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1.
This paper presents a seismic hazard evaluation and develops an earthquake catalogue for the Constantine region over the period from 1357 to 2014. The study contributes to the improvement of seismic risk management by evaluating the seismic hazards in Northeast Algeria. A regional seismicity analysis was conducted based on reliable earthquake data obtained from various agencies (CRAAG, IGN, USGS and ISC). All magnitudes (M l, m b) and intensities (I 0, I MM, I MSK and I EMS) were converted to M s magnitudes using the appropriate relationships. Earthquake hazard maps were created for the Constantine region. These maps were estimated in terms of spectral acceleration (SA) at periods of 0.1, 0.2, 0.5, 0.7, 0.9, 1.0, 1.5 and 2.0 s. Five seismogenic zones are proposed. This new method differs from the conventional method because it incorporates earthquake magnitude uncertainty and mixed datasets containing large historical events and recent data. The method can be used to estimate the b value of the Gutenberg-Richter relationship, annual activity rate λ(M) of an event and maximum possible magnitude M max using incomplete and heterogeneous data files. In addition, an earthquake is considered a Poisson with an annual activity rate λ and with a doubly truncated exponential earthquake magnitude distribution. Map of seismic hazard and an earthquake catalogue, graphs and maps were created using geographic information systems (GIS), the Z-map code version 6 and Crisis software 2012.  相似文献   

2.
The high-pressure behavior of a vanadinite (Pb10(VO4)6Cl2, a = b = 10.3254(5), c = 7.3450(4) Å, space group P63/m), a natural microporous mineral, has been investigated using in-situ HP-synchrotron X-ray powder diffraction up to 7.67 GPa with a diamond anvil cell under hydrostatic conditions. No phase transition has been observed within the pressure range investigated. Axial and volume isothermal Equations of State (EoS) of vanadinite were determined. Fitting the P–V data with a third-order Birch-Murnaghan (BM) EoS, using the data weighted by the uncertainties in P and V, we obtained: V 0 = 681(1) Å3, K 0 = 41(5) GPa, and K′ = 12.5(2.5). The evolution of the lattice constants with P shows a strong anisotropic compression pattern. The axial bulk moduli were calculated with a third-order “linearized” BM-EoS. The EoS parameters are: a 0 = 10.3302(2) Å, K 0(a) = 35(2) GPa and K′(a) = 10(1) for the a-axis; c 0 = 7.3520(3) Å, K 0(c) = 98(4) GPa, and K′(c) = 9(2) for the c-axis (K 0(a):K 0(c) = 1:2.80). Axial and volume Eulerian-finite strain (fe) at different normalized stress (Fe) were calculated. The weighted linear regression through the data points yields the following intercept values: Fe a (0) = 35(2) GPa for the a-axis, Fe c (0) = 98(4) GPa for the c-axis and Fe V (0) = 45(2) GPa for the unit-cell volume. The slope of the regression lines gives rise to K′ values of 10(1) for the a-axis, 9(2) for the c-axis and 11(1) for the unit cell-volume. A comparison between the HP-elastic response of vanadinite and the iso-structural apatite is carried out. The possible reasons of the elastic anisotropy are discussed.  相似文献   

3.
The earthquake hazard parameters and earthquake occurrence probabilities are computed for the different regions of the North Anatolia Fault Zone (NAFZ) using Bayesian method. A homogenous earthquake catalog for M S magnitude which is equal or larger than 4.0 is used for a time period between 1900 and 2015. Only two historical earthquakes (1766, M S = 7. 3 and 1897, M S = 7. 0) are included in Region 2 (Marmara Region) where a large earthquake is expected in the near future since no large earthquake has been observed for the instrumental period. In order to evaluate earthquake hazard parameters for next 5, 10, 20, 50, 100 years, M max (maximum regional magnitude), β value, λ (seismic activity or density) are computed for the different regions of NAFZ. The computed M max values are changed between 7.11 and 7.89. While the highest magnitude value is calculated in the Region 9 related to Tokat-Erzincan, the lowest value in the Region 10 including the eastern of Erzincan. The “quantiles” of “apparent” and “true” magnitudes of future time intervals of 5, 10, 20, 50, and 100 years are calculated for confidence limits of probability levels of 50, 70 and 90 % of the 10 different seismic source regions. The region between Tokat and Erzincan has earthquake hazard level according to the determined parameters. In this region the expected maximum earthquake size is 7.8 with 90 % occurrence probability in next 100 years. While the regional M max value of Marmara Region is computed as 7.61, expected maximum earthquake size is 7.37 with 90 % occurrence probability in next 100 years.  相似文献   

4.
The crystal structure of a new compound [Mg(H2O)4(SeO4)]2(H2O) (monoclinic, P2 1/a, a = 7.2549(12), b = 20.059(5), c = 10.3934(17) Å, β = 101.989(13), V = 1479.5(5) Å3) has been solved by direct methods and refined to R 1 = 0.059 for 2577 observed reflections with |F hkl | ≥ 4σ|F hkl |. The structure consists of [Mg(H2O)4(SeO4)]0 chains formed by alternating corner-sharing Mg octahedrons and (SeO4)2? tetrahedrons. O atoms of Mg octahedrons that are shared with selenate tetrahedrons are in a trans orientation. The heteropoly-hedral octahedral-tetrahedral chains are parallel to the c axis and undulate within the (010) plane. The adjacent chains are linked by hydrogen bonds involving H2O molecules not bound with M2+ cations.  相似文献   

5.
In this paper, we present a seismic hazard scenario for the Garhwal region of the north-western Himalayan range, in terms of the horizontal Peak Ground Acceleration. The scenario earthquake of moment magnitude M w 8.5 has a 10% exceedance probability over the next 50 years. These estimates, the first for the region, were calculated through a stepwise process based on:
  • An estimation of the Maximum Credible Earthquake from the seismicity of the region and Global Seismic Hazard Assessment Program considerations, and
  • four seismotectonic parameters abstracted from near field weak-motion data recorded at five stations installed in Chamoli District of the Garhwal region in the aftermath of the 1999 Chamoli earthquake. The latter include
  • The frequency dependent power law for the shear wave quality factor, Q S
  • the site amplification at each station using horizontal-to-vertical-spectral ratio and generalized inversion technique
  • source parameters of various events recorded by the array and application of the resulting relations between the scalar seismic moment M 0 (dyne-cm) and moment magnitude M w and the corner frequency, ? c (Hz) and moment magnitude M w to simulate spectral acceleration due to higher magnitude events corresponding to the estimated Maximum Credible Earthquake, and
  • regional and site specific local spectral attenuation relations at different geometrically central frequencies in the low, moderate and high frequency bands.
  相似文献   

6.
High pressure in situ synchrotron X-ray diffraction experiment of strontium orthophosphate Sr3(PO4)2 has been carried out to 20.0 GPa at room temperature using multianvil apparatus. Fitting a third-order Birch–Murnaghan equation of state to the P–V data yields a volume of V 0 = 498.0 ± 0.1 Å3, an isothermal bulk modulus of K T  = 89.5 ± 1.7 GPa, and first pressure derivative of K T ′ = 6.57 ± 0.34. If K T ′ is fixed at 4, K T is obtained as 104.4 ± 1.2 GPa. Analysis of axial compressible modulus shows that the a-axis (K a  = 79.6 ± 3.2 GPa) is more compressible than the c-axis (K c  = 116.4 ± 4.3 GPa). Based on the high pressure Raman spectroscopic results, the mode Grüneisen parameters are determined and the average mode Grüneisen parameter of PO4 vibrations of Sr3(PO4)2 is calculated to be 0.30(2).  相似文献   

7.
The crystal structure of the unstable mineral alumoklyuchevskite K3Cu3AlO2(SO4)4 [monoclinic, I2, a = 18.772(7), b = 4.967(2), c = 18.468(7) Å, β = 101.66(1)°, V = 1686(1) Å] was refined to R 1 = 0.131 for 2450 unique reflections with F ≥ 4σF hkl. The structure is based on oxocentered tetrahedrons (OAlCu 3 7+ ) linked into chains via edges. Each chain is surrounded by SO4 tetrahedrons forming a structural complex. Each complex is elongated along the b axis. This type of crystal structure was also found in other fumarole minerals of the Great Tolbachik Fissure Eruption (GTFE, Kamchatka Peninsula, Russia, 1975–1976), klyuchevskite, K3Cu3Fe3+O2(SO4)4; and piypite, K2Cu2O(SO4)2.  相似文献   

8.
We analyzed macroseismic data and considered the effect of extremely long range propagation of sensible shocks during the deep-focus earthquake in the Sea of Okhotsk on May 24, 2013 (Mw = 8.3). In order to explain this effect, we formulated and qualitatively solved the problem of superposition of P-waves over the radial mode 0S0 of the natural oscillations of the Earth during this earthquake. Our results confirmed the possibility of such an interpretation of the observed macroseismic effect and also allowed us to explain the fact of anomalously low decay of seismic disturbances with distance.  相似文献   

9.
A seismic hazard map of Kanpur city has been developed considering the region-specific seismotectonic parameters within a 500-km radius by deterministic and probabilistic approaches. The maximum probable earthquake magnitude (M max) for each seismic source has been estimated by considering the regional rupture characteristics method and has been compared with the maximum magnitude observed \(\left ({M_{\max }^{\text {obs}}}\right )\), \(M_{\max }^{\text {obs}} +0.5\) and Kijko method. The best suitable ground motion prediction equations (GMPE) were selected from 27 applicable GMPEs based on the ‘efficacy test’. Furthermore, different weight factors were assigned to different M max values and the selected GMPE to calculate the final hazard value. Peak ground acceleration and spectral acceleration at 0.2 and 1 s were estimated and mapped for worst-case scenario and 2 and 10% probability of exceedance for 50 years. Peak ground acceleration (PGA) showed a variation from 0.04 to 0.36 g for DSHA, from 0.02 to 0.32 g and 0.092 to 0.1525 g for 2 and 10% probability in 50 years, respectively. A normalised site-specific design spectrum has been developed considering three vulnerable sources based on deaggregation at the city center and the results are compared with the recent 2011 Sikkim and 2015 Nepal earthquakes, and the Indian seismic code IS 1893.  相似文献   

10.
Ab initio calculations of thermo-elastic properties of beryl (Al4Be6Si12O36) have been carried out at the hybrid HF/DFT level by using the B3LYP and WC1LYP Hamiltonians. Static geometries and vibrational frequencies were calculated at different values of the unit cell volume to get static pressure and mode-γ Grüneisen’s parameters. Zero point and thermal pressures were calculated by following a standard statistical-thermodynamics approach, within the limit of the quasi-harmonic approximation, and added to the static pressure at each volume, to get the total pressure (P) as a function of both temperature (T) and cell volume (V). The resulting P(V, T) curves were fitted by appropriate EoS’, to get bulk modulus (K 0) and its derivative (K′), at different temperatures. The calculation successfully reproduced the available experimental data concerning compressibility at room temperature (the WC1LYP Hamiltonian provided K 0 and K′ values of 180.2 Gpa and 4.0, respectively) and the low values observed for the thermal expansion coefficient. A zone-centre soft mode \( P6/mcc \to P\bar{1} \) phase transition was predicted to occur at a pressure of about 14 GPa; the reduction of the frequency of the soft vibrational mode, as the pressure is increased, and the similar behaviour of the majority of the low-frequency modes, provided an explanation of the thermal behaviour of the crystal, which is consistent with the RUM model (Rigid Unit Model; Dove et al. in Miner Mag 59:629–639, 1995), where the negative contribution to thermal expansion is ascribed to a geometric effect connected to the tilting of rigid polyhedra in framework silicates.  相似文献   

11.
Seismic hazard analysis of the northwest Himalayan belt was carried out by using extreme value theory (EVT). The rate of seismicity (a value) and recurrence intervals with the given earthquake magnitude (b value) was calculated from the observed data using Gutenberg–Richter Law. The statistical evaluation of 12,125 events from 1902 to 2017 shows the increasing trend in their inter-arrival times. The frequency–magnitude relation exhibits a linear downslope trend with negative slope of 0.8277 and positive intercept of 4.6977. The empirical results showed that the annual risk probability of high magnitude earthquake M?≥?7.7 in 50 years is 88% with recurrence period of 47 years, probability of M?≤?7.5 in 50 years is 97% with recurrence period of 27 years, and probability of M?≤?6.5 in 50 years is 100% with recurrence period of 4 years. Kashmir valley, located in the NW Himalaya, encompasses a peculiar tectonic and structural setup. The patterns of the present and historical seismicity records of the valley suggest a long-term strain accumulation along NNW and SSE extensions with the decline in the seismic gap, posing a potential threat of earthquakes in the future. The Kashmir valley is characterized by the typical lithological, tectono-geomorphic, geotechnical, hydrogeological and socioeconomic settings that augment the earthquake vulnerability associated with the seismicity of the region. The cumulative impact of the various influencing parameters therefore exacerbates the seismic hazard risk of the valley to future earthquake events.  相似文献   

12.
Zinclipscombite, a new mineral species, has been found together with apophyllite, quartz, barite, jarosite, plumbojarosite, turquoise, and calcite at the Silver Coin mine, Edna Mountains, Valmy, Humboldt County, Nevada, United States. The new mineral forms spheroidal, fibrous segregations; the thickness of the fibers, which extend along the c axis, reaches 20 μm, and the diameter of spherulites is up to 2.5 mm. The color is dark green to brown with a light green to beige streak and a vitreous luster. The mineral is translucent. The Mohs hardness is 5. Zinclipscombite is brittle; cleavage is not observed; fracture is uneven. The density is 3.65(4) g/cm3 measured by hydrostatic weighing and 3.727 g/cm3 calculated from X-ray powder data. The frequencies of absorption bands in the infrared spectrum of zinclipscombite are (cm?1; the frequencies of the strongest bands are underlined; sh, shoulder; w, weak band) 3535, 3330sh, 3260, 1625w, 1530w, 1068, 1047, 1022, 970sh, 768w, 684w, 609, 502, and 460. The Mössbauer spectrum of zinclipscombite contains only a doublet corresponding to Fe3+ with sixfold coordination and a quadrupole splitting of 0.562 mm/s; Fe2+ is absent. The mineral is optically uniaxial and positive, ω = 1.755(5), ? = 1.795(5). Zinclipscombite is pleochroic, from bright green to blue-green on X and light greenish brown on Z (X > Z). Chemical composition (electron microprobe, average of five point analyses, wt %): CaO 0.30, ZnO 15.90, Al2O3 4.77, Fe2O3 35.14, P2O5 33.86, As2O5 4.05, H2O (determined by the Penfield method) 4.94, total 98.96. The empirical formula calculated on the basis of (PO4,AsO4)2 is (Zn0.76Ca0.02)Σ0.78(Fe 1.72 3+ Al0.36)Σ2.08[(PO4)1.86(AsO4)0.14]Σ2.00(OH)1. 80 · 0.17H2O. The simplified formula is ZnFe 2 3+ (PO4)2(OH)2. Zinclipscombite is tetragonal, space group P43212 or P41212; a = 7.242(2) Å, c = 13.125(5) Å, V = 688.4(5) Å3, Z = 4. The strongest reflections in the X-ray powder diffraction pattern (d, (I, %) ((hkl)) are 4.79(80)(111), 3.32(100)(113), 3.21(60)(210), 2.602(45)(213), 2.299(40)(214), 2.049(40)(106), 1.663(45)(226), 1.605(50)(421, 108). Zinclipscombite is an analogue of lipscombite, Fe2+Fe 2 3+ (PO4)2(OH)2 (tetragonal), with Zn instead of Fe2+. The mineral is named for its chemical composition, the Zn-dominant analogue of lipscombite. The type material of zinclipscombite is deposited in the Mineralogical Collection of the Technische Universität Bergakademie Freiberg, Germany.  相似文献   

13.
A pyroxene with composition LiNiSi2O6 was synthesized at T = 1,473 K and P = 2.0 GPa; the cell parameters at T = 298 K are a = 9.4169(6) Å, b = 8.4465(7) Å, c = 5.2464(3) Å, β = 110.534(6)°, V = 390.78(3) Å3. TEM examination of the LiNiSi2O6 pyroxene showed the presence of h + k odd reflections indicative of a primitive lattice, and of antiphase domains obtained by dark field imaging of the h + k odd reflections. A HT in situ investigation was performed by examining TEM selected area diffraction patterns collected at high temperature and synchrotron radiation powder diffraction. In HTTEM the LiNiSi2O6 was examined together with LiCrSi2O6 pyroxene. In LiCrSi2O6 the h + k odd critical reflections disappear at about 340 K; they are sharp up to the transition temperature and do not change their shape until they disappear. In LiNiSi2O6 the h + k odd reflections are present up to sample deterioration at 650 K. A high temperature synchrotron radiation powder diffraction investigation was performed on LiNiSi2O6 between 298 and 773 K. The analysis of critical reflections and of changes in cell parameters shows that the space group is P-centred up to the highest temperature. The comparative analysis of the thermal and spontaneous strain contributions in P21/c and C2/c pyroxenes indicates that the high temperature strain in P-LiNiSi2O6 is very similar to that due to thermal strain only in C2/c spodumene and that a spontaneous strain contribution related to pre-transition features is not apparent in LiNiSi2O6. A different high-temperature behaviour in LiNiSi2O6 with respect to other pyroxenes is suggested, possibly in relation with the presence of Jahn–Teller distortion of the M1 polyhedron centred by low-spin Ni3+.  相似文献   

14.
The crystal structure of Pb6Bi2S9 is investigated at pressures between 0 and 5.6 GPa with X-ray diffraction on single-crystals. The pressure is applied using diamond anvil cells. Heyrovskyite (Bbmm, a = 13.719(4) Å, b = 31.393(9) Å, c = 4.1319(10) Å, Z = 4) is the stable phase of Pb6Bi2S9 at ambient conditions and is built from distorted moduli of PbS-archetype structure with a low stereochemical activity of the Pb2+ and Bi3+ lone electron pairs. Heyrovskyite is stable until at least 3.9 GPa and a first-order phase transition occurs between 3.9 and 4.8 GPa. A single-crystal is retained after the reversible phase transition despite an anisotropic contraction of the unit cell and a volume decrease of 4.2%. The crystal structure of the high pressure phase, β-Pb6Bi2S9, is solved in Pna2 1 (a = 25.302(7) Å, b = 30.819(9) Å, c = 4.0640(13) Å, Z = 8) from synchrotron data at 5.06 GPa. This structure consists of two types of moduli with SnS/TlI-archetype structure in which the Pb and Bi lone pairs are strongly expressed. The mechanism of the phase transition is described in detail and the results are compared to the closely related phase transition in Pb3Bi2S6 (lillianite).  相似文献   

15.
A new potassium uranyl selenate compound K(UO2)(SeO4)(OH)(H2O) has been synthesized for the first time using the technique of evaporation from water solution. Its crystal structure has been solved by direct methods (monoclinic, P21/c,a = 8.0413(9) Å, b = 8.0362(9) Å, c = 11.6032(14) Å, β = 106.925(2)°, V = 717.34(14) Å3) and refined to R 1 = 0.0319 (wR 2 = 0.0824) for 1285 reflections with |F 0| > 4σ F . The structure consists of [(UO2(SeO4)(OH)(H2O)]? chains extending along axis b. In the chains, the uranyl pentagonal bipyramids are linked via bridged hydroxyl anions and tetrahedral oxoanions [SeO4]2?. Potassium ions are situated between these chains. No chains of that type have been observed in uranyl compounds earlier, but they had been detected in the structures of butlerite, parabutlerite, uklonskovite, fibroferrite, and a number of synthetic compounds.  相似文献   

16.
Crystals of lead oxychloride Pb13O10Cl6 have been synthesized on the basis of high-temperature solid-state reactions. The Pb13O10Cl6 structure was studied using X-ray single-crystal diffraction analysis. The compound is monoclinic, and the space group is C2/c; the unit-cell dimensions are a = 16.1699(14), b = 7.0086(6), c = 23.578(2) Å, β = 97.75°, and V = 2647.6(4) Å3. The structure has been solved by direct methods and refined to R 1 = 0.0505 for 2671 observed unique reflections. The structure is a 3D framework consisting of OPb4 tetrahedrons. Chlorine atoms are located in the framework channels. The structure contains seven symmetrically independent Pb atoms, which are coordinated by 2 to 4 O2? and 2 to 4 Cl? anions. The synthesized compound is compared with other natural and synthetic lead oxyhalides.  相似文献   

17.
Radio interferometric observations of an H2O maser flare in the Orion Nebula at epoch 1982.9 have been used to determine the flare’s spatial structure. Antennas in the Crimea, Effelsberg, and Onsala were used. The emission region consists of three groups of components. The angular sizes of the components are 0.2–0.9 mas, and the widths of the emitted lines are 0.2–0.7 km/s. The velocities of the components are correlated with their relative positions, which correspond to expanding concentric rings. Assuming a 1 M⊙ protostar in a Keplerian approximation, the radius of the inner ring R is 15 AU, the velocity of its rotation Vrot is 8.98 km/s, and the radial component of the velocity Vrad is 1.79 km/s. For the outer ring, R=15.7 AU, Vrot=8.79 km/s, and Vrad=2.61 km/s.  相似文献   

18.
Using a diamond-anvil cell and synchrotron X-ray diffraction, the compressional behavior of a synthetic qandilite Mg2.00(1)Ti1.00(1)O4 has been investigated up to about 14.9 GPa at 300 K. The pressure–volume data fitted to the third-order Birch–Murnaghan equation of state yield an isothermal bulk modulus (K T0) of 175(5) GPa, with its first derivative \(K_{T0}^{{\prime }}\) attaining 3.5(7). If \(K_{T0}^{{\prime }}\) is fixed as 4, the K T0 value is 172(1) GPa. This value is substantially larger than the value of the adiabatic bulk modulus (K S0) previously determined by an ultrasonic pulse echo method (152(7) GPa; Liebermann et al. in Geophys J Int 50:553–586, 1977), but in general agreement with the K T0 empirically estimated on the basis of crystal chemical systematics (169 GPa; Hazen and Yang in Am Miner 84:1956–1960, 1999). Compared to the K T0 values of the ulvöspinel (Fe2TiO4; ~148(4) GPa with \(K_{T0}^{{\prime }} = 4\)) and the ringwoodite solid solutions along the Mg2SiO4–Fe2SiO4 join, our finding suggests that the substitution of Mg2+ for Fe2+ on the T sites of the 4–2 spinels can have more significant effect on the K T0 than that on the M sites.  相似文献   

19.
On 8th August 2017, a magnitude Ms 7.0 earthquake struck the County of Jiuzhaigou, in Sichuan Province, China. It was the third Ms ≥?7.0 earthquake in the Longmenshan area in the last decade, after the 2008 Ms 8.0 Wenchuan earthquake and the 2013 Ms 7.0 Lushan earthquake. The event did not produce any evident surface rupture but triggered significant mass wasting. Based on a large set of pre- and post-earthquake high-resolution satellite images (SPOT-5, Gaofen-1 and Gaofen-2) as well as on 0.2-m-resolution UAV photographs, a polygon-based interpretation of the coseismic landslides was carried out. In total, 1883 landslides were identified, covering an area of 8.11 km2, with an estimated total volume in the order of 25–30?×?106 m3. The total landslide area was lower than that produced by other earthquakes of similar magnitude with strike-slip motion, possibly because of the limited surface rupture. The spatial distribution of the landslides was correlated statistically to a number of seismic, terrain and geological factors, to evaluate the landslide susceptibility at regional scale and to identify the most typical characteristics of the coseismic failures. The landslides, mainly small-scale rockfalls and rock/debris slides, occurred mostly along two NE-SW-oriented valleys near the epicentre. Comparatively, high landslide density was found at locations where the landform evolves from upper, broad valleys to lower, deep-cut gorges. The spatial distribution of the coseismic landslides did not seem correlated to the location of any known active faults. On the contrary, it revealed that a previously-unknown blind fault segment—which is possibly the north-western extension of the Huya fault—is the plausible seismogenic fault. This finding is consistent with what hypothesised on the basis of field observations and ground displacements.  相似文献   

20.
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