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1.
甲基膦酸二甲庚脂(简称P_(350))作为镓、金的萃取剂已有报道,但迄今未见P_(350)萃取色谱分离镓的报导。本文研究了以聚二乙烯苯(X—5)型大孔吸附树脂为担体,P_(350)为固定相,考查对镓的反向色谱行为,以及盐析剂效应等,试验表明P_(350)是分离镓的良好固定相,痕量镓可从大量Fe、Al、Cu、Pb、Zn、Hg、Sn、Ag、Bi,Cd,Cr、In、Tl等分离出来,最后以Ga—CAS— 相似文献
2.
本文以动态法为基础研究了H_2SO_4-NaBr体系P_(350)萃取色谱分离Ga-In和Tl的色谱行为,并探索了影响分离的各种因素。首次提出P_(350)萃取色谱连续分离Ga、In和Tl的新途径。拟定了岩石、矿物中痕量Ga、In和Tl全差示吸光度法检测条件。 本法Ga、In和Tl的定量测定下限分别为0.05、0.11和0.09ppm;含量区间Ga在0.05—3ppm范围,RSD为4—9％;In在0.1—5ppm范围,RSD在6—21％;Tl在0.1—3ppm范围,RSD为6—16％。用拟定 相似文献
3.
目前研究萃取分离富集镓大多偏向在强酸性体系中,一定程度上给操作带来安全风险,另需耐酸器皿设备,易污染,空白背景值高。本文开发了一种在弱酸性条件下萃取分离富集痕量镓的方法。以大孔吸附树脂为载体,十六烷基三甲基溴化铵调节其表面极性,热固化负载2-乙基己基磷酸(2-乙基己基)酯,制备了镓的萃取树脂。动态考察了固相萃取镓的吸附容量,优化选择固相萃取分离富集条件,实验表明萃取条件温和,分离富集痕量镓效果理想。当溶液酸度为pH 2.5时,Ga(Ⅲ)达到最大的回收率99%,并确定了掺氧空气乙炔火焰原子吸收光谱法(FAAS)测定镓的最佳参数,提升了常规空气乙炔FAAS测定镓的灵敏度。方法检出限(3σ)为2.6ng/mL,相对标准偏差(RSD,n=7)为2.87%,加标回收率在95.7%～102.0%之间,理论富集倍数为40。本方法已应用于自来水、中药材和水培蔬菜样品中痕量镓的测定,简便、快速、可靠。 相似文献
4.
本文选用水溶性比TBP小30倍而对钍、铀分离效率高的P_(350)为萃取色层的固定相和对有机萃取剂吸附容量大、传质速度快的新型大孔吸附树脂x-5(聚二乙烯苯)为支持体,以含15%HNO_3和15%NH_4NO_3(或7%Al(NO_3)_3)及2%酒石酸的混合液为铀、钍上柱液,采用5NHCl及0.2%NaF分别解脱钍和铀,分光光度法分别测定之。 相似文献
5.
6.
萃取树脂作为一种化学分离手段,国外七十年代就有报导,近年国内兄弟单位研制合成了各类型萃取树脂,并相继用于分析工作中,P_(507)萃取树脂最近问世,给稀土元素的分离富集带来了佳音。该树脂是在P_(507)萃取色层的基础上研制而成的,并具有离子交换的优点。本文研究了P_(507)萃取树脂分离稀土的条件及偶氮氯膦—PN与稀土元素的显色反应;拟定了一个 相似文献
7.
泡塑吸附分离萃取光度法测定粉煤灰中的镓 总被引：2，自引：2，他引：0
试验了在盐酸介质中聚氨酯泡沫塑料吸附分离镓的性能,将该性能用于粉煤灰分离镓的预处理过程,罗丹明B萃取光度法定量测定镓含量。结果表明,室温条件下,在6 mol/L盐酸溶液中,聚氨酯泡沫塑料对镓有良好的吸附性能,90 m in可达吸附平衡,饱和吸附量为每克泡塑可吸附42 mg镓;被吸附的镓可用0.5 mol/L氯化铵溶液定量洗脱;用罗丹明B萃取光度法测定镓含量时,镓浓度在0~1.0μg/mL服从比尔定律,检出限为0.008 mg/L。测定粉煤灰样品中镓的含量,加标回收率在103%~107%,相对标准偏差(RSD,n=20)为1.5%,富集分离效果明显,选择性高。 相似文献
8.
研究了P350在硫酸介质中吸附铼的性能和微色谱柱分离微量铼的条件和选择性，确定了以P350萃淋树脂为固定相，硫酸溶液为流动相萃取色谱分离微量铼的最佳条件，以2mol／L硫酸为上拄液，4mol／L硫酸为淋洗液，水为解析液，使铼与铀(Ⅵ)、钼(Ⅵ)、铁(Ⅲ)、锰(Ⅱ)、铬(Ⅵ)、钛(Ⅳ)等金属离子分离。采用丁基罗丹明B光度法测定铀矿石中微量铼，分析结果符合要求。 相似文献
9.
MIBK-HBr体系萃取分光光度法测定镓铟铊 总被引：1，自引：0，他引：1
萃取分离测定同一样品中镓、铟和铊的工作,国内外近年来都有研究。本文在A.E.HuberT等工作的基础上提出,在氢溴酸介质中,以甲基异丁基甲酮(MIBK)为萃取剂,甲苯为稀释剂,调节水相酸度,分步萃取,有机相直接显色分光光度法测定同一样品浸提液中镓、铟和铊。该方法的特点是分步萃取后,有机相既不经反萃取也不经蒸干,直接用分光光度法进行测定,具有简便,准确的优点并成功地应用于矿样分析。 实验 1.仪器及试剂 721分光光度计(上海第三分析仪器厂) 氢溴酸 分析纯40％约为7mol/L(用时可进行标定)。 相似文献
10.
萃取树脂作为一种化学分离手段,国外七十年代就有报导,近年国内兄弟单位研制合成了各类型萃取树脂,并相继用于分析工作中,P_(507)萃取树脂最近问世,给稀土元素的分离富集带来了佳音。该树脂是在P_(507)萃取色层的基础上研制而成的,并具有离子交换的优点。 本文研究了P_(507)萃取树脂分离稀土的条件及偶氮氯膦—PN与稀土元素的显色反应;拟定了一个分离效果良好、简便、灵敏度比偶氮胂Ⅲ高一倍的稀土总量的分析流程,可作为稀土分析的新方法。 实验部分 相似文献
11.
Modelling of gravity and airborne magnetic data integrated with seismic studies suggest that the linear gravity and magnetic anomalies associated with Moyar Bhavani Shear Zone (MBSZ) and Palghat Cauvery Shear Zone (PCSZ) are caused by high density and high susceptibility rocks in upper crust which may represent mafic lower crustal rocks. This along with thick crust (44–45 km) under the Southern Granulite Terrain (SGT) indicates collision of Dharwar craton towards north and SGT towards south with N–S directed compression during 2.6–2.5 Ga. This collision may be related to contemporary collision northwards between Eastern Madagascar–Western Dharwar Craton (WDC) and Eastern Dharwar Craton (EDC). Arcuate shaped N and S-verging thrusts, MBSZ-Mettur Shear and PCSZ-Gangavalli Shear, respectively across Cauvery Shear zone system (CSZ) in SGT also suggest that the WDC, EDC and SGT might have collided almost simultaneously during 2.6–2.5 Ga due to NW–SE directed compressional forces with CSZ as central core complex in plate tectonics paradigm preserving rocks of oceanic affinity. Gravity anomalies of schist belts of WDC suggest marginal and intra arc basin setting.The gravity highs of EGFB along east coast of India and regional gravity low over East Antarctica are attributed to thrusted high-density lower crustal/upper mantle rocks at a depth of 5–6 km along W-verging thrust, which is supported by high seismic velocity and crustal thickening, respectively. It may represent a collision zone at about 1.0 Ga between India and East Antarctica. Paired gravity anomalies in the central part of Sri Lanka related to high density intrusives under western margin of Highland Complex and crustal thickening (40 km) along eastern margin of Highland Complex with several arc type magmatic rocks of about 1.0 Ga in Vijayan Complex towards the east may represent collision between them with W-verging thrust as in case of EGFB. The gravity high of Sri Lanka in the central part falls in line with that of EGFB, in case it is fitted in Gulf of Mannar and may represent the extension of this orogeny in Sri Lanka. 相似文献
12.
Rare felsic volcanic rocks of dacitic to rhyolitic composition occur in the central part of the Jack Hills metasedimentary belt in the Narryer Terrane of Western Australia, interleaved with clastic sedimentary rocks and amphibolite. Representative samples of the four identified felsic volcanic units reveal a similar complex pattern of zircon age distribution, with all samples containing zircon populations at ∼3.3–3.4, ∼3.0–3.1, ∼2.6 and ∼1.8–1.9 Ga. The ∼3.3–3.4 Ga zircons show well-developed oscillatory zoning in cathodoluminescence (CL) images and are interpreted as inherited igneous zircon derived from granitic precursors, similar to the ∼3.3 Ga trondhjemitic granitoids currently exposed along the northern and southern margins of the belt. The ∼3.0–3.1 Ga zircons also reveal well-developed oscillatory zoning in CL and are most likely derived from granitoid and/or volcanic rocks of this age, as recorded in the Murchison domain to the south and possibly also present in the Narryer Terrane. The ∼2.6 Ga population matches the age of nearby late Archean granitoids intruding the Jack Hills belt and their oscillatory zoning and U–Th chemistry is consistent with their origin from such a source. The youngest discrete group of zircon grains, with ages ranging from ∼1970 to ∼1775 Ma, show strong oscillatory zoning and average Th/U ratios of 0.76, features consistent with an igneous origin. These younger zircons are therefore interpreted as defining the age of crystallisation of the volcanic rocks. These results establish that the Jack Hills metasedimentary belt contains significant post-Archean components. Taken together with similar results obtained from zircon occurring as detrital grains in clastic sedimentary rocks at Jack Hills, these results overturn the generally-accepted view that the belt is entirely Archean in age and that sedimentation was completed around 3.0 Ga ago. Instead, there is a distinct possibility that much of the material currently exposed in the Jack Hills belt formed in the Proterozoic. A further implication of this study is that the metamorphism affecting these rocks also occurred in the Proterozoic and consequently the rocks should not be considered as forming an Archean greenstone or metasedimentary belt. The paucity of zircons >4 Ga in the known Proterozoic sedimentary rocks and their total absence in the felsic volcanic rocks suggests that such ancient source rocks were no longer present in the area. 相似文献
13.
As part of the Guyana Shield, the basement rocks of French Guyana, between latitudes 3° and 3°30′N, consist of greenstones belts of Proterozoic age (2.0–2.1 Ga) enclosed by anatectic granitoïds and migmatites, and of acid or basic intrusives. 相似文献
14.
The Santa Catarina granulite complex (SCGC) is mainly composed of intermediate to felsic orthogneisses of trondhjemitic, tonalitic and granodioritic compositions (TTG) intruded by subsidiary basic-ultrabasic rocks, and a small metasedimentary component. The ortho-derived rocks belong to different igneous suites. Nd model ages TDM of 2.7-2.8 Ga date the first major mantle-crust differentiation in the area, while 2.6 Ga Rb-Sr whole rock isochron ages in both depleted and undepleted granulites and Nd model ages of 2.4-2.3 Ga record subsequent magmatic events. Regional granulite-facies which reached 800°C at ca. 5-8 kb finished at 2.3 Ga according to U-Pb zircon and Sm-Nd mineral isochron ages, and was also followed by a regional amphibolite facies metamorphism at 2.0 Ga, recorded by Pb-Pb, Rb-Sr whole rock isochrons in rocks with little orthopyroxene and predominant amphibole. Tectonic stabilization was complete at the end of the Transamazonian Cycle at 1.9 Ga as indicated by K-Ar mineral ages, and apart from local reactivation along faults at the margins of the complex and granite intrusion, the SCGC was not affected by the Neoproterozoic Brasiliano Cycle, during which it acted as a microplate and was incorporated onto the eastern border of the Paraná Craton. Isotopic and geochemical characteristics of Brasiliano crustal granites which intrude the complex suggest that it is not an adequate source for the melts, and thus the SCGC may be underlain by different Paleoproterozoic (2.0 Ga) crustal material. 相似文献
15.
Xi-Yao Li Sanzhong Li Tong-Shan Wang Yunpeng Dong Xiao-Guang Liu Shu-Juan Zhao Kun Wang Jiao-Peng Sun Li-Ming Dai Yan-Hui Suo 《地学前缘(英文版)》2020,(2):679-696
Paleo-to Mesoproterozoic sedimentary rocks in the southern margin of the North China Craton(NCC)are represented by the Ruyang and Luoyu groups.We studied the sedimentary rocks from the Yunmengshan and Beidajian formations of the Ruyang Group and the Cuizhuang and Sanjiaotang formations of the Luoyu Group.Detrital zircon grains from these formations have U–Pb age populations of 3.64–3.31 Ga,2.96–2.86 Ga,2.72–2.59 Ga,2.56–2.47 Ga,2.45–2.0 Ga,1.99–1.85 Ga and 1.84–1.65 Ga.The geochemical features of the sedimentary rocks suggest that some of the sediments were sourced from intermediate to felsic magmatic rocks.The age groups of the detrital zircon are roughly consistent with the tectono-thermal events in the southern margin of the NCC.The Hf isotopic compositions of detrital zircon from the sedimentary rocks in Ruyang and Luoyu groups suggest that significant crustal growth and reworking of the NCC took place during the Neoarchean and early-to mid-Paleoproterozoic,while crustal reworking at the Paleoarchean and late-Paleoproterozoic,and crustal growth at the Mesoarchean.We suggest the depositional times of the Ruyang Group and Luoyu Group are constrained to no older than 1.75–1.7 Ga and 1.7–1.65 Ga,respectively.Formation of late-Paleoproterozoic basins related to the strike slip and extrusion tectonics that cross-cut the NCC during the late Paleoproterozoic(<1.75 Ga),and the late Paleoproterozoic sedimentation once isochronous developed in the southern margin of the NCC through the Taihang region of the interior NCC and linked the Yanshan–Liaoxi regions of the northern NCC. 相似文献
16.
阿拉善地块南缘龙首山东段“龙首山岩群”的再厘定——来自碎屑锆石U-Pb定年的证据 总被引：4，自引：0，他引：4
龙首山东段滑石口井地区存在一套浅变质的沉积岩系,原被认为属于古元古代“龙首山岩群”.本文取自这套变沉积岩系的2件样品的碎屑锆石年龄范围介于0.52～3.56 Ga之间,与相邻的寒武系大黄山群碎屑锆石年龄谱相似,其时代可能为中、晚寒武世.取自原“龙首山岩群”和寒武系大黄山群的3件变沉积岩样品中,共获得129个谐和的碎屑锆石年龄,主要分布在0.7～1.2 Ga(约占47％,峰值～0.8、～0.94、～1.0 Ga)和2.5～2.8 Ga(约占31％,峰值～2.5、～2.7 Ga),相对较小的年龄群集中在0.5～0.6 Ga(约占7％,峰值～0.56 Ga)和1.4～1.8 Ga(约占10％,峰值～1.5 Ga),其余年龄零星分布于1.8～2.4 Ga,少量锆石年龄＞3.0 Ga.碎屑物源分析认为,大黄山群的碎屑物质主要来自祁连地块,其中新元古代末一早古生代初期的碎屑物质来自北祁连造山带相关的火成岩,新元古代碎屑物质来自祁连地块广泛分布的新元古代岩浆岩,而中元古代一太古宙碎屑物质可能来自祁连地块再循环的变质基底岩石.结合区域地质资料认为,龙首山东段的浅变质沉积岩系和寒武系大黄山群可能沉积于祁连地块北侧的大陆边缘,在构造背景上属于祁连造山带,而不属于阿拉善地块. 相似文献
17.
武当地区新元古代岩浆岩地球化学特征及其对南秦岭晋宁期区域构造性质的指示 总被引：28，自引：12，他引：28
对南秦岭武当地区武当群火山岩、基性侵入岩墙群和耀岭河群火山岩系统的元素和Nd同位素地球研究化学研究表明，武当群火山岩为形成于约1．0－0．9Ga的新元古代陆缘岛弧火山岩，而耀岭河群火山岩与武当地区基性侵入岩墙群为0．82－0．78Ga形成的大陆裂谷型同源岩浆岩；分别可与扬子克拉通北缘西乡群和南秦岭陕西境内的镇安磨沟峡火山岩、扬子克拉通北缘的火地垭群铁船山组碱性火山岩和望江山基性侵入岩群相对比，揭示出南秦岭与扬子克拉通北缘于晋宁期属统一的陆块。扬子克拉北缘和南秦岭大量的新元古代岩浆岩所具有的1．2－0．9GaNd同位素模式年龄和较高的εNd正值特征表明，晋宁期是扬子克拉通地壳增生和大陆岩石圈演化的重要时期之一。 相似文献
18.
在扬子板块西缘断续分布有多套变质沉积岩系,厘定区内不同岩石单元的时代对于探讨扬子西缘的构造演化具有重要意义。本文对出露于扬子板块西缘米易垭口地区的五马箐组变沉积岩以及侵入其中的片麻状黑云二长花岗岩体进行了锆石LA-ICP-MS U-Pb定年和Lu-Hf同位素分析。结果表明:区内五马箐组的沉积时代介于1.19~1.01Ga,其地层归属为会理群而非康定群,位于五马箐组之下的“冷竹关组”并非变沉积地层而是一套片麻状黑云二长花岗岩体。五马箐组碎屑锆石年龄存在~1.56Ga、~2.50Ga两个主要峰值以及~1.43Ga、~1.68Ga、~1.87Ga、~2.32Ga、~2.68Ga五个次要峰值,推断其物质来源主要为扬子板块西南缘的撮科杂岩、隐伏的或还暂未发现的太古代基底岩石、同时期岩浆岩和早期变沉积岩的再循环。碎屑锆石的ε_(Hf)(t)值在~1.7Ga发生了显著变化,暗示扬子板块西缘的构造体制由陆壳汇聚向裂谷活动转变,且在~1.56Ga处于裂谷岩浆活动的峰期。花岗岩体正的ε_(Hf)(t)值反映出扬子板块西缘在~1.0Ga有一次新生陆壳生长事件,可能是格林威尔造山后的伸展塌陷构造背景下裂谷岩浆活动的产物。 相似文献
19.
The paper presents data on high-grade silicate–carbonate rocks (calciphyres) from the Irkut block (Sharyzhalgai uplift, southwestern Siberian craton). Their origin and age were determined from the rock characteristics, U–Pb dating, REE content, and Hf isotope composition of zircon. The calciphyres occur both as independent section fragments and as interbeds within Paleoproterozoic garnet-bearing and high-alumina (cordierite- and sillimanite-bearing) gneisses. They were produced by metamorphism of terrigenous-carbonate sediments. The terrigenous sediments range in maturity from arenites and wackes to argillaceous rocks; this is consistent with the reconstruction of the sedimentary protoliths of paragneisses, which are predominant in the metasedimentary rocks. The petrogeochemical features of the calciphyres, their LREE enrichment relative to “pure” carbonate rocks, and a distinct Eu anomaly were inherited from the terrigenous component of calc-silicate sediments. The Nd model age (2.4–2.7 Ga) of the calciphyres and the value THf(DM-2st) = 2.5–3.0 Ga for zircon from these rocks indicate that carbonate accumulation was accompanied by the supply of terrigenous material, which formed during the erosion of Archean and Paleoproterozoic crust. Zircon from the calciphyres is similar to metamorphic zircon in REE patterns and Th/U ratios. It might have been of detrital origin and then recrystallized during high-temperature metamorphism. Terrigenous-silicate rocks were metamorphosed at ca. 1.87 Ga. This is close to the previous age estimates for the terrigenous rocks metamorphism (1.85–1.86 Ga) and the age of baddeleyite from apocarbonate metasomatic rocks (1.86 Ga). 相似文献
20.
The presence of 1.52–1.50 Ga charnockites from the anorthosite–mangerite–charnockite–granite (AMCG) Mazury complex in southern Lithuania and NE Poland, in the western East European Craton (EEC) is revealed by secondary ion mass-spectrometry (SIMS) and EPMA geochronology. Early 1.85–1.82 Ga charnockites are related to major orogeny in the region whereas the newly studied charnockites intrude the already consolidated crust. The 1.52–1.50 Ga charnockite magmatism (SIMS data on zircon) was followed by high-grade metamorphism (EPMA data on monazite), which strongly affected the surrounding rocks. The 1.85–1.81 Ga zircon cores in Lazdijai and 1.81 Ga monazite domains in the Lanowicze charnockites represent the protolith age of a volcanic island arc. The 1.52–1.50 Ga charnockite magmatism and metamorphism are likely related to the distal, Danopolonian, orogeny further to the west, at the margin of Baltica. The c.1.52–1.50 Ga AMCG magmatism and metamorphism in the western EEC as well as the paired accretionary-rapakivi suites in Amazonia, may be the inboard manifestations of the same early Mesoproterozoic orogeny associated with the juxtaposition of Amazonia and Baltica during the amalgamation of the supercontinent Columbia. 相似文献