共查询到20条相似文献，搜索用时 31 毫秒
1.
包裹体研究──盆地流体追踪的有力工具 总被引：67，自引：5，他引：67
矿物包裹体在研究碳酸盐岩的成岩作用，恢复盆地的热演化历史，指示油气生成、运移、聚集方面取得了很大进展。矿物包裹体是盆地流体的原始样品，它记录了地质历史中盆地流体的很多信息，有效地测定各期矿物流体包裹体的均一温度，是直接了解盆地热流体活动的重要数据；系统测定各类流体包裹体的初熔温度和冰点温度，能大致判断流体的矿化类型和矿化程度；流体包裹体的ｐ－Ｖ－Ｔ－ｘ研究，是探讨流体温度、压力的依据；荧光显微镜等对有机包裹体的有效鉴别，色谱方法对流体包裹体有机和无机成分的分析能提供流体组成和烃类赋存的多种信息；特别是近年来大力发展的单个包裹体的激光拉曼光谱等探针分析，以及包裹体群的ＧＣ－ＭＳ和δ￣（１３）Ｃ、δＤ、δ￣（１８）Ｏ同位素分析在追踪盆地流体性质、成因及其与油气等矿产的关系方面将发挥愈来愈大的作用。 相似文献
2.
近年来激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)应用于单个流体包裹体成分定量分析已成为研究流体包裹体的最佳手段之一。该实验过程和数据处理比较复杂,目前国内外采用的数据分析软件为一款基于MATLAB的SILLS软件,该软件主要是对矿物(锆石)、流体包裹体以及熔体包裹体LA-ICP-MS分析结果进行处理。本文以萤石流体包裹体LA-ICP-MS分析为例,阐述了样品制备与流体包裹体的优选方法,对流体包裹体片厚度以及单个流体包裹体的选取要求作了详细描述,对仪器参数设置、内外标样选取和剥蚀方法等进行了说明。基于SILLS软件采用尖峰消除的方法对待处理数据进行校正,对不同种类型的波峰进行峰宽的选取。在元素比值校正和等效盐度计算过程中,由于被测样品是萤石,Ca元素具有较高的背景值,选择以Na作为流体包裹体的内标元素,以Ca作为寄主矿物的内标元素对寄主矿物浓度进行计算,同时提出以电价平衡代替质量平衡进行等效盐度计算。以上方案提高了LA-ICP-MS分析单个萤石流体包裹体的准确性,有助于解释成矿流体来源和矿床成因等问题。 相似文献
3.
A. M. Logvinova R. Wirth D. A. Zedgenizov L. A. Taylor 《Geochemistry International》2018,56(4):283-291
An aragonite inclusion in natural diamond was identified using techniques of transmission electron microscopy, electron microdiffraction, and microprobe analysis. The inclusion is hosted in a colorless octahedral diamond crystal from the Komslomolskaya pipe in Yakutia. The diamond crystal shows a zoned distribution of its admixtures and defects. The structure parameters of the inclusion (∠[001]/[201] = 66° and certain lattice spacings) correspond to the calculated parameters of the orthorhombic unit cell of a Ca carbonate polymorph. The aragonite inclusion contains admixtures of MgO (0.81), MnO (0.58), and FeO (0.13 wt %). The find of a syngenetic aragonite inclusion in diamond is unique and proves that diamond can be formed in carbonatized mantle peridotite at depths of at least 300 km. The inclusion hosts identifiable microphases of Ni-rich sulfides (37–41 wt % Ni), titanite, hydrous silicate, magnetite, and fluid. This association indicates that the diamond and aragonite crystallized from a carbonate–silicate–sulfide melt or highdensity fluid. 相似文献
4.
5.
A new approach, the fluid inclusion plane technique coupled with fluid inclusion microthermometry and field measurements have been applied to demonstrate the exhumation and relative vertical displacements of an allochthonous, Permian granite intrusion (Velence Mts.) which was situated in the Middle Triassic at the western end of the Neotethys rift system. The pressure and the temperature conditions during the Permian fluid flow (>350 °C and ∼2 kbar) in the granite were considerably higher than during the Triassic fluid flow (<250 °C and ∼0.5 kbar), which indicates the exhumation of the granite intrusion in a primarily extensional tectonic stress regime. The fluid inclusion planes with NE–SW and NW–SE strike prove stress field permutation that can be explained by the exhumation of the host granite during the Middle Triassic fluid flow.It is suggested that the exhumation of the Velence Mts. along with the regional fluid flow can be connected to the passive pre-rift phase of the northern Adriatic Block, during the Middle–Late Triassic. The variations in homogenization temperatures of Triassic regional fluid inclusion assemblages between the blocks of the granite, as well as variations in the fluid inclusion plane orientations, suggest a post-Triassic vertical segmentation and relative block rotation of the granite. 相似文献
6.
流体包裹体在矿床研究中的作用 总被引：20，自引：4，他引：16
流体包裹体分析是现代矿床学研究的一个重要手段,对矿床类型的划分及成矿流体成分、温度、压力的研究有着重要的作用.在矿质沉淀的主要机制中,流体相分离及流体混合的主要证据来自流体包裹体;对金属在气相中的搬运的认识,也主要来自包裹体研究.成矿流体成分对认识金属在热液中的搬运方式起着重要作用,流体温度和压力数据是成矿流体动力学模式的重要制约. 相似文献
7.
Analysis of individual fluid inclusions using synchrotron X-ray fluorescence microprobe: progress toward calibration for trace elements 总被引：1，自引：0，他引：1
Bénédicte Ménez Pascal PhilippotMichelle Bonnin-Mosbah Alexandre SimionoviciFrançois Gibert 《Geochimica et cosmochimica acta》2002,66(4):561-576
A critical problem for conducting quantitative analysis of individual fluid inclusions using Synchrotron X-Ray Fluorescence (SXRF) technique relates to the standardization and the calibration of the X-ray spectra. In this study, different approaches have been tested for calibration purposes: (a) the use of chlorine when Cl content can be estimated either from melting point depressions of undersaturated fluid inclusions or from saturation limits for halite-bearing fluid inclusions, (b) the use of calcium from synthetic fluid inclusions of known CaCl2 content as an external standard. SXRF analysis was performed on individual fluid inclusions from the Chivor and Guali emerald deposits, Columbia. These well-known samples contain a single fluid inclusion population for which detailed crush-leach analyses are available, thus providing a relevant compositional reference frame. Concentration estimates were also compared to Particle Induced X-ray Emission (PIXE) analysis carried out independently on the same fluid inclusions.Results of the calibration tests indicate that major (Cl, K, Ca, Fe, Mn) and trace element (Cu, Zn, As, Br, Rb, Sr, Ba, Pb) concentration estimates can be performed without precise knowledge of the analytical volume and the inclusion’s 3D geometry. Although the standard deviation of the SXRF results can be relatively high depending on the calibration mode used, mean concentration estimates for most elements are in good agreement with PIXE and crush-leach analysis. Elemental distributions within single fluid inclusions were also established. Associated correlation diagrams argue for the homogeneous distribution of most elements in the fluid inclusion. In contrast, Br shows a bimodal distribution interpreted to reflect a significant enrichment of the vapor portion of the inclusion fluid. 相似文献
8.
莺—琼盆地1号断裂带含烃热流体活动初探 总被引：3，自引：1，他引：2
１号断裂带是莺－琼盆地油气勘探的重点地区之一,有机包裹体研究有助于追踪油气及热流体活动的痕迹,为油气运聚成藏提供地球化学依据,通过包裹体薄片镜下观察,均一温度和盐度测试,认为工区内发育五种类型的有机包裹体：（１）液态烃包裹体;（２）气流态烃包裹体;（３）气态烃包裹体;（４）含烃ＣＯ２包裹体;（５）烃子矿物包裹体,含烃ＣＯ２包裹体一般与气态烃共生,含烃子矿物包裹体既无液态烃共生又与气态烃共生,包裹体 相似文献
9.
流体包裹体研究对成矿流体动力学模式的制约 总被引：1，自引：0，他引：1
热液矿床的形成既包括地球化学过程也包括流体动力学过程,后者主要研究成矿流体的驱动力、流动方向、速度及持续时间。流体及金属的来源,金属在热液中的溶解度及溶解机制,以及矿石的沉淀机制等可以通过多种地球化学手段来研究,而流体动力学过程的确定相对比较困难。流体包裹体分析不仅可以为成矿地球化学过程,而且可为流体动力学过程提供制约,因为流体包裹体研究所得到的流体P-V-T-X性质与流体流动、热传导及质量迁移等控制方程直接相关。本文阐述流体包裹体与流体动力学研究的理论关系,流体包裹体研究对已有成矿流体动力学模式的贡献,以及未来的研究方向。从流体包裹体研究得出的流体压力状态为岩浆热液及造山型成矿系统的超压驱动模式提供了关键的证据。流体包裹体均一温度及其分布为沉积盆地成矿流体动力学模式提供了重要的制约。流体包裹体研究在揭示流体混合及流体相分离等重要成矿过程方面提到了至关重要的作用,但它们在研究流体混合及多相流体流动的物理过程方面的潜力有待进一步开发。精心设计的流体包裹体研究有可能应用于古流体流动数值模型的调试。 相似文献
10.
地幔流体及其成矿作用 总被引：8，自引：0，他引：8
高灵敏度、高精密度、低检出限、多元素同时检测并可提供同位素组成比值信息的等离子体质谱与高空间分辨率的紫外激光采样技术结合 ,可定量地测定单个流体包裹体中常、微量元素含量 ,为成矿流体的研究提供了一个新的研究手段。文中简要地介绍了激光剥蚀电感耦合等离子体质谱 (LA ICP MS)分析仪器的发展 ,结合实验室的研究工作 ,就激光剥蚀池的设计、单个流体包裹体的剥蚀方法、元素的分馏效率、定量校正技术及其在成矿成因物理化学机制研究中的应用等进行评述 ,并阐述单个流体包裹体元素组成的LA ICP MS分析技术存在的局限和发展趋势。 相似文献
11.
Darren F. Mark John Parnell Simon P. Kelley Sarah C. Sherlock 《Journal of Geochemical Exploration》2006,89(1-3):259
Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data. 相似文献
12.
George D. Miron Thomas Wagner Markus Wälle Christoph A. Heinrich 《Contributions to Mineralogy and Petrology》2013,165(5):981-1008
The chemical composition of fluid inclusions in quartz crystals from Alpine fissure veins was determined by combination of microthermometry, Raman spectroscopy, and LA-ICPMS analysis. The veins are hosted in carbonate-bearing, organic-rich, low-grade metamorphic metapelites of the Bündnerschiefer of the eastern Central Alps (Switzerland). This strongly deformed tectonic unit is interpreted as a partly subducted accretionary wedge, on the basis of widespread carpholite assemblages that were later overprinted by lower greenschist facies metamorphism. Veins and their host rocks from two locations were studied to compare several indicators for the conditions during metamorphism, including illite crystallinity, graphite thermometry, stability of mineral assemblages, chlorite thermometry, fluid inclusion solute thermometry, and fluid inclusion isochores. Fluid inclusions are aqueous two-phase with 3.7–4.0 wt% equivalent NaCl at Thusis and 1.6–1.7 wt% at Schiers. Reproducible concentrations of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, B, Al, Mn, Cu, Zn, Pb, As, Sb, Cl, Br, and S could be determined for 97 fluid inclusion assemblages. Fluid and mineral geothermometry consistently indicate temperatures of 320 ± 20 °C for the host rocks at Thusis and of 250 ± 30 °C at Schiers. Combining fluid inclusion isochores with independent geothermometers results in pressure estimates of 2.8–3.8 kbar for Thusis, and of 3.3–3.4 kbar for Schiers. Pressure–temperature estimates are confirmed by pseudosection modeling. Fluid compositions and petrological modeling consistently demonstrate that chemical fluid-rock equilibrium was attained during vein formation, indicating that the fluids originated locally by metamorphic dehydration during near-isothermal decompression in a rock-buffered system. 相似文献
13.
Research on fluid inclusions of the Yinshan polymetallic deposit, Jiangxi Province, China 总被引：1，自引：0，他引：1
In this paper some new advances in the study of fluid inclusions of the Yinshan deposit in Jiangxi Province,China,are presented.The fluid inclusions of the deposit can be divided into four types:1) gas-rich inclusions;2)liquid-rich inclusions;3)salt-saturated H2O inclusions;and 4)single-phase or multiphase CO2-rich inclusions.Homogenization temperatures of the fluid inclusions range from 100 to 520℃,aminly in the range 120-400℃.The daughter crystal-bearing multiphase inclusions present in quartz porphyries(including Nos.13 and 4 dikes)have been observed.In ore veins,some daughter crystal-bearing multiphase inclusions have been observed.too.On the basis of the results of fluid inclusion research,the authors suggest that the ore-forming fluid must have a close genetic relation to magmatic hydrothermal solution.The ore-forming fluid was dominantly originated from the depth and the mixing of magmatic solution with meteoric water was enhanced during ascending of the fluid,accompanying immiscibility and boiling of fluid.Teher may be a conceales igneous body at the depth of the Yinshan deposity,which furnishes the scientific basis for metallogenic prognosis at th depth of the Yinshan deposit. 相似文献
14.
Petroleum inclusions in sedimentary basins: systematics, analytical methods and applications 总被引：21，自引：0，他引：21
Fluid dynamics in sedimentary basins is of tremendous interest, both from a scientific and an economic point of view. Integration between fluid inclusion and present-day fluid data provides the time aspect necessary for reconstruction of fluid flow paths, and can be used for mapping fluid dynamics both on a regional basin scale or on the more local scale of petroleum reservoirs. This paper presents a review of analytical and modelling methods for petroleum in fluid inclusions. Essentially, four types of data for petroleum inclusions can be established through analysis and modelling: (1) textures (which give indirect information of the time aspect), (2) fluid composition, (3) fluid properties and (4) pressure–temperature of trapping. During the last decade, development of analytical methods for determination of inclusion fluid compositions has taken place. Traditional correlation studies for characterisation of maturity and source facies may now therefore include fluid inclusion data. The development has also been directed towards an improved understanding of the physical properties of petroleum inclusions. Although these methods are in their early stages concerning precision and accuracy, data necessary for fluid flow modelling, such as fluid densities, viscosities, pressure and temperature, can be estimated. 相似文献
15.
拉曼光谱在矿物包裹体成分研究中的应用近年来已有一些报导,而在国内则刚刚开始。 通过矿物包裹体成分的分析可以获得成矿溶液的化学组成及有关的物理化学参数,这是矿床研究的宝贵资料。但是,矿物包裹体极其细小,一般只有几微米到几十微米。样品提取十分困难,且忌污染,分析是超微量的。目前,所采用的破坏性包裹体成分分析方法存在的一些难以克服的缺点影响了分析结果的解释和应用。其缺点是:(1)不能区分原生包裹体和次生包裹体,提供的分析 相似文献
16.
研究与成藏过程相关的古流体活动有助于深入认识油气成藏过程,从经济目的出发预测储层质量,精确分析不同阶段古流体活动对油气成藏的影响具有重要意义。目前国内外石油地质学家主要利用同位素地球化学、元素地球化学、流体包裹体分析等无机地球化学方法分析古流体活动特征及其对油气成藏的影响。在归纳前人研究成果的基础上,总结了各种无机地球化学方法的最新研究进展,认为同位素地球化学方法有助于分析古流体来源与成因,元素地球化学方法可示踪烃类流体的运移,流体包裹体分析技术结合岩相学研究可分析油气运移的时间、期次、相态、通道和油气藏的富集规律,并指出油气运移和聚集的有利方向。在运用无机地球化学方法研究古流体活动时不应局限于单一方法,综合利用多种无机地球化学方法更有利于全面分析古流体活动特征。 相似文献
17.
Masanori Kurosawa Sadayoshi Shimano Kunihiro Shima 《Geochimica et cosmochimica acta》2003,67(22):4337-4352
Single fluid inclusion analogues with known elemental composition and regular shape were analyzed for trace element contents by particle-induced X-ray emission (PIXE)—a nondestructive method for the analysis of single fluid inclusions—to evaluate the accuracy and detection limits of this type of analysis. Elements with concentrations of 10 to 1000 ppm were measured with average estimated relative error of ±7%. For natural fluid inclusions with 30 μm radius and 20 μm depth in quartz, the total analytical errors were estimated to be ±40% relative for Ca, ±16% for Fe, ±13% for Zn, ±12% for Sr, and ±11% for Br and Rb, by considering uncertainties in microscopic measurements of inclusion depths. Detection limits of 4 to 46 ppm for elements of mass numbers 25-50 were achieved for analyses of a spherical fluid inclusion with 30 μm radius and 20 μm depth in quartz, at an integrated charge of 1.0 μC. The trace element compositions of single fluid inclusions in a hydrothermal quartz crystal were also determined. The elemental concentrations in the inclusions varied widely: 0.2-9 wt.% for Ca and Fe, 300-8000 ppm for Mn and Zn, 40-3000 ppm for Cu, 100-4000 ppm for Br, Rb, Sr, and Pb, and less than 100 ppm for Ge. Elemental concentrations of secondary fluid inclusions on the same trail varied over an order of magnitude, even though all these inclusions were formed from the same fluid. Elemental concentrations in inclusions on the same trail are positively correlated with each other, except for Cu and Rb. Ratios of almost all elements in the inclusions on the trail were essentially unchanged; thus, the elemental ratios can provide original information on trace element compositions of a hydrothermal fluid. 相似文献
18.
江西省全南县大吉山钨矿成矿流体演化特征 总被引：20，自引：1，他引：19
大吉山钨矿位于南岭W、Sn成矿省,是我国著名的大型W矿床。本文旨在通过对大吉山脉形钨矿2513号脉中的包裹体进行详细的岩相学及显微测温学研究,对成矿流体的演化过程及矿床形成深度进行探讨。包裹体的岩相学研究表明,包裹体类型复杂主要由富液包裹体、含CO2、CH4三相包裹体及含子矿物包裹体组成;包裹体组合复杂,各种类型的包裹体常叠加在一起;原生、次生包裹体产状区别明显,较易识别,原生包裹体主要由含CO2、CH4三相包裹体及充填度较小的富液包裹体组成,次生包裹体主要为充填度较大的富液包裹体。显微测温分析发现不同类型的包裹体的盐度、均一温度差别显著,呈现复杂的流体演化过程。包裹体的爆裂曲线显示,曲线有高低温两个起爆点,分别对应原次生包裹体包裹体群的起爆温度;由深部到浅部,原生包裹体的起爆温度逐渐降低。利用显微共焦激光拉曼探针仪对原生包裹体进行成分分析发现,成矿流体主要由H2ONaCl和H2OCO2CH4NaCl体系组成。包裹体的显微测温结果显示,成矿流体演化经历了自然冷却、不混溶作用和混合作用等过程,各种过程相互作用造成了钨的沉淀。通过对不混溶包裹体的测温数据进行计算,得出大吉山脉型钨矿成矿流体的压力约为114～132MPa,矿床形成深度约为4.6～5.3km。 相似文献
19.
Fluid inclusion petrography 总被引：32，自引：0，他引：32
20.
Fluid inclusions in sedimentary and diagenetic systems 总被引：25，自引：0，他引：25
Some of the major problems in sedimentary geology can be solved by using fluid inclusions in sedimentary and diagenetic minerals. Important fluids in the sedimentary realm include atmospheric gases, fresh water of meteoric origin, lake water, seawater, mixed water, evaporated water, formation waters deep in basins, oil, and natural gas. Preserving a record of the distribution and composition of these fluids from the past should contribute significantly to studies of paleoclimate and global-change research, is essential for improving understanding of diagenetic systems, and provides useful information in petroleum geology. Applications of fluid inclusions to sedimentary systems are not without their complexities. Some fluid inclusions exposed to natural conditions of increasing temperature may be altered by thermal reequilibration, which results in stretching, or leakage and refilling, of some fluid inclusions. Similarly, overheating in the laboratory can also cause reequilibration of fluid inclusions, so fluid inclusions from the sedimentary realm must be handled carefully and protected from overheating. Natural overheating of fluid inclusions must be evaluated through analysis of the most finely discriminated events of fluid inclusion entrapment, fluid inclusion assemblages (FIA). Consistency in homogenization temperatures within a fluid inclusion assemblage, consisting of variably sized and shaped inclusions, is the hallmark of a data set that has not been altered through thermal reequilibration. In contrast, fluid inclusion assemblages yielding variable data may have been altered through thermal reequilibration. If a fluid inclusion assemblage has not been altered by thermal reequilibration, its fluid inclusions may be useful as geothermometers for low- and high-temperature systems, or useful as geobarometers applicable throughout the sedimentary realm. If a fluid inclusion assemblage has been altered partially by thermal reequilibration, techniques for distinguishing between altered and unaltered fluid inclusions may be applied.
In studies of global change, fluid inclusions can be used as sensitive indicators of paleotemperature of surface environments. Fluid inclusions also preserve microsamples of ancient seawater and atmosphere, the analysis of which could figure prominently into discussions of past changes in chemistry of the atmosphere and oceans. In petroleum geology, fluid inclusions have proven to be useful indicators of migration pathways of hydrocarbons; they can delineate the evolution of the chemistry of hydrocarbons; and they remain important in understanding the thermal history of basins and relating fluid migration events to evolution of reservoir systems. In studies of diagenesis, fluid inclusions can be the most definitive record. Most diagenetic systems are closely linked to temperature and salinity of the fluid. Thus, fluid inclusions are sensitive indicators of diagenetic environments. 相似文献