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1.
Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, <S i i (t)>, and the plume centroid covariance, R i i (t) (i=1,2), were simulated for the variance of Y=log T, σ Y 2=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ Y 2=0.1, all simulated <S i i (t)>−S i i (0) and R i i (t) agree well with the first-order theoretical values, where S i i (0) are the initial values of S i i (t). For σ Y 2=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, <S 11(t)>−S 11(0) and R 11(t), agree well with the first-order theoretical results but the simulated transverse moments <S 22(t)>−S 22(0) and R 22(t) are significantly larger than the first-order values. For the same two larger values of σ Y 2 but the line sources parallel to μ, the simulated <S 11(t)>−S 11(0) are larger than but the simulated R 11 are smaller than the first-order values, and both simulated <S 22(t)>−S 22(0) and R 22(t) stay larger than the first-order values. For a fixed value of σ Y 2, the summations of <S i i (t)>−S i i (0) and R i i , i.e., X i i (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X 11 are in good agreement with the first-order theory but the simulated X 22 are significantly larger than the first-order values. The simulated X 22, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of <S 22(t)>−S 22(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ Y 2 is small.  相似文献   

2.
Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, <S i i (t)>, and the plume centroid covariance, R i i (t) (i=1,2), were simulated for the variance of Y=log T, σ Y 2=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ Y 2=0.1, all simulated <S i i (t)>−S i i (0) and R i i (t) agree well with the first-order theoretical values, where S i i (0) are the initial values of S i i (t). For σ Y 2=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, <S 11(t)>−S 11(0) and R 11(t), agree well with the first-order theoretical results but the simulated transverse moments <S 22(t)>−S 22(0) and R 22(t) are significantly larger than the first-order values. For the same two larger values of σ Y 2 but the line sources parallel to μ, the simulated <S 11(t)>−S 11(0) are larger than but the simulated R 11 are smaller than the first-order values, and both simulated <S 22(t)>−S 22(0) and R 22(t) stay larger than the first-order values. For a fixed value of σ Y 2, the summations of <S i i (t)>−S i i (0) and R i i , i.e., X i i (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X 11 are in good agreement with the first-order theory but the simulated X 22 are significantly larger than the first-order values. The simulated X 22, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of <S 22(t)>−S 22(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ Y 2 is small.  相似文献   

3.
Tonalites from the island arc rock assemblage in the Zêtang segment of the Yarlung Zangbo suture zone were analyzed for major, trace elements (including REE) and Sr-Nd isotope. The experimental datademonstrate that the tonalites have the adakite-like characteristics, including high SiO2 (58%-63%),Al2O3 (18.4%-22.4%), Sr (810×10-6-940×10-6), Sr/Y (77-106), low HREE (Y=9×10-6-11×10-6, Yb=1×10-6-1.3×10-6), with LREE enrichment and faint Eu positive anomaly. Isr (0.70421-0.70487) is relatively low whereas 143Nd/144Nd (0.512896-0.512929) and εNd(t) values ( 6.7- 7.3) are high. These feainvolvement of a small amount of oceanic sediments. The identification of Z(e)tang adakites, derived from slab melting, presents new evidence for the intra-Tethyan subduction and the previous suggestion about the existence of intra-oceanic island arc within Tethys.  相似文献   

4.
Ａｌｉｇｎｍｅｎｔｓｉｌｋｗｏｒｍｓａｓｓｅｉｓｍｉｃａｎｉｍａｌａｎｏｍａｌｏｕｓｂｅｈａｖｉｏｒ（ＳＡＡＢ）ａｎｄｅｌｅｃｔｒｏｍａｇｎｅｔｉｃｍｏｄｅｌｏｆａｆａｕｌｔ：ａｔｈｅｏｒｙａｎｄｌａｂｏｒａｔｏｒｙｅｘｐｅｒｉｍｅｎｔＭＯＴＯ...  相似文献   

5.
Fogang granitic batholith, the largest Late Mesozoic batholith in the Nanling region, has an exposure area of ca. 6000 km2. Wushi diorite-hornblende gabbro body is situated at the northeast part of the ba- tholith. Both the granitic batholith main body and the diorite-hornblende gabbro body belong to high-K calc alkaline series. Compared with the granitic main body, the Wushi body has lower Si (49%―55%), higher Fe, Mg, Ca, lower REE, less depletion of Eu, Ba, P, Ti, and obvious depletion of Zr, Hf. Zircon LA-ICP-MS dating and the mineral-whole rock isochron dating reveal that Fogang granitic main body and Wushi body were generated simultaneously at ca. 160 Ma. The Fogang granitic main body has high (87Sr/86Sr)i ratios (0.70871―0.71570) and low εNd(t) values (?5.11―?8.93), suggesting the origins of the granitic rocks from crustal materials. Their Nd two-stage model ages range from 1.37―1.68 Ga. The Sr and Nd isotopic compositions and the Nd model ages of the granitic rocks may suggest that the giant Fogang granitic main body was generated from a heterogeneous source, with participation of mantle component. Wushi diorite-hornblende gabbro is an unusual intermediate-basic magmatic rock series, with high (87Sr/86Sr)i ratios (0.71256―0.71318) and low εNd(t) values (?7.32―?7.92), which was possibly formed through mixing between the mantle-derived juvenile basaltic magma and the magma produced by the dehydration melting of lower crustal basaltic rocks.  相似文献   

6.
Chronology and geochemistry of the Shangyu gabbro-diorite in western Shandong were studied to understand their petrogenesis and the nature of the Mesozoic lithospheric mantle. The Shangyu intru-sion is mainly composed of a suite of gabbro-diorite. Zircons from the intrusion display eu-hedral-subhedral in shape and have high Th/U ratios (1.23―2.87), implying their magmatic origin. LA-ICP-MS zircon U-Pb dating results for two samples indicate that they were formed in the Early Cre-taceous, yielding weighted mean 206Pb/238U ages of 129±1Ma and 134±2Ma, respectively. Except for early cumulate such as sample QT-19, their SiO2 and MgO contents range from 50.12% to 56.37% and from 3.52% to 6.37%, respectively. Moreover, the gabbro-diorites are characterized by high Mg# (0.54―0.63), enrichment in Na (Na2O/K2O ratios more than 1), Cr (73×10-6―217×10-6) and Ni (34×10-6―241×10-6), and intensive enrichments in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). Their initial 87Sr/86Sr ratios and ε Nd(t) values range from 0.70962 to 0.71081 and from-16.60 to-13.04, respectively. Taken together with the Early Creta-ceous high-Mg diorites and the mantle xenoliths from the Tietonggou and Jinling as well as basalts from the Fangcheng and Feixian, it is suggested that the primary magma for the Shangyu gab-bro-diorites should be derived from the enriched lithospheric mantle intensively modified by conti-nental crust. The Sr-Nd-Pb isotopic compositions for the Early Cretaceous high-Mg diorites in western Shandong display a trend of spatial variations, i.e., initial 87Sr/86Sr, 207Pb/204Pb and 208Pb/204Pb ratios de-creasing and ε Nd(t) values increasing from southeast to northwest in western Shandong, which is con-sistent with the tectonic model that the Yangtze Craton subducted beneath the North China Craton oriented in north-west direction in the Early Mesozoic.  相似文献   

7.
This paper reports geochemical and Pb-Sr-Nd isotopic compositions of the Indosinian Yangba (215 Ma),Nanyili (225 Ma) and Mopi granitoids from the Bikou block of the northwestern margin of the Yangtze plate. These granitoids are enriched in Al (Al2O3:14.56%―16.48%) and Sr (352 μg/g―1047 μg/g),and depleted in Y (<16 μg/g) and HREE (e.g. Yb<1.61 μg/g),resulting in high Sr/Y (36.3―150) and (La/Yb)N (7.8―36.3) ratios and strongly fractionationed REE patterns. The Indosinian granotoids show initial Sr isotopic ratios (ISr) from 0.70419 to 70752,εNd(t) values from-3.1 to -8.5,and initial Pb isotopic ratios 206Pb/204Pb=17.891-18.250,207Pb/204Pb=15.494-15.575,and 208Pb/204Pb=37.788-38.335. Their geochemi-cal signatures indicate that the granitoids are adakitic. However,they are distinct from some adakites,generated by partial melting of subducted oceanic slab and/or underplated basaltic lower crust,be-cause they have high K (K2O: 1.49%―3.84%) and evolved Nd isotopic compositions,with older Nd iso-topic model ages (TDM=1.06―1.83 Ga). Geochemical and Sr-Nd isotopic compositions suggest that the magmas of the Insoninian adakitic rocks in the Bikou block were derived from partial melting of thick-ened basaltic lower crust. Combined with regional analyses,a lithospheric delamination model after collision between the North China and South China plates can account for the Indosinian adakitic magma generation. On the other hand,based on the Pb-Sr-Nd isotopic probing to the magma sources of the adakitic rocks,it is suggested that there is an unexposed continent-type basement under the exposed Bikou Group volcanic rocks. This can constrain on the Bikou Group volcanic rocks not to be MORB-or OIB-type.  相似文献   

8.
ＩｎｔｒｏｄｕｃｔｉｏｎＳｉｎｃｅｔｈｅ１９６０′ｓ,ｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｍｏｄｅｒｎｓｃｉｅｎｃｅａｎｄｔｅｃｈｎｏｌｏｇｙｈａｓｇｒａｄｕａｌｙｍａｄｅｉｔｐｏｓｉｂｌｅｔｏｐｒｅｄｉｃｔｅａｒｔｈｑｕａｋｅｓａｎｄｈａｓｐｒｏｍｏｔ...  相似文献   

9.
The paper presents a model of the kinetics of electronically excited O2(c1Σu−,v), O2(A′3Δu,v), O2(A3Σu+,v) molecules at heights of the lower thermosphere and mesosphere with allowance for electronic excitation transfer processes during molecular collisions. The model is used to calculate the relative O2(A3Σu+,v) and O2(A′3Δu,v) populations at heights of 80–110 km. The calculated populations are compared with the available literature results on experimental estimates, and good agreement is obtained. It is shown how the increase in the quenching rates of the considered states by oxygen atoms affects the calculation results.  相似文献   

10.
There is a general agreement that forest ecosystems in the Northern Hemisphere function as signifi-cant sinks for atmospheric CO2; however, their magnitude and distribution remain large uncertainties. In this paper, we report the carbon (C) stock and its change of vegetation, forest floor detritus, and mineral soil, annual net biomass increment and litterfall production, and respiration of vegetation and soils between 1992 to 1994, for three temperate forest ecosystems, birch (Betula platyphylla) forest, oak (Quercus liaotungensis) forest and pine (Pinus tabulaeformis) plantation in Mt. Dongling, Beijing, China. We then evaluate the C budgets of these forest ecosystems. Our results indicated that total C density (organic C per hectare) of these forests ranged from 250 to 300 t C ha-1, of which 35―54 t C ha-1 from vegetation biomass C and 209―244 t C ha-1 from soil organic C (1 m depth, including forest floor detritus). Biomass C of all three forests showed a net increase, with 1.33―3.55 t C ha-1 a-1 during the study period. Litterfall production, vegetation autotrophic respiration, and soil heterotrophic respira-tion were estimated at 1.63―2.34, 2.19―6.93, and 1.81―3.49 t C ha-1 a-1, respectively. Ecosystem gross primary production fluctuated between 5.39 and 12.82 t C ha-1 a-1, about half of which (46%―59%, 3.20―5.89 t C ha-1 a-1) was converted to net primary production. Our results suggested that pine forest fixed C of 4.08 t ha-1 a-1, whereas secondary forests (birch and oak forest) were nearly in balance in CO2 exchange between the atmosphere and ecosystems.  相似文献   

11.
Relative ‘echo intensity’ data (dI) from a bottom-mounted four-beam 300 kHz acoustic Doppler current profiler (ADCP) are used to infer propagation of vigorous processes above a continental slope. The 3- to 60-m horizontal beam spread and the 2-Hz sampling allow the distinction of different arrival times t i , i = 1,..., 4, at different distances in the acoustic beams from sharp changes in dI-content associated with frontal non-linear and turbulent bores or ‘waves’. The changes in dI are partially due to variations in amounts of resuspended material carried by the near-bottom turbulence and partially due to the fast variations in density stratification (‘stratified turbulence’), as inferred from 1-Hz sampled thermistor string data above the ADCP. Such bores are observed to pass the mooring up to 80 m above the bottom, having typical propagation speeds c = 0.15–0.5 m s−1, as determined from dI(t i ). Particle speeds in the immediate environment of a bore amount to |u|env=c ± 0.05 m s−1, the equality being a necessary condition for kinematic instability, whilst the maximum particle speeds amount |u|max = 1.2–2c. The dI-determined directions of up-, down- and alongslope processes are all to within ±10° of the ADCP’s beam-spread averaged current (particle velocity) data.  相似文献   

12.
The U-Th-~(40)K concentrations of granite are on 1―2 orders of magnitude greater than those of basal- tic-ultrabasic rocks. Radiogenic heat of a granitic melt has significant influence on the cool- ing-crystallization period of the melt. In this paper we derived a formula to calculate prolongation period (tA) of cooling-crystallization of a granitic melt caused by radiogenic heat. Calculation using this for- mula and radioactive element concentrations (U=5.31×10-6; Th=23.1×10-6; K=4.55%) for the biotite adamellite of the Jinjiling batholith shows that the tA of the adamellite is 1.4 times of the cooling period of the granitic melt without considering radiogenic heat from the initial temperature (Tm=960℃) to crystallization temperature (Tc=600℃) of the melt. It has been demonstrated that the radiogenic heat produced in a granitic melt is a key factor influencing the cooling-crystallization process of the granitic melt, and is likely one of the reasons for inconsistence between emplacement ages and crystallization ages of many Meso-Cenozoic granitoids.  相似文献   

13.
Based on the three-dimensional elastic inclusion model proposed by Dobrovolskii, we developed a rheological inclusion model to study earthquake preparation processes. By using the Corresponding Principle in the theory of rheologic mechanics, we derived the analytic expressions of viscoelastic displacement U(r, t) , V(r, t) and W(r, t), normal strains εxx (r, t), εyy (r, t) and εzz (r, t) and the bulk strain θ (r, t) at an arbitrary point (x, y, z) in three directions of X axis, Y axis and Z axis produced by a three-dimensional inclusion in the semi-infinite rheologic medium defined by the standard linear rheologic model. Subsequent to the spatial-temporal variation of bulk strain being computed on the ground produced by such a spherical rheologic inclusion, interesting results are obtained, suggesting that the bulk strain produced by a hard inclusion change with time according to three stages (α, β, γ) with different characteristics, similar to that of geodetic deformation observations, but different with the results of a soft inclusion. These theoretical results can be used to explain the characteristics of spatial-temporal evolution, patterns, quadrant-distribution of earthquake precursors, the changeability, spontaneity and complexity of short-term and imminent-term precursors. It offers a theoretical base to build physical models for earthquake precursors and to predict the earthquakes.  相似文献   

14.
Zircon U-Pb results of basalt from the Dashizhai Town in Inner Mongolia, NE China, shows that the basaltic lava was erupted at 439±3 Ma, much older than the “Permian basalts” as previously thought. These rocks show arc-type trace element patterns (i.e., Nb-Ta depletion and light REE and large ion lithophile element enrichment) and unradiogenic Sr and highly radiogenic Nd and Hf isotope compositions. They can be subdivided into two petrogenetic groups: Group 1 basalts have relatively high TiO2, MgO and compatible elements and low Sr and Th, characterized by mid-oceanic ridge basalt (MORB)-type Sr-Nd-Hf isotope compositions (87Sr/86Sr(i)=0.7028−0.7032, εNd(t)=+9.8−+11.2, εHf(t)=+16.1−+18.4). Group 2 has lower TiO2, MgO and compatible elements and higher Sr and Th, and relatively evolved Sr-Nd-Hf isotope compositions (87Sr/86Sr(i)=0.7037−0.7038, εNd(t)=+5.7−+7.3, εHf(t)=+12.6−+13.0). Both groups were interpreted as melts derived from a metasomatized mantle wedge formed during the subduction of Paleo-Asian Ocean. The mantle source for Group 1 was probably a highly isotopically depleted oceanic mantle modified by predominant slab fluids; whereas subducted sediments had an important contribution to the melting source for Group 2. The petrogenesis of the Dashizhai basalts provides clear evidence for early Paleozoic subduction of the Paleo-Asian Ocean, and the highly radiogenic Nd and Hf compositions in these rocks suggest that these lavas and their possible intrusive counterparts were one of the important components for Phanerozoic crustal growth. Our and previous studies on the “Dashizhai Formation” volcanic rocks yield an unrealistic eruption range of 440-270 Ma for different rock types, we thus advise to disassemble the previously defined “Dashizhai Formation” into multiple lithologic units and to reinterpret the spatial and temporal distributions of different volcano-sedimentary associations. Supported by National Basic Research Program of China (Grant No. 2006CB403504)  相似文献   

15.
The intrinsic dissipation and scattering attenuation in southwestern (SW) Anatolia, which is a tectonically active region, is studied using the coda waves. First the coda quality factor (Qc) assuming single scattering is estimated from the slope of the coda-wave amplitude decay. Then the Multiple Lapse Time Window (MLTW) analysis is performed with a uniform earth model. Three non-overlapping temporal data windows are used to calculate the scattered seismic energy densities against the source-receiver distances, which, in turn, are used to calculate separate estimates of the intrinsic and scattering factors. In order to explore the frequency dependency, the observed seismograms are band pass-filtered at the center frequencies of 0.75, 1.5, 3.0, 6.0 and 12.0. The scattering attenuation (Qs−1) is found lower than the intrinsic attenuation (Qi−1) at all frequencies except at 0.75 Hz where the opposite is observed. Overall the intrinsic attenuation dominates over the scattering attenuation in the SW Anatolia region. The integrated energy curves obtained for the first energy window (i.e., 0–15 s) are somewhat irregular with distance while the second (i.e., 15–30 s) and third (i.e., 30–45 s) data windows exhibit more regular change with distance at most frequencies. The seismic albedo B0 is determined as 0.61 at 0.75 Hz and 0.34 at 12.0 Hz while the total attenuation factor denoted by Le−1 changes in the range 0.034–0.017. For the source-station range 20–180 km considered the scattering attenuation is found strongly frequency dependent given by the power law Qs−1 = 0.010*f−1.508. The same relations for Qi−1, Qt−1 (total), Qc−1 and (expected) hold as Qi−1 = 0.0090*f−1.17, Qt−1 = 0.019*f−1.31, Qc−1 = 0.008*f−0.84 and respectively. Compared to the other attenuation factors Qc−1 and are less dependent on the frequency.  相似文献   

16.
The sorption of Eu species onto nano-size silica-water interfaces is investigated at pH range of 1―8.5 and the initial Eu concentrations (CEu) of 2×10−5, 2×10−4 and 2×10−3 M using fluorescence spectroscopy. The sorption rate of Eu is initially low, but significantly increases at pH > 4. For the initial CEu of 2×10−5, 2×10−4 and 2×10−3 M, the dissolved Eu species are completely sorbed onto silica-water interfaces at pH = 4.75, −5.8 and 6.6, respectively, with the respective sorption densities of −1.58×10−8, 1.58×10−7 and 1.58×10−6 mol/m2. The sorbed Eu species at pH < 6 is aquo Eu3+, which is sorbed onto silica-water interfaces as an outer-sphere complex at pH < 5, but may be sorbed as an inner-sphere bidentate complex at 5 < pH < 6, due to the decrease of the NH2O to −6 at pH = 6. At pH = 6 – 8, Eu(OH)2+, Eu(CO3)+and Eu(CO3)2 − form in the solutions, and Eu(CO3)+is dominant at pH = −7.5. These ions may be sorbed onto silica-water interfaces as inner-sphere bidentate complexes or multi-nuclear pre-cipitates.  相似文献   

17.
The characteristic of seismic coda wave attenuation in Yunnan area in 7 frequency-bands range from 1 Hz to 20 Hz was estimated by using the local earthquake's waveform data recorded from 22 Yunnan digital seismic stations.Coda attenuation Q-c1 of each station was firstly calculated by single scattering method. Then, mean free path Le and seismic albedo Bo of each station were calculated, and scattering attenuation Q-1s and intrinsic attenuation Q-1i were separated from total attenuation Q-1t by multiple lapse time window analysis based on the multiple scattering model in uniform random isotropic scattering medium. The attenuating characteristics in Yunnan show that most value of Le are in 10～30 km, with maximal within 2～6 Hz;Bo are about 0.5 at 1～2 Hz, but less than 0.5at other frequency-bands, which means Q-1i is comparable with Q-1s at 1～2 Hz, and after 1～2 Hz, Q-1i is greater than Q-1s and dominates the attenuation process. Q-1c is close to Q-1i at other frequency bands except 1～2 Hz.Results show that Q-1 especially Qs-1 varies spatially, Q-1 in eastern Yunnan zone is a bit higher than in northwestern Yunnan zone;northwestern Yunnan zone higher than southwestern Yunnan zone. Comparing with other results in global, Qs-1 in Yunnan is lower than the global average value among these results, Q-1i is higher than the global average value, and Q-1t lies the middle among these results.  相似文献   

18.
The study of seismic anomalies, related both to the temporal trend of aftershock sequences and to the temporal series of mainshocks, is important for an understanding of the physical processes relating to the existence and the characteristics of seismic precursors. The purpose of this work is to highlight some methodological aspects related to the observation of possible anomalies in the temporal decay of an aftershock sequence. It is realized by means of several parameters. We focused our work on an analysis of the Papua New Guinea seismic sequence that occurred on November 16, 2000. The magnitude of the mainshock is M = 8.2. The observed temporal series of shocks per day can be considered as a sum of a deterministic contribution and a stochastic contribution. If the decay can be modeled as a nonstationary Poisson process where the intensity function is equal to n(t) = K(t + c)−p + K 1, the number of aftershocks in a small time interval Δt is the mean value n(t)Δt, with a standard deviation σ = √n(t)Δt. We observe that there are some variations in seismicity that can be considered as seismic anomalies before the occurrence of a large aftershock. The data, checked according to completeness criteria, come from the website of the USGS NEIC data bank (). The text was submitted by the authors in English.  相似文献   

19.
It is shown that within the framework of the Kolmogorov model the “energy” of the pole E(t) = x 12 + x 22 can be interpreted as a Markovian process. The exact analytical expression has been obtained for the density of the conditional probability of the quantity E(t) and the problem of the first passage time of the process E(t) has been analyzed. It was shown that the available data on the swing of the function E(t) are not at variance with the Kolmogorov model and a short-period drop of the amplitude of the Chandler wobble in the early 20th century fits this model at Q = 50–200 too; values of Q > 350 are less reasonable.  相似文献   

20.
 The vesiculation of a peralkaline rhyolite melt (initially containing ∼0.14 wt.% H2O) has been investigated at temperatures above the rheological glass transition (T g≈530  °C) by (a) in situ optical observation of individual bubble growth or dissolution and (b) dilatometric measurements of the volume expansion due to vesiculation. The activation energy of the timescale for bubble growth equals the activation energy of viscous flow at relatively low temperatures (650–790  °C), but decreases and tends towards the value for water diffusion at high temperatures (790–925  °C). The time dependence of volume expansion follows the Avrami equation ΔV (t)∼{1–exp [–(t/τav) n ]} with the exponent n=2–2.5. The induction time of nucleation and the characteristic timescale (τav) in the Avrami equation have the same activation energy, again equal to the activation energy of viscous flow, which means that in viscous melts (Peclet number <1) the vesiculation (volume expansion), the bubble growth process, and, possibly, the nucleation of vesicles, are controlled by the relaxation of viscous stresses. One of the potential volcanological consequences of such behavior is the existence of a significant time lag between the attainment of a super-saturated state in volatile-bearing rhyolitic magmas and the onset of their expansion. Received: March 20, 1995 / Accepted: October 24, 1995  相似文献   

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