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1.
Petrographic analyses of six cores penetrating the Inglis and Avon Park Formations, from Crystal River, Florida, U.S.A., reveal a general regressive—transgressive cycle, aerial exposure and diagenesis. Three distinct lithofacies are represented: (I) biomicrite—poorly washed biosparite; (II) dolomitized biopelmicrite—biosparite and algal dololithite; and (III) pellet- and intraclast-bearing biosparite. These lithofacies were deposited under shallow-marine conditions, at times even above the strand line.Lithofacies I was deposited in a shallow basin partly covered by marine grasses and dasyclad algae. Lithofacies II was deposited in the supratidal and intertidal zones and closely resembles the sedimentary characteristics of Holocene mud-flat deposits. Lithofacies III is the shallow-marine counterpart of the supratidal dolostone of lithofacies II and can be compared with a Holocene bank environment.This study illustrates the importance of Holocene analogues in determining and interpreting environments and demonstrates the need to consider sedimentary processes, both physical and biological, which operate in these zones. 相似文献
2.
3.
Albert Baltres 《Sedimentary Geology》1975,13(4):291-302
In the hypersaline Techirghiol Lake adjacent to the Black Sea, sporadically formed lithified blocks and grapestone are found which are the result of cementation of carbonate sediments with aragonite and possibly kutnahorite (manganesian calcite). The lithified blocks are characterized by a central cavity bordered by a lithified envelope. The formation of the carbonate cement is due to subaquatic bacterial processes of calcium sulfate reduction and the synthesis of calcium carbonate at the expense of gypsum concretions derived from Pleistocene red clays cropping out along the shore of the lake. These lithified blocks have geological significance as they may be usable as criteria for the recognition of sediments deposited in the past near to the shores of hypersaline lakes. 相似文献
4.
本文根据岩矿特征、沉积构造、生物组合等标志将巴楚-柯坪地区上石炭统碳酸盐岩沉积环境自西往东划分为:广海盆地相、台地边缘浅滩相、开阔台地相及滨岸浅滩相。并采用阴极发光,扫描电镜、X射线衍射分析、TAS-plus图像分析仪及测定镜质体反射率等分析手段,对该地区碳酸盐岩的压实、压溶、胶结、溶解及白云化作用进行了详细研究,推断了该岩层经历的最高成岩温度和所处的成岩阶段,并对其孔隙演化特点进行了分析,指出了次生孔隙发育的有利地带。 相似文献
5.
The geological storage of nuclear waste includes multibarrier engineered systems where a large amount of cement-based material is used. Predicting the long term behaviour of cement is approached by reactive transport modelling, where some of the boundary conditions can be defined through studying natural cement analogues (e.g. at the Maqarin natural analogue site). At Maqarin, pyrometamorphism of clay biomicrites and siliceous chalks, caused by the in-situ combustion of organic matter, produced various clinker minerals. The interaction of infiltrating groundwater with these clinker phases resulted in a portlandite-buffered hyperalkaline leachate plume, which migrated into the adjacent biomicrite host rock, resulting in the precipitation of hydrated cement minerals.In this study, rock samples with different degrees of interaction with the hyperalkaline plume were investigated by various methods (mostly SEM-EDS). The observations have identified a paragenetic sequence of hydrous cement minerals, and reveal how the fractures and porosity in the biomicrite have become sequentially filled. In the alkaline disturbed zone, C-A-S-H (an unstoichiometric gel of Ca, Al, Si and OH) is observed to fill the pores of the biomicrite wallrock, as a consequence of reaction with a high pH Ca-rich fluid circulating in fractures. Porosity profiles indicate that in some cases the pores of the rock adjacent to the fractures became tightly sealed, whereas in the veins some porosity is preserved. Later pulses of sulphate-rich groundwater precipitated ettringite and occasionally thaumasite in the veins, whereas downstream in the lower pH distal regions of the hyperalkaline plume, zeolite was precipitated.Comparing our observations with the reactive transport modelling results reveals two major discrepancies: firstly, the models predict that ettringite is precipitated before C-A-S-H, whereas the C-A-S-H is observed as the earlier phase in Maqarin; and, secondly, the models predict that ettringite acts as the principal pore-filling phase in contrast to the C-A-S-H observed in the natural system. These discrepancies are related to the fact that our data were not available at the time the modelling studies were performed. However, all models succeeded in reproducing the porosity reduction observed at the fracture–rock interface in the natural analogue system. 相似文献
6.
CEES VAN der LAND FURU MIENIS HENK DE HAAS NORBERT FRANK RUDY SWENNEN TJEERD C. E. VAN WEERING 《Sedimentology》2010,57(3):912-931
Cold water coral covered carbonate mounds at the south‐west margin of the Rockall Trough form ridges several kilometres long and up to 380 m high. Piston cores obtained at three mound crests reveal the complex internal structure of the mound build up, with alternating unlithified coral‐dominated intervals and lithified intervals. The most recent lithified interval is covered by corals embedded in a fine‐grained matrix, comprising ca 11 000 years of continuous mound evolution. Before this time 230Th/U dating shows the presence of several hiatuses in mound build‐up. Aragonitic coral material is absent or only present as mouldic porosity in the lithified intervals and coccoliths display widespread overgrowth. Downcore X‐ray fluorescence scanning, computer tomography scan images and petrographic observations indicate different degrees of diagenetic alteration. The upper boundary of the most recent lithified interval shows some erosional features, but petrographic observations indicate that initial lithification of the sediments is not related to this erosive event or to long‐term non‐sedimentation, but to earlier sub‐surface diagenesis. Organic matter oxidation and the subsequent lowering of the saturation state of the carbonate system drives dissolution of the unstable aragonitic coral skeletons. Depending on the openness of the system, this can lead to precipitation of a more stable low‐magnesium carbonate. A model is presented describing the sedimentary and diagenetic processes leading to the formation of lithified intervals. 相似文献
7.
Basaltic boulders dredged from the Mid-Atlantic Ridge contain lithified coccolith-foraminiferal ooze in fractures and small pockets. Textural and isotopic studies of this sediment provide no evidence for high temperature metamorphism. The lithified carbonate sediment occurs together with palagonitized basaltic glass and zeolitic tuff, and appears to have been squeezed into cracks and other voids within the congealed margins of partly-cooled basalt pillows which intruded soft carbonate ooze. Thermal metamorphism probably was precluded by rapid heat dissipation in convecting pore waters and by the thermal stability of calcareous microplankton. Low temperature alteration of basaltic glass appears to have provided the chemical milieu for precipitation of calcite cement as well as zeolites in the sediment. 相似文献
8.
Isotopic and trace element evidence for submarine lithification of hardgrounds in the Jurassic of eastern England 总被引：1，自引：0，他引：1
Geochemical and petrographic data suggest early submarine cementation of hardgrounds from the Lincolnshire Limestone Formation, Middle Jurassic, England. The three hardgrounds, from Cowthick, Castle Bytham and Leadenham quarries, developed in tidal-inlet, on-barrier and lagoonal sub-environments of a carbonate barrier-island complex. At Cowthick early composite (acicular-bladed) radial-fibrous cements, which pre-date aragonite dissolution, completely fill intergranular pore-space at the hardground surface; away from it isopachous fringing cements decrease in thickness. Microprobe analyses demonstrate zoning within the fringes with magnesium concentrations (> 2 wt % MgCO3) higher than those in allochems or later, ferroan cement (?0.5 wt % MgCO3, 1.7 wt % FeCO3). At Castle Bytham early granular isopachous cements, which post-date aragonite dissolution, occur within 5 cm of the surface. At Leadenham early lithification is superficial and represented by ferruginous crusts and micritic internal sediment. Late blocky cement fills residual pore-space in all three examples. Carbon and oxygen isotopic composition of whole-rock samples taken at intervals away from each hardground surface demonstrate the increasing proportion of late 18O depleted cements (δ18O – 8 to – 10). Early cements must have a marine isotopic composition; different δ18O values from each hardground reflect the intensity of early lithification and exclusion of late cements at the hardened surface. There is no isotopic evidence for subaerial cement precipitation during possible emergence at Castle Bytham. Oyster samples (with δ18O, – 2.9 and δ13C, 2.4) give estimated palaeotemperatures of 22–25°C. Early cements from Cowthick are enriched in 18O and 13C (δ18O = 0 δ13C ? 3‰) compared to the oyster values. In conjunction with trace element data this is interpreted as evidence for high-magnesium calcite precursor cements which underwent replacement in a system with a low water: rock ratio. The intensity of early lithification is related to depositional environment: maximum circulation of sea-water producing the most lithified hardground (Cowthick). This is directly analogous to the formation of Recent hardgrounds. 相似文献
9.
ABSTRACT
The carbon and oxygen isotopic composition of the Austin Chalk was examined in cores representing a range of depths from surface to 3000 m in order to document the effects of burial diagenesis on carbon and oxygen isotopic composition. Low magnesium calcite oysters were separated (from 500 um wide areas) and analysed to estimate the starting composition of Cretaceous marine sediment. These gave an average value of -2·5%δ18 O; + 2·0%δ13 C (PDB). The compositions of micrite, intergranular cement, and fracture cement were analysed, and their deviation from this original marine composition was evaluated to document the progression of chalk diagenesis. Interestingly, micrite exhibits only minor variation in composition from marine values despite present burial depth ranges in excess of 3000 m. The average deviation from δ18O marine is less than 1·5. Furthermore, intergranular cement and particularly fracture cements, which occur only in the deepest cores and which clearly post-date micrite lithification, are generally indistinguishable from micrite in composition. Isotopic compositions exhibit no correlation with depth of burial despite abundant petrographic evidence of deep burial diagenesis. This uniformity in composition is interpreted as reflecting a closed, rock-dominated diagenetic system in which the compositions of precipitated carbonate cements were controlled by the composition of dissolving carbonates during lithification. As such, the composition of burial cement is not representative of the rock-water temperatures during precipitation.
Thus, in the context of isotopic analyses from other carbonate systems, unless the degree of openness of the diagenetic system is known, oxygen isotopic signatures of cements cannot directly be converted to the rock-water temperatures at which they were precipitated unless the composition of the ambient porefluid is also known. 相似文献
The carbon and oxygen isotopic composition of the Austin Chalk was examined in cores representing a range of depths from surface to 3000 m in order to document the effects of burial diagenesis on carbon and oxygen isotopic composition. Low magnesium calcite oysters were separated (from 500 um wide areas) and analysed to estimate the starting composition of Cretaceous marine sediment. These gave an average value of -2·5%δ
Thus, in the context of isotopic analyses from other carbonate systems, unless the degree of openness of the diagenetic system is known, oxygen isotopic signatures of cements cannot directly be converted to the rock-water temperatures at which they were precipitated unless the composition of the ambient porefluid is also known. 相似文献
10.
This paper describes the occurrence of dolostone and the mechanism of dolomitization of the Upper Devonian Gölbo?az? Formation in the allochthonous Taurus Mountains Alada? unit in Turkey. The Upper Devonian Gölbo?az? Formation carbonates, with dominant ostracod-bearing mudstone and wackestone, formed tidal and subtidal environments, and some of these rocks were dolomitized from shallow to deep burial. On the basis of the field, the petrographic and geochemical features, four different replaceable and cement dolostone phases have been recognized. The replacive dolostones contain (1) very fine to fine crystalline planar-s dolostone (df1), (2) medium to coarse crystalline planar-s to planar-e dolostone (df2), (3) coarse to very coarse crystalline non-planar-a dolostone (df3), and (4) coarse to very coarse crystalline planar dolostone cement (df4). The replacive dolostones are disordered to moderate the ordered and calcium-rich. They are non-stoichiometric and have 46–59 mol% CaCO3 and 41–54 mol% MgCO3 total contents. The df1 dolostones have MgCO3 contents of 41–54 mol%, the df2 dolostones have 41–53 mol%, the df3 dolostones have 49 mol%, and the df4 dolostones have 49–50 mol%, respectively. The Gölbo?az? dolostones have δ18O values of ?9.44 to ?2.20‰ Vienna Pee Dee Belemnite (VPDB) and δ13C values of ?1.58 to +2.52 VPDB. Sr, Na, Mn, and Fe concentrations of replacive dolostones are 74–184, 148–593, below detection level (bdl)–619, and 1049–9233 ppm, respectively. The petrographic and geochemical data demonstrate that the replacive dolostones occurred prior to the chemical compaction at shallow to intermediate burial depths from Late Devonian seawater and/or seawater lightly modified by water–rock interaction process and later recrystallized by basinal brines at increasing burial depths and temperature. The North American Shale Composite-normalized rare earth element values of both limestone and dolostone show very similar rare earth element patterns characterized by slightly or considerably negative cerium (Ce) anomalies and a clear depletion in all rare earth element species. The dedolomitization observed in the Gölbo?az? Formation is thought to occur by the oxidizing effect of the meteoric water in the shallow burial environment during the telodiagenesis. 相似文献
11.
Ibrahim M. Ghandour Hamad A. Al-Washmi Rashad A. Bantan Mohamed M. Gadallah 《Arabian Journal of Geosciences》2014,7(1):355-365
The present study describes the petrographic and petrophysical characteristics of three stratigraphically asynchronous beachrocks (A, B, and C) along the Red Sea coast at Al-Shoaiba area, Saudi Arabia, to identify the compositional, depositional, and diagenetic controls on beachrock formation and their petrophysical properties. The beachrocks at the three locations consist basically of calcareous skeletal remains of different types and grain size reflecting the composition of adjacent beach sediments and the depositional conditions. They were cemented by aragonite and high-Mg calcite (HMC) in intertidal zone. The cement exhibits three major fabrics: (1) micritic coatings, (2) isopachous to asymmetric aragonite rim, and (3) cryptocrystalline pore-fillings HMC. In addition, some intergranular and intragranular pores were partially filled with infiltrated silt-sized carbonate and siliciclastic sediments. The cementation was accomplished by the combination of inorganic and organic processes, and the former was dominant through evaporation of pore-filling seawater under hot and dry climatic conditions. Cementation in the present beachrocks is selective; carbonate grains are cemented, whereas siliciclastic grains are cement free. The cement nucleation on carbonate grains was easier than on siliciclastic grains which do not provide good "seed crystals" for carbonate cement growth. The petrophysical measurements are in agreement with petrographic studies. The degree of cementation is the major control on petrophysical characteristics where the lowest and highest porosity and permeability values were obtained from the least cemented beachrocks of location A and the highest cemented beachrocks of location B, respectively. The thickness of cement seems to be controlled by cement precipitation rate, grain size, and size and shape of pore spaces. The coarse sediments of beachrocks at location B were deposited under higher depositional energy than those at locations A and C, and therefore, their primary pore spaces were large enough to be filled with seawaters. Under hot and dry climate, cement precipitation increases leading to partial to complete occlusion of pore spaces. 相似文献
12.
STEPHEN T. SOLOMON 《Sedimentology》1989,36(3):399-418
Dark mottles are a prominent and widespread feature of the regressive, cyclic, shallow marine limestones which form the late Asbian succession in many parts of Britain. The colour difference which defines mottles in outcrop is caused by distinct but often subtle petrographic differences in the limestone fabric. Specifically, mottles contain a light brown coloured opaque inclusion-rich calcite spar with characteristic dull brown luminescence; ‘mottle spar’. Outside mottle margins this calcite spar is absent, with clear inequant blocky cements forming the pore filling phase. ‘Mottle spar’ comprises a fabric of irregular crystals predominantly 5–40 μm in diameter, with more regular crystals up to 100 μm diameter often occurring in intraparticle and large interparticle pores. Under cathodoluminescence, ‘mottle spar’ displays crystal morphologies and growth patterns which indicate that both localized neomorphism and patchy cementation contributed to mottle formation. Cathodoluminescence cement stratigraphy shows that ‘mottle spar’ pre-dates all other major pore filling cements in the local Asbian succession, but post-dates marine micritization. ‘Mottle spar’ sharply defines the moulds of former aragonitic allochems which are now filled by the later clear, inequant spar cements. This shows that aragonite dissolution occurred after the formation of ‘mottle spar’. Mottles in calcretes contain unaltered allochems which have been protected from the effects of subaerial micritization by ‘mottle spar’, although mottles are often affected by subaerial brecciation. This evidence shows that mottles formed during early diagenesis; after marine micritization, but before dissolution of aragonite, subaerial exposure and meteoritic phreatic cementation. Mottles represented lithified patches of very low porosity which are interpreted to have formed in the marine/freshwater mixing zone, during the repeated phases of regression and emergence in the late Asbian. 相似文献
13.
The Late Jurassic-early Senonian Cehennemdere Formation extending in an E-W direction in a wide area at the south of the Bolkar Mountains (Central Taurides, Turkey) is composed of platform carbonates. The formation was deposited in an environment that was being transformed from a shallow carbonate platform to an open shelf and a continental slope, and was buried until late Paleocene uplift. The formation, with a thickness of about 360 m, was chiefly developed as textures consisting of mudstone and wackestone and has been commonly dolomitized. Based on petrographic and geochemical properties, four types of replacement dolomites and two types of dolomite cements were distinguished. Replacement dolomite (RD), which is cut by low-amplitude stylolites developed as (1) fine crystalline planar-s dolomite (RD1); (2) medium crystalline planar-s dolomite (RD2); (3) medium-coarse crystalline planar-e dolomite (RD3) and; (4) coarse crystalline planar-s (e) dolomite (RD4). Two types of dolomite cements (CD) observed in low abundance and overlie low-amplitude stylolites: (1) coarse crystalline dolomite cement (CD1) filling dissolution voids and fractures in RD1 dolomites, and; (2) rim dolomite cement (CD2) that commonly develops on the space-facing surfaces of RD4 dolomite. Replacement dolomites are non-stoichiometric (Ca54–59Mg41–46), have similar geochemical properties, and are generally dull red/non luminescent in appearance. Replacement dolomite is represented by δ18O values from −4.5 to −0.5‰ VPDB, δ13C values of −0.7 to 2.7‰ VPDB, and 87Sr/86Sr ratios ranging from 0.707178 to 0.707692. Petrographic and geochemical data indicate that replacement dolomite (particularly RD2, RD3, and RD4 dolomite) was formed at shallow-intermediate burial depths during the Late Jurassic-Early Cretaceous, from seawater and/or from slightly modified seawater. The replacement dolomite (RD) was then recrystallized at increased burial depths and temperatures. Dolomite cements are similar to replacement dolomites in that they are non-stoichiometric (Ca55Mg45) and have similar trace element compositions. CD1 dolomite, which cuts low-amplitude stylolites, was formed during intermediate to deep burial following stylolite development. CD2 dolomite was precipitated in intercrystal pores in association with RD4 dolomite. Remaining pore space was filled with bitumen. 相似文献
14.
Thomas Mann Andr Wizemann Marleen Stuhr Yannis Kappelmann Alexander Janßen Jamaluddin Jompa Hildegard Westphal 《Sedimentology》2022,69(1):282-300
Early-diagenetic cementation of tropical carbonates results from the combination of numerous physico-chemical and biological processes. In the marine phreatic environment it represents an essential mechanism for the development and stabilization of carbonate platforms. However, diagenetic cements that developed early in the marine phreatic environment are likely to become obliterated during later stages of meteoric or burial diagenesis. When lithified sediment samples are studied, this complicates the recognition of processes involved in early cementation, and their geological implications. In this contribution, a petrographic microfacies analysis of Holocene Halimeda segments collected on a coral island in the Spermonde Archipelago, Indonesia, is presented. Through electron microscopical analyses of polished samples, this study shows that segments are characterized by intragranular cementation of fibrous aragonite, equant High-Mg calcite (3.9 to 7.2 Mol% Mg), bladed Low-Mg calcite (0.4 to 1.0 Mol% Mg) and mini-micritic Low-Mg calcite (3.2 to 3.3 Mol% Mg). The co-existence and consecutive development of fibrous aragonite and equant High-Mg calcite results initially from the flow of oversaturated seawater along the aragonite template of the Halimeda skeleton, followed by an adjustment of cement mineralogy towards High-Mg calcite as a result of reduced permeability and fluid flow rates in the pores. Growth of bladed Low-Mg calcite cements on top of etched substrates of equant High-Mg calcite is explained by shifts in pore water pH and alkalinity through microbial sulphate reduction. Microbial activity appears to be the main trigger for the precipitation of mini-micritic Low-Mg calcite as well, based on the presumable detection of an extracellular polymeric matrix during an early stage of mini-micrite Low-Mg calcite cement precipitation. Radiocarbon analyses of five Halimeda segments furthermore indicate that virtually complete intragranular cementation in the marine phreatic environment with thermodynamically/kinetically controlled aragonite and High-Mg calcite takes place in about 100 years. Collectively, this study shows that early-diagenetic cements are highly diverse and provides new quantitative constraints on the rate of diagenetic cementation in tropical carbonate factories. 相似文献
15.
Pleistocene fluctuations of sea level have left marine and aeolian limestones intercalated with glacial red soils on the Bermuda Carbonate Platform (Atlantic, 64°50W, 32°20N). Successive eustatic highstands of similar amplitude drowned the tectonically stable platform and piled up similar sets of sediments. Up to three Pleistocene beaches are stacked in shorelines sections. Post-depositional diagenetic histories of these beaches can be linked to repeated changes in sea level and pore waters.This paper presents field evidence and petrographic results (microscope, X-ray, cathodoluminescence, SEMEDAX) for the diagenetic histories of two superimposed Pleistocene beaches in Whalebone Bay, Bermuda North Shore. The younger beach was deposited during isotopic stage 5e, about 120 ka ago. The age of the older beach may be isotopic stage 9 or older.Diagenesis drastically altered the older beach before the stage 5e transgression. Primary high-Mg calcite (HMC) and aragonite were no longer present. Marine skeletal grains were instead leached or recrystallized to low-Mg calcite (LMC). Primary and secondary pore space were largely reduced by LMC cement. Lines of needle relics reminiscent of marine aragonite cement occur as inclusions within syntaxial rim cements around echinoderm grains, indicating that a marine influence had at least once interrupted this period of freshwater alteration. Finally, before the rocks became buried by the sediments of the younger beach, a crust of marine, bladed HMC cement was precipitated throughout the pore space.The younger beach consists of skeletal grains that are, apart from the effects of non-selective dissolution, essentially unaltered. The sediments are only weakly lithified by cryptocrystalline LMC showing an alveolar texture, tangential fibres and other features characteristic of calichification. A younger post-depositional marine influence is not recorded.These results suggest that, under favourable conditions, diagenetic processes can document sea-level fluctuations. The recorded fluctuations, however, are difficult to assess because even major sea-level highstands may not produce a diagenetic imprint.
Correspondence to: R. Vollbrecht 相似文献
16.
Seven petrographic thin sections of lunar rock sample 14321, ‘Big Bertha’, have been examined. It is a complex rock incorporating diverse lithic and single crystal fragments and represents a sampling of the heterogeneous Fra Mauro formation, considered by the writers to be lithified debris from the Imbrium impact event. Electron probe microanalysis and microscopic study of textures reveal the assembly history of this breccia which in turn allows some interpretation of the nature of the pre-Imbrium crust and the effect of the Imbrium impact and the subsequent transportation to the Apollo 14 site. The present-day polymict breccia 14321 is composed of basaltic clasts originating from the fragmentation of a single or closely related set of lava cooling units, a set of fragmental clasts designated as microbreccia 3 (themselves polymict microbreccias), and a light colored matrix which formed rock 14321 by cementing the two major groups of clasts. The light colored matrix material is derived from the fragmentation and mutual abrasion of the basalt and microbreccia 3. On the basis of consistent textural relations two older sets of microbreccias have been identified within microbreccia 3. Microbreccia 1 clasts are well-rounded, relatively light colored, and noritic. They are always completely enclosed within microbreccia 3, most often forming the central cores of rounded accretionary lapilli structures which we have designated as microbreccia 2. Microbreccias 1, 2, 3, and macrobreccia 14321 represent a chronological series of fragmentation and lithification events. Each of these events involved some thermal and/or shock metamorphism as evidenced by mineralogical and textural criteria, and the chronological order of formation of the breccias also corresponds to a decreasing intensity of associated thermal effects. The petrology and mineralogy of 14321 are described in detail in this paper. A more general interpretation of the combined petrographic and chemical data is given in Duncanet al. (1975a). 相似文献
17.
AXEL MUNNECKE HILDEGARD WESTPHAL† JOHN J. G. REIJMER† CHRISTIAN SAMTLEBEN 《Sedimentology》1997,44(6):977-990
Comparison of ultrastructures in Pliocene periplatform carbonates from the Bahamas with Silurian limestones from Gotland (Sweden) reveals that despite the differences in primary sediment composition and age, they reflect a similar mechanism of lithification. In both sequences calcite microspar was formed as a primary cement at an early stage of marine burial diagenesis. Neither significant compression nor meteoric influence are necessary for the formation of calcite microspar. A model is proposed for the process of microsparitic cementation of fine-grained aragonite needle muds comprising four stages: (1) unconsolidated, aragonite-dominated carbonate mud; (2) precipitation of microspar that engulfs aragonite needles; (3) dissolution of aragonite, resulting in pitted surfaces of the microspar crystals; and (4) slight recrystallization. Our results contradict the widespread opinion that microspar necessarily is a product of secondary recrystallization of a previously lithified micrite. 相似文献
18.
Methane-derived high-Mg calcite submarine cement in Holocene nodules from the Fraser Delta, British Columbia, Canada 总被引：1，自引：0，他引：1
Carbonate nodules and slabs in late Holocene shelly terrigenous deposits of the modern Fraser River delta (～49°N) are formed close to the seafloor by precipitation from saline pore waters of mainly fibrous to bladed crystals of high-Mg (～ 10–20 mol% MgCO3) calcite cement as coalescing isopachous crusts on grains. Previous reports that the cement is low-Mg calcite are not supported by this study. Highly negative δ13C values of ? 7 to ? 59‰ for the cements indicate that the bulk of their carbonate carbon was derived from the microbiological degradation of organic matter in the deltaic deposits during shallow burial. In particular, the production of biogenic methane (CH4) by anaerobic bacterial fermentation, its upward migration, chemical or biological oxidation to CO2 and neutralization in the near-surface sediment, and diffusion to microenvironments relatively enriched in organic components, are a possible set of conditions influencing the process and sites of carbonate cementation. Methane-derived Mg-calcite appears also to be the major submarine cement in several other modern occurrences of lithified shallow-water terrigenous sands and muds at non-tropical latitudes. 相似文献
19.
Morphology and genesis of nodular chalks and hardgrounds in the Upper Cretaceous of southern England 总被引：4，自引：0，他引：4
The Upper Cretaceous chalks of southern England are a thick sequence of rhythmically bedded, bioturbated coccolith micrites, deposited in an outer shelf environment in water depths which varied between 50 and 200–300 m. The products of sea floor cementation are widely represented in the sequence, and a series of stages of progressive lithification can be recognized. These began with a pause in sedimentation and the formation of an omission surface, followed by (a) growth of discrete nodules below the sediment-water interface to form a nodular chalk, erosion of which produced intraformational conglomerates. (b) Further growth and fusion of nodules into continuous or semicontinuous layers: incipient hardgrounds. (c) Scour, which exposed the layer as a true hardground. At this stage, the exposed lithified chalk bottom was subject to boring and encrustation by a variety of organisms, whilst calcium carbonate was frequently replaced by glauconite and phosphate to produce superficial mineralized zones. In many cases, the processes of sedimentation, cementation, exposure and mineralization were repeated several times, producing composite hardgrounds built up of a series of layers of cemented and mineralized chalk, indicating a long and complex diagenetic history. Petrographic study of early cemented chalks indicates lithification was the result of the precipitation of small crystals on and between coccoliths and coccolith fragments. By analogy with known occurrences of early lithification in Recent deeper water carbonates, the cement is believed to have been either high magnesian calcite or aragonite, and more probably the former. The vast scale of operations involved in the cementation process precludes carbonate in expelled pore fluids as the source of cement, whilst quantities of aragonite incorporated in sediment are also inadequate. This, plus the observed association of horizons of early lithification with pauses in sedimentation associated with omission surfaces suggests seawater as a source of cementing materials. Stratigraphic studies indicate that processes of early lithification leading to hardground formation proceeded to completion in intervals to be measured in tens or hundreds of years. Regional studies suggest that early lithification characterized relatively shallow water phases associated with regional regression over the whole of the area, whilst in detail, the distribution of mature mineralized hardground complexes is strongly correlated with sedimentary thinning and condensation over small areas and the buried flanks of massifs. Early cementation in more basinal areas is typically in the form of nodular developments and incipient hardgrounds, whilst day contents in excess of a few percent appear to have inhibited early lithification. The striking rhythmicity of hardgrounds and nodular chalks is no more than a particular expression of the overall rhythmicity of chalk sequences. The stage of early lithification reached in any instance is dependent on sediment type, the time interval represented by the associated omission surface and the degree of associated scour and erosion (if any). Chalk hardgrounds differ from most others described in the geological literature in their widespread distribution (individual hardgrounds may cover up to 1500 km2), the presence of striking glauconite and phosphate replacements of lithified carbonate matrices, their frequently sparse epifaunas, and boring infaunas dominated by clionid sponges. These differences reflect the deeper water shelf setting of the chalk, and the more open marine, oceanic circulatory system, both strikingly different from the setting of other, shallower water hardgrounds. Litho- and biostratigraphic variation in the chalk sequences of the area studied are summarized in an appendix. 相似文献
20.
RUSSELL J. WHITE GLENN A. SPINELLI PETER S. MOZLEY NELIA W. DUNBAR 《Sedimentology》2011,58(5):1138-1154
A minor amount (ca 1 wt%) of amorphous silica cement sourced from volcanic glass inhibits consolidation of hemipelagic sediment approaching the Nankai Trough subduction zone throughout the Shikoku Basin. The distribution and nature of the cement were examined via secondary and backscattered electron imaging. The amorphous silica occurs as altered material in contact with volcanic glass, coating grains (including grain contacts) and filling pores. Based on chemical and petrographic evidence, the cement is probably sourced from volcanic glass; this is in contrast to a previous suggestion that this silica cement is sourced dominantly from biogenic silica. Amorphous silica sourced from disseminated volcanic glass shards has the ability to form a thin coating on clay‐dominated sediment throughout the Shikoku Basin. Measured amorphous silica content in hemipelagic sediments suggests that the cementing process is active throughout the Shikoku Basin (at sites separated by >500 km). The cementation process may occur in other locations where sediment containing hydrated disseminated volcanic glass is buried sufficiently for heat to facilitate alteration (i.e. Central America, Cascadia and the Gulf of Alaska). 相似文献