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1.
Molecular R -matrix calculations are performed to give rotational excitation rates for electron collisions with linear molecular ions. Results are presented for CO+, HCO+, NO+ and H2+ up to electron temperatures of 10 000 K. De-excitation rates and critical electron densities are also given. It is shown that the widely used Coulomb–Born approximation is valid for Δ j =1 transitions when the molecular ion has a dipole greater than about 2D, but otherwise is not reliable for studying electron-impact rotational excitation. In particular, transitions with Δ j >1 are found to have appreciable rates and are found to be entirely dominated by short-range effects.  相似文献   

2.
A multitransition 3-mm molecular line single pointing and mapping survey was carried out towards 29 massive star-forming cores in order to search for the signature of inward motions. Up to seven different transitions, optically thick lines HCO+(1-0), CS(2-1), HNC(1-0), HCN(1-0) and 12CO(1-0), and optically thin lines C18O(1-0) and 13CO(1-0) were observed towards each source. The normalized velocity differences (     ) between the peak velocities of optically thick lines and optically thin line C18O(1-0) for each source were derived. Prominent inward motions are probably present in either HCO+(1-0) or CS(2-1) or HNC(1-0) observations in most sources. Our observations show that there is a significant difference in the incidence of blueshifted asymmetric line profiles between CS(2-1) and HCO+(1-0). The HCO+(1-0) shows the highest occurrence of obvious asymmetric features, perhaps owing to different optical depth between CS(2-1) and HCO+(1-0). HCO+(1-0) appears to be the best inward motion tracer. The mapping observations of multiple line transitions enable us to identify six strong infall candidates: G123.07-6.31, W75(OH), S235N, CEP-A, W3(OH) and NGC 7538. The infall signature is extended up to a linear scale  >0.2 pc  .  相似文献   

3.
We report the discovery of high-velocity dense gas from a bipolar outflow source near NGC 2068 in the L1630 giant molecular cloud. CO and HCO+ J =3→2 line wings have a bipolar distribution in the vicinity of LBS 17-H with the flow orientated roughly east–west and perpendicular to the elongation of the submillimetre dust continuum emission. The flow is compact (total extent ∼0.2 pc) and contains of the order of 0.1 M⊙ of swept-up gas. The high-velocity HCO+ emission is distributed over a somewhat smaller area <0.1 pc in extent.
A map of C18O J =2→1 emission traces the LBS 17 core and follows the ambient HCO+ emission reasonably well, with the exception of the direction towards LBS 17-H where there is a significant anticorrelation between the C18O and HCO+. A comparison of beam-matched C18O and dust-derived H2 column densities suggests that CO is depleted by up to a factor of ∼50 at this position if the temperature is as low as 9 K, although the difference is substantially reduced if the temperature is as high as 20 K. Chemical models of collapsing clouds can account for this discrepancy in terms of different rates of depletion on to dust grains for CO and HCO+.
LBS 17-H has a previously known water maser coincident with it but there are no known near-infrared, IRAS or radio continuum sources associated with this object, leading to the conclusion that it is probably very young. A greybody fit to the continuum data gives a luminosity of only 1.7 L⊙ and a submillimetre-to-bolometric luminosity ratio of 0.1, comfortably satisfying the criteria for classification as a class 0 protostar candidate.  相似文献   

4.
We have carried out a systematic search for the molecular ion CO+ in a sample of eight protoplanetary and planetary nebulae in order to determine the origin of the unexpectedly strong HCO+ emission previously detected in these sources. An understanding of the HCO+ chemistry may provide direct clues for the physical and chemical evolution of planetary nebulae. We find that the integrated intensity of the CO+ line may be correlated with that of HCO+, suggesting that the reaction of CO+ with molecular hydrogen may be an important formation route for HCO+ in these planetary nebulae.  相似文献   

5.
Anomalous molecular line profile shapes are the strongest indicators of the presence of the infall of gas that is associated with star formation. Such profiles are seen for well-known tracers, such as HCO+, CS and H2CO. In certain cases, optically thick emission lines with appropriate excitation criteria may possess the asymmetric double-peaked profiles that are characteristic of infall. However, recent interpretations of the HCO+ infall profile observed towards the protostellar infall candidate B335 have revealed a significant discrepancy between the inferred overall column density of the molecule and that which is predicted by standard dark cloud chemical modelling.
This paper presents a model for the source of the HCO+ emission excess. Observations have shown that, in low-mass star-forming regions, the collapse process is invariably accompanied by the presence of collimated outflows; we therefore propose the presence of an interface region around the outflow in which the chemistry is enriched by the action of jets. This hypothesis suggests that the line profiles of HCO+, as well as other molecular species, may require a more complex interpretation than can be provided by simple, chemically quiescent, spherically symmetric infall models.
The enhancement of HCO+ depends primarily on the presence of a shock-generated radiation field in the interface. Plausible estimates of the radiation intensity imply molecular abundances that are consistent with those observed. Further, high-resolution observations of an infall-outflow source show HCO+ emission morphology that is consistent with that predicted by this model.  相似文献   

6.
We have searched for molecular absorption lines at millimetre wavelengths in 11 gravitational lens systems discovered in the JVAS/CLASS surveys of flat spectrum radio sources. Spectra of only one source 1030+074 were obtained in the 3-, 2- and 1.3-mm bands at the frequencies corresponding to common molecular transitions of CO and HCO+ as continuum emission was not found in any of the other sources. We calculated upper limits to the column density in molecular absorption for 1030+074, using an excitation temperature of 15 K, to be N CO<6.3×1013 cm−2 and N HCO+<1.3×1011 cm−2 , equivalent to hydrogen column density of the order N H<1018 cm−2 , assuming standard molecular abundances. We also present the best upper limits of the continuum at the lower frequency for the other 10 gravitational lenses.  相似文献   

7.
The evolution of star-forming core analogues undergoing inside-out collapse is studied with a multipoint chemodynamical model which self-consistently computes the abundance distribution of chemical species in the core. For several collapse periods the output chemistry of infalling tracer species such as HCO+, CS and N2H+ is then coupled to an accelerated Λ-iteration radiative transfer code, which predicts the emerging molecular line profiles using two different input gas/dust temperature distributions. We investigate the sensitivity of the predicted spectral line profiles and line asymmetry ratios to the core temperature distribution, the time-dependent model chemistry, as well as to ad hoc abundance distributions. The line asymmetry is found to be strongly dependent on the adopted chemical abundance distribution. In general, models with a warm central region show higher values of blue asymmetry in optically thick HCO+ and CS lines than models with a starless core temperature profile. We find that in the formal context of Shu-type inside-out infall, and in the absence of rotation or outflows, the relative blue asymmetry of certain HCO+ and CS transitions is a function of time and, subject to the foregoing caveats, can act as a collapse chronometer. The sensitivity of simulated HCO+ line profiles to linear radial variations, subsonic or supersonic, of the internal turbulence field is investigated in the separate case of static cores.  相似文献   

8.
Molecular R-matrix calculations are performed at a range of energies to give rotational and vibrational excitation and de-excitation cross-sections and, hence, rates for electron collisions with HeH+ up to electron temperatures of 20 000 K. Critical electron densities are also given. The rotational calculations include the Coulomb–Born completion of the cross-sections for high l values. Rates for the transition j  = 0 → 2, which have previously been assumed to be negligible, are found to be up to half those for j  = 0 → 1, raising the prospect of observing the HeH+ j  = 2 → 1 emission line at 74.8 μm.  相似文献   

9.
A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C2 and CO, and predicts a column density of 91010 cm2 for HCO+.  相似文献   

10.
The wavelength and Einstein A coefficient are calculated for all rotation–vibration transitions of  4He1H+, 3He1H+, 4He2H+  and  3 He2H+  , giving a complete line list and the partition function for  4HeH+  and its isotopologues. This opacity is included in the calculation of the total opacity of low-metallicity stars and its effect is analysed for different conditions of temperature, density and hydrogen number fraction. For a low helium number fraction (as in the Sun), it is found that HeH+ has a visible but small effect for very low densities  (ρ≤ 10−10 g cm−3)  , at temperatures around 3500 K. However, for high helium number fraction, the effect of HeH+ becomes important for higher densities  (ρ≤ 10−6 g cm−3)  , its effect being most important for a temperature around 3500 K. Synthetic spectra for a variety of different conditions are presented.  相似文献   

11.
Compact regions of enhanced HCO+ and NH3 emission have been detected close to a number of Herbig–Haro objects. An interpretation of these detections is the following: a transient clump within the molecular cloud has been irradiated by the shock that generates the Herbig–Haro object. The irradiation releases icy mantles from the grains within the transient clump and initiates a photochemistry. On the basis of this picture, we have developed an extensive chemical model which predicts that a wide range of species, other than NH3 and HCO+, should also be detectable. These include CH3OH, H2S, C3H4, H2CO, SO, SO2, H2CS and NS. The chemical effects should last ∼  104 yr  .  相似文献   

12.
We have computed optical absorption-line profiles of CH+ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C+(H2, H)CH+. Whilst CH+ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH+3(e−, H2)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH+ and CH line profiles is found to be no more than approximately 2 km s−1, which is smaller than has previously been assumed. We also investigate OH and HCO+, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.  相似文献   

13.
HCO+ has been detected for the first time towards the star Cygnus OB2 No. 12 through emission of the 1–0 rotational transition at 89 GHz. The CO( J =2−1) transition has also been observed. The observations are consistent with a model of dense regions embedded in a low-density clump gas. If actually present, the dense component would have an aggregate size L 1300 au, in agreement with estimates of small-scale density fluctuations observed along diffuse lines of sight.  相似文献   

14.
The origin of the strong CO Cameron band emission in the Red Rectangle is investigated. From a comparison of laboratory spectroscopic data and astronomical observations in combination with chemical modelling, it is concluded that the Cameron band emission of CO originates from the dissociative recombination of HCO+, and its intensity provides a measure of the product of the density of HCO+ ions and the electron density, integrated along the line of sight.  相似文献   

15.
Effective collision strengths for electron-impact excitation of the N-like ion S  x are calculated in the close-coupling approximation using the multichannel R -matrix method. Specific attention is given to the 10 astrophysically important fine-structure forbidden transitions among the 4So, 2Do and 2Po levels in the 2s22p3 ground configuration. The total (e−+ion) wavefunction is expanded in terms of the 11 lowest LS eigenstates of S  x , and each eigenstate is represented by extensive configuration-interaction wavefunctions. The collision strengths obtained are thermally averaged over a Maxwellian distribution of velocities, for all 10 fine-structure transitions, over the range of electron temperatures log  T (K)=4.6–6.7 (the range appropriate for astrophysical applications). The present effective collision strengths are the only results currently available for these fine-structure transition rates.  相似文献   

16.
Effective collision strengths for electron-impact excitation of the N-like ion Ne  iv are calculated in the close-coupling approximation using the multichannel R-matrix method. Specific attention is given to the 10 astrophysically important fine-structure forbidden transitions among the 4So, 2Do and 2Po levels in the 2s22p3 ground-state configuration. The expansion of the total wavefunction incorporates the lowest 11 LS eigenstates of Ne  iv , consisting of eight n  = 2 terms with configurations 2s22p3, 2s2p4 and 2p5, together with three n  = 3 states of configuration 2s22p23s. We present in graphical form the effective collision strengths obtained by thermally averaging the collision strengths over a Maxwellian distribution of velocities, for all 10 fine-structure transitions, over the range of electron temperatures log T (K) = 3.6 to log T (K) = 6.1 (the range appropriate for astrophysical applications). Comparisons are made with the earlier, less sophisticated close-coupling calculation of Giles, and excellent agreement is found in the limited temperature region where a comparison is possible [log T (K) = 3.7 to log T (K) = 4.3]. At higher temperatures the present data are the only reliable results currently available.  相似文献   

17.
We have studied the chemistry of the molecular gas in evolved planetary nebulae. Three pseudo-time-dependent gas-phase models have been constructed for dense (104–105 cm−3) and cool ( T ∼15 K) clumpy envelopes of the evolved nebulae NGC 6781, M4-9 and NGC 7293. The three nebulae are modelled as carbon-rich stars evolved from the asymptotic giant branch to the late planetary nebula phase. The clumpy neutral envelopes are subjected to ultraviolet radiation from the central star and X-rays that enhance the rate of ionization in the clumps. With the ionization rate enhanced by four orders of magnitude over that of the ISM, we find that resultant abundances of the species HCN, HNC, HC3N and SiC2 are in good agreement with observations, while those of CN, HCO+, CS and SiO are in rough agreement. The results indicate that molecular species such as CH, CH2, CH2+ , HCl, OH and H2O are anticipated to be highly abundant in these objects.  相似文献   

18.
The evolved star HD 179821 continues to be the subject of much debate as to whether it is a nearby     post-asymptotic giant branch (post-AGB) star or a distant     high initial mass     post-red supergiant. We have mapped the OH maser emission around HD 179821 in the 1612- and 1667-MHz lines with the MERLIN interferometer array at a resolution of 0.4 arcsec and 0.35 km s−1. The OH emission lies in a thick shell with inner and outer radii of 1.3 and         and expansion velocity of 30 km s−1. Although we find some evidence for acceleration and for deviations from spherical symmetry, the bulk of the maser emission is consistent with a constant-velocity spherical shell. The extent of the shell agrees with H2O and OH dissociation models and supports a distance estimate of 6 kpc. However, the shell is incomplete and appears to have been disrupted by more recent collimated outflow activity within the last 1500 yr. We suggest that this activity is also responsible for the active envelope chemistry (in particular the presence of HCO+) and for the apparent offset of the star from the centre of the shell. The luminous yellow hypergiant star IRC +10420 also shows signs of recent outflows, and HD 179821 may be at a similar, perhaps slightly earlier, phase of evolution. We suggest that the SiO thermal emission arises from the same detached envelope as the OH maser emission as in IRC +10420. If so then this would strengthen the connection between these two stars and probably rule out a post-AGB status for HD 179821.  相似文献   

19.
We have found a bar of shocked molecular hydrogen (H2) towards the OH(1720 MHz) maser located at the projected intersection of supernova remnant (SNR)  G359.1–0.5  and the non-thermal radio filament known as the Snake. The H2 bar is well aligned with the SNR shell and almost perpendicular to the Snake. The OH(1720 MHz) maser is located inside the sharp western edge of the H2 emission, which is consistent with the scenario in which the SNR drives a shock into a molecular cloud at that location. The spectral line profiles of 12CO, HCO+ and CS towards the maser show broad-line absorption, which is absent in the 13CO spectra and most probably originates from the pre-shock gas. A density gradient is present across the region and is consistent with the passage of the SNR shock, while the H2 filament is located at the boundary between the pre-shock and post-shock regions.  相似文献   

20.
We present multimolecular line maps obtained with the Mopra telescope towards the southern giant molecular cloud (GMC) complex G333, associated with the H  ii region RCW 106. We have characterized the GMC by decomposing the 3D data cubes with gaussclumps , and investigated spatial correlations among different molecules with principal component analysis (PCA). We find no correlation between clump size and linewidth, but a strong correlation between emission luminosity and linewidth. PCA classifies molecules into high- and low-density tracers, and reveals that HCO+ and N2H+ are anticorrelated.  相似文献   

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