共查询到20条相似文献，搜索用时 764 毫秒
1.
An empirical model is developed to predict the dissolution rate of calcite in saline solutions that are saturated with respect to dissolved \(\hbox {CO}_2\) over a broad range of both subcritical and supercritical conditions. The focus is on determining the rate of calcite dissolution within a temperature range of 50–100 \(^\circ \hbox {C}\) and pressures up to 600 bar, relevant for \(\hbox {CO}_2\) sequestration in saline aquifers. A general reaction kinetic model is used that is based on the extension of the standard Arrhenius equation with an added, solubility-dependent, pH term to account for the saturated concentration of dissolved \(\hbox {CO}_2\). On the basis of this kinetic model, a new rate equation is obtained using multi-parameter, nonlinear regression of experimental data to determine the dissolution of calcite as a function of temperature, pressure and salinity. Different models for the activity coefficient of \(\hbox {CO}_2\) dissolved in saline solutions are accounted for. The new rate equation helps us obtain good agreement with experimental data, and it is applied to study the geochemically induced alterations of fracture geometry due to calcite dissolution. 相似文献
2.
Literature thermodynamic data on species and particles existing in the heterogeneous PdO-H2O system were checked for consistency, and the equilibrium constants for dissolution of palladium oxide and hydroxide in water and for Pd2+ (aq) hydrolysis were recommended. Δ f G 298.15 ° obtained in this work for Pd2+(aq) sharply differs (no less than by 6 kJ/mol) from values that are reported in fundamental thermodynamic reference books and based on experimentally measured palladium electrode potential at 25°C. Detailed examination of literature data on the thermodynamic properties of compounds in the Cl-Pd(aq) system is required to account for revealed inconsistency. 相似文献
3.
V. Yu. Lavrushin Yu. G. Israfailov B. G. Polyak B. G. Pokrovsky M. I. Bujakaite I. L. Kamensky 《Lithology and Mineral Resources》2018,53(1):53-75
It is shown that the gas and water phases of the thermal nitrogen–methane waters in the Talysh fold zone of the Lesser Caucasus mountain system contain helium and strontium with mantle isotope signatures (3Не/4Не from 200 × 10–8 to 401 × 10–8 and 87Sr/86Sr from 0.70490 to 0.70562). At the same time, clear signs of the mantle component in other gases (nitrogen, methane, and carbon dioxide) are absent. The δ15N value in nitrogen varies from +0.3 to +1.7‰, methane is mainly characterized by δ13C from–57.4 to–38.0‰, while δ13C(CО2) varies from–24.4 to–11.3‰. An increase of the CО2 content is accompanied by the decrease of δ13C in CО2, against the background of increasing SO4 content in the salt composition of waters. This indicates a microbial nature of CO2 in the studied gases. Thus, the presence of mantle helium and strontium in the thermal waters is likely related to their leaching from the Pleogene–Neogene host volcanic rocks. The studies of the oxygen and hydrogen isotope composition in water revealed quite different mechanisms for the formation of cold and thermal waters of the region. The cold waters are mainly fed by local infiltration, whereas the feeding of thermal nitrogen–methane waters is strongly provided by transit atmogenic waters (>50%), which are formed in the mountain ranges at altitudes no less than 1600 m and spaced at 20–40 km or more from the thermal discharge sites. 相似文献
4.
《Geochimica et cosmochimica acta》1999,63(19-20):3077-3085
The effect of temperature on the adsorption of H+ onto corundum was investigated experimentally by conducting potentiometric titrations at 25, 30, 40, 50, 60 and 70°C. These titrations were used to determine apparent acidity constants, given by the product of an intrinsic adsorption constant and a coulombic term (Kiapp = Kiinte(−ΔZFΨ/RT)) at the above temperatures.First and second intrinsic acidity constants were determined using a constant capacitance model (CCM). These constants and the point of zero charge change linearly with inverse temperature. These data were used to determine thermodynamic constants for the proton adsorption reactions.In the coulombic term, only the capacitance and the surface charge change with temperature and both were determined with the titration data at the various temperatures. Results show that the change in capacitance can be predicted with changes in the dielectric constant of water with increasing temperature. At a given pH, changes in the surface charge with temperature can, in turn, be predicted with a linear regression.With the above model, apparent acidity constants of corundum (including the chemical and electrostatic interactions) can be predicted for any temperatures between 25 and 70°C and possibly higher. These apparent constants change over several orders of magnitude in this temperature range (mainly due to a change in the coulombic term) and small temperature changes could have a strong influence on the stability of surface complexes. 相似文献
5.
6.
We present the results of twenty-year observations of a complete sample of 68 flat-spectrum radio sources with flux densities S 3.9 GHz > 200 mJy carried out at centimeter wavelengths with the RATAN-600 radio telescope. Since 1995, we have observed simultaneously at six frequencies between 0.97 and 21.7 GHz. Of the 56 sources identified with optical objects, 41 are quasars with redshifts between 0.293 and 3.263. Based on our analysis of the spectral shapes, we divide the sources into four classes. Changes of spectral class for individual sources are fairly rare. Based on the light curves and spectra, in most cases, a flare’s evolution is in accordance with a model in which the variations result from the evolution of a shock in the radio jet. The main result of our study is that there is no redshift dependence for the true linear sizes of the radiating regions, the variability indices derived for all 20 years of data or for individual flares, or the peak frequencies of the spectra of the compact radio emission. We suggest that this testifies to an absence of cosmological evolution of the sample quasars, at least to z ≈ 3. 相似文献
7.
Dhammika A. Tantrigoda M. M. P. M. Fernando 《Journal of the Geological Society of India》2013,82(4):430-434
Satellite free air gravity anomalies over the Indian ocean region 79°E–86°E, 2°S–8°S were obtained from the website http://topex.ucsd.edu and a contour map was compiled. Five profiles of the anomaly have been interpreted in terms of two-dimensional structures in the ocean. Thickness of sediments lying on the oceanic crust determined from the interpretation of gravity profiles were used to compile an isopach map of the region 79°E–86°E, 2°S–8°S. This map in combination with one of the isopach maps compiled by previous workers, provides information regarding the thickness of sediments up to 6° S. According to this map sediment thickness varies from ～600 m over the middle part of the region to ～800 m further south, indicating that thinning of sediments in the middle part of the region is only localized. Information provided by this gravity study may be useful in planning detailed seismological studies to delimit the outer edge of the continental margin of Sri Lanka, defined according to the United Nations Convention of the Law of the Sea (UNCLOS). 相似文献
8.
A. G. Sokol A. A. Tomilenko T. A. Bul’bak G. A. Palyanova Yu. N. Palyanov N. V. Sobolev 《Doklady Earth Sciences》2017,474(2):680-683
The composition of a reduced C–O–H fluid was studied by the method of chromatography–mass spectrometry under the conditions of 6.3 GPa, 1300–1400°C, and fO2 typical of the base of the subcratonic lithosphere. Fluids containing water (4.4–96.3 rel. %), methane (37.6–0.06 rel. %), and variable concentrations of ethane, propane, and butane were obtained in experiments. With increasing fO2, the proportion of the CH4/C2H6 peak areas on chromatograms first increases and then decreases, whereas the CH4/C3H8 and CH4/C4H10 ratios continually decrease. The new data show that ethane and heavier HCs may be more stable to oxidation, than previously thought. Therefore, when reduced fluids pass the “redox-front,” carbon is not completely released from the fluid and may be involved in diamond formation. 相似文献
9.
Yukihiro Matsuhisa Julian R. Goldsmith Robert N. Clayton 《Geochimica et cosmochimica acta》1978,42(2):173-182
Oxygen isotopic exchange between quartz and water, using a novel technique in which both 18O/16O and 17O/16O fractionations were measured, yielded an equilibrium fractionation Δ18 = 9.0 at 250°C and 15 kbar. The reaction proceeds predominantly by solution of fine grains and growth of larger grains. Exchange by solid-state diffusion is immeasurably slow at this temperature. Under the same experimental conditions, cristobalite behaves quite differently, becoming transformed to sub-micron quartz crystals in a few minutes. The phase transformation is accompanied by a kinetic isotope effect yielding quartz in isotopic disequilibrium with water. It is possible that such disequilibrium products are also formed in other experiments involving phase transitions or mineral syntheses. 相似文献
10.
I. F. Gablina I. G. Dobretsova E. V. Narkevskii A. N. Gustaitis T. A. Sadchikova N. V. Gor’kova A. T. Savichev A. D. Lyutkevich O. M. Dara 《Lithology and Mineral Resources》2017,52(5):335-357
Based on materials obtained in Cruises 33 and 34 of the R/V Professor Logachev, the paper addresses formation conditions, morphology, structures, mineral composition of the present-day oceanic sulfide ores, and their relationships with the host (biogenic carbonate) bottom sediments in the 19°–20° N MAR (Zenith-Victoria and Petersburg hydrothermal fields) region. The grain size distribution, mineral composition of the carbonate (background) and ore-hosting sediments, as well as physicochemical parameters of their interstitial waters, are examined. The results suggest a significant role of hydrothermal-metasomatic processes in the formation of ores and ore-bearing sediments. A model is proposed for the formation of sulfide mineralization in oceanic sediments at the geochemical barrier in the zone of their interaction with the acid hydrothermal (diffuse-type) ore-bearing solutions delivered from rocks of the ocean floor. 相似文献
11.
Three major diastrophic cycles, defined by their structural style and their spatial distribution are recognized in the Andean Basement of this region. The oldest structures are related to the Panamerican Orogeny (500 to 700 m. a.) which produced in the Central Craton multiply deformed complexes of schists, gneisses and granites, that are covered discordantly by unmetamorphosed Cambrian and Ordovician beds. West of the Central Craton Ordovician sedimentary beds are folded with a simple structural style and intruded by granites. Both the sedimentry beds and the granites are covered discordantly by undeformed Devonian sequences. The folding of the Ordovician is attributed to the ocloyic phase of the Caledonian movements. West of the ocloyic belt is another foldbelt consisting of strongly folded Devonian beds attributed to the chanic phase (hercynian). The chanic belt is intruded by carboniferous and permian granites and covered discordantly by Carboniferous and Permian sequences.The features observed in the eastern slope of the Andes suggest that the Paleozoic foldbelts are intracratonic. Whether there are accreted terrains in the Pacific Coastal Cordillera is matter of controversy.
Zusammenfassung Im Andenbasement dieser Region lassen sich drei diastrophische Hauptzyklen, die durch ihren strukturellen Baustil und ihre geographische Verbreitung definiert sind, unterscheiden. Die ältesten Strukturen sind verknüpft mit den Bewegungen der Panamerikanischen Orogenese (500–700 m. a.), welche im Zentralkraton einen polydeformierten Komplex von Schiefern, Gneissen und Graniten erzeugte. Diesem lagern diskordant kambrische und ordovizische Sequenzen ohne Metamorphose und präandiner Deformation auf. Nach Westen zu gibt es einen Gürtel stark deformierter ordovizischer Sedimente, die einen einfacheren Baustil als das präkambrische Basement aufweisen, und diskordant von undeformierten devonischen Abfolgen bedeckt sind. Die Faltung des Ordoviziums wird der Ocloyischen Phase der Kaledonischen Bewegung zugerechnet.Weiter westwärts tritt ein jüngerer Faltengürtel aus devonischen Sedimenten auf, die während der Chanischen Phase der Herzynischen Bewegung intensiv deformiert wurden, und von karbonischen und permischen Sequenzen diskordant überlagert sind.Der Ocloyische Gürtel ist von postordovizischen Graniten die von devonischen Schichten überlagert sind, und der Chanische Gürtel von karbonischen und permischen Graniten intrudiert. Im präkambrischen Basement des Zentralkratons treten einerseits präkambrische Granite auf, denen diskordant kambrische Schichten auflagern. Andererseits findet man Granite mit paläozoischen Isotopenaltern, letztere aber in Gebieten, wo wegen des Fehlens von Deckschichten eine stratigraphische Kontrolle unmöglich ist.Die gemachten Beobachtungen scheinen darauf hinzudeuten, daß die paläozoischen Faltengürtel intrakratonisch sind. Ob es allochtone »terrains« in der pazifischen Küstenkordillere gibt, ist Gegenstand der Kontroverse.
Resumen En el basamento de los Andes de esta región se distinguen tres ciclos diastróficos mayores definidos por sus estilos estructurales y su distributión espacial. Las estructuras mas antiguas responden a movimientos que culminaron con la Orogénesis Panamericana (500–700 m. a.) que produjo en el Cratógeno Central un complejo de esquistos, gneises y granitos polideformados, al que se le superponen discordantemente secuencias cámbricas y ordovicicas sin metamorfismo ni déformatión preandina. Hacia el oeste hay un cinturón de sedimentos ordovícicos intensamente deformados con un estilo de plegamiento mas simple que el del basamento precámbrico y cubierto discordantemente por secuencias marinas devónicas sin deformatión. Los movimientos responsables de este plegamiento se atribuyen a la fase oclóyica de los movimientos caledónicos. Más hacia el oeste se manifiesta una franja de deformatión mas jóven atribuída a la Fase chánica de los movimientos hercínicos, en ella se encuentran sedimentitas devónicas intensamente plegadas cubiertas discordantemente por secuencias carbónicas y pérmicas.El cinturón oclóyico esta acompanãdo por granitos postordovícicos cubiertos por Devónico. Asimismo, el cinturón chánico (hercínico) esta intruido por granitos probablemente carbónicos. Con respecta a los granitos intruidos en el zócalo antiguo, hay algunos indudablemente precámbricos por estar cubiertos discordantemente por secuencias cámbricas sin metamorfismo, además hay granitos de edad dudosa que han dado valores isotópicos paleozoicos pero en lugares donde el control estratigráfico no es posible por ausencia de la cobertura paleozoica. De acuerdo a los hechos observados en la ladera oriental de los Andes surge la idea de que los cinturones de plegamiento paleozoicos son intracratónicos, aun es materia de controversia si en la Cordillera de la Costa junto al Pacifico hay terrenos alóctonos acrecionados.
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12.
The results of 0.97, 2.3, 3.9, 7.7, 11.1, and 21.7 GHz observations of a complete sample of radio sources obtained on the RATAN-600 radio telescope are presented. The sample is comprised of sources from the 4.85-GHz MGB survey, and contains all sources at declinations 10°–12°30′ (J2000) with Galactic latitudes |b|>15° and flux densities S4.85>200 mJy. Optical identifications have been obtained for about 86% of the radio sources with flat spectra and 59% of those with steep spectra. The spectra of the flat-spectrum sources have been decomposed into extended and compact components. 相似文献
13.
David Völker Jacob Geersen Eduardo Contreras-Reyes Javier Sellanes Silvio Pantoja Wolfgang Rabbel Martin Thorwart Christian Reichert Martin Block Wilhelm Reimer Weinrebe 《International Journal of Earth Sciences》2014,103(7):1765-1787
The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile. 相似文献
14.
The paper reports the results of ten-year centimeter-wavelength observations with the RATAN-600 radio telescope of a complete sample of 83 flat-spectrum sources from the GB6 catalog of the MGB Survey, with S 4.85 > 200 mJy at declinations 10°?C12°30??. Starting in 2000, the observations were conducted simultaneously at six frequencies in the range 0.97?C21.7 GHz. Seventy-six sources (including 54 quasars) have been identified with optical objects, which have redshifts in the range z = 0.331?C3.601. Analysis of light curves and spectra at different activity phases has shown that, in most cases, the dynamics of the development of flares is consistent with a model in which the variability results from the evolution of a shock in a radio jet. A relationship between the time scales for the rise and fall of the flares has been found. There is no redshift dependence of the true linear dimensions of the radiating regions and the variability indices obtained over ten years. These facts can be interpreted as an absence of cosmological evolution of quasars at least up to z ?? 3. 相似文献
15.
S. A. Silantyev L. V. Danyushevsky A. A. Plechova L. Dosso B. A. Bazylev V. E. Bel’tenev 《Petrology》2008,16(1):36-62
Data presented in the paper suggest significant differences between the thermodynamic conditions under which magmatic complexes were formed in MAR at 29°–34° N and 12°–18° N. The melts occurring at 29°–34° N were derived by the melting of a mantle source with a homogeneous distribution of volatile components and arrived at the surface without significant fractionation, likely, due to their rapid ascent. The MAR segments between 12° and 18° N combine contrasting geodynamic environments of magmatism, which predetermined the development of a large plume region with the widespread mixing of the melting products of geochemically distinct mantle sources. At the same time, this region is characterized by conditions favorable for the origin of localized zones of anomalous plume magmatism. These sporadic magmatic sources were spatially restricted to MAR fragments with the Hess crust, whose compositional and mechanical properties were, perhaps, favorable for the focusing and localization of plume magmatism. The plume source between 12° and 18°N beneath MAR may be geochemically heterogeneous. 相似文献
16.
The Pampas plain (30°–41°S) has historically been considered as a sector that evolved independently from the adjacent Andean ranges. Nevertheless, the study of the Pampas showed that it is reasonable to expect an important influence from the Andes into the extraandean area. The Pampas plain can be divided into two sectors: the northern portion, adjacent to the Pampean Ranges, has been studied by Davila (2005, 2007, 2010). The southern sector (34°–41°S) is the objective of the present work. The study of this area allowed to characterize two separate foreland basins: the Southern Pampa basin and the Northern Patagonian basin. The infill is composed of Late Miocene and Pliocene units, interpreted as distal synorogenic sequences associated with the late Cenozoic Andean uplift at this latitudinal range. These foreland basins have been defined based on facies changes, distinct depositional styles, along with the analysis of sedimentary and isopach maps. The basins geometries are proposed following De Celles and Gilles (1996) taking into account the infill geometry, distribution and grain size. In both cases, these depocenters are located remarkably far away from the Andean tectonics loads. Therefore they cannot be explained with short-wave subsidence patterns. Elastic models explain the tectonic subsidence in the proximal depocenters but fail to replicate the complete distal basins. These characteristics show that dynamic subsidence is controlling the subsidence in the Southern Pampas and Northern Patagonian basins. 相似文献
17.
《Geochimica et cosmochimica acta》2001,65(16):2691-2708
The concentration and transport of metals in hydrothermal solutions depend on how metals ions combine with ligands to form complexes, and experimental methods are necessary to identify the important complexes. UV-Vis-NIR spectrophotometry was used to study the formation of Cu(II)-chloride complexes in LiCl brines up to very high chlorinities (18 m LiCl), at temperatures between 25°C and 90°C. The number of Cu(II)-chloride complexes necessary to account for the variation in spectra with varying chloride molality at each temperature was estimated using principal component analysis. The molar absorptivity coefficients and concentrations of each complex were then determined using a “model-free” analysis, which does not require any assumption about the chemistry of the system, other than the number of absorbing species present. Subsequently, the results from the “model-free” analysis were integrated with independent experimental evidence to develop a thermodynamic speciation model, where the logarithms of the equilibrium constants for Cu(II)-chloride formation reactions were fitted to the data using a non-linear least-squares approach. Maps of the residual function were used to estimate uncertainties in the fitted equilibrium constants.The results of this study are similar to published properties of distorted octahedral [CuCl(OH2)5]+ and [CuCl2(OH2)4]0 at all temperatures, but diverge for [CuCl3(OH2)3]− and distorted tetrahedral [CuCl4]2−. Moreover, the data suggest the presence of [CuCl5]3−, probably with D3h point group, at very high salt concentration. This study demonstrates that it is possible to determine apparent thermodynamic equilibrium constants for the formation of complexes of trace amount of metals in highly concentrated brines, such as those associated with many ore deposits. The results are dependent on the choice of activity coefficients for charged and neutral aqueous complexes, but this influence is relatively small compared with the experimental uncertainty. This study shows that Cu2+ chloro-complexes, predominantly [CuCl2(OH2)4]0 and [CuCl4]2−, will play a dominant role in nature where free oxygen is available (near-surface), and where chloride activities are very high (evaporitic basins; hypersaline soils). 相似文献
18.
《Geochimica et cosmochimica acta》1999,63(19-20):3247-3259
The rate of Si release from dissolving bytownite feldspar in abiotic batch reactors increased as temperatures increased from 5° to 35°C. Metabolically inert subsurface bacteria (bacteria in solution with no organic substrate) had no apparent effect on dissolution rates over this temperature range. When glucose was added to the microbial cultures, the bacteria responded by producing gluconic acid, which catalyzed the dissolution reaction by both proton- and ligand-promoted mechanisms. The metabolic production, excretion, and consumption of gluconic acid in the course of glucose oxidation, and therefore, the degree of microbial enhancement of mineral dissolution, depend on temperature. There was little accumulation of gluconic acid and therefore, no significant enhancement of mineral dissolution rates at 35°C compared to the abiotic controls. At 20°C, gluconate accumulated in the experimental solutions only at the beginning of the experiment and led to a twofold increase in dissolved Si release compared to the controls, primarily by the ligand-promoted dissolution mechanism. There was significant accumulation of gluconic acid in the 5°C experiment, which is reflected in a significant reduction in pH, leading to 20-fold increase in Si release, primarily attributable to the proton-promoted dissolution mechanism. These results indicate that bacteria and microbial metabolism can affect mineral dissolution rates in organic-rich, nutrient-poor environments; the impact of microbial metabolism on aluminum silicate dissolution rates may be greater at lower rather than at higher temperatures due to the metabolic accumulation of dissolution-enhancing protons and ligands in solution. 相似文献
19.
A. K. Sharma M. V. Rokade R. Kondala Rao S. Gurubaran P. T. Patil 《Journal of Earth System Science》2010,119(4):461-470
The main aim of the paper is to describe mesosphere and lower thermosphere (MLT) wind field observed between June 2000 and
May 2002 by medium frequency (MF) radars at two locations near the equatorial region and at tropical latitude. We have presented
and compared observations of mean horizontal winds in the mesosphere and lower thermosphere (MLT) region over Kolhapur (16.8°N,
74.2°E) and Tirunelveli (8.7°N, 77.8°E). Our analysis reveals annual oscillation in the zonal wind and semi-annual oscillation
in the meridional wind over Kolhapur. On the other hand, results over Tirunelveli reveal semi-annual oscillation (SAO) in
the zonal wind and annual oscillation in the meridional wind. Also we have observed enhanced magnitude of wind speed in spring
equinox period of 2002 exhibiting the signatures of the quasi-biennial oscillation (QBO) over Tirunelveli. 相似文献
20.
V. G. Thomas S. Z. Smirnov O. A. Kozmenko V. A. Drebushchak V. S. Kamenetsky 《Petrology》2014,22(3):293-309
In order to determine the mechanisms of formation and properties of natural hydrosilicate liquids (HSLs), which are formed during the transition from magmatic to hydrothermal mineral formation in granitic pegmatites and rare-metal granites, the formation of HSLs was experimentally studied in the Na2O-SiO2-H2O, Na2O-Al2O3-SiO2-H2O, and Na2O-K2O-Li2O-Al2O3-SiO2-H2O systems at 600°C and 1.5 kbar. It was shown that the sequential extension of composition does not suppress HSL formation in the systems and expands the stability field of this phase. However, HSLs formed in extended chemical systems have different structure and properties: the addition of alumina induces some compression of the structure of the silicate framework of HSLs, which results in a decrease in water content in this phase and probably hinders the reversibility of its dehydration. It was demonstrated that HSL can be formed by the coagulation of silica present in a silica-oversaturated alkaline aqueous fluid. It was supposed that the HSL formed during this process has a finely dispersed structure. It was argued that anomalous enrichment in some elements in natural HSLs can be due to their sorption by the extensively developed surface of HSL at the moment of its formation. 相似文献