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近年来,报道了内蒙白云鄂博群中一些新认识的岩石类型(徐志平等,1980;李继亮与胡辅佑,1981;李继亮,1981)。这些岩石的深入研究,无疑将对内蒙地区元古代地质发展史和白云鄂博群的成矿作用提供有益的证据。1980年,我们考查了白云鄂博镇西面元古界白云鄂博群的酸性火山岩,并进行了初步的室内分析,这里作一简要报道。 相似文献
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关于褐钇铌矿族的研究,国内外积累了不少资料。其主要产在黑云母花岗岩、花岗伟晶岩、微斜长石岩、交代变质岩、蚀变花岗岩、白岗岩及花岗岩的残坡积和冲积砂中。1979年我们在进行内蒙白云鄂博铌、稀土、铁矿床物质成分的研究时,在白云石型铌、稀土矿石中发现含铈褐钇铌矿,与该区原已发现的褐铈铌矿等矿物组成了褐钇铌矿-褐铈铌矿系列。 相似文献
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白云鄂博矿床是世界上最大的稀土矿床,同时也是一个特大型铌矿和大型铁矿,其成矿时代及成因至今仍有多种不同认识。本研究从东部接触带(菠萝头山)3号铌矿体内的金云母岩中获得残留锆石和热液独居石,测得其U-Pb年龄分别为269.5±3.1 Ma和249±13 Ma;从巴音敖包伟晶岩中获得热液锆石,测得其U-Pb年龄为248.9±2.5 Ma。结合阿尔泰—天山—北山—内蒙古—大兴安岭—小兴安岭造山带中的成矿年龄资料,笔者推测,在248%251 Ma白云鄂博地区发生了一次强烈的热液活动,该热液活动的时间可以代表白云鄂博矿床的成矿年龄。基于绝大多数稀有金属热液矿床都是与花岗质岩浆活动关联的,本研究对白云鄂博地区出露的两类花岗岩进行了岩相学、矿物学、地球化学和锆石学分析,从而确定白云鄂博花岗岩基中的黑云母二长花岗岩(主体相)为同碰撞花岗岩,其定位年龄为269.8±2.0 Ma;而白云鄂博花岗岩基中的二云母碱长花岗岩(补体相)为碰撞后花岗岩,其定位年龄为250.5±6.0 Ma。根据二云母碱长花岗岩的成岩年龄等于白云鄂博矿床的成矿年龄,以及大量的野外地质现象和区域地质资料,笔者认为:(1)该二云母碱长花岗岩为白云鄂博矿床的成矿母岩,它的岩浆直接来自地壳深部岩浆房;(2)该岩浆房就是同碰撞花岗岩浆的岩浆房,这意味着留存在该岩浆房中的巨量花岗岩浆经历了近20 Ma的分离结晶作用,从而在岩浆房上部聚集了富含成矿物质的残余花岗岩浆;(3)当构造环境由挤压转为拉张时,该残余花岗岩浆沿着张性断裂被动侵位。由于快速上升引起压力和温度的骤降,富含稀有金属(稀土和铌)、卤素(氟)和碱金属的硅质热液从残余花岗岩浆中分离出来;(4)这种硅质热液沿断裂构造率先进入白云鄂博群H_8白云岩岩层,与碳酸盐发生交代反应,其稀土和铌金属元素沉淀成矿;同时,H_8白云岩岩层中的菱铁矿和铁白云石分解,释放出Fe~(2+)和[CO_3](2-),前者(Fe~(2+))经近距离迁移后沉淀成铁矿,后者([CO_3]~(2-))与少量稀土—铌元素结合成金属—碳酸络合物,呈脉状穿插在H_8白云岩中,或迁移至H_8白云岩的外围。该认识首次将白云鄂博地区的构造、成岩和成矿有机地统一起来,从而阐释了一个致白云鄂博矿床形成的能量和物质的运移过程;同时,该认识可以整合多种流行的白云鄂博矿床成因认识("正常或热水沉积说"、"火成碳酸岩说"、"热液交代说"等等)中的合理因素;笔者认为,它是一个全面、系统而又新颖的白云鄂博矿床的成矿模式。 相似文献
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内蒙古白云鄂博地区晚古生代闪长质-花岗质岩石年代学框架及其地质意义 总被引：12，自引：6，他引：6
华北克拉通北缘的内蒙古白云鄂博地区分布着由辉长岩、辉长闪长岩、花岗闪长岩、二长花岗岩、黑云母花岗岩及钾长花岗岩等基性-中酸性-碱性花岗岩组成的闪长质-花岗质杂岩体,它们曾被认为是泥盆纪至侏罗纪多期次侵位的产物,而新的年代学资料揭示这些侵入体都是在晚古生代形成的.白云鄂博地区15件不同岩性的锆石LA-ICP-MS U-Pb测年表明,其侵位年龄具有很好的一致性,仅发生在263～281Ma狭窄时间段内,峰期年龄269Ma.这表明白云鄂博矿床的形成与这些闪长质-花岗质岩石的侵入活动没有直接的成因联系,也为重新认识华北克拉通北缘晚古生代构造环境及演化史提供了新的年代学资料. 相似文献
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内蒙古白云鄂博REE-Nb-Fe矿是目前世界上最大的稀土矿床。在白云鄂博东矿体的东南侧,分布有大面积的晚古生代花岗岩。花岗岩与赋矿白云岩(H_8)呈直接的侵入接触关系,接触带发育强烈的矽卡岩化和小型铁矿化。我们在东矿采坑南侧22线1598m平台北倾探矿钻孔650～660m岩芯段,首次发现两段矽卡岩化蚀变带。对矽卡岩中的金云母进行超低本底Rb-Sr法定年,获得309±12Ma年龄。结合矽卡岩与矿体的侵入接触关系,可以认为,晚古生代花岗岩虽已深入到矿体下部,但其侵位时间应晚于矿区最后一期强烈的稀土矿化事件,它对白云鄂博矿床来说只是一次后期破矿的构造—岩浆活动。 相似文献
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有关白云鄂博铁稀土矿床中稀土元素的组成特点和赋存形式,我所在六十年代曾作了大量工作,积累了大批数据。本文主要是利用这些数据,对该矿床中的稀土元素特别是其中的Nd、Sm、Eu的分配特点作初步阐述。 相似文献
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Granitic rocks of various ages and composition are found in the Schwarzwald region of West Germany. These granites range in age from Upper Devonian to Upper Carboniferous (370-280 m.y.) and in composition from granodiorites to alkali feldspar granites. 14 representative samples of twelve different types were analysed for their La, Ce, Nd, Sm, Eu, Tb, Dy, Yb, Lu by instrumental neutron activation. The studies reveal that there are characteristic differences between the different types of granitic rocks both as regards to their total REE content as well as the distribution pattern of these elements. These differences can not be directly related to the variations in the major element chemistry or the mineralogy of the granites. On the other hand, a relationship is found between the age of the granitic rocks and the total REE as well as their distribution pattern. In general the ΣREE varies from 22 to 215 ppm in different types. The ΣLa-Lu increases gradually in the direction Upper Devonian→Lower Carboniferous, however, in the granitic rocks of the Upper Carboniferous this trend is reversed and there is again a marked depletion in the content of REE. The chondrite normalised patterns of all the older types give a smooth concave curve with decrease of concentration from La to Lu. All the Upper Carboniferous granites on the other hand are characterised by a progressive pronounced negative Eu anomaly. The gradual increase of the ΣREE in the older granites is related to their evolution by progressive anatexis, whereas, the decrease in the total REE content in case of the younger Upper Carboniferous granites is due to processes of magmatic differentiation. The depletion of Eu in these K-feldspar rich types of granite is probably related to the breakdown of biotite in the anatectic starting material. 相似文献
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秦岭造山带东江口花岗岩体群的地球化学研究及其构造环境 总被引：3，自引：0，他引：3
陕南秦岭造山带东江口花岗岩体群含磁铁矿极高,并含镁质黑云母,稀土元素负铕异常极不明显,氧同位素和锶初始比值都较低.因此,东江口岩体肛为一典型的Ⅰ型花岗岩.用数学地质和图解法与全球重要造山带花岗岩的地质地球化学特征类比后发现,本岩体群花岗岩为碰撞型花岗岩,是秦岭造山带碰撞造山的产物.据此分析了晚古生代秦岭造山带的演化.讨论了花岗岩成因类型与其构造环境的关系,认为碰撞型花岗岩既可是S型花岗岩,也可以是Ⅰ型花岗岩,这主要与花岗岩的源区岩石有关.而与构造环境没有必然的关系. 相似文献
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Studies of Mesozoic granites associated with rare earth element (REE)‐rich weathered crust deposits in southernmost Jiangxi Province indicate that they have high‐K to shoshonite compositions and belong to ilmenite‐series I‐type granites. Of the studied rocks at 59–292 ppm of bulk REE content, the highest are seen in the biotite granites of Dingnan (358, 429 ppm) and mafic biotite granite of the Wuliting Granite (344 ppm) near the Dajishan tungsten mine, both areas where weathered‐crust REE deposits occur. REE‐bearing accessory minerals in these granites are mainly zircon, apatite and allanite, and REE‐fluorocarbonates are common. REE enrichment occurs in the rims of apatite crystals, and in fluorocarbonates that occur along grain boundaries of and cracks in major silicate minerals, and in fluorocarbonates that replaced altered biotite. It is therefore thought that a major part of the REE content of these granites was concentrated during deuteric activity, rather than during magmatic crystallization. The crack‐filling REE‐fluorocarbonates could subsequently have been easily leached out and deposited in weathered crust developed during a long period of exposure. 相似文献
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内蒙古那仁乌拉埃达克质花岗岩的发现、成因、锆石U-Pb年龄及其构造意义 总被引：2，自引：0，他引：2
在中亚造山带东段华北克拉通北缘,识别出一套晚古生代那仁乌拉黑云母花岗岩。其LA-ICP-MS锆石U-Pb年龄为267.2Ma±1.4 Ma(MSWD=1.3,n=21)和捕获锆石年龄为296.3Ma～296.1Ma、278.8Ma～277.4 Ma;岩石为低钾(拉斑)到高钾钙碱性,弱准铝质到过铝质I型;ΣREE较低,轻重稀土分馏较强(LaN/YbN:15.59～32.36)。在稀土元素配分模式图上,都表现为轻稀土富集,重稀土亏损的右倾散开式。弱到正的铕负异常(δEu:0.79～1.08);在微量元素蛛网图上,相对富集LREE(La,Ce),LILE(K,Rb)和HFSE(Zr,Hf),元素Nb,Ta,P,Ti,Y,Yb,Lu亏损程度较大,元素U,Th,Sr由相对亏损到富集。岩石整体具有埃达克质岩的亲合性,形成于弧向同碰撞过渡的构造环境;锆石εHf(t)值(0.95～4.05)显示具有弱亏损的幔源组分特性,与主量元素、微量元素及REE一致,变化范围都较大,共同暗示其源岩的壳幔混源性。较年轻的锆石Hf模式年龄(1 030.9Ma～1 226.8Ma)与兴蒙造山带范围一致;那仁乌拉花岗岩与西部乌拉特中旗克布岩体,东部吉林大玉山岩体共同组成一条华北克拉通北缘埃达克质岩浆带,其都为与古亚洲洋俯冲碰撞引起的具有弧岩浆性质的年轻的基性玄武质下地壳部分熔融有关的C型埃达克岩。这条埃达克质岩浆带与稍晚期的华北克拉通北缘碱性岩浆带相对应,都具有西部形成早于东部的特征,可能暗示古亚洲洋自西向东逐渐闭合的规律。 相似文献
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The Archean granites exposed in the Mesorchean Rio Maria granite-greenstone terrane (RMGGT), southeastern Amazonian craton can be divided into three groups on the basis of petrographic and geochemical data. (1) Potassic leucogranites (Xinguara and Mata Surrão granites), composed dominantly of biotite monzogranites that have high SiO2, K2O, and Rb contents and show fractionated REE patterns with moderate to pronounced negative Eu anomalies. These granites share many features with the low-Ca granite group of the Yilgarn craton and CA2-type of Archean calc-alkaline granites. These granites result from the partial melting of rocks similar to the older TTG of the RMGGT. (2) Leucogranodiorite-granite group (Guarantã suite, Grotão granodiorite, and similar rocks), which is composed of Ba- and Sr-rich rocks which display fractionated REE patterns without significant Eu anomalies and show geochemical affinity with the high-Ca granite group or Transitional TTG of the Yilgarn craton and the CA1-type of Archean calc-alkaline granites. These rocks appear to have been originated from mixing between a Ba- and Sr-enriched granite magma and trondhjemitic liquids or alternatively product of interaction between fluids enriched in K, Sr, and Ba, derived from a metasomatized mantle with older TTG rocks. (3) Amphibole-biotite monzogranites (Rancho de Deus granite) associated with sanukitoid suites. These granites were probably generated by fractional crystallization and differentiation of sanukitoid magmas enriched in Ba and Sr.The emplacement of the granites of the RMGGT occurred during the Mesoarchean (2.87–2.86 Ga). They are approximately coeval with the sanukitoid suites (∼2.87 Ga) and post-dated the main timing of TTG suites formation (2.98–2.92 Ga). The crust of Rio Maria was probably still quite warm at the time when the granite magmas were produced. In these conditions, the underplating in the lower crust of large volumes of sanukitoid magmas may have also contributed with heat inducing the partial melting of crustal protoliths and opening the possibility of complex interactions between different kinds of magmas. 相似文献
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大兴安岭中段五岔沟地区蛤蟆沟林场A型花岗岩年代学、岩石地球化学及构造背景研究 总被引：5，自引：0，他引：5
对大兴安岭中部五岔沟镇蛤蟆沟林场花岗岩体研究结果表明,蛤蟆沟林场花岗岩体主要岩性组合为碱长花岗岩、黑云母正长花岗岩、黑云母二长花岗岩和花岗斑岩,其LA-ICP-MS锆石U-Pb测年结果为136.97±0.99Ma、135.85±0.78Ma、126.04±0.48Ma和135.87±0.49Ma,表明其形成时代为早白垩世。岩石主量元素具有富硅、富钾的特征,A/CNK值介于0.997~1.05之间,稀土元素相对富集轻稀土元素、亏损重稀土元素,并具有较为明显的Eu负异常,微量元素相对富集大离子亲石元素和高场强元素,贫Ba、Sr、Ti、P,这些特征表明蛤蟆沟林场花岗岩为铝质A型花岗岩,是中下地壳岩石部分熔融的产物,形成于大陆裂谷或板内构造环境（A1型花岗岩）,代表了伸展的大地构造背景,可能是受到古太平洋俯冲和蒙古鄂霍次克洋闭合的双重影响。 相似文献
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内蒙古乌拉特中旗海西期黑云母二长花岗岩锆石SHRIMP U-Pb年龄及其地质意义 总被引：4，自引：0，他引：4
对乌拉特中旗德尔斯地区黑云母二长花岗岩岩相学、锆石SHRIMP U-Pb年代学和岩石地球化学进行了研究,并讨论了岩石成因及研究区晚海西期构造演化。黑云母二长花岗岩发育两期:早期为中粗粒斑状黑云母二长花岗岩,晚期为中细粒黑云二长花岗岩。岩石中的锆石大部分具核-边结构:边部震荡环带发育,Th/U值为0.16~0.50,反映了岩浆成因;核部呈浑圆状,多数具岩浆环带,个别弱分带-无分带,Th/U值为0.06~0.44,表明核部大部分属岩浆型残留锆石,个别为变质型残留锆石。测年结果显示：边部锆石加权平均年龄为早、中二叠世((279±3) Ma、(266±3) Ma),代表黑云母二长花岗岩形成时代;核部残留锆石加权平均年龄为(1 972±63) Ma 、(1 962±43) Ma,代表源岩的形成时代。岩石属于亚碱性系列,REE配分形式呈右倾型,LREE/HREE为5.86~22.81,明显亏损高场强元素Nb,富集大离子亲石元素Rb、Ba,显示活动大陆边缘火成岩的地球化学特征。黑云母二长花岗岩地球化学属性反映了早、中二叠世古亚洲洋向华北板块北缘的俯冲作用及古亚洲洋消亡的演化历史。 相似文献
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北祁连金佛寺岩体地球化学特征及构造意义 总被引：1，自引：0，他引：1
金佛寺岩体为北祁连华力西早期形成的一个较大的复式深成岩基,主要岩石类型为二长花岗岩、黑云二长花岗岩和正长花岗岩,为高钾钙碱性岩系,具高钾、高铝和低钛的特点;REE分布模式为弱Eu异常;在Peace的Rb-Y-Nb图解中位于后碰撞花岗岩类区。岩体的同位素锆石U-Pb年龄为345.0±75.0Ma,代表其形成时代为晚泥盆世... 相似文献
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Arfvedsonite granites are most prevalent in the northern sector of the Nigerian anorogenic ring-complex province wherein they form the main granitic rocks at Kudaru and Fagam and are important components of Kila-Warji, Ririwai and Dutsen-Wai ring-complexes. The albitized variety of these rocks hosts pyrochlore to varying extents depending on the degree of albitization and are, therefore, important targets for niobium investigation. Geochemical data of the granites reveal that niobium has a mean concentration of 111 ppm in the arfvedsonite granite, increasing to 168 ppm in the aegirine arfvedsonite granite and reaching 1568 ppm in the albite arfvedsonite granite. Niobium is thus enriched in the albite arfvedsonite granite by a factor of 8-11 relative to its mean value in the aegirine arfvedsonite and arfvedsonite granites, respectively. Uranium contents show a sympathetic trend with niobium, being also enriched in the albite arfvedsonite granite relative to its abundance in both the aegirine arfvedsonite granite and arfvedsonite granite by a factor of 15. The uranium abundance in the albite arfvedsonite granite is more than 48 times higher than the mean background values in low-calcium granite.The REE fractionation patterns in all three arfvedsonite granite varieties are characterized by enrichment of both the light (La-Sm) and heavy (Gd-Lu) rare earth elements and a significant negative Eu anomaly. The albite arfvedsonite granite is, however, preferentially more enriched in the heavy REE relative to the aegirine arfvedsonite and the arfvedsonite granites. A plot of the ∑REE against Na2O and niobium reveals positive correlation in the arfvedsonite granites. There is also a linear relationship and strongly positive correlation between Nb and Na2O because the pyrochlore is most abundant in the most extensively albitized variety of the arfvedsonite granites. 相似文献