Mafic silicate mapping on Mars: effects of palagonitic material, multiple mafic silicates, and spectral resolution     

Edward A. Cloutis  James F. Bell III 《Icarus》2004,172(1):233-254

The visible to near-infrared spectral reflectance properties of intimate and areal pyroxene?+?palagonitic material mixtures as well as pure mafic silicates (low-calcium pyroxene, high-calcium pyroxene, pigeonite, olivine) and mixtures of these minerals were analyzed at high spectral resolution (5 nm) as well as with non-contiguous band passes equivalent to recent HST observations and the Pathfinder IMP in order to determine the quality and quantity of mineralogical information (end member compositions, abundances, and grain sizes) derivable in the presence of palagonitic material. In the case of pyroxene?+?palagonitic material mixtures, pyroxene is detectable at abundances as low as 10 wt%, and its composition can be constrained because (a) its diagnostic absorption feature (located near 1000 nm) persists even for high palagonitic material abundances, and (b) palagonitic material does not appreciably alter the wavelength position of this band (<4 nm variation). For broad band data (such as Pathfinder IMP band passes), different mafic silicates can be discriminated and palagonitic material abundances constrained using a variety of reflectance ratios and three-point “absorption band depths.” However, other properties of mafic silicate?±?palagonitic material assemblages, such as mafic silicate major element compositions, grain sizes, and end member abundances, generally cannot be rigorously quantified. The use of multiple reflectance ratios can, however, be used to identify relative changes in these properties, as most changes in mafic silicate?±?palagonitic material assemblage properties are characterized by a unique corresponding set of reflectance ratio variations. The observed spectral-assemblage property trends are consistent with those expected from the known spectral properties of the end members.  相似文献   

Spectral reflectance properties of carbonaceous chondrites: 2. CM chondrites     

E.A. Cloutis  P. Hudon  T. Hiroi 《Icarus》2011,216(1):309-346

We have examined the spectral reflectance properties and available modal mineralogies of 39 CM carbonaceous chondrites to determine their range of spectral variability and to diagnose their spectral features. We have also reviewed the published literature on CM mineralogy and subclassification, surveyed the published spectral literature and added new measurements of CM chondrites and relevant end members and mineral mixtures, and measured 11 parameters and searched pair-wise for correlations between all quantities. CM spectra are characterized by overall slopes that can range from modestly blue-sloped to red-sloped, with brighter spectra being generally more red-sloped. Spectral slopes, as measured by the 2.4:0.56 μm and 2.4 μm:visible region peak reflectance ratios, range from 0.90 to 2.32, and 0.81 to 2.24, respectively, with values <1 indicating blue-sloped spectra. Matrix-enriched CM spectra can be even more blue-sloped than bulk samples, with ratios as low as 0.85. There is no apparent correlation between spectral slope and grain size for CM chondrite spectra - both fine-grained powders and chips can exhibit blue-sloped spectra. Maximum reflectance across the 0.3-2.5 μm interval ranges from 2.9% to 20.0%, and from 2.8% to 14.0% at 0.56 μm. Matrix-enriched CM spectra can be darker than bulk samples, with maximum reflectance as low as 2.1%. CM spectra exhibit nearly ubiquitous absorption bands near 0.7, 0.9, and 1.1 μm, with depths up to 12%, and, less commonly, absorption bands in other wavelength regions (e.g., 0.4-0.5, 0.65, 2.2 μm). The depths of the 0.7, 0.9, and 1.1 μm absorption features vary largely in tandem, suggesting a single cause, specifically serpentine-group phyllosilicates. The generally high Fe content, high phyllosilicate abundance relative to mafic silicates, and dual Fe valence state in CM phyllosilicates, all suggest that the phyllosilicates will exhibit strong absorption bands in the 0.7 μm region (due to Fe³⁺-Fe²⁺ charge transfers), and the 0.9-1.2 μm region (due to Fe²⁺ crystal field transitions), and generally dominate over mafic silicates. CM petrologic subtypes exhibit a positive correlation between degree of aqueous alteration and depth of the 0.7 μm absorption band. This is consistent with the decrease in fine-grained opaques that accompanies aqueous alteration. There is no consistent relationship between degree of aqueous alteration and evidence for a 0.65 μm region saponite-group phyllosilicate absorption band. Spectra of different subsamples of a single CM can show large variations in absolute reflectance and overall slope. This is probably due to petrologic variations that likely exist within a single CM chondrite, as duplicate spectra for a single subsample show much less spectral variability. When the full suite of available CM spectra is considered, few clear spectral-compositional trends emerge. This indicates that multiple compositional and physical factors affect absolute reflectance, absorption band depths, and absorption band wavelength positions. Asteroids with reflectance spectra that exhibit absorption features consistent with CM spectra (i.e., absorption bands near 0.7 and 0.9 μm) include members from multiple taxonomic groups. This suggests that on CM parent bodies, aqueous alteration resulted in the consistent production of serpentine-group phyllosilicates, however resulting absolute reflectances and spectral shapes seen in CM reflectance spectra are highly variable, accounting for the presence of phyllosilicate features in reflectance spectra of asteroids across diverse taxonomic groups.  相似文献   

A coordinated spectral, mineralogical, and compositional study of ordinary chondrites     

Tasha L. Dunn  Timothy J. McCoy  Harry Y. McSween Jr. 《Icarus》2010,208(2):789-797

Mineral compositions and abundances derived from visible/near-infrared (VIS/NIR or VNIR) spectra are used to classify asteroids, identify meteorite parent bodies, and understand the structure of the asteroid belt. Using a suite of 48 equilibrated (types 4-6) ordinary (H, L, and LL) chondrites containing orthopyroxene, clinopyroxene, and olivine, new relationships between spectra and mineralogy have been established. Contrary to previous suggestions, no meaningful correlation is observed between band parameters and cpx/(opx + cpx) ratios. We derive new calibrations for determining mineral abundances (ol/(ol + px)) and mafic silicate compositions (Fa in olivine, Fs in pyroxene) from VIS/NIR spectra. These calibrations confirm that band area ratio (BAR) is controlled by mineral abundances, while Band I center is controlled by mafic silicate compositions. Spectrally-derived mineralogical parameters correctly classify H, L and LL chondrites in ∼80% of cases, suggesting that these are robust relationships that can be applied to S(IV) asteroids with ordinary chondrites mineralogies. Comparison of asteroids and meteorites using these new mineralogical parameters has the advantage that H, L and LL chemical groups were originally defined on the basis of mafic silicate compositions.  相似文献   

Spectral reflectance properties of carbonaceous chondrites: 3. CR chondrites     

E.A. Cloutis  P. Hudon  T. Hiroi  M.J. Gaffey 《Icarus》2012,217(1):389-407

Powdered samples of a suite of 14 CR and CR-like chondrites, ranging from petrologic grade 1 to 3, were spectrally characterized over the 0.3–2.5 μm interval as part of a larger study of carbonaceous chondrite reflectance spectra. Spectral analysis was complicated by absorption bands due to Fe oxyhydroxides near 0.9 μm, resulting from terrestrial weathering. This absorption feature masks expected absorption bands due to constituent silicates in this region. In spite of this interference, most of the CR spectra exhibit absorption bands attributable to silicates, in particular an absorption feature due to Fe²⁺-bearing phyllosilicates near 1.1 μm. Mafic silicate absorption bands are weak to nonexistent due to a number of factors, including low Fe content, low degree of silicate crystallinity in some cases, and presence of fine-grained, finely dispersed opaques. With increasing aqueous alteration, phyllosilicate: mafic silicate ratios increase, resulting in more resolvable phyllosilicate absorption bands in the 1.1 μm region. In the most phyllosilicate-rich CR chondrite, GRO 95577 (CR1), an additional possible phyllosilicate absorption band is seen at 2.38 μm. In contrast to CM spectra, CR spectra generally do not exhibit an absorption band in the 0.65–0.7 μm region, which is attributable to Fe³⁺–Fe²⁺ charge transfers, suggesting that CR phyllosilicates are not as Fe³⁺-rich as CM phyllosilicates. CR2 and CR3 spectra are uniformly red-sloped, likely due to the presence of abundant Fe–Ni metal. Absolute reflectance seems to decrease with increasing degree of aqueous alteration, perhaps due to the formation of fine-grained opaques from pre-existing metal. Overall, CR spectra are characterized by widely varying reflectance (4–21% maximum reflectance), weak silicate absorption bands in the 0.9–1.3 μm region, overall red slopes, and the lack of an Fe³⁺–Fe²⁺ charge transfer absorption band in the 0.65–0.7 μm region.  相似文献   

Spectral reflectance‐compositional properties of spinels and chromites: Implications for planetary remote sensing and geothermometry     

Edward A. Cloutis  J. M. Sunshine  R. V. Morris 《Meteoritics & planetary science》2004,39(4):545-565

Abstract— Reflectance spectra of spinels and chromites have been studied as a function of composition. These two groups of minerals are spectrally distinct, which relates largely to differences in the types of major cations present. Both exhibit a number of absorption features in the 0.3–26 μm region that show systematic variations with composition and can be used to quantify or constrain certain compositional parameters, such as cation abundances, and site occupancies. For spinels, the best correlations exist between Fe²⁺ content and wavelength positions of the 0.46, 0.93, 2.8, Restrahelen, 12.3, 16.2, and 17.5 μm absorption features, Al and Fe³⁺ content with the wavelength position of the 0.93 μm absorption feature, and Cr content from the depth of the absorption band near 0.55 μm. For chromites, the best correlations exist between Cr content and wavelength positions of the 0.49, 0.59, 2, 17.5, and 23 μm absorption features, Fe²⁺ and Mg contents with the wavelength position of the 1.3 μm absorption feature, and Al content with the wavelength position of the 2 μm absorption feature. At shorter wavelengths, spinels and chromites are most readily distinguished by the wavelength position of the absorption band in the 2 μm region (<2.1 μm for spinels, >2.1 μm for chromite), while at longer wavelengths, spectral differences are more pronounced. The importance of being able to derive compositional information for spinels and chromites from spectral analysis stems from the relationship between composition and petrogenetic conditions (pressure, temperature, oxygen fugacity) and the widespread presence of spinels and chromites in the inner solar system. When coupled with the ability to derive compositional information for mafic silicates from spectral analysis, this opens up the possibility of deriving petrogenetic information for remote spinel‐ and chromite‐bearing targets from analysis of their reflectance spectra.  相似文献   

Ultraviolet spectral reflectance properties of common planetary minerals     

Edward A. Cloutis  Kaitlyn A. McCormack  Amanda R. Hendrix  Michael A. Craig  Stanley A. Mertzman  Miriam A. Riner 《Icarus》2008,197(1):321-347

Ultraviolet spectral reflectance properties (200-400 nm) of a large number of minerals known or presumed to exist on the surfaces of Mars, the Moon, and asteroids, and in many meteorites, were investigated. Ultraviolet reflectance spectra (200-400 nm) of these minerals range from slightly blue-sloped (reflectance decreasing toward longer wavelengths) to strongly red-sloped (reflectance increasing toward longer wavelengths). Most exhibit one or two absorption features that are attributable to FeO charge transfers involving Fe³⁺ or Fe²⁺. The UV region is a very sensitive indicator of the presence of even trace amounts (<0.01 wt%) of Fe³⁺ and Fe²⁺. The major Fe³⁺O absorption band occurs at shorter wavelengths (∼210-230 nm), and is more intense than the major Fe²⁺O absorption band (∼250-270 nm). Ti-bearing minerals, such as ilmenite, rutile and anatase exhibit UV absorption bands attributable to Ti⁴⁺O charge transfers. While the positions of metal-O charge transfer bands sometimes differ for different minerals, the variation is often not diagnostic enough to permit unique mineral identification. However, iron oxides and oxyhydroxides can generally be distinguished from Fe-bearing silicates in the 200-400 nm region on the basis of absorption band positions. Within a given mineral group (e.g., low-calcium pyroxene, olivine, plagioclase feldspar), changes in Fe²⁺ or Fe³⁺ abundance do not appear to result in a measurable change in absorption band minima positions. Absorption band positions can vary as a function of grain size, however, and this variation is likely due to band saturation effects. The intensity of metal-O charge transfers means that some minerals will exhibit saturated UV absorption bands even for fine-grained (<45 μm) powders. In cases where absorption bands are not saturated (e.g., Fe²⁺O bands in some plagioclase feldspars and pyroxenes), changes in Fe²⁺ content do not appear to cause variations in band position. In other minerals (e.g., olivine), changes in band positions are correlated with compositional and/or grain size variations, but this is likely due to increasing band saturation rather than compositional variations. Overall, we find that the UV spectral region is sensitive to different mineral properties than longer wavelength regions, and thus offers the potential to provide complementary capabilities and unique opportunities for planetary remote sensing.  相似文献   

Icy Galilean satellite reflectance spectra: Less ice on Ganymede and Callisto?     

《Icarus》1987,70(1):99-110

Recent interpretations of the reflectance spectra of the icy Galilean satellites (Europa, Ganymede, and Callisto) have implied very ice-rich surfaces, as high as 90 wt% ice even on the dark surface of Callisto. A reevaluation of the spectra, taking into account the depth of the 3-μm fundamental water ice absorption feature as well as the shorter wavelength bands, suggests that the spectra of at least Ganymede and Callisto may also be consistent with much lower ice abundances if the ice is segregated from the nonicy material. Reasonable fits to all band depths (including the shallow 1.04- and 1.25-μm bands) are obtained with around 50% areal coverage of ice on Ganymede and 10% on Callisto, the rest of the surface being occupied by carbonaceous chondrite-like material which has a strong 3-μm absorption due to bound water. Europa's spectrum probably indicates a homogeneous icy surface. The darkness beyond 3 μm, and lack of a 3.6-μm peak, for all three objects may be consistent with the presence of small quantities of sulfuric acid on the satellite surfaces.  相似文献   

The 506 nm absorption feature in pyroxene spectra: Nature and implications for spectroscopy-based studies of pyroxene-bearing targets     

Edward A. Cloutis  Rachel L. Klima 《Icarus》2010,207(1):295-313

High-resolution (0.34 nm) reflectance spectra of a suite of terrestrial ortho- and clinopyroxenes were characterized in the 506-nm region. This region exhibits absorption bands attributed to spin-forbidden transitions in Fe²⁺ located in the M2, and possibly M1, crystallographic site(s). The most intense absorption bands (up to 3.8% deep in <45 μm fractions) are present in low Ca-content orthopyroxene spectra. This region exhibits two (spectral Group I) or more (spectral Group II) absorption bands in the 500-515 nm interval. Group I spectra are associated with the lowest Ca-content samples. For orthopyroxenes, the number of constituent absorption bands and band depths vary as a function of Ca content; increasing Ca content results the appearance of more than two absorption bands and a general reduction in band depths, offsetting an expected increase in band depth with increasing Fe²⁺ content; band depths may also be reduced due to the long wavelength wing of ultraviolet region Fe-O charge transfer absorptions. Band depths and shapes in this region are also a function of grain size, with the strongest bands appearing for larger grain sizes - in the 90-250 μm range. The number and position of constituent absorption bands can be used to constrain factors such as cooling rates, as expressed in the formation of Guinier-Preston zones versus coarser-grained augite exsolution lamellae. Band depths in the spectra of fine-grained (<45 μm) clinopyroxenes do not exceed 1% and are generally lowest for spectral type A clinopyroxenes, where most of the Fe²⁺ is present in the M1 crystallographic site. The appearance of the 506 nm band in the spectra of pyroxene-bearing asteroids can be used to constrain pyroxene composition and structure. The results of this study suggest that detailed analysis of absorption features in the 506 nm region is a powerful tool for determining the composition and structure of pyroxenes. The spectral resolution of the VIR-MS spectrometer aboard the Dawn spacecraft - which will examine Asteroid 4 Vesta, a body possessing surficial pyroxenes - will be sufficient to provide some constraints on pyroxene composition.  相似文献   

Spectral properties and mineral compositions of acapulcoite–lodranite clan meteorites: Establishing S‐type asteroid–meteorite connections     

Michael P. Lucas  Joshua P. Emery  Takahiro Hiroi  Harry Y. McSween 《Meteoritics & planetary science》2019,54(1):157-180

Except for asteroid sample return missions, measurements of the spectral properties of both meteorites and asteroids offer the best possibility of linking meteorite groups with their parent asteroid(s). Visible plus near‐infrared spectra reveal distinguishing absorption features controlled mainly by the Fe²⁺ contents and modal abundances of olivine and pyroxene. Meteorite samples provide relationships between spectra and mineralogy. These relationships are useful for estimating the olivine and pyroxene mineralogy of stony (S‐type) asteroid surfaces. Using a suite of 10 samples of the acapulcoite–lodranite clan (ALC), we have developed new correlations between spectral parameters and mafic mineral compositions for partially melted asteroids. A well‐defined relationship exists between Band II center and ferrosilite (Fs) content of orthopyroxene. Furthermore, because Fs in orthopyroxene and fayalite (Fa) content in olivine are well correlated in these meteorites, the derived Fs content can be used to estimate Fa of the coexisting olivine. We derive new equations for determining the mafic silicate compositions of partially melted S‐type asteroid parent bodies. Stony meteorite spectra have previously been used to delineate meteorite analog spectral zones in Band I versus band area ratio (BAR) parameter space for the establishment of asteroid–meteorite connections with S‐type asteroids. However, the spectral parameters of the partially melted ALC overlap with those of ordinary (H) chondrites in this parameter space. We find that Band I versus Band II center parameter space reveals a clear distinction between the ALC and the H chondrites. This work allows the distinction of S‐type asteroids as nebular (ordinary chondrites) or geologically processed (primitive achondrites).  相似文献   

A Hapke model implementation for compositional analysis of VNIR spectra of Mercury     

J. Warell  B.J.R. Davidsson 《Icarus》2010,209(1):164-178

An implementation of Hapke’s radiative transfer-based photometric model for light scattering in semi-transparent porous media is presented with special emphasis on the analysis of reflectance spectra of Mercury. The model allows intimate mixing of an arbitrary number of regolith components with varying modal abundances, modal chemistries and grain sizes, matured by microphase iron. Reflectance spectra of suites of silicates of varying grain sizes and chemistries are used to calculate the imaginary coefficient of the complex index of refraction as a function of chemistry, thus limiting the modeling effects of chemically atypical laboratory samples, and allowing controlled modeling of minerals with varying chemical compositions. The performance of the model in the visual to near-infrared wavelength range is evaluated for a range of chemically characterized silicate mixtures of terrestrial powders, meteorite powders, matured lunar return samples, and remotely sensed lunar spectra.  相似文献   

Effects of space weathering on diagnostic spectral features: Results from He+ irradiation experiments     

Xiaohui Fu  Yongliao Zou  Yongchun Zheng  Ziyuan Ouyang 《Icarus》2012,219(2):630-640

We performed ion irradiation of mineral samples with 50 keV He⁺, aimed to investigate ion irradiation effects on diagnostic spectral features. Reflectance spectra of samples in 0.375–2.5 μm are measured before and after ion irradiation. Silicates, including Luobusha olivine, plagioclase and basaltic glass, have shown reddening and darkening of reflectance spectra at the VIS–NIR range. Olivine is more sensitive to ion irradiation than plagioclase and basaltic glass. Irradiated Panzhihua ilmenite exhibits higher reflectance and stronger absorption features, which is totally different from lunar soil and analog silicate materials in other experiments. Using continuum removal and MGM fit, we extracted and compared absorption features of olivine spectra before and after irradiation. Ion irradiation can induce band strength decrease of olivine but negligible band centers shift. We estimate band centers shift caused by ion irradiation are quite limited, even less than variations due to chemical composition in silicates. It provides one possible explanation for no systematic shift in band positions in lunar soil. Irradiated Luobusha olivine spectrum matches spectra of olivine-dominated asteroids. Our results suggest space weathering should be new clues to explain the subtle difference between A-type asteroid spectra and laboratory spectra of olivine.  相似文献   

Modeling infrared absorption bands with nonspherical particles     

T. V. Zinov’eva 《Astronomy Letters》2005,31(7):458-473

We investigated the two deepest absorption bands observed in the spectra of stars and protostars, the water-ice band with the center near 3.1 μm and the silicate band with the center near 9.7 μm, by using a core-mantle confocal spheroid model with various axial ratios and relative volumes of the core material. We considered the effect of grain size, shape, structure, chemical composition, and orientation on the central wavelengths of the two bands, their full widths at half maximum (FWHMs), the ratio of the optical depths at their centers, and the polarization. We found that the observed relationships between the FWHMs of the bands and the ratio of their optical depths at the band centers could be explained if we chose slightly oblate or prolate particles (a/b ? 2) of small sizes (r_v ? 0.35 μm) with a silicate core and a thin ice mantle (V_core/V_total ? 0.7).  相似文献   

Polarization in IR bands and the structure of cosmic dust grains     

M. S. Prokopjeva  V. B. Il’in 《Astronomy Letters》2007,33(10):699-705

The water ice and silicate dust bands centered at about 3 and 10 μm, respectively, are simultaneously observed in the spectra of several objects. So far the wavelength dependence of the polarization in both bands has been modeled using two-layer spheroids, with the shape of the silicate core being confocal to that of the ice mantle. We show that nonconfocality of the spheroidal core and mantle boundaries changes fundamentally the wavelength dependence of the polarization within the 10-μm silicate band and affects significantly the polarization within the 3-μm water ice band, while the extinction profiles of these bands remain essentially unchanged. Since the results have been obtained for a theoretical model, we discuss their applicability and significance for cosmic dust grains. Original Russian Text ? M.S. Prokopjeva, V.B. Il’in, 2007, published in Pis’ma v Astronomicheskiĭ Zhurnal, 2007, Vol. 33, No. 10, pp. 784–791.  相似文献   

Spatial variations of methane absorption on Jupiter according to the results of quasicontinuous CCD spectrophotometry     

V. G. Tejfel  G. A. Kharitonova 《Solar System Research》2014,48(6):424-438

Spectrophotometry observations of Jupiter were carried out during four nights in November–December 1999. Three hundred and eighty eight CCD-spectrograms of the central meridian of the planet were obtained and processed with doubly overlapped longitudes with a step of 1.8°. Latitudinal variations in central depths of methane absorption bands were studied corresponding to the wavelengths of 619, 725, 798, and 887 nm. It has been shown that these variations are mainly present at all longitudes, but for different absorption bands the positions of maxima and minima do not coincide. Zonal differences do not correlate with positions of dark and bright cloud belts in absorption, with one exception for the band 887 nm, which for a long time shows a well-expressed minimum in the equatorial zone of Jupiter. The 798 nm band reveals great dispersion of the depths at low latitudes as compared to other bands, which can be related with the presence of the ammonium absorption band. Comparison of the latitudinal absorption band variability at wave-lengths 619 and 725 nm shows a “loop-like” form of the relation between the depths of these bands in the low-latitude zone of Jupiter. Indicative estimates of the effective optical depth formation and absorption and their difference in the framework of simple two-layer model indicate the existence of vertical heterogeneity of the cloud cover varying with latitude.  相似文献   

Equivalent widths of the 10-μm interstellar silicate feature and dust temperatures in infrared sources     

J. Dorschner  C. Friedemann  J. Gürtler 《Astrophysics and Space Science》1978,54(1):181-185

For 22 infrared sources showing the 10-m silicate absorption band, the optical depths, dust temperatures and equivalent widths have been calculated for two assumed simple models.  相似文献   

10-µm images and spectra of T Tauri stars     

J. E. Van Cleve  T. L. Hayward  J. W. Miles  G. E. Gull  J. Schoenwald  J. R. Houck 《Astrophysics and Space Science》1994,212(1-2):231-238

T Tauri stars are young stars usually surrounded by dusty disks similar to the one from which we believe our own Solar System formed. Most T Tauri stars exhibit a broad emission or absorption band between 7.5 and 13.5µm which is attributed to silicate grains in the circumstellar environment. We imaged three spatially resolved T Tauri binaries through a set of broadband filters which include the spectral region occupied by the silicate band. Two of these objects (T Tauri and Haro 6–10) are infrared companion systems in which one component is optically much fainter but contributes strongly in the infrared. Both infrared companions exhibit a deep silicate absorption which is not present in their primaries, indicating that they suffer very strong local extinction which may be due to an edge-on circumstellar disk or to a dense shell. We also took low resolution spectra of the silicate feature of two unresolved T Tauris to look for narrow features in the silicate band which would indicate the presence of specific minerals such as olivine. We observed GK Tau, for which Cohen and Witteborn (1985) reported a narrow emission feature at 9.7µm, but do not find evidence for this feature, and conclude that it is either time-dependent or an artifact of absorption by telluric ozone.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.  相似文献   

Infrared extinction of heavy ion irradiated and amorphous olivine,with applications to interstellar dust     

W. Krätschmer  Donald R. Huffman 《Astrophysics and Space Science》1979,61(1):195-203

A smooth surface layer of highly disordered olivine, (Mg, Fe)₂SiO₄, has been produced by exposure of polished, natural olivine to a dose of 5×10¹⁶ cm^–2 of 1.5 MeV neon ions from a Van de Graaff accelerator. The dielectric functions of the disordered silicate in the wavelength range from 8 to 30 m have been determined from analysis of specular reflectance data, and extinction for Rayleigh particles of such disordered olivine has been calculated. Extinction measurements for amorphous olivine smoke collected on a substrate are also presented. The small particle extinctions of both kinds of structurally disordered olivine are shown to agree well with the main features of the absorption and emission spectra from interstellar grains in the 10 and 20 m region.  相似文献   

Infrared reflectance spectroscopy on thin films: Interference effects     

B.D. Teolis 《Icarus》2007,190(1):274-279

Laboratory simulations of processes on astronomical surfaces that use infrared reflectance spectroscopy of thin films to analyze their composition and structure often ignore important optical interference effects which often lead to erroneous measurements of absorption band strengths and give an apparent dependence of this quantity on film thickness, index of refraction and wavelength. We demonstrate these interference effects experimentally and show that the optical depths of several absorption bands of thin water ice films on a gold mirror are not proportional to film thickness. We describe the method to calculate accurately band strengths from measured absorbance spectra using the Fresnel equations for two different experimental cases, and propose a way to remove interference effects by performing measurements with P-polarized light incident at Brewster's angle.  相似文献   

Detection and discrimination of sulfate minerals using reflectance spectroscopy   总被引：1，自引：0，他引：1  

Edward A. Cloutis  Frank C. Hawthorne  Katherine Krenn  Dionne Marcino  Johnathon Strong  Diana L. Blaney  Faith Vilas 《Icarus》2006,184(1):121-157

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.  相似文献   

A critical evaluation of oxidation versus reduction during metamorphism of L and LL group chondrites,and implications for asteroid spectroscopy     

Heather K. Gastineau‐Lyons  Harry Y. McSween  Michael J. Gaffey 《Meteoritics & planetary science》2002,37(1):75-89

Abstract— Modal mineralogies of individual, equilibrated (petrologic type 4–6 L and LL chondrites have been measured using an electron microprobe mapping technique, and the chemical compositions of coexisting silicate minerals have been analyzed. Progressive changes in the relative abundances and in the molar Fe/Mn and Fe/Mg ratios of olivine, low‐Ca pyroxene, and diopside occur with increasing metamorphic grade. Variations in olivine/low‐Ca pyroxene ratios (Ol/Px) and in metal abundances and compositions with petrologic type support the hypothesis that oxidation of metallic iron accompanied thermal metamorphism in ordinary chondrites. Modal Ol/Px ratios are systematically lower than normative Ol/Px ratios for the same meteorites, suggesting that the commonly used C.I.P.W. norm calculation procedure may not adequately estimate silicate mineral abundances in reduced chondrites. Ol/Px ratios calculated from visible and near‐infrared (VISNIR) reflectance spectra of the same meteorites are not in agreement with other Ol/Px determinations, possibly because of spectral complexities arising from other minerals in chondrites. Characteristic features in VISNIR spectra are sensitive to the proportions and compositions of olivine and pyroxenes, the minerals most affected by oxidative metamorphism. This work may allow spectral calibration for the determination of mineralogy and petrologic type, and thus may be useful for spectroscopic studies of asteroids.  相似文献