首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition rates during the March 2001–March 2003 period, coupled with previous measurements from 1997 to 2000 (Appl Geochem 16:985–1000, 2001), were compared with the variation of SO2 flux, volcanic activity and rainfall. The deposition rate was mainly controlled by rainfall. Commonly, about 0.1–0.9% of HF, HCl and SO2 emitted by the summit crater's plume were deposited around the volcano. We estimate that ∼2 Gg of volcanogenic sulphur were deposited over the Etnean area during the 2002–2003 flank eruption, at an average rate of ∼24 Mg day−1 which is two orders of magnitude higher than that typical of quiescent degassing phases.  相似文献   

2.
 The Soufrière Hills Volcano, Montserrat, erupting since 18 July 1995, intensified its degassing in early 1996 with the continuing growth of the lava dome inside the summit crater. During this period of increased activity, between 11 and 18 March 1996, we measured gases and particles within the visible plume to determine whether at that time it posed a health risk to the population of Plymouth, the capital town, which is 5 km southwest (downwind) and was then still occupied. Gravimetric measurements were made of total suspended particles (TSP) and particles having an aerodynamic diameter of less than 10 μm (PM10). Measurements were made of sulphur dioxide (SO2), hydrochloric acid (HCl), hydrofluoric acid (HF), nitric acid (HNO3), acetic acid (CH3COOH), formic acid (HCOOH), and particulate sulphate (SO4 2–), chloride (Cl–), nitrate (NO3 –), fluoride (F–), methanesulphonate (CH3SO3 –), acetate (CH3COO–), formate (HCOO–), ammonium (NH4 +), sodium (Na+) and acidity (H+). Trace metals having human health implications [chromium (Cr), nickel (Ni), cobalt (Co), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), tin (Sn), mercury (Hg) and lead (Pb)] were also determined. Mean concentrations of HCl, SO2 and HF obtained in the town of Plymouth were 14.0, 5.9 and 0.8 ppbv, respectively. Corresponding concentrations in the mixed plume on the crater edge were 533, 168 and 22 ppbv. There were no direct emissions of HNO3, although nitrate was detected in coarse particles at the source. Higher concentrations of CH3COOH and HCOOH were measured close to the crater. Mean TSP and PM10 were 64 and 15 μg m–3 in Plymouth, and 455 and 47 μg m–3 on the upper volcano slope. Aerosols were highly acidic at the source but rapidly neutralised during transport. Trace metals were enriched in the aerosol relative to crater surface material. The concentrations of the acid gases, sulphur dioxide in particular, and particles were found to be too small to pose a health hazard at the time of these measurements, when relatively modest volcanic activity was occurring. Received: 9 September 1998 / Accepted: 29 August 1999  相似文献   

3.
Using China's ground observations, e.g., forest inventory, grassland resource, agricultural statistics, climate, and satellite data, we estimate terrestrial vegetation carbon sinks for China's major biomes between 1981 and 2000. The main results are in the following: (1) Forest area and forest biomass car- bon (C) stock increased from 116.5×106 ha and 4.3 Pg C (1 Pg C = 1015 g C) in the early 1980s to 142.8×106 ha and 5.9 Pg C in the early 2000s, respectively. Forest biomass carbon density increased form 36.9 Mg C/ha (1 Mg C = 106 g C) to 41.0 Mg C/ha, with an annual carbon sequestration rate of 0.075 Pg C/a. Grassland, shrub, and crop biomass sequestrate carbon at annual rates of 0.007 Pg C/a, 0.014― 0.024 Pg C/a, and 0.0125―0.0143 Pg C/a, respectively. (2) The total terrestrial vegetation C sink in China is in a range of 0.096―0.106 Pg C/a between 1981 and 2000, accounting for 14.6%―16.1% of carbon dioxide (CO2) emitted by China's industry in the same period. In addition, soil carbon sink is estimated at 0.04―0.07 Pg C/a. Accordingly, carbon sequestration by China's terrestrial ecosystems (vegetation and soil) offsets 20.8%―26.8% of its industrial CO2 emission for the study period. (3) Considerable uncertainties exist in the present study, especially in the estimation of soil carbon sinks, and need further intensive investigation in the future.  相似文献   

4.
Volcanoes provide important contributions to atmospheric budgets of SO2 and reactive halogens, which play significant roles in atmospheric oxidative capacity and radiation. However, the global source strengths of volcanic emissions remain poorly constrained. These uncertainties are highlighted here by the first measurements of gas emission rates from Ambrym volcano, Vanuatu. Our initial airborne ultraviolet spectroscopic measurements made in January 2005 indicate fluxes of 18–270 kg s-1 of SO2, and 62–110 g s-1 of BrO, into the atmosphere, placing Ambrym amongst the largest known contemporary point sources of both these species on Earth. We also estimate high Cl and F fluxes of ~8–14 and ~27–50 kg s-1, respectively, for this period. Further observations using both airborne and spaceborne remote sensing reveal a fluctuating SO2 output between 2004 and 2008, with a surge in the first half of 2005, and underline the substantial contribution that a single passively degassing volcano can make to the atmospheric budget of sulfur and halogens.  相似文献   

5.
 Measurements of CO2 fluxes from open-vent volcanos are rare, yet may offer special capabilities for monitoring volcanos and forecasting activity. The measured fluxes of CO2 and SO2 from Mount St. Helens decreased from July through November 1980, but the record includes variations of CO2/SO2 in the emitted gas and episodes of greatly increased fluxes of CO2. We propose that the CO2 flux variations reflect two gas components: (a) a component whose flux decreased in proportion to 1/ √t with a CO2/SO2 mass ratio of 1.7, and (b) a residual flux of CO2 consisting of short-lived, large peaks with a CO2/SO2 mass ratio of 15. We propose two hypotheses: (a) the 1/ √t dependence was generated by crystallization in a deep magma body at rates governed by diffusion-limited heat transfer, and (b) the gas component with the higher CO2/SO2 was released from ascending magma, which replenished the same magma body. The separation of the total CO2 flux into contributions from known processes permits quantitative inferences about the replenishment and crystallization rates of open-system magma bodies beneath volcanos. The flux separations obtained by using two gas sources with distinct CO2/SO2 ratios and a peak minus background approach to obtain the CO2 contributions from an intermittent source and a continuously emitting source are similar. The flux separation results support the hypothesis that the second component was generated by episodic magma ascent and replenishment of the magma body. The diffusion-limited crystallization hypothesis is supported by the decay of minimum CO2 and SO2 fluxes with 1/ √t after 1 July 1980. We infer that the magma body at Mount St. Helens was replenished at an average rate (2.8×106 m3 d–1) which varied by less than 5% during July, August, and September 1980. The magma body volume (2.4–3.0 km3) in early 1982 was estimated by integrating a crystallization rate function inferred from CO2 fluxes to maximum times (20±4 years) estimated from the increase of sample crystallinity with time. These new volcanic gas flux separation methods and the existence of relations among the CO2 flux, crystallization rates, and magma body replenishment rates yield new information about the dynamics of an open-vent, replenished magma body. Received: 15 February 1995 / Accepted: 30 March 1996  相似文献   

6.
Fogang granitic batholith, the largest Late Mesozoic batholith in the Nanling region, has an exposure area of ca. 6000 km2. Wushi diorite-hornblende gabbro body is situated at the northeast part of the ba- tholith. Both the granitic batholith main body and the diorite-hornblende gabbro body belong to high-K calc alkaline series. Compared with the granitic main body, the Wushi body has lower Si (49%―55%), higher Fe, Mg, Ca, lower REE, less depletion of Eu, Ba, P, Ti, and obvious depletion of Zr, Hf. Zircon LA-ICP-MS dating and the mineral-whole rock isochron dating reveal that Fogang granitic main body and Wushi body were generated simultaneously at ca. 160 Ma. The Fogang granitic main body has high (87Sr/86Sr)i ratios (0.70871―0.71570) and low εNd(t) values (?5.11―?8.93), suggesting the origins of the granitic rocks from crustal materials. Their Nd two-stage model ages range from 1.37―1.68 Ga. The Sr and Nd isotopic compositions and the Nd model ages of the granitic rocks may suggest that the giant Fogang granitic main body was generated from a heterogeneous source, with participation of mantle component. Wushi diorite-hornblende gabbro is an unusual intermediate-basic magmatic rock series, with high (87Sr/86Sr)i ratios (0.71256―0.71318) and low εNd(t) values (?7.32―?7.92), which was possibly formed through mixing between the mantle-derived juvenile basaltic magma and the magma produced by the dehydration melting of lower crustal basaltic rocks.  相似文献   

7.
 The 1963 eruption of Gunung Agung produced 0.95 km3 dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100  °C at an assumed pressure of 2 kb, f O2>NNO, and an average melt volatile content (H2O±CO2) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×1012 g (Mt) of SO2 and 3.4 Mt of Cl released from the 0.65 km3 of juvenile tephra which contributed to stratospheric injection of H2SO4 aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO2 release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO2 was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO2 emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO2 emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions. Received: 29 June 1994 / Accepted: 25 April 1996  相似文献   

8.
Low-mature gases and typical low-mature gas fields in China   总被引：2，自引：0，他引：2  
No natural gas pool of industrial importance could be formed at the low-evolution stage of organic matter. In the 1980s, on the basis of the development in exploration practice, the hypotheses of bio-thermo-catalytic transitional zone gases and early thermogenic gases were proposed. The lower-limit Ro values for the formation and accumulation of natural gases of industrial importance have been expanded to 0.3%―0.4%. In the light of the two-stage model established on the basis of carbon isotope fractionation in coal-type natural gases, the upper-limit Ro values have been set at 0.8%―1.0%. In terms of the geological practice in the low-mature gas zones and China's main coal-type gas fields, it is feasible and proper to set the upper-limit Ro value of low-mature gases at 0.8%. Supper-large gas fields such as the Urengoy gas field in western Siberian Basin should belong to low-mature gas fields, of which the natural gas reserves account for more than 20% of the global proven reserves, providing strong evidence for the significance of such a type of resources. The proven natural gas reserves in the Turpan-Hami Basin of China have almost reached 1000 × 108 m3. The main source rocks in this area are the Jurassic Xishanyao Formation, which occurs as a suite of coal series strata. The corresponding thermal evolution indices (Ro ) are mainly within the range of about 0.4%―0.8%, the δ 13C1 values of methane vary between-44‰ and-39‰ (correspondingly Ro =0.6%―0.8%), and those of ethane are within the range of-29‰―-26‰, indicating that natural gases in the Turpan-Hami Basin should be designated to coal-type low-mature gases. The light hydrocarbon evolution indices of natural gases also fall within the area of low evolution while the precursor type of light hydrocarbons also shows the characteristics of the coal-type. The geological background, carbon isotopic composition and light hydrocarbon index all provide strong evidence suggesting that the proven natural gases in the Turpan-Hami Basin are low-mature gases. In China a gas field with the gas reserves reaching 300 ×108 m3 can be defined as a large gas field, and thus the proven low-mature gases in the Turpan-Hami Basin are equivalent to the reserves of three large gas fields. Its existence is of great significance in research on and exploration of low-mature gases in China.  相似文献   

9.
On the basis of the study of volcanic products during 1199–1200AD eruption of Baitou Mountain (Baitoushan), the released volatile content was estimated by comparing Cl, F, S, H2O concentrations of undegassed glass inclusions with those of degassed matrix glasses. The calculations show that volatile yields, released from the melt, are 109.88 × 106 ton of HCl, 196.80 × 106 ton of HF, 1477.84 × 106 ton of H2O, 23.14 × 106 ton of SO2, which could have formed 35.43 x106 ton of H2SO4 aerosol in the atmosphere. They could have substantial effect on paleoclimate and paleo-environment.  相似文献   

10.
This paper reports geochemical and Pb-Sr-Nd isotopic compositions of the Indosinian Yangba (215 Ma),Nanyili (225 Ma) and Mopi granitoids from the Bikou block of the northwestern margin of the Yangtze plate. These granitoids are enriched in Al (Al2O3:14.56%―16.48%) and Sr (352 μg/g―1047 μg/g),and depleted in Y (<16 μg/g) and HREE (e.g. Yb<1.61 μg/g),resulting in high Sr/Y (36.3―150) and (La/Yb)N (7.8―36.3) ratios and strongly fractionationed REE patterns. The Indosinian granotoids show initial Sr isotopic ratios (ISr) from 0.70419 to 70752,εNd(t) values from-3.1 to -8.5,and initial Pb isotopic ratios 206Pb/204Pb=17.891-18.250,207Pb/204Pb=15.494-15.575,and 208Pb/204Pb=37.788-38.335. Their geochemi-cal signatures indicate that the granitoids are adakitic. However,they are distinct from some adakites,generated by partial melting of subducted oceanic slab and/or underplated basaltic lower crust,be-cause they have high K (K2O: 1.49%―3.84%) and evolved Nd isotopic compositions,with older Nd iso-topic model ages (TDM=1.06―1.83 Ga). Geochemical and Sr-Nd isotopic compositions suggest that the magmas of the Insoninian adakitic rocks in the Bikou block were derived from partial melting of thick-ened basaltic lower crust. Combined with regional analyses,a lithospheric delamination model after collision between the North China and South China plates can account for the Indosinian adakitic magma generation. On the other hand,based on the Pb-Sr-Nd isotopic probing to the magma sources of the adakitic rocks,it is suggested that there is an unexposed continent-type basement under the exposed Bikou Group volcanic rocks. This can constrain on the Bikou Group volcanic rocks not to be MORB-or OIB-type.  相似文献   

11.
Multiple sulfur and oxygen isotope compositions in Beijing aerosol   总被引：1，自引：0，他引：1  
Multiple sulfur isotopes(32S, 33 S, 34 S, 36S) and oxygen isotopes(16O, 18O) in Beijing aerosols were measured with MAT-253 isotope mass spectrometer. The δ34S values of Beijing aerosol samples range from 1.68‰ to 12.57‰ with an average value of 5.86‰, indicating that the major sulfur source is from direct emission during coal combustion. The δ18O values vary from 5.29‰ to 9.02‰ with an average value of 5.17‰, revealing that the sulfate in Beijing aerosols is mainly composed of the secondary sulfate. The main heterogeneous oxidation of SO2 in atmosphere is related to H2O2 in July and August, whereas H2O2 oxidation and Fe3+ catalytic oxidation with SO2 exist simultaneously in September and October. Remarkable sulfur isotope mass-independent fractionation effect is found in Beijing aerosols, which is commonly attributed to the photochemical oxidation of SO2 in the stratosphere. In addition, thermochemical reactions of sulfur-bearing compounds might be also a source of sulfur isotope anomalies based on the correlation between ?33S and CAPE.  相似文献   

12.
This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins.  相似文献   

13.
Field observation showed that there are many irregular leucocratic intrusive rocks in pillow lavas in the Danfeng Group in the Xiaowangjian area, north Qinling orogenic belt. Photomicrographs indicated that the protoliths of those altered leucocratic intrusive rocks are dioritic rocks. Geochemical analyses showed that pillow lavas have a range of SiO2 from 47.35% to 51.20%, low abundance of TiO2 from 0.97% to 1.72%, and percentages of MgO (MgO#=41―49). Chondrite-normalized REE patterns of pillow lavas are even, indicative of a weak differentiation between LREE and HREE (La/YbN=1.52―0.99). N-MORB-normalized trace element abundances showed that pillow lavas are enriched in incompatible elements (e.g., K, Rb, and Ba). Leucocratic intrusive rocks in pillow lavas have a wide range of SiO2 from 53.85%―67.20%, low abundances of TiO2 from 0.51%―1.10%, and MgO (MgO#=40―51), and higher percentages of Al2O3 (13.32%―16.62%) and concentration of Sr (342-539 μg/g), ratios of Na2O/K2O (2―7) and Sr/Y (17―28). Chondrite-normalized REE patterns of leucocratic intrusive rocks showed highly differentiation between LREE and HREE (La/YbN=12.26―19.41). N-MORB-normalized trace element abundances showed that leucocratic intrusive rocks are enriched in incompatible elements (e.g., K, Rb, and Ba), and significantly depleted in HFSE (e.g., Nb, Ta, Zr and Ti), indicative of a relationship to subduction. Isotopically, leucocratic intrusive rocks have a similar εNd(t) ( 7.45― 13.14) to that of MORB ( 8.8― 9.7), which indicates that those leucocratic intrusive rocks sourced from depleted mantle most likely. SHRIMP U-Pb analyses for zircon showed that those leucocratic intrusive rocks were formed at 442±7 Ma, yielding an age of subduction in the early Paleozoic in the north Qinling orogenic belt.  相似文献   

14.
Miocene(16―10 Ma) basalts,together with significantly well-preserved fossils(including animal and plant fossils) in the contemporaneously tephra-rich Maar sediments,are located in Shanwang volcanic region,Shandong Province,China.Distribution area of the basaltic eruption products is about 240 km2.Detailed field observations indicate that most of basaltic rocks are fissure eruptive products and some are central eruptives constrained by linear faults.The well-preserved fossils in the lacustrine deposits have been considered to be a result of mass mortalities.Based on physically volcanologic modeling results,eruption column of the basaltic fissure activities in the Shanwang volcanic region is estimated to have entered the stratosphere.Petrographic observations indicate that the basalts have porphyritic textures with phenocrysts of olivine,pyroxene,plagioclase feldspar and alkali feldspar setting in groundmass of plagioclase feldspar,alkali feldspar,quartz,apatite and glass.Based on observations of tephra,tuff and tuffites collected in the Maar sediments of the Shanwang area,we determined major element oxide concentrations and volatile composition of melt inclusions in phenocrysts and matrix glasses by electron microprobe analysis.Volatile(including S,Cl,F and H2O) concentrations erupted into the stratosphere were estimated by comparing pre-and post-eruptive volatile concentrations.Our determination results show that contents of S,Cl,F and H2O emitted into the stratosphere were 0.18%― 0.24%,0.03%―0.05%,0.03%―0.05% and 0.4%―0.6%,respectively,which was characterized by high-S contents erupted.Amounts of volatiles emitted in the Shanwang volcanic region are much higher than those in eruptions which had a substantial effect on climate and environment.According to the com-positions and amounts of the volatiles erupted from the Miocene basaltic volcanism in Shanwang,we propose a hypothesis that volatile-rich basaltic volcanism could result in the mass mortalities by in-jecting volatiles(e.g.,SO2,H2S,HCl,HF and H2O) into the stratosphere that would have triggered abrupt environmental changes(including formation of acid rain,temperature decline,ozone depletion,etc.) and altered lake chemistry,and subsequently volcanic ash fall buried and covered the dead animals and plants,forming well-preserved fossils in Shanwang Maar sediments.  相似文献   

15.
The sorption of AuCl4 −,AuCl2 − and Au(S2O3)3- on δ-MnO2 was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO3 solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO2 are 0.18–0.21 and 0.28μmoL/m2 for AuCl4 − and Au(S2O3)2 3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO2. The Au sorption decreases in the sequence of Au(S2O3)2 3- >AuCl4 − >AuC12 −. The intrinsic equilibrium constants (logK int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl4 - are preferentially adsorbed by δ-MnO2 and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.  相似文献   

16.
We present an uncertainty analysis of ecological process parameters and CO2 flux components (R eco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance measurements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different models and optimization methods in influencing estimation of key parameters and CO2 flux components. The results show that: (1) Random flux error more closely follows a double-exponential (Laplace), rather than a normal (Gaussian) distribution. (2) Different optimization methods result in different estimates of model parameters. Uncertainties of parameters estimated by the maximum likelihood estimation (MLE) are lower than those derived from ordinary least square method (OLS). (3) The differences between simulated Reco, NEE and GEE derived from MLE and those derived from OLS are 12.18% (176 g C·m−2·a−1), 34.33% (79 g C·m−2·a−1) and 5.4% (92 g C·m−2·a−1). However, for a given parameter optimization method, a temperature-dependent model (T_model) and the models derived from a temperature and water-dependent model (TW_model) are 1.31% (17.8 g C·m−2·a−1), 2.1% (5.7 g C·m−2·a−1), and 0.26% (4.3 g C·m−2·a−1), respectively, which suggested that the optimization methods are more important than the ecological models in influencing uncertainty in estimated carbon fluxes. (4) The relative uncertainty of CO2 flux derived from OLS is higher than that from MLE, and the uncertainty is related to timescale, that is, the larger the timescale, the smaller the uncertainty. The relative uncertainties of Reco, NEE and GEE are 4%−8%, 7%−22% and 2%−4% respectively at annual timescale. Supported by the National Natural Science Foundation of China (Grant No. 30570347), Innovative Research International Partnership Project of the Chinese Academy of Sciences (Grant No. CXTD-Z2005-1) and National Basic Research Program of China (Grant No. 2002CB412502)  相似文献   

17.
 Two methods were used to quantify the flux of volcanic sulphur (as the equivalent mass of SO2) to the stratosphere over different timescales during the Holocene. A combination of satellite-based measurements of sulphur yields from recent explosive volcanic eruptions with an appropriate rate of explosive volcanism for the past 200 years constrains the medium-term (∼102 years) flux of volcanic sulphur to the stratosphere to be ∼1 Mt a–1, with lower and upper bounds of 0.3 and 3 Mt a–1. The short-term (∼10- to 20-year) flux due to small magnitude (1010–1012 kg) eruptions is of the order of 0.4 Mt a–1. At any time the instantaneous levels of sulphur in the stratosphere are dominated by the most recent (0–3 years) volcanic events. The flux calculations do not attempt to address this very short timescale variability. Although there are significant errors associated with the raw sulphur emission data on which this analysis is based, the approach presented is general and may be readily modified as the quantity and quality of the data improve. Data from a Greenland ice core support these conclusions. Integration of the sulphate signals from presumed volcanic sources recorded in the GISP2 core provides a minimum estimate of the 103–year volcanic SO2 flux to the stratosphere of 0.5–1 Mt a–1 over the past 9000 years. The short-term flux calculations do not account for the impact of rare, large events. The ice-core record does not fully account for the contribution from small, frequent events. Received: 27 September 1995 / Accepted: 13 December 1995  相似文献   

18.
Based on the stem analysis of 59 individuals of Pinus elliottii in combination with tree biomass models, we calculated annual biomass increment of forest plots at Qianyanzhou Ecological Station, Chinese Academy of Sciences in subtropical China. In addition, canopy layer and community NPP were calculated based on 12 years’ litter fall data. NPP of the 21-year-old forest was estimated by using the BIOME BGC model; and both measured NPP and estimated NPP were compared with flux data. Community biomass was 10574 g · m−2; its distribution patterns in tree layer, shrub layer, herbaceous layer, tree root, herbaceous and shrub roots and fine roots were 7542, 480, 239, 1810, 230, 274 and 239 g · m−2, respectively. From 1999 to 2004, the average annual growth rate and litter fall were 741 g · m−2 · a−1 (381.31 gC · m−2 · a−1) and 849 g · m−2 · a−1 (463 gC · m−2 · a−1), respectively. There was a significant correlation between annual litter fall and annual biomass increment; and the litter fall was 1.19 times the biomass increment of living trees. From 1985 to 2005, average NPP and GPP values based on BGC modeling were 630.88 (343.31–906.42 gC · m−2 · a−1) and 1 800 gC · m−2 · a−1 (1351.62–2318.26 gC · m−2 · a−1). Regression analysis showed a linear relationship (R 2=0.48) between the measured and simulated tree layer NPP values. NPP accounted for 30.2% (25.6%–32.9%) of GPP, while NEP accounted for 57.5% (48.1%–66.5%) of tree-layer NPP and 41.74% (37%–52%) of stand NPP. Soil respiration accounted for 77.0% of measured tree NPP and 55.9% of the measured stand NPP. NEE based on eddy covariance method was 12.97% higher than the observed NEP. Supported by the National Key Basic Research Special Foundation of China (Grant No. 2002CB4125), International Joint Research Project under Ministry of Science and Technology of China (Grant No. 2006DFB91920)  相似文献   

19.
 The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO3 thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ18O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in 18O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH4 in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO4 springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO3 springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO4 waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s). Received: 9 November 1998 / Accepted: 15 July 1999  相似文献   

20.
Lastarria volcano (25°10′ S, 68°31′ W; 5,697 m above sea level), located in the Central Andes Volcanic Zone (northern Chile), is characterized by four distinct fumarolic fields with outlet temperatures ranging between 80°C and 408°C as measured between May 2006–March 2008 and April–June 2009. Fumarolic gasses contain significant concentrations of high temperature gas compounds (i.e., SO2, HCl, HF, H2, and CO), and isotopic ratios (3He/4He, δ13C–CO2, δ18O–H2O, and δD–H2O) diagnostic of magmatic gas sources. Gas equilibria systematics, in both the H2O-H2-CO2-CO-CH4 and alkane–alkene C3 system, suggest that Lastarria fumarolic gasses emanate from a superheated vapor that is later cooled and condensed at relatively shallow depths. This two-stage process inhibits the formation of a continuous aquifer (e.g., horizontal liquid layer) at relatively shallow depth. Recent developments in the magmatic gas system may have enhanced the transfer and release of heat causing shallow aquifer vaporization. The consequent pressure increase and aquifer vaporization likely triggered the inflation events beginning in 2003 at the Lastarria volcano.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号