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1.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

2.
TheConvectiveDiffusionObserved byRemoteSensors (CONDORS) field experiment conducted at the Boulder Atmospheric Observatory used innovative techniques to obtain three-dimensional mappings of plume concentration fields, /Q, of oil fog detected by lidar and chaff detected by Doppler radar. It included extensive meteorological measurements and, in 1983, tracer gases measured at a single sampling arc. Final results from ten hours of elevated and surface release data are summarized here. Many intercomparisons were made. Oil fog /Q measured 40m above the arc are mostly in good agreement withSF 6 values, except in a few instances with large spacial inhomogeneities over short distances. After a correction scheme was applied to compensate for the effect of its settling speed, chaff dy/Q agreed well with those of oil except in two cases of oil fog hot spots. Mass or frequency distribution vs. azimuth or elevation angle comparisons were made for chaff, oil, and wind, with mostly good agreements. Spacial standard deviations, y and z, of chaff and oil agree overall and are consistent at short range with velocity standard deviations vand w 0.6w* (the convective scale velocity), as measured atz>100m. Surface release y is enhanced up to 60% at smallx, consistent with the Prairie Grass measurements and with larger v and reduced wind speed measured near the surface. Decreased y at small dimensionless average times is also noted. Finally, convectively scaled dy, C y, were plotted versus dimensionlessx andz for oil, chaff, and corrected chaff for each 30–60 min period. Aggregated CONDORSC y fields compare well with laboratory tank and LES numerical simulations; surface-released oil fog compares expecially well with the tank experiments. However, large deviations from the norm occurred in individual averaging periods; these deviations correlated strongly with anomalies in measured distributions.On assignment to the US Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory, RTP, NC.  相似文献   

3.
A previously published technique for using tethered spherical balloons as anemometers for measuring light low-level winds has been further developed. Earlier data on the relationship between the aerodynamic drag coefficient and the Reynolds number of spherical rubber balloons were combined with a large number of new data and re-analysed; and the errors in the relationship were estimated. The results allowed a more accurate calculation of wind speed from the deflection of a tethered balloon from the vertical. When combined with a new technique for calculating the effects of the tether, this enabled light to moderate low-level winds at fixed heights up to 600 m or more to be measured with simple, cheap, and readily mobile equipment; and a slight modification of the technique allowed measurement of winds in and above fog. Wind speeds measured by the ballon technique showed reasonably good agreement with measurements by an anemometer carried beneath the balloon.Glossary of Symbols a, b, c Coefficients in the relationship between lnC d and lnR - A Quantity under square root in solution for lnV whena0 - C d Wind drag coefficient for balloon - C dc Value ofC d given by calibration curve of Table I - D Dynamic wind pressure force on balloon - F Buoyant free lift of balloon with load - Re Reynold's number of balloon (sphere) - R = Re/105 - r Radius of sphere - T Tension in tether - V Wind speed - 83() =(lnC dc -lnC d ) when 83° , or 0 for other - Error in lnC d - Elevation of tether where attached to balloon - Elevation of balloon from ground tether point - Molecular viscosity of air - Ratio of circumference to diameter of circle - Density of air  相似文献   

4.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

5.
The mass accommodation coefficient HONO of gaseous nitrous acid on water surfaces has been determined in a cooperation between the Universities of Strasbourg and Bonn. The droplet train technique (Strasbourg) yielded 0.04<HONO<0.09 for an estimated surface temperature of 245 K, while the liquid jet technique (Bonn) yielded 0.03<HONO<0.15 for a surface temperature of 297 K. The uncertainty ranges allow for experimental scatter and estimated uncertainties in diffusion coefficients. The same HONO source and analytical equipment were used for both experiments, which were run in parallel. The results indicate that the exchange rate of HONO between atmospheric water droplets and interstitial air is not inhibited by interfacial resistance.  相似文献   

6.
A Comparative Analysis of Transpiration and Bare Soil Evaporation   总被引：4，自引：0，他引：4  
Transpiration Ev and bare soil evaporation Eb processes are comparatively analysed assuming homogeneous and inhomogeneous areal distributions of volumetric soil moisture content . For a homogeneous areal distribution of we use a deterministic model, while for inhomogeneous distributions a statistical-deterministic diagnostic surface energy balance model is applied. The areal variations of are simulated by Monte-Carlo runs assuming normal distributions of .The numerical experiments are performed for loam. In the experiments we used different parameterizations for vegetation and bare soil surface resistances and strong atmospheric forcing. According to the results theEv()-Eb() differences are great, especially in dry conditions. In spite of this, the available energy flux curves of vegetation Av() and bare soil Ab() surfaces differ much less than the Ev() and Eb() curves. The results suggest that Ev is much more non-linearly related to environmental conditions than Eb. Both Ev and Eb depend on the distribution of , the wetness regime and the parameterization used. With the parameterizations, Eb showed greater variations than Ev. These results are valid when there are no advective effects or mesoscale circulation patterns and the stratification is unstable.  相似文献   

7.
We analyze the checkerboard problem of many alternating surfaces with different properties, on scales up to (say) 3,000 m. Power-law representations of the vertical profiles of mean wind speed and eddy diffusivity lead to solutions in terms of Kelvin and trigonometric functions.These solutions are used to determine blending heights (*), where deviations from the mean of concentration, or of vertical flux density, fall to some small fraction, , of their value at the surface. Values of *are important for regional and larger-scale meteorological models. In smaller scale micrometeorological studies, they may serve also as the top levels of surface boundary layers.An important result for both theoretical and experimental contexts is that deviations of flux persist with elevation much more strongly than those of concentration, so that, in general, * should be based on flux rather than concentration. Representative values of *, for = 0.05, are of order 5 and 30 m for surface pattern wavelengths of 102 and 103 m, respectively. Values of * are robust to changes in adopted power-law indices, and are independent of wind speed. Surface roughness has a mild but calculable effect.  相似文献   

8.
Summary This study presents an analytical investigation of the local behaviour of the solution to a mesoscale model with Newtonian nudging when observed winds are time varying. The analysis examines each Fourier component of the time series of observed winds. Unlike the case with a constant observed wind, the nudged wind vector does not asymptotically approach the observed wind. In response to sinusoidal oscillation of the observed wind, the nudged wind vector is always on a half circle connecting the vector ends of the observed and un-nudged modelled winds. When nudging parameter 0, the nudged wind vector approaches the un-nudged wind; when , the nudged wind vector approaches the observed wind. For commonly used values of nudging parameter , the modelled wind field always carries errors.A target nudging scheme is devised in this study in order to ensure the model result is identical to observed winds with sinusoidal oscillation. Investigation shows that such a target wind exists for a finite value of , and the magnitude of the target-nudging term is about the same as that of a normal nudging term if f, wheref is the Coriolis parameter and is the frequency of the wind oscillation.With 7 Figures  相似文献   

9.
The formulation of a new land surface scheme (LSS) with vegetation dynamics for coupling to the McGill Paleoclimate Model (MPM) is presented. This LSS has the following notable improvements over the old version: (1) parameterization of deciduous and evergreen trees by using the models climatology and the output of the dynamic global vegetation model, VECODE (Brovkin et al. in Ecological Modelling 101:251–261 (1997), Global Biogeochemical Cycles 16(4):1139, (2002)); (2) parameterization of tree leaf budburst and leaf drop by using the models climatology; (3) parameterization of the seasonal cycle of the grass leaf area index; (4) parameterization of the seasonal cycle of tree leaf area index by using the time-dependent growth of the leaves; (5) calculation of land surface albedo by using vegetation-related parameters, snow depth and the models climatology. The results show considerable improvement of the models simulation of the present-day climate as compared with that simulated in the original physically-based MPM. In particular, the strong seasonality of terrestrial vegetation and the associated land surface albedo variations are in good agreement with several satellite observations of these quantities. The application of this new version of the MPM (the green MPM) to Holocene millennial-scale climate changes is described in a companion paper, Part II.
Yi WangEmail: Phone: +1-514-3987448Fax: +1-514-3986115
  相似文献   

10.
Horizontal u and vertical w velocity fluctuations have been measured together with temperature fluctuations in the atmospheric surface layer, at a small height above a wheat crop canopy. Marginal probability density functions are presented for both individual fluctuations u, w, and for the instantaneous Reynolds stress uw, and heat fluxes w and u. Probability density functions of the velocity fluctuations deviate less significantly from the Gaussian form than the probability density of temperature. There appears to be closer similarity between statistics of the instantaneous heat fluxes than between the momentum flux and either of the heat fluxes investigated. The mean momentum flux receives equal contributions from the events referred to as ejections and sweeps in laboratory boundary layers. Sweeps provide the largest contribution to the heat fluxes.  相似文献   

11.
This is one of a series of papers on the Askervein Hill Project. It presents results on the variations in mean wind speed at fixed heights (z) above the ground from linear arrays of anemometer posts and towers. Most of the data are for z = 10 m but some are for z = 3 m. Selected and directionally grouped data from the 55 Mean Flow runs are presented together with mean flow data from Askervein '83 Turbulence runs. Comparisons are made between the data and guideline estimates of fractional speed-up ratio at hilltop locations and between the data and MS3DJH/3 model predictions along the tower lines. There is good agreement in most cases.  相似文献   

12.
Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.  相似文献   

13.
The standard E – model generates aplanetary boundary layerthat appears to be much too deep. The cause of theproblem is traced to the equation for the dissipationrate () of turbulent kinetic energy (E), specifically theparameterization of dissipation production anddestruction. In the context of atmosphericboundary-layer modelling, we argue that a part of thedissipation production should be modelled as the inputto the spectral cascade from the energy-containingpart of the spectrum, with a characteristic length , while the equilibrium imbalancebetween local production and destruction ofdissipation is modelled as proportional toE2/E, as in the standard model. Wepropose an E – – turbulence closurescheme, in which both the mixing length, m, and are prescribed. The importance ofthe equation is diminished, though itstill determines the dissipation rate in the Eequation.  相似文献   

14.
Components of the radiation and energy balances were measured over a clear-cut area and a mature, mixed forest during the summer of 1981 at the Petawawa National Forestry Institute, Chalk River, Ontario. The work concentrated on the clear-cut site which supported a canopy layer composed primarily of bracken fern and logging remnants.Forty days of radiation data were collected at the clear-cut site. After the first four weeks of measurements (the green season), most of the ferns quickly died, and their foliage changed appearance from a green to brownish colour (the brown season). The daily mean reflection coefficient of solar radiation determined over the green season was 0.20 and decreased to 0.13 for the brown season. The corresponding value for the forest was 0.13, based on a limited amount of data. The clear-cut site received 11% and 21% less net radiation than the forest on a 24-hr and daylight-hours basis, respectively, as a consequence of the higher reflection coefficient and larger daytime longwave radiation emission.A reversing temperature difference measurement system (RTDMS), incorporating ten-junction thermopiles was employed at each site in order to determine Bowen ratios () via differential psychrometry. Both systems performed well, especially the RTDMS over the forest which was capable of resolving very small differences of temperature, typically less than 0.2 °C over a height of 3 m. The mean hourly Bowen ratio, calculated from values from 0800 to 1600 hr, varied from 0.2 to 1.0 for the forest and from 0.4 to 0.8 for the clear-cut site in the green season.A significant canopy heat storage component of the energy balance, Q S , was found at the clear-cut site. In the early morning, a portion of the available energy was used to heat the biomass materials and air within the canopy layer. The stored heat within the canopy was released later in the day, increasing the available energy total.The daily mean value of the Priestley-Taylor coefficient (Priestley and Taylor, 1972) for the green season at the clear-cut site was 1.14, and individual values tended to increase during wet surface conditions and decrease when the surface dried. The daylight mean value during dry canopy conditions at the forest was 1.05, and much higher values occurred when the canopy was wet. The enhancement of for the wet forest was a result of the evaporation of intercepted rain (which is not limited by stomatal resistance) and the concomitant transfer of sensible heat to the forest.  相似文献   

15.
Equilibrium evaporation beneath a growing convective boundary layer   总被引：1，自引：1，他引：0  
Expressions for the equilibrium surface Bowen ratio ( s ) and equilibrium evaporation are derived for a growing convective boundary layer (CBL) in terms of the Bowen ratio at the top of the mixed layer i and the entrainment parameter A R . If AR is put equal to zero, the solution for s becomes-that previously obtained for the zero entrainment or closed box model. The Priestley-Taylor parameter is also calculated and plotted in terms ofA R and i . Realistic combinations of the atmospheric parameters give values of in the range 1.1 to 1.4.  相似文献   

16.
The impact of climate change on the river rhine: A scenario study   总被引：3，自引：0，他引：3  
This paper concerns the impact of human-induced global climate change on the River Rhine discharge. For this purpose a model for climate assessment, named ESCAPE, is coupled to a water balance model, named RHINEFLOW. From climate scenarios, changes in regional annual water availability and seasonal discharge in the River Rhine Basin are estimated. The climate scenarios are based on greenhouse gases emissions scenarios. An assessment is made for best guess seasonal discharge changes and for changes in frequencies of low and high discharges in the downstream reaches of the river. In addition, a quantitative estimation of the uncertainties associated with this guess is arrived at.The results show that the extent and range of uncertainty is large with respect to the best guess changes. The uncertainty range is 2–3 times larger for the Business-as-Usual than for the Accelerated Policies scenarios. This large range stems from the doubtful precipitation simulations from the present General Circulation Models. This scenario study showed the precipitation scenarios to be the key-elements within the present range of reliable climate change scenarios.For the River Rhine best guess changes for annual water availability are small according to both scenarios. The river changes from a present combined snow-melt-rain fed river to an almost entirely rain fed river. The difference between present-day large average discharge in winter and the small average discharge in autumn should increase for all scenarios. This trend is largest in the Alpine part of the basin. Here, winter discharges should increase even for scenarios forecasting annual precipitation decreases. Summer discharge should decrease. Best guess scenarios should lead to increased frequencies of both low and high flow events in the downstream (Dutch) part of the river. The results indicate changes could be larger than presently assumed in worst case scenarios used by the Dutch water management authorities.  相似文献   

17.
Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (Exc/Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at Exc/Em240/405 nm and Exc/Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.  相似文献   

18.
Antlers of different deer species are of particular importance for assessing temporal and/or spatial variations in environmental pollution with bone-seeking pollutants, such as Pb. Since antlers have a well-defined annual growth cycle, they accumulate Pb during a seasonally fixed time span, which provides natural standardisation of samples. Moreover, they are kept as trophies in well-dated collections enabling their use in historical studies. Considering these benefits, Pb levels were determined (by inductively coupled plasma mass spectrometry after the wet digestion of samples) in 116 antlers of roe deer (Capreolus capreolus L.), shot in the period 1961–2002 in the vicinity of the largest Slovene thermal power plant of otanj (TPP). Irrespective of the year of antler growth and the age of the animal analysed (no age-dependent influences were revealed), Pb levels ranged from 0.20 to 7.28 mg kg–1 (mean: 1.32 ± 0.19 mg kg–1), with the highest contents in the oldest and the lowest contents in the most recent samples. Since the mid-1960s, lead pollution has continuously decreased in the study area; three very evident drops (after 1975, 1985 and 1995, respectively) indicate the combined effect of three different remediation measures as follows: construction of a remote heating system in the seventies; introduction of unleaded petrol in the late-1980s, and construction of clean-up devices at the TPP in the late-1990s. The high positive correlation between the annual emissions from the TPP and the mean yearly Pb levels in antlers showed that roe deer antlers may be an useful tool for assessing temporal trends of ambient Pb pollution.  相似文献   

19.
A numerical study of stably stratified flow over a three-dimensional hill is presented. Large-eddy simulation is used here to examine in detail the laboratory experimental flows described in the landmark work of Hunt and Snyder about stratified flow over a hill. The flow is linearly stratified and U/Nh is varied from 0.2 to 1.0. Here N and U are the buoyancy frequency and freestream velocity respectively, and h is the height of the hill. The Reynolds number based on the hill height is varied from 365 to 2968. The characteristic flow patterns at various values of U/Nh have been obtained and they are in good agreement with earlier theoretical and experimental results. It is shown that the flow field cannot be predicted by Drazin's theory when recirculation exists at the leeside of the hill even at UNh 1. The wake structure agrees well with a two-dimensional wake assumption when U/Nh 1 but lee waves start to influence the wake structure as U/Nh increases. The dividing-streamline heights obtained in the simulation are in accordance with experimental results and Sheppard's formula. The energy loss along the dividing streamline due to friction/turbulence approximately offsets the energy gained from pressure field. When lee waves are present, linear theory always underestimates the amplitude and overestimates the wavelength of three-dimensional lee waves. The simulated variations of drag coefficients with the parameterK (=ND/ U) are qualitatively consistent with experimental data and linear theory. Here D is the depth of the tank.  相似文献   

20.
Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km2 Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.  相似文献   

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