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1.
We measured dissolved N(2)O, CH(4), O(2), NH(4)(+), NO(3)(-) and NO(2)(-) on 7 transects along the polluted Adyar River-estuary, SE India and estimated N(2)O and CH(4) emissions using a gas exchange relation and a floating chamber. High NO(2)(-) implied some nitrification of a large anthropogenic NH(4)(+) pool. In the lower catchment CH(4) was maximal (6.3+/-4.3 x 10(4)nM), exceeding the ebullition threshold, whereas strong undersaturation of N(2)O and O(2) implied intense denitrification. Emissions fluxes for the whole Adyar system approximately 2.5 x 10(8) g CH(4)yr(-1) and approximately 2.4 x 10(6)gN(2)O yr(-1) estimated with a gas exchange relation and approximately 2 x 10(9) g CH(4)yr(-1) derived with a floating chamber illustrate the importance of CH(4) ebullition. An equivalent CO(2) flux approximately 1-10 x 10(10)gy r(-1) derived using global warming potentials is equivalent to total Chennai motor vehicle CO(2) emissions in one month. Studies such as this may inform more effective waste management and future compliance with international emissions agreements.  相似文献   

2.
The radionuclides (210)Po and (210)Pb were examined to trace the cycling of particulate organic carbon (POC) and particulate organic nitrogen (PON) in the Zhubi coral reef lagoon. The net export flux of POC to the open sea is 14 mg Cm(-2) d(-1). However, the net exchange of PON has not yet been observed. On average, the vertical export fluxes in the lagoon of POC and PON, as derived from (210)Po/(210)Pb disequilibria, are 43 mg Cm(-2) d(-1) and 13.8 mg Nm(-2) d(-1), respectively. The deficit of (210)Po relative to (210)Pb in particulate matter provides evidence for the degradation of particulate organic matter. According to the mass balance budgets, 310 mg Cm(-2) d(-1) and 121 mg Nm(-2) d(-1) were recycled into dissolved fractions. Based on a first-order kinetics model, the degradation rate constants of POC and PON are 0.28 and 0.30 m(-1), respectively. Thus, (210)Po and (210)Pb can quantify the cycling of carbon and nitrogen in this coral lagoon.  相似文献   

3.
Landscape evolution is modulated by the regional tectonic uplift,climate change,and river dynamics.However,how to distinguish these mechanisms through the research of surface exhumation and fluvial incision remains controversial.In this study,cosmogenic~(10)Be,~(26)Al,and~(21)Ne concentrations in quartz from cave deposits,modern river sediments,and bedrocks were measured to constrain the applicability of cosmogenic~(21)Ne and discuss Quaternary landscape evolution history in the Guizhou Plateau,southeast China.Using the~(26)Al-~(10)Be and~(21)Ne-~(10)Be pairs to distinguish the cosmogenic~(21)Ne concentration from the excess~(21)Ne,we found that the nucleogenic~(21)Ne produced by the U and Th decay in quartz is significant in the samples although there is the possibility of inherited cosmogenic~(21)Ne.Combining with previous studies,we suggest that the precise approach for applying the cosmogenic~(21)Ne could be reached by (1) estimating the contribution from nucleogenic~(21)Ne,(2) avoiding samples with complex burial histories to exclude inherited cosmogenic~(21)Ne,and (3) combining the~(10)Be-~(26)Al-~(21)Ne nuclides method for the Quaternary samples.In addition,both pre-burial basin denudation rates and burial ages derived from the~(26)Al-~(10)Be pair were used to determine the different timescale surface denudation rate and fluvial incision rate in relation to previous work.The consistency of the different timescales pre-burial basin denudation rate,~(36)Cl surface denudation rate,and modern basin denudation rate indicates that the landscape-scale surface denudation has been likely stabilized since the Quaternary in the Guizhou Plateau area.The slightly higher river incision rates than the local surface denudation rate show that the river dynamics may not have reached a steady-state due to the regional tectonic uplift in the Guizhou Plateau.  相似文献   

4.
Tricyclic and tetracyclic terpanes are important constituents of crude oil and source rock extracts.However,they have not been reported in the Offshore Niger Delta Basin,Nigeria.Thus,the present study investigated the geochemical significance of tricyclic and tetracyclic terpanes in source rock extracts from the Offshore Niger Delta Bain,Nigeria with gas chromatography-mass spectrometry(GC-MS).The total relative abundances of tricyclic terpanes,C_(19)TT-C_(21)TT,and C23 TT in the rock samples ranged from 82.50 to 96.37%,50.08 to 74.17%,and 25.83 to 49.92%,respectively.These values showed the source rocks were formed from a mixed origin(terrestrial and marine).Among the tricyclic and tetracyclic terpanes identified in the rock extracts,the conventional(C_(20)TT,C_(23)TT,C_(24)TT,C_(24)TeT) and recent(Y1,X1,Z1)were more prominent than all others,indicating mixed input of terrigenous and marine organic matter.The C_(24)TT/C_(23)TT,C_(24)TeT/(C_(24)TeT+C_(26)TT),C_(19)TT/C_(23)TT,C_(20)TT/C_(23)TT,C_(25)TT/C_(24)TeT,C_(25)TT/C_(26)TT,C_(19)TT/C_(20)TT,C_(24)TeT/C_(26)TT,Z1/(Z1+C_(24)TT),and Y1/(Y1+C~(24)TT)in the rock samples range from 0.33 to 1.30,0.76 to 0.90,0.18 to 0.73,0.34 to 1.05,0.33 to 1.74,0.30 to 1.39,0.31 to0.89,1.66 to 4.33,0.36 to 0.83,and 0.34 to 0.79,respectively.These values further showed that the rock samples were formed from mixed input of terrigenous and marine organic matter and deposited under oxic to suboxic conditions in lacustrine-fluvial/deltaic environments.Also,the C_(24)TeT/C_(20-26)TT,C_(24)TeT/C_(30)HOP,and C_(23)TT/C_(30)HOP ranged from 0.16 to 0.45,0.02 to 0.42,and 0.01 to 0.48,respectively.This range of values suggests that source rocks were within immature to early mature stage.Thus,this study showed that tricyclic and tetracyclic terpanes were effective in determining the origin,depositional environments,and thermal maturity of source rocks in the Niger Delta Basin,Nigeria.  相似文献   

5.
In recent years, there has been increasing interest in the significance of natural radionuclides, particularly (210)Po, in the marine environment. (210)Po, a naturally occurring alpha emitter, accumulates in marine organisms and reflects differences in their diets. In the literature, there is no data for (210)Po and (210)Pb activity concentrations for fish species on the Turkish coast of Aegean Sea. Therefore, in this study, multiple fish species were collected from six stations seasonally on the Turkish coast of Aegean Sea and were analyzed for their (210)Po and (210)Pb content. The (210)Po and (210)Pb concentrations in the fish samples were found to vary from undetectable levels to 499 ± 44 Bq kg(-1) dry weight (dw) and from 1.0 ± 0.3 Bq kg(-1) to 35 ± 4.0 Bq kg(-1) (dw), respectively. There were no significant differences in the activity concentrations of (210)Po and (210)Pb in fish samples between seasons (ANOVA, P>0.05). The highest dose contribution of (210)Po to humans was calculated to be 10,530 μSv year(-1).  相似文献   

6.
Pacific oyster (Crassostrea gigas Thunberg) embryos, bay mussel (Mytilus edulis Linnaeus) embryos, and Dungeness crab (Cancer magister Dana) zoea I stage larvae were exposed to arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, and zinc salts. The two bivalve species were exposed through the completion of embryogenesis (48 h), and the effects of the metals upon abnormal development were monitored. The crab larval stages were exposed to the metal solutions for 96 h. Concentrations (μg l.?1 as metal) which caused 50% abnormal development in the two species of bivalve larvae and which were fatal to 50% of the crab larvae ranged from 5.3 (oyster) to 49 (crab) for copper; 5.8 (mussel) to 8.2 (crab) for mercury; 14 (mussel) to 55 (crab) for silver; 119 (oyster) to 456 (crab) for zinc; 232 (crab) to 3000 (mussel) for arsenic; 247 (crab) to 1200 (mussel) for cadmium; 349 (oyster) to 4360 (crab) for nickel; 476 (mussel) to 758 (oyster) for lead; 3440 (crab) to 4538 (oyster) for hexavalent chromium; and selenium greater than 10 000 for the three species. The acute toxicity testing of C. gigas embryo together with two California native species confirmed its usefulness for predicting toxicity to the latter species.  相似文献   

7.
W. Krauß 《Ocean Dynamics》1965,18(5):193-210
Zusammenfassung Entsprechend der Reynoldsschen Konzeption werden die virtuellen Reibungskr?fte berechnet. Die Orbitalbewegungen der Oberfl?chen- und internen Wellen stellen die st?rksten Abweichungen vom mittleren Strom dar. Der auf diesen Bewegungen basierende Reynoldssche Spannungstensor wird aus dem Gleichungssystem (12) bis (14) ermittelt. Formale L?sungen sind (25) bis (28), wennW(z) aus (24) für beliebigeū(z) bekannt ist. Für Oberfl?chenwellen reduziert sich (24) auf (29) mit der N?herungsl?sung (34). Hieraus folgen (37) und (38). Absch?tzung der Integrale führt für Wellen endlicher Kamml?nge auf (55), woraus die Reibungskr?fte (56) bis (58) folgen. Station?re mittlere Str?mungen sind dann durch (61) beschreibbar. μ, gegeben durch (62), wird in Anlehnung an die bestehende Nomenklatur als “virtueller Reibungskoeffizient” bezeichnet. Er ist durch die Parameter des Seeganges bestimmt. Im Gegensatz zu V. W. Ekman werden Triftstr?me durch (67) bis (69) mit den L?sungen (71), (72) bzw. (73), (74) beschrieben. Aus dem sinusoidalen Verlauf der Reibungskoeffizienten (62) folgt eine Streifenstruktur des Triftstromes, wie sie Abb. 3 in Zuordnung zum Seegang zeigt. Die Geschwindigkeitsverteilung eines Streifens ist in Abb. 2 wiedergegeben. Eine Rechtsablenkung analog zur Ekman-Spirale tritt nicht auf; der Strom setzt stets in Richtung des Windes. Durch Messungen in der Ostsee mit Rhodamin wurde die theoretisch zu erwartende Streifenbildung für verschiedene Windgeschwindigkeiten qualitativ nachgewiesen (Abb. 4 und Tafeln 8 und 9).
The theory of the drift current and the virtual friction in the sea
Summary According to the Reynolds' procedure, the “turbulent” stresses due to surface and internal waves are computed. Starting from Eqs. (12) to (14) for linear internal and surface waves we get the solutions (25) to (28) withW(z) as a solution of (24) for arbitrary mean currents. For surface waves, (24) reduces to (29) with the approximate solution (34). From this follow (37) and (38). Estimating the integrals, we get (55) for waves of finite crests. From this follow (56) to (58) for the frictional forces due to waves. Stationary mean currents are then described by (61). The coefficient (62) is called “eddy viscosity”. It depends on the wave parameters. In contrast to Ekman's theory, drift currents are described by (67) to (69) with the solutions (71), (72) or (73), (74). Due to the sinusoidal shape of the eddy viscosity coefficients (62) the drift current has a band structure. This structure is shown in Fig. 3. The current distribution within a band is shown in Fig. 2. The current runs always in the direction of the wind, a deflection to the right due to Coriolis force is not observed. The forming of bands has been tested by Rhodamin. The results are in qualitative agreement with the theory (Fig. 4 and Plates 8 and 9).
La théorie du courant de dérive et du frottement virtuel en mer
Résumé Les forces de frottement virtuelles sont calculées d'après la conception de Reynolds. Les mouvements périodiques dans la couche de surface et les ondes internes constituent les écarts les plus importants par rapport au courant moyen. Le tenseur de Reynolds qui prend pour base ces mouvements, est obtenu au moyen du système d'équations (12) à (14). Les solutions obtenues sont (25) à (28) lorsqu'on conna?tW(z) au moyen de (24) pour desū(z) quelconques. Pour les ondes de surface, (24) se réduit à (29) avec la solution approchée (34); les solutions (37) et (38) s'en déduisent. De l'évaluation de l'intégrale on déduit (55) pour des ondes d'une longueur de crête finie et on en tire les forces de frottement (56) à (58). Des courants moyens stationnaires peuvent alors être décrits au moyen de (61). μ, donné par (62) est appelé ?coefficient de frottement virtuel? suivant les dénominations admises et il est déterminé par les paramètres des vagues. Contrairement à V. W. Ekman les courants de dérive sont décrits par (67) à (69) avec les solutions (71), (72) ou encore (73), (74). Du fait de la forme sinuso?dale prise par les coefficients de frottement (62) le courant de dérive se présente sous forme de bandes comme le montre la fig. 3 d'après l'état de la mer. La fig. 2 indique la distribution des vitesses dans une bande. On ne constate pas de déviation vers la droite analogue à celle de la spirale d'Ekman: le courant suit toujours la direction du vent. Des mesures effectuées en mer Baltique avec de la rhodamine ont confirmé quantitativement la formation des bandes théoriquement prévisibles pour différentes vitesses de vent (fig. 4 et planches 8 et 9).
Hierzu Tafeln 8 und 9  相似文献   

8.
We compared total mercury (THg) concentrations in the fur of northern fur seals (Callorhinus ursinus) from the depleted Pribilof Islands population with those of both declining and thriving populations of Steller sea lions (Eumetopias jubatus) from Prince William Sound (PWS) and Southeast Alaska (SEA), respectively. Relatively low wet weight concentrations (ranges) of THg were detected in the fur of Steller sea lion (SSL) pups (0.90-3.14 microg/g) and juveniles (0.56-6.75 microg/g) from both areas in 1998 and 2000 compared to northern fur seal (NFS) pups (3.15-8.14 microg/g) in 2000. The mean concentration +/- SD for SSLs sampled were 1.46 +/- 0.64 microg/g for pups (n = 22) and 2.74 +/- 2.89 microg/g for juveniles (n = 6). Analyses indicated higher THg concentrations from SSL pups from PWS compared to the SEA. Mean +/- SD. THg in the NFS pups was 4.90 +/- 1.42 microg/g (n = 34) and for post-partum dams was 7.84 +/- 1.78 microg/g (n = 12).  相似文献   

9.
The occurrence of persistent organic pollutants (POPs) as polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and polybrominated diphenyl ethers (PBDE) in crabs Hepatus pudibundus and Callinectesdanae was assessed from two different places inside of the Santos Bay and Moela Island near one of the most economically important metropolitan areas in Southern Brazil. Among POPs analyzed, ∑PCBs (222-923 ng g(-1)lipid weight) and ∑DDTs (154-410 ng g(-1)lw) exhibited the highest concentrations in the crabs. ∑HCHs ranged from 10.3 to 30.9 ng g(-1)lw and were found in all individuals. Other OCPs found in lower concentration was Mirex (7.6-41.6 ng g(-1)lw) and HCB (5.83-16.9 ng g(-1)lw). ∑PBDEs (24.1 ng g(-1)lw) were only found in one male individual from the species C. danae collected near to the submarine sewage of Santos. Male crabs showed higher POP concentrations than female crabs for those two species.  相似文献   

10.
CO(2) ocean storage by which liquefied CO(2) is injected into the deep-sea to mitigate the climate change would increase the CO(2) concentrations of the surrounding seawater. The biological impacts of such dynamic CO(2) environments are, however, unknown. We examined the acute toxicity of temporally changing seawater CO(2) concentrations on juveniles of Sillago japonica. Step-wise increases in ambient CO(2) to fCO(2) (fractional CO(2) concentration of the gas mixture bubbled into seawater) levels of 7% and 9% resulted in mortalities of 0.15 and 0.40-0.67 after 18 h, respectively. In contrast, one-step increases to these CO(2) levels killed all fish within 15 min. Further, a sudden drop of fCO(2) from 9-10% CO(2) to normocapnia (0.038%) killed all the surviving fish within a few minutes. These results demonstrate that impacts of ocean CO(2) storage need to be examined under conditions mimicking the dynamic changes in CO(2) levels expected to occur by the CO(2) injection procedure.  相似文献   

11.
The presence of arsenic (As) in water is of great public concern. Arsenic exists in three common valence states viz., As(0) metalloid arsenic, As(III) (arsenite) and As(V) (arsenate). Arsenite [As(III)] is the most toxic form among arsenicals which, predominates in anaerobic conditions, generally in flooded soils and in the water with high BOD. Experiments were conducted to investigate the effect of As(III) on the mycorrhization in vetiver (Vetiveria zizanioides (L.) Nash) grass in hydroponics. Studies showed significant alteration in the mycorrhizal colonization in the roots of vetiver exposed to higher concentrations of As(III) starting from 1.0, 2.0, 3.0, 4.0 to 5.0 mg/L prepared in 5% Hoagland nutrient solution without addition of phosphate ions. Considerable reduction in the mycorrhizal intensity (M) was observed in all the treatment sets as compared to the control suggesting a negative impact of the As(III) on the mycorrhizal association. Simultaneously, the study also showed that, As(III) is toxic to the vetiver plants having mycorrhizal association however plants with non‐mycorrhizal (cleansed) roots were found to be able to survive for a longer period exposed to As(III).  相似文献   

12.
本文应用动态系统时间连续模型建立的新方法（ＤＭ（ｎ，ｈ）模型），通过对唐山老震区ＭＬ＞４．７级地震的建模，讨论ＤＭ（ｎ，ｈ）模型对唐山老震区晚期强余震预测的可行性。并比较了ＤＭ（ｎ，ｈ）模型与ＧＭ（ｎ，ｈ）模型，发现ＤＭ（ｎ，ｈ）模型优于ＧＭ（ｎ，ｈ）模型，同时，给出了唐山老震区晚期强余震的预报结果。  相似文献   

13.
Manganese oxide has been widely investigated for oxidation of arsenite (As(III)) to arsenate (As(V)) due to its high redox potential; however, it becomes extremely unstable after reuse. Here, As(III) oxidation activity and stability of manganese oxide in the presence of peroxymonosulfate (PMS) is investigated. Batch experimental results reveal that manganese oxide/PMS exhibits high catalytic activity for As(III) oxidation compared to manganese oxide or PMS alone. Addition of PMS to manganese oxide not only reveals long‐term stability for As(III) oxidation, but also shows high As(III) oxidation activity in the presence of coexisting ions such as As(V) and phosphate. Quenching tests reveal that As(III) oxidation in the manganese oxide/PMS system is attributed to activation of PMS by manganese oxide at different oxidation states (Mn(III) and Mn(IV)), and the generation of sulfate radicals that are responsible for As(III) oxidation.  相似文献   

14.
Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.  相似文献   

15.
Using a method and definition given earlier (Roy and Apparao, 1971), this paper computes the depths of investigation in homogeneous ground for (a) the Wenner α, β and γ configurations, (b) the three electrode system and (c) the dipole-dipole arrangements when the dipole lengths are not infinitesimally small. The results for (a) and (b) have been summarised in a table, while those for (c) are shown as contour diagrams. In all the dipolar arrangements examined in this paper, except the equatorial, the depth of investigation decreases (and the vertical resolution increases) with increase in any or both of the dipole lengths. For the equatorial set up, this decrease (or increase) is very small.  相似文献   

16.
A single-hole multilevel sampling piezometer system (MLSPS) has been designed by the Geological Survey of Canada (GSC) to be installed using drilling systems that continuously core (e.g., Rotosonic) or continuously sample (e.g., hollow-stem auger, Becker hammer) overburden and that have the flexibility of allowing additional coring (diamond drilling) or sampling (hammer drilling) of bedrock. The GSC-MLSPS (under license to Solinst Canada Ltd.) uses a patented GSC dry injection system for accurate emplacement of filter packs and seals. This system permits (a) the use of variable screen lengths; (b) the complete evacuation of piezometers before introduction of new ground water (no bailing); (c) the use of a number of types of hydraulic tests (e.g., slug, withdrawal/recovery, vacuum, pressure-pulse); (d) ground water sampling under a nitrogen atmosphere; (e) dissolved gas sampling; (f) a great deal of flexibility in the use of design materials; and (g) the elimination of bridging and collapse of filter packs and seals.  相似文献   

17.
This paper presents a new approach for the evaluation of accurate lateral force distributions for the Linear Static Analysis (LSA) of Base Isolated (BI-) buildings. In essence, the proposed lateral force distributions depend on a factor measuring the degree of non- linearity of the Isolation System (IS) and on the ratio between the effective period of the BI-structure (Tis) and the fundamental period of the Fixed Based (FB-) structure (Tfb). The proposed approach is fully compatible with the Direct Displacement-Based Design (DDBD) method, recently developed by Priestley and co-workers. The proposed lateral force distributions have been derived from the results of a large number of Nonlinear Time-History Analyses (NTHA), carried out on six numerical models of multi-storey buildings, differing in storey number (3, 5 and 8, respectively) and fundamental period of vibration (from 0.25 to 0.8 s) in the fixed-base configuration. A great variety of Isolation Systems (ISs), characterised by either Elasto-Plastic with Hardening (EPH) or Flag-Shaped (FS) force-displacement behaviour, have been considered in the NTHA. The numerical parameters of the IS models have been varied in such a way as to reproduce the actual mechanical behaviour of the main currently used ISs, including: (i) Lead Rubber Bearings (LRB), (ii) High-Damping Rubber Bearings (HDRB), (iii) Friction Pendulum Bearings (FPB), (iv) combinations of flat Sliding Bearings (SB) and Low-Damping Rubber Bearings (LDRB) and (v) Combinations of flat SB and re-centring devices based on Shape Memory Alloys (SMA). Comparisons between the storey shear forces derived with the proposed method and those obtained from NTHA clearly show the great improvements in the accuracy of LSA predictions, when using the proposed lateral force distributions.  相似文献   

18.
Denitrification (as N(2) flux) and organic matter mineralization (as O(2) uptake) were simultaneously measured in the same set of core sediments from a natural sandy and a constructed muddy tidal flat of Ago Bay, Japan. Denitrification rates at both tidal flats fluctuated between ca. 2-20 micromol N(2)m(-2)h(-1) without showing a clear seasonal pattern, and appeared to be substrate limited as NO(3)(-) enrichment (final concentration ca. 225 microM) caused prompt and similar enhancements of ca. 10-folds. Organic matter mineralization rates were markedly higher at constructed muddy flat compared to those of natural sandy flat, especially in summer, and exhibited pronounced temperature dependent (p<0.01) seasonality for both tidal flats. O(2) uptake rates were generally ca. 2-3 order greater than respective denitrification rates indicating dominance of mineralization processes over N(2) losses.  相似文献   

19.
Current study presents the application of chemometric techniques to comprehend the interrelations among sediment variables whilst identifying the possible pollution source at Langat River,Malaysia.Surface sediment samples（0-10 cm）were collected at 22 sampling stations and analyzed for total metals（~（48）Cd,~（29）Cu,~（30）Zn,~（82）Pb）,pH,redox potential（Eh）,salinity,electrical conductivity（EC）,loss on ignition（LOI）and cation exchange capacity（CEC）.The principal component analysis（PCA）scrutinized the origin of environmental pollution by various anthropogenic and natural activities：four principal components were obtained with 86.34%（5 cm）and88.34%（10 cm）.Standard,forward and backward stepwise discriminant analysis effectively discriminate 2variables（84.06%）indicating high variation of heavy metals accumulation at both depth.The cluster analysis accounted for high input of Zn and Pb at LA8,LA 10,LA 11 and LA 12 that mergers three（5 cm）and four（10cm）into clusters.This is consistent with the contamination factor（C_1）that shows high Cd（LA 1）and Pb（LA 7,LA 8,LA 10,LA 11 and LA 12）contaminations at 5cm.These indicate that Pb and Zn are the most bioavailable metals in the sediment with significant positive linear relationship at both sediment depths.Therefore,this approach is a good indication of environmental pollution status that transfers new findings on the assessment of heavy metals by interpreting large complex datasets and predicting the fate of heavy metals in the sediment.  相似文献   

20.
Sixteen sediment samples collected from eight transects in a mangrove swamp of the Jiulong River Estuary, Fujian, China were investigated for their content of polycyclic aromatic hydrocarbons (PAHs) and the biodegradation potential of the indigenous microorganisms. The bacterial community structures in the mangrove sediments and in enrichment cultures were also investigated. The results showed that the total PAHs concentration of mangrove sediments ranged from 280 to 1074 ng g(-1) dry weight, that the PAHs composition pattern in the mangrove sediments was dominated by high molecular weight PAH components (4-6 rings), and that Benzo[ghi]perylene and Indeno[1,2,3-cd]pyrene were the most dominant at different stations. Abundant PAH-degrading bacteria were found in all the stations, the values of phenanthrene-degrading bacteria ranged from 5.85 x 10(4) to 7.80 x 10(5) CFU g(-1) dry weight, fluoranthene-degrading bacteria ranged from 5.25 x 10(4) to 5.79 x 10(5) CFU g(-1) dry weight, pyrene-degrading bacteria ranged from 3.10 x 10(4) to 6.97 x 10(5) CFU g(-1) dry weight and the benzo(a)pyrene-degrading bacteria ranged from 5.25 x 10(4) to 7.26 x 10(5) CFU g(-1) dry weight. DGGE analysis of PCR-amplified 16S rDNA gene fragments confirmed that there was a remarkable shift in the composition of the bacterial community due to the addition of the different model PAH compound phenanthrene (three ring PAH), fluoranthene(four ring PAH), pyrene(four ring PAH) and benzo(a)pyrene(five ring PAH) during enrichment batch culture. Eleven strains were obtained with different morphology and different degradation ability. The presence of common bands for microbial species in the cultures and in the native mangrove sediment DNA indicated that these strains could be potential in situ PAH-degraders.  相似文献   

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