpentine ratios are higher than in the Orgueil CI chondrite and are similar to the Tagish Lake carbonaceous chondrite. Transmission electron microscope (TEM) observation indicates that serpentine occupies core regions of fine‐grained saponite, pyrrhotite has a low‐Ni concentration, and Mg‐Fe carbonate shows unique concentric ring structures and has a mean molar Mg/(Mg + Fe) ratio of 0.7. Comparison of the mineralogy to hydrated chondrites and interplanetary dust particles (IDPs) suggests that the micrometeorites are most similar to the carbonate‐poor lithology of the Tagish Lake carbonaceous chondrite and some hydrous IDPs, but they show a carbonate mineralogy dissimilar to any primitive chondritic materials. Therefore, they are a new variant of saponite‐rich micrometeorite extracted from a primitive hydrous asteroid and recently accreted to Antarctica.  相似文献   

2.
Abstract— Over 100 000 large interplanetary dust particles in the 50–500 μm size range have been recovered in clean conditions from ～600 tons of Antarctic melt ice water as both unmelted and partially melted/dehydrated micrometeorites and cosmic spherules. Flux measurements in both the Greenland and Antarctica ice sheets indicate that the micrometeorites deliver to the Earth's surface ～2000× more extraterrestrial material than brought by meteorites. Mineralogical and chemical studies of Antarctic micrometeorites indicate that they are only related to the relatively rare CM and CR carbonaceous chondrite groups, being mostly chondritic carbonaceous objects composed of highly unequilibrated assemblages of anhydrous and hydrous minerals. However, there are also marked differences between these two families of solar system objects, including higher C/O ratios and a very marked depletion of chondrules in micrometeorite matter; hence, they are “chondrites-without-chondrules.” Thus, the parent meteoroids of micrometeorites represent a dominant and new population of solar system objects, probably formed in the outer solar system and delivered to the inner solar system by the most appropriate vehicles, comets. One of the major purposes of this paper is to discuss applications of micrometeorite studies that have been previously presented to exobiologists but deal with the synthesis of prebiotic molecules on the early Earth, and more recently, with the early history of the solar system.  相似文献   

3.
Abstract– On the basis of morphological and petrographic characteristics, eight “giant” unmelted micrometeorites in the 300–1100 μm size range were selected from the Transantarctic Mountain micrometeorite collection, Victoria Land, Antarctica. Mineralogical and geochemical data obtained by means of scanning electron microscopy, electron probe microanalyses, and synchrotron X‐ray diffraction allow their classification as chondritic micrometeorites. The large size of the micrometeorites increases considerably the amount of mineralogical and geochemical information compared to micrometeorites in smaller size fractions, therefore allowing a better definition of their parent material. A large variety of material is observed: five micrometeorites are related to unequilibrated and equilibrated ordinary chondrite, one to CV chondrite, one to CM chondrite, and one to CI chondrite parent materials. Besides reporting the first occurrence of a CV‐like micrometeorite, our study shows that the abundance of chondritic material supports observations from recent studies on cosmic spherules that a large part of the micrometeorite flux in this size range is of asteroidal origin.  相似文献   

4.
Extraterrestrial particulate materials on the Earth can originate in the form of collisional debris from the asteroid belt, cometary material, or as meteoroid ablation spherules. Signatures that link them to their parent bodies become obliterated if the frictional heating is severe during atmospheric entry. We investigated 481 micrometeorites isolated from ~300 kg of deep sea sediment, out of which 15 spherules appear to have retained signatures of their provenance, based on their textures, bulk chemical compositions, and relict grain compositions. Seven of these 15 spherules contain chromite grains whose compositions help in distinguishing subgroups within the ordinary chondrite sources. There are seven other spherules which comprise either entirely of dusty olivines or contain dusty olivines as relict grains. Two of these spherules appear to be chondrules from an unequilibrated ordinary chondrite. In addition, a porphyritic olivine pyroxene (POP) chondrule‐like spherule is also recovered. The bulk chemical composition of all the spherules, in combination with trace elements, the chromite composition, and presence of dusty olivines suggest an ordinary chondritic source. These micrometeorites have undergone minimal frictional heating during their passage through the atmosphere and have retained these features. These micrometeorites therefore also imply there is a significant contribution from ordinary chondritic sources to the micrometeorite flux on the Earth.  相似文献   

5.
Abstract— We discuss the relationship between large cosmic dust that represents the main source of extraterrestrial matter presently accreted by the Earth and samples from comet 81P/Wild 2 returned by the Stardust mission in January 2006. Prior examinations of the Stardust samples have shown that Wild 2 cometary dust particles contain a large diversity of components, formed at various heliocentric distances. These analyses suggest large‐scale radial mixing mechanism(s) in the early solar nebula and the existence of a continuum between primitive asteroidal and cometary matter. The recent collection of CONCORDIA Antarctic micrometeorites recovered from ultra‐clean snow close to Dome C provides the most unbiased collection of large cosmic dust available for analyses in the laboratory. Many similarities can be found between Antarctic micrometeorites and Wild 2 samples, in terms of chemical, mineralogical, and isotopic compositions, and in the structure and composition of their carbonaceous matter. Cosmic dust in the form of CONCORDIA Antarctic micrometeorites and primitive IDPs are preferred samples to study the asteroid‐comet continuum.  相似文献   

6.
Abstract— Depending on their velocity, entry angle and mass, micrometeorites suffer different degrees of heating during their deceleration in the Earth's atmosphere, leading, in most cases, to significant textural, mineralogical and chemical modifications. One of these modifications is the formation of a magnetite shell around most micrometeorites, which until now could not be reproduced, neither theoretically nor experimentally. The present study was designed to better understand the entry heating effects on micrometeorites and especially the formation of the magnetite shell. Fragments of the Murchison and Orgueil meteorites were used as analogue material in flash‐heating experiments performed in a high‐temperature furnace; effects of temperature, heating duration, and oxygen fugacity were investigated. These experiments were able to reproduce most of the micrometeorites textures, from the vesicular fine‐grained micrometeorites to the totally melted cosmic spherules. For the first time, the formation of a magnetite shell could be observed on micrometeorite analogues. We suggest that the most plausible mechanism for the formation of this shell is a peripheral partial melting with subsequent magnetite crystallization at the surface of the micrometeorite. Furthermore, with this study, it is possible to estimate the atmospheric entry conditions of micrometeorites, such as the peak temperature and the duration of flash‐heating.  相似文献   

7.
The early stages of atmospheric entry are investigated in four large (250–950 μm) unmelted micrometeorites (three fine‐grained and one composite), derived from the Transantarctic Mountain micrometeorite collection. These particles have abundant, interconnected, secondary pore spaces which form branching channels and show evidence of enhanced heating along their channel walls. Additionally, a micrometeorite with a double‐walled igneous rim is described, suggesting that some particles undergo volume expansion during entry. This study provides new textural data which links together entry heating processes known to operate inside micrometeoroids, thereby generating a more comprehensive model of their petrographic evolution. Initially, flash heated micrometeorites develop a melt layer on their exterior; this igneous rim migrates inwards. Meanwhile, the particle core is heated by the decomposition of low‐temperature phases and by volatile gas release. Where the igneous rim acts as a seal, gas pressures rise, resulting in the formation of interconnected voids and higher particle porosities. Eventually, the igneous rim is breached and gas exchange with the atmosphere occurs. This mechanism replaces inefficient conductive rim‐to‐core thermal gradients with more efficient particle‐wide heating, driven by convective gas flow. Interconnected voids also increase the likelihood of particle fragmentation during entry and, may therefore explain the rarity of large fine‐grained micrometeorites among collections.  相似文献   

8.
The scientific value of micrometeorites collected from deep-sea sediments or glacial deposits can be limited by poorly constrained accumulation times or severe alteration, coupled with a complex infrastructure of sampling expeditions. Collecting micrometeorites from rooftops has recently become a feasible alternative, but extraction methods have not been optimized or standardized to date. Here, we show that existing methods for the recovery of melted cosmic spherules (CSs) can be strongly improved by using a sequence of mineral separation techniques, including shape separation with an asymmetric vibrator and heavy liquid density separation with overflow centrifuges. We retrieved 1006 micrometeorites from the gutter of a barn in Budel, the Netherlands. Particle diameters are 80–515 μm, with the major mode at 130 μm and a slope exponent of −4.88. Differences in size distributions among various types of CSs indicate a multi-source influx, with CS textures controlled by their parent body's mineralogy and orbital parameters. Repeated sampling of the rooftop after accumulation times of 959 and 333 days allows for a time-integrated global mass flux estimate of 472 t year−1. This estimate is notably higher than previous rooftop-based estimates but is still severely affected by micrometeorite loss from the gutter through drainage. The mass flux peaks at an equivalent particle diameter of ~200 μm. The Budel collection is the first rooftop collection to contain abundant vitreous micrometeorites and include the coarse-grained S-type CS class. Unmelted and I-type micrometeorites remain difficult to extract from rooftop samples. Vitreous micrometeorites display various stages of weathering, showing that severe alteration of glass can progress at a faster rate in populated regions than previously assumed. This study demonstrates that methodological adjustments can drastically increase the scientific potential of rooftop micrometeorite collections.  相似文献   

9.
X‐ray microtomography (XMT), X‐ray diffraction (XRD), and magnetic hysteresis measurements were used to determine micrometeorite internal structure, mineralogy, crystallography, and physical properties at μm resolution. The study samples include unmelted, partially melted (scoriaceous), and completely melted (cosmic spherules) micrometeorites. This variety not only allows comparison of the mineralogy and porosity of these three micrometeorite types but also reveals changes in meteoroid properties during atmospheric entry at various velocities. At low entry velocities, meteoroids do not melt and their physical properties do not change. The porosity of unmelted micrometeorites varies considerably (0–12%) with one friable example having porosity around 50%. At higher velocities, the range of meteoroid porosity narrows, but average porosity increases (to 16–27%) due to volatile evaporation and partial melting (scoriaceous phase). Metal distribution seems to be mostly unaffected at this stage. At even higher entry velocities, complete melting follows the scoriaceous phase. Complete melting is accompanied by metal oxidation and redistribution, loss of porosity (1 ± 1%), and narrowing of the bulk (3.2 ± 0.5 g cm?3) and grain (3.3 ± 0.5 g cm?3) density range. Melted cosmic spherules with a barred olivine structure show an oriented crystallographic structure, whereas other subtypes do not.  相似文献   

10.
Abstract— We have investigated the texture, bulk chemistry, mineralogy, as well as the anhydrous minerals oxygen isotopic composition of 67 small Antarctic micrometeorites (AMMs) collected at Cap Prudhomme, Antarctica, and belonging to the currently poorly studied size fraction 25–50 μm. When compared to larger (50–400 μm) micrometeorites collected at the same site in Antarctica with the same techniques, no significant differences are found between the two populations. We therefore conclude that the population of Cap Prudhomme AMMs is homogeneous over the size range 25–400 μm. In contrast, small AMMs have different textures, mineralogy, and oxygen isotopic compositions than those of stratospheric interplanetary dust particles (IDPs). Because small AMMs (<50 μm) overlap in size with IDPs, the differences between these two important sources of micrometeorites can no longer be attributed to a variation of the micrometeorite composition with size. Physical biases introduced by the collection procedures might account for these differences.  相似文献   

11.
Abstract— Cosmic dust accreted by the Earth can be extensively reprocessed during atmospheric encounters. The textures and compositions of reprocessed material provide important constraints by which the processes affecting extraterrestrial matter in the Earth's atmosphere can be better understood. Here we report results on an unusual Antarctic glassy cosmic spherule that demonstrates strong textural evidence for at least two grazing incidence encounters with the Earth's atmosphere prior to final reentry. The particle consists of a central glassy core with four peripheral glass lobes that transect a silicate particle rim. The texture of the particle confirms previous theoretical speculations that some high velocity, low incidence angle interplanetary particles experience numerous encounters with the Earth's atmosphere and also indicates that micrometeorites demonstrating multiple melting episodes should be interpreted with caution.  相似文献   

12.
Abstract— Calcium, aluminum-rich inclusions (CAIs) are characteristic components in carbonaceous chondrites. Their mineralogy is dominated by refractory oxides and silicates like corundum, perovskite, spinel, hibonite, melilite, and Ca-pyroxene, which are predicted to be the first phases to have condensed from the cooling solar nebula. Allowing insights into processes occurring in the early solar system, CAIs in carbonaceous and ordinary chondrites were studied in great detail, whereas only a few refractory inclusions were found and studied in stratospheric interplanetary dust particles (IDPs) and micrometeorites. This study gives a summary of all previous studies on refractory inclusions in stratospheric IDPs and micrometeorites and will present new data on two Antarctic micrometeorites. The main results are summarized as follows: (a) Eight stratospheric IDPs and six micrometeorites contain Ca, Al-rich inclusions or refractory minerals. The constituent minerals include spinel, perovskite, fassaite, hibonite, melilite, corundum, diopside and anorthite. (b) Four of the seven obtained rare-earth-element (REE) patterns from refractory objects in stratospheric IDPs and micrometeorites are related to Group III patterns known from refractory inclusions from carbonaceous chondrites. A Group II related pattern was found for spinel and perovskite in two micrometeorites. The seventh REE pattern for an orthopyroxene is unique and can be explained by fractionation of Gd, Lu, and Tb at highly reducing conditions. (c) The O-isotopic compositions of most refractory objects in stratospheric IDPs and micrometeorites are similar to those of constituents from carbonaceous chondrites and fall on the carbonaceous chondrites anhydrous minerals mixing line. In fact, in most cases, in terms of mineralogy, REE pattern and O-isotopic composition of refractory inclusions in stratospheric IDPs and micrometeorites are in good agreement with a suggested genetic relation of dust particles and carbonaceous chondrites. Only in the case of one Antarctic micrometeorite does the REE pattern obtained for an orthopyroxene point to a link of this particle to enstatite chondrites.  相似文献   

13.
The effect of micrometeorite impacts upon the surface of a spacecraft on the accuracy of astrometric measurements made by scanning with instruments onboard the spacecraft is considered. This effect is shown to be marginal for HIPPARCOS measurements. However, disregarding this kind of effect for all the currently projected spacecraft may result in the declared measurement accuracy being unachievable. Spacecraft maintaining constant spatial orientation during measurements are essentially not subject to the errors caused by collisions with micrometeorites.  相似文献   

14.
We identified 66 chromite grains from 42 of ~5000 micrometeorites collected from Indian Ocean deep‐sea sediments and the South Pole water well. To determine the chromite grains precursors and their contribution to the micrometeorite flux, we combined quantitative electron microprobe analyses and oxygen isotopic analyses by high‐resolution secondary ion mass spectrometry. Micrometeorite chromite grains show variable O isotopic compositions with δ18O values ranging from ?0.8 to 6.0‰, δ17O values from 0.3 to 3.6‰, and Δ17O values from ?0.9 to 1.6‰, most of them being similar to those of chromites from ordinary chondrites. The oxygen isotopic compositions of olivine, considered as a proxy of chromite in chromite‐bearing micrometeorites where chromite is too small to be measured in ion microprobe have Δ17O values suggesting a principal relationship to ordinary chondrites with some having carbonaceous chondrite precursors. Furthermore, the chemical compositions of chromites in micrometeorites are close to those reported for ordinary chondrite chromites, but some contribution from carbonaceous chondrites cannot be ruled out. Consequently, carbonaceous chondrites cannot be a major contributor of chromite‐bearing micrometeorites. Based on their oxygen isotopic and elemental compositions, we thus conclude with no ambiguity that chromite‐bearing micrometeorites are largely related to fragments of ordinary chondrites with a small fraction from carbonaceous chondrites, unlike other micrometeorites deriving largely from carbonaceous chondrites.  相似文献   

15.
Fe‐Ni metal is a common constituent of most meteorites and is an indicator of the thermal history of the respective meteorites, it is a diagnostic tool to distinguish between groups/subgroups of meteorites. In spite of over a million micrometeorites collected from various domains, reports of pure metallic particles among micrometeorites have been extremely rare. We report here the finding of a variety of cosmic metal particles such as kamacite, plessite, taenite, and Fe‐Ni beads from deep‐sea sediments of the Indian Ocean, a majority of which have entered the Earth unaffected by frictional heating during atmospheric entry. Such particles are known as components of meteorites but have never been found as individual entities. Their compositions suggest precursors from a variety of meteorite groups, thus providing an insight into the metal fluxes on the Earth. Some particles have undergone heating and oxidation to different levels during entry developing features similar to I‐type cosmic spherules, suggesting atmospheric processing of individual kamacites/taenite grains as another hitherto unknown source for the I‐type spherules. The particles have undergone postdepositional aqueous alteration transforming finally into the serpentine mineral cronstedtite. Aqueous alteration products of kamacite reflect the local microenvironment, therefore they have the potential to provide information on the composition of water in the solar nebula, on the parent bodies or on surfaces of planetary bodies. Our observations suggest it would take sustained burial in water for tens of thousands of years under cold conditions for kamacites to alter to cronstedtite.  相似文献   

16.
Abstract– Previous studies of limestone beds of mid‐Ordovician age from both Sweden and China show that the Earth saw an at least two orders of magnitude increase in the influx of extraterrestrial material approximately 470 Ma, following the disruption of an L‐chondrite parent body in the asteroid belt. Recovered extraterrestrial material consists of fossil meteorites and sediment‐dispersed extraterrestrial chromite (SEC) grains, both with L‐chondritic origin. Ne isotope analysis of SEC grains from one of the Swedish limestone sections revealed that the vast majority of the grains were delivered to Earth as micrometeorites. In this study, we extend the previous work, both in time and geographically, by measuring concentrations and isotopic ratios of Ne in individual SEC grains (60–120 μm in diameter) from three different beds from a contemporary Middle Ordovician limestone section in China. All of the Chinese SEC grains, 44 in total, contain surface‐implanted Ne of fractionated solar wind composition, implying that these grains were, as in the case of the Swedish SEC grains, delivered to Earth as micrometeorites. This gives further compelling evidence that the two to three orders of magnitude increase in the influx of micrometeoritic material following the breakup of the L‐chondrite parent body was indeed a global event. The rain of micrometeorites prevailed for at least 2 Myr (the estimated time of the deposition of the topmost Chinese bed) after the breakup event.  相似文献   

17.
The orientations of dehydration cracks and fracture networks in fine‐grained, unmelted micrometeorites were analyzed using rose diagrams and entropy calculations. As cracks exploit pre‐existing anisotropies, analysis of their orientation provides a mechanism with which to study the subtle petrofabrics preserved within fine‐grained and amorphous materials. Both uniaxial and biaxial fabrics are discovered, often with a relatively wide spread in orientations (40°–60°). Brittle deformation cataclasis and rotated olivine grains are reported from a single micrometeorite. This paper provides the first evidence for impact‐induced shock deformation in fine‐grained micrometeorites. The presence of pervasive, low‐grade shock features in CM chondrites and CM‐like dust, anomalously low‐density measurements for C‐type asteroids, and impact experiments which suggest CM chondrites are highly prone to disruption all imply that CM parent bodies are unlikely to have remained intact and instead exist as a collection of loosely aggregated rubble‐pile asteroids, composed of primitive shocked clasts.  相似文献   

18.
The X-ray spectrometer of the Near-Earth Asteroid Rendezvous (NEAR) mission discovered a low abundance of sulfur on the surface of asteroid Eros, which is seemingly inconsistent with the match of the overall surface composition to that of ordinary chondrites. Since troilite, FeS, is the primary sulfur-bearing mineral in ordinary chondrites, we investigated the hypothesis that sulfur loss from surface FeS could result from ‘space weathering’ by impact of solar wind ions and micrometeorites. We performed laboratory studies on the chemical alteration of FeS by 4 keV ions simulating exposure to the solar wind and by nanosecond laser pulses simulating pulsed heating by micrometeorite impact. We found that the combination of laser irradiation followed by ion impact lowers the S:Fe atomic ratio on the surface by a factor of up to 2.5, which is consistent with the value of at least 1.5 deduced from the NEAR measurements. Thus, our results support the hypothesis that the low abundance of sulfur at the surface of Eros is caused by space weathering.  相似文献   

19.
Abstract— The C contents and δ13C values of eleven individual micrometeorites have been determined using a combination of stepped combustion and static mass spectrometry. A new low-blank procedure, involving pretreatment of the samples with a solvent to remove surficial contaminants, has enabled samples of 6–84 μg to be analysed successfully. The eleven samples (seven separated from Greenland cryoconite and four from Antarctic ice) were each split prior to C determination and a fragment taken for study using analytical electron microscopy. In this way, the chemical compositions were obtained thereby allowing comparison with other investigations. As with previous studies of micrometeorites collected at the Earth's surface, the major difficulty with interpreting the results involves distinguishing indigenous components from terrestrial contaminants. Overall C contents were typically <0.2 wt%, although one of the Greenland samples contained 1.5 wt% C, considered to arise mainly from algal contamination. For the other samples, around 0.05–0.15 wt% of the total C in each micrometeorite was considered to be organic in nature with at least some of this (if not all) being terrestrial in origin; the remainder was probably indigenous, being analogous to the macromolecular organic material found in primitive carbonaceous chondrites. The generally low content of this indigenous organic material, compared to conventional meteorites, is presumably a reflection of C loss from the micrometeorites either during atmospheric heating, or subsequent weathering. For that C combusting between 500 and 600 °C, ten of the samples appeared to show a simple two-component system (i.e., a mixture of blank and an isotopically light component; δ13C > ?32%). It is possible that the light component is Cδ, a fine-grained form of presolar diamond which is known to be prevalent in primitive chondritic meteorites. If so, then it is present in the micrometeorites at concentrations of ～30–600 ppm (typically 200 ppm), which is a similar level to that in meteorites. An analysis of algae separated from Greenland cryoconite shows tentative evidence for the presence of extraterrestrial silicon carbide; however, further work will be needed to substantiate this  相似文献   

20.
In this study, we present a method for high precision Δ′17O (Δ′17ORL = ln(δ17O + 1) – λRL ln(δ18O + 1)) analysis of small mass silicate and oxide materials. The analyses were conducted by laser fluorination in combination with gas chromatography and continuous flow isotope ratio monitoring gas spectrometry. We could analyze the oxygen isotope composition of samples down to 1 μg, which corresponded to about 13 nmol O2. The analytical error (we report the 1σ external reproducibility of a single analysis) in δ18O increases with decreasing sample sizes from ~0.2‰ for ~20 μg samples to ~0.9‰ for 1 μg samples. For Δ′17O, we achieved an external reproducibility of 0.04‰ for a sample mass range between 1 and 27 μg. The uncertainty in Δ′17O is smaller than the uncertainty in δ18O due to the correlated errors in δ17O and δ18O. We applied the method to urban micrometeorites, that is, small meteorites (<2 mm) that were sampled from a rooftop in Berlin, Germany. A total of 10 melted micrometeorites (S-type cosmic spherules, masses between 11 and 22 μg) were analyzed. The oxygen isotope compositions are comparable to that of modern Antarctic collections, indicating that the urban micrometeorites sample the same population. No indication for terrestrial weathering had been identified in the studied set of urban micrometeorites making them suitable materials for the study of micrometeorite origins.  相似文献   

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