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1.
The distribution of the natural radionuclide 210Po in the water column along a horizontal transect of the continental shelf, slope and deep basin regions of the East Sea (Sea of Japan), a marginal sea of the Northwest Pacific Ocean, was investigated, and its behavior is described here. The settling fluxes of particulate 210Po in the deep basin along with 210Pb, 234Th and biogenic matter were also determined. 210Po inventories in the water column were observed to decrease from winter to summer in all stations, probably due to increased influx of 210Po-poor Kuroshio Water of the Northwest Pacific Ocean during summer. Vertical profiles of dissolved and particulate 210Po along with the settling fluxes of particulate 210Po in the deep basin station have enabled us to evaluate temporal variations and residence times of 210Po. In the slope and basin, activities of dissolved 210Po generally decreased from the surface to the bottom water, with maximum activity just below the subsurface chlorophyll a maximum at 50–75 m depth in spring and summer. These subsurface peaks of dissolved 210Po activity were attributed to the release of 210Po from the decomposition of 210Po-laden biogenic particulate organic matter. In the deep basin, despite the decrease in total mass flux, the sinking flux of particulate 210Po was higher in the deeper trap (2000 m) than in the shallower one (1000 m), probably due to scavenging of dissolved 210Po from the water column during particle descent and/or break-down of 210Po-depleted particulate matter between 1,000 m and 2,000 m depths. In general, the ratios of the particulate phase to the dissolved phase of 210Po (Kd) increased with depth in the slope and basin stations. 210Po removal from the water column appears to depend on the primary productivity in the upper waters. There is an inverse relationship between Kd and suspended particulate matter (SPM) concentration in the water column. From the 210Po activity/chlorophyll a concentration ratios, it appears that sinking particles arriving at 1000 m depth were similar to those in the surface waters.  相似文献   

2.
Anthropogenic 90Sr, 239,240Pu and 241Am were used as tracers of water mass circulation in the Crozet Basin of the South Indian Ocean, represented by three main water fronts—Agulhas (AF), Subtropical (STF) and Subantarctic (SAF). Higher 90Sr concentrations observed north of 43°S were due to the influence of AF and STF, which are associated with the south branch of the Subtropical gyre, which acts as a reservoir of radionuclides transported from the North to the South Indian Ocean. On the other hand, the region south of 43°S has been influenced by SAF, bringing to the Crozet Basin Antarctic waters with lower radionuclide concentrations. The 238Pu/239,240Pu activity ratios observed in water and zooplankton samples indicated that, even 35 years after the injection of 238Pu to the Indian Ocean from the burn-up of the SNAP-9A satellite, the increased levels of 238Pu in surface water and zooplankton are still well visible. The radionuclide concentrations in seawater and their availability to zooplankton are responsible for the observed 210Po, 239,240Pu and 241Am levels in zooplankton.  相似文献   

3.
Ag, Al, Ca, Cd, Cu, Fe, Mg, Mn, Pb and Zn concentrations and 210Po and 210Pb activities were measured in 26 specimens of the squid Nototodarus gouldi taken from the waters of Bass Strait in one jigging operation. All the elements show wide ranges in concentrations in specimens apparently subject to the same environmental conditions. Copper concentration was 27-1 200 μg/g, and 210Po activity 4·8–24·2 Bq/g. The animal wet weights, the elements Ag, Al, Cd, Fe and Zn, and the radionuclide 210Po have coefficients of variation in the range 40–60%; Ca, Mg and Mn show the smallest variability (CV = < 30%), and Cu the greatest (CV = 12%). Significant correlations (p < 0·001) were found between the following pairs of elements: Cd-Zn, Cd-Cu, Zn-Cu, Mg-Mn, Fe-Mn, Ca-Mg and Fe-210Po.  相似文献   

4.
-The applicability of the doubie-layer model for 210Pb chronology in coastal marine environments was discussed,which is successfully used in the study of mixing rates and sedimentation rates in Meizhou Bay. Differences among sedimentation rates deduced from 210Pb, 210Po, and 137Cs were compared. Mixing rates in the sediment surface layer were determined by means of excess 234Th.  相似文献   

5.
The disequilibrium between 210Po and its grandparent 210Pb has been proposed as a tracer of the vertical flux of sinking particulate organic matter in the ocean. The mechanism of association between 210Po and organic matter is, however, still unclear. To investigate this association we measured trace metals, minerals, organic carbon, nitrogen, and the natural radioisotopes 234Th, 228Th, 210Po, and 210Pb in sinking particles collected in sediment traps at 200 m in the northwestern Mediterranean. Pigments, fatty acids, and amino acids were used to identify the types and sources of particulate organic matter. Multivariate analyses were used to determine which components of sinking particulate matter are traced by 210Po and/or by the 210Po/210Pb ratio. Statistical analysis of the results indicates that the distribution of polonium in sinking marine particles is influenced by fresh phytoplankton-derived, nitrogen-rich organic matter as well as sulfur-containing amino acids. These findings are consistent with previous laboratory observations that the distribution of 210Po in biota parallels the distributions of both sulfur and protein, and indicate that these associations persist as material sinks through the water column. While this research generally supports the use of 210Po as a specific tracer of the flux of organic matter, the signals traced by 210Po/210Pb and 234Th/238U are not as distinct in the field as in laboratory experiments. Further work is needed to determine more precisely what 210Po/210Pb traces in order to increase the correspondence of 210Po/210Pb measurements to biogeochemically important rates and quantities.  相似文献   

6.
This article summarizes the author's work on210Pb and210Po distributions in the marine environment for which the Okada Prize of the Oceanographical Society of Japan was awarded. In this review, the work of other investigators and the studies now going on are also included. The210Pb concentration in the surface water of the ocean is controlled by the atmospheric flux of210Pb and productivity. The disequilibrium between226Ra and210Pb in the deep sea reveals that the oceanic residence time of lead is less than a hundred years rather than of the order of thousands of years as thought before based on stable lead measurement in ocean water. Particulate removal of210Pb from the water column is likely to be the major cause of the deficiency of210Pb in the water, however more investigations would be needed to clarify the detailed removal mechanism of210Pb. The experiments on particulate flux by using sediment traps will provide an unique opportunity to examine this. 210Pb in excess of226Ra in sediment is useful for geochronology of shallow water sediments and the study on bioturbation rates on the deep sea sediments.  相似文献   

7.
Vertical profiles of dissolved and particulate 210Po and 210Pb were measured across the redox transition zone at Station F1 in Framvaren Fjord, Norway. In this fjord, a sharp decrease in pH above the O2/H2S interface facilitates the aerobic dissolution of MnO2. In contrast, Fe(II) concentrations begin to increase only at the O2/H2S interface depth. Activity profiles reveal that dissolved 210Po and 210Pb are sequestered efficiently by particulates in surface waters. As polonium-210 and lead-210 activities descend down into the aerobic manganese reduction (AMR) zone, they are remobilized during the reductive dissolution of the carrier phase oxyhydroxides. Both 210Po and 210Pb are highly enriched at the O2/H2S interface where an active community of microbes, such as anoxygenic phototrophs (e.g., Chromatium, Chlorobium sp.), thrives. The coincident peaks in 210Po, 210Pb and microbial biomass suggest a strong biological influence on the behavior of these radionuclides. There is a strong covariance between the vertical distribution of Mn and Pb, indicating that their redox cycling is closely coupled and is likely microbially mediated.  相似文献   

8.
234Th (T1/2=24.1 d) and 210Po (T1/2=138.4 d) are particle reactive radioisotopes that are used as tracers for particle cycling in the upper ocean. Particulate organic carbon (POC) export has frequently been estimated using 234Th/238U disequilibrium. Recent evidence suggests that 210Po/210Pb disequilibrium may be used as an additional tool to examine particle export, given the direct biological uptake of 210Po into cellular material. Differences in these two radioisotope pairs with regard to their half-lives, particle reactivity and scavenging affinity in seawater should provide complementary information to be obtained on the processes occurring in the water column. Here, we review eight different studies that have simultaneously used both approaches to estimate POC export fluxes from the surface ocean. Our aim is to provide a complete “dataset” of all the existing POC flux data derived from the coupled use of both 234Th and 210Po and to evaluate the advantages and limitations of each tracer pair. Our analysis suggests that the simultaneous use of both radiotracers provides more useful comparative data than can be derived from the use of a single tracer alone. The difference in half-lives of 234Th and 210Po enables the study of export production rates over different time scales. In addition, their different biogeochemical behaviour and preferred affinity for specific types of particles leads to the conclusion that 234Th is a better tracer of total mass flux, whereas 210Po tracks POC export more specifically. The synthesis presented here is also intended to provide a basis for planning future sampling strategies and promoting further work in this field to help reveal the more specific application of each tracer under specific water column biogeochemistries.  相似文献   

9.
U–Th decay series isotopes, δ18O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ18O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. 234Th and 210Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l−1). 228Ra and 226Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, 210Pb and 210Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. 232Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor.  相似文献   

10.
为揭示中国东南沿海地区210Po和210Pb的大气沉降时空变化特征,探讨该地区气溶胶的停留时间,于2013年1月至2014年12月对厦门地区210Po和210Pb的大气沉降通量进行了时间序列研究。结果发现,210Po和210Pb的平均日沉降通量分别为(65.38±4.79) mBq/(m2·d)(n=54)和(0.78±0.09) Bq/(m2·d)(n=54),表现出明显的周年变化。东北季风期间,210Po和210Pb的沉降通量较高,而西南季风期间其通量较低。2013年和2014年,210Po的年沉降通量分别为19.29 Bq/(m2·a)和9.25 Bq/(m2·a),210Pb的年沉降通量分别为159.2 Bq/(m2·a)和189.6 Bq/(m2·a)。两核素的年沉降通量表现出不同程度的年际差异。210Po与210Pb沉降通量之间存在显著的线性正相关关系,揭示了大气中210Po和210Pb具有相同的迁出机制,降雨和大气中核素含量是影响210Po和210Pb沉降通量的主要因素。该研究结果可以为探求台湾海峡海水中210Po与210Pb的收支平衡提供大气来源项。  相似文献   

11.
Quantifying relative affinities of Po and Pb in different populations of marine particulate matter is of great importance in utilizing 210Po as a tracer for carbon cycling. We collected and analyzed water samples for the concentrations of dissolved and total 210Po and 210Pb from the upper 600 m of the water column at Bermuda Time-series Study site (September 1999–September 2000) to investigate their seasonality of concentrations and their activity ratio (210Po/210Pb activity ratio, AR). Sinking particles collected in sediment traps at depths of 500 m, 1500 m, and 3200 m from the Oceanic Flux Program (OFP) time-series sediment traps were analyzed over a period of 12 months (May 1999–May 2000). The objective was to compare the deficiencies of 210Po with respect to 210Pb in the water column to that measured in the sediment traps and to assess the relative affinities of Po and Pb with different particle pools.Inventories of 210Po in the upper 500 m water column varied by a factor of 2, indicating seasonal variations of particulate flux dominated the removal of 210Po. The 210Po/210Pb ARs in the dissolved phase were generally less than the secular equilibrium value (1.0) in the upper 600 m, while were generally greater than 1.0 in the particulate phase, indicating higher removal rates of 210Po relative to 210Pb by particulate matter. The measured fluxes of 210Po and 210Pb in the 500 m, 1500 m, and 3200 m traps increased with depth, while the 210Po/210Pb ARs decreased with depth except from May–August 1999. From the measured fluxes of 210Po and 210Pb at these three traps and the concentrations of 210Po and 210Pb in the water column, this region appears to be a sink for 210Pb which is likely brought-in by lateral advection.  相似文献   

12.
Activities of 210Po and concentrations of the chalcogen elements S and Se, were measured in muscle, stomach, gill, and hepatopancreas tissues of two groups of the common squid, Todarodes pacificus, from common spawning grounds but different feeding grounds: The Yellow Sea and the East/Japan Sea. All elements displayed lowest concentrations in the muscle tissues, but while S was highest in stomach and gills tissues, Se and 210Po were highest in hepatopancreas tissues, probably due to compartmentalization based on their toxicity. Whole body burden calculations based on organ weight contributions confirmed that the majority of the squids total S is contributed by the muscle while the majority of 210Po is contributed by the hepatopancreas. Overall, squids from the East/Japan Sea displayed significantly higher 210Po activities than those from the Yellow Sea, in line with previous reports on higher activities of dissolved 210Po in the water column of the former compared to the latter, which likely affects bioaccumulation by the foodweb. Tissue-based correlation patterns of the three chalcogens with each other and with the toxic heavy metal Cd suggest S- and Se-containing detoxifying mechanisms for 210Po and Cd in stomach and gills, but not in the hepatopancreas, which supports previous hypotheses that both 210Po and Cd could be bound to S- and Se-depleted compounds in the squid hepatopancreas.  相似文献   

13.
在2011年丰水期(7月)和2012年枯水期(3月),分别对钦州湾的内湾和外湾开展了浮游动物调查,研究了枯水期和丰水期钦州湾浮游动物的种类组成、数量分布和季节变化特征。丰水期和枯水期浮游动物种类数量分别为27种和44种,以优势度指数Y0.02确定的优势种丰水期和枯水期分别为3种和4种。丰水期浮游动物丰度为4.0~133.6ind/m3,平均丰度为50.9ind/m3;枯水期浮游动物丰度为1.2~1 725.0ind/m3,平均丰度为272.2ind/m3。丰水期浮游动物(包含鱼卵仔鱼)生物量为1.7~179.2mg/m3,平均生物量为44.0mg/m3;枯水期浮游动物(包含鱼卵仔鱼)生物量为3.1~3 530.0mg/m3,平均生物量为474.9mg/m3。无论是浮游动物的种类数量、丰度和生物量,均显示出内湾低于外湾的空间分布特征,以及枯水期高于丰水期的变化特征。钦州湾浮游动物的这种季节变化和空间分布特征主要是与浮游植物生物量、贝类养殖、环境的稳定度以及人为干扰等有着密切的关系。  相似文献   

14.
Relationship between atmospheric deposition fluxes and concentrations of Si and210Po in the surface air were examined through daily basis simultaneous observation at the coast of the Japan Sea. Both the Si and210Po, the atmospheric fluxes were highly variable from day to day. According to correlation analysis, there was no significant correlation between flux and atmospheric concentration of these terrigenous materials in the surface air. On the other hand, flux of Si and210Po significantly correlated to precipitation rate. These results indicate that the atmospheric flux of terrigenous material is not constantly proportional to atmospheric concentration in the surface air. This may be due to the deposition flux represents an integrated value throughout the air column of in-and below-cloud, while the air concentration represents only the environment of earth's surface.  相似文献   

15.
234Th (T1/2=24.1 d) and 210Po (T1/2=138.4 d) are particle reactive radioisotopes that are used as tracers for particle cycling in the upper ocean. Particulate organic carbon (POC) export has frequently been estimated using 234Th/238U disequilibrium. Recent evidence suggests that 210Po/210Pb disequilibrium may be used as an additional tool to examine particle export, given the direct biological uptake of 210Po into cellular material. Differences in these two radioisotope pairs with regard to their half-lives, particle reactivity and scavenging affinity in seawater should provide complementary information to be obtained on the processes occurring in the water column. Here, we review eight different studies that have simultaneously used both approaches to estimate POC export fluxes from the surface ocean. Our aim is to provide a complete “dataset” of all the existing POC flux data derived from the coupled use of both 234Th and 210Po and to evaluate the advantages and limitations of each tracer pair. Our analysis suggests that the simultaneous use of both radiotracers provides more useful comparative data than can be derived from the use of a single tracer alone. The difference in half-lives of 234Th and 210Po enables the study of export production rates over different time scales. In addition, their different biogeochemical behaviour and preferred affinity for specific types of particles leads to the conclusion that 234Th is a better tracer of total mass flux, whereas 210Po tracks POC export more specifically. The synthesis presented here is also intended to provide a basis for planning future sampling strategies and promoting further work in this field to help reveal the more specific application of each tracer under specific water column biogeochemistries.  相似文献   

16.
Myctophids are among the most abundant fishes in the world׳s ocean and occupy a key position in marine pelagic food webs. Through their significant diel vertical migrations and metabolism they also have the potential to be a significant contributor to carbon export. We investigated the feeding ecology and contribution to organic carbon export by three myctophid species, Benthosema glaciale, Protomyctophum arcticum, and Hygophum hygomii, from a structurally and ecologically unique ecosystem- the Mid-Atlantic Ridge (MAR). Similar to the results of previous studies, the diet of these fishes was primarily copepods and euphausiids, however, gelatinous zooplankton was identified in the diet of B. glaciale for the first time. Ridge section and time of day were significant explanatory variables in the diet of B. glaciale as determined by canonical correspondence analysis, while depth was the only significant explanatory variable in the diet of P. arcticum. Daily consumption by MAR myctophids was less than 1% of dry body weight per day and resulted in the removal of less than 1% of zooplankton biomass daily. Although lower than previous estimates of carbon transport by myctophids and zooplankton in other areas, MAR myctophid active transport by diel vertical migration was equivalent to up to 8% of sinking particulate organic carbon in the North Atlantic. While highly abundant, myctophids do not impart significant predation pressure on MAR zooplankton, and play a modest role in the active transport of carbon from surface waters.  相似文献   

17.
海南岛近岸海域夏初浮游动物与环境因子的关系   总被引:4,自引:1,他引:3  
根据2011年夏初在海南岛近岸海域采集的浮游动物样本,分析了该海域浮游动物的种类组成、优势种类、丰度、生态类群,生物多样性及均匀度,并对浮游动物与环境因子之间的关系进行了探讨。海南岛近岸海域共鉴定出终生性浮游动物164种,阶段性浮游幼体11个类群,其中以桡足类的种类最多,40属82种。优势种主要有棘皮动物幼体Echinodermata larva、鸟喙尖头溞Penilia avirostris、异体住囊虫Oikopleura dioica、长尾类幼体Macrura larva、肥胖软箭虫Ferosagitta enflata、羽长腹剑水蚤Oithona plumifera、小齿海樽Doliolum denticulatum、中型莹虾Lucifer intermedius、泡抱球虫Globigerina bulloides、微驼隆哲水蚤Acrocalanus gracilis等。海南岛近岸海域浮游动物丰度平均值为1 348.68ind/m3,东部海域浮游动物丰度最高,由近岸向远岸呈递减趋势,而北部湾海域和南部海域由近岸向远岸则呈先增后减的趋势。夏初由于受沿岸流和南海暖流的影响,海南岛近岸海域的生态类群以暖水沿岸种和广布暖水外海种为主。浮游动物多样性指数和均匀度平均值为3.03和0.72,东部海域的多样性指数和均匀度较低,主要原因是阶段性浮游幼体的偶然性暴发。相关性分析显示,海南岛近岸海域浮游动物丰度与pH值呈极显著负相关(p0.05,r=-0.360);与浮游植物丰度(PA)呈极显著正相关(p0.01,r=0.395);与盐度、DO、CODMn、NO3-N浓度、NH4-N浓度、PO4-P浓度成正相关,与温度、NO2-N浓度、SiO3-Si浓度呈负相关。  相似文献   

18.
Sediment trap experiments were carried out in two oceans, the eastern Pacific Ocean and the Antarctic Ocean, which have very different biological productivities. The natural radionuclides,234Th,210Po and210Pb were used as tracers of reactive metals. Larger particulate fluxes of these radionuclides were found in the seas where total mass fluxes were larger, although the concentrations of these radionuclides in the settling particles were somewhat smaller. The concentrations of234Th in the settling particles varied widely and irregularly with depth, whereas the concentrations of210Po and210Pb in the settling particles steadily increased with increasing water depth. The ratios of210Po/210Pb in the settling particulates were larger than unity which the ratio of234Th/excess210Po as larger than234Th/210Po in the deep water. These results suggest that, when the particles sink through the water column, these radionuclides are being absorbed by settling particles in the order234Th>210Po>210Pb. The observed particulate fluxes of210Pb are about one eighth of those calculated from the disequilibria between226Ra and210Pb at the stations in the subtropical eastern Pacific, although the observed fluxes are the same as the calculated ones in the northern North Pacific and the Antarctic Ocean. Thus, there must be a horizontal flow carrying these reactive metals from the oligotorophic ocean to the biologically productive ocean where the metals are removed by settling particles even in deep water.  相似文献   

19.
Export processes play a major role in regulating global marine primary production by reducing the efficiency of nutrient cycling and turnover in surface waters. Most studies of euphotic zone export focus on passive fluxes, that is, sinking particles. However, active transport, the vertical transfer of material by migrating zooplankton, can also be an important component of carbon (C) and nitrogen (N) removal from the surface ocean. Here we demonstrate that active transport is an especially important mechanism for phosphorus (P) removal from the euphotic zone at Station ALOHA (Hawaii Ocean Time-series program; 22°45′N, 158°W), a P-stressed site in the North Pacific Subtropical Gyre. Migrant excretions in this region are P-rich (C51:N12:P1) relative to sinking particles (C250:N31:P1), and migrant-mediated P fluxes are almost equal in magnitude (82%) to P fluxes from sediment traps. Migrant zooplankton biomass and therefore the importance of this P removal pathway relative to sinking fluxes has increased significantly over the past 12 years, suggesting that active transport may be a major driving force for enhanced P-limitation of biological production in the NPSG. We further assess the C:N:P composition of zooplankton size fractions at Station ALOHA (C88:N18:P1, on average) and discuss migrant-mediated P export in light of the balance between zooplankton and suspended particle stoichiometries. We conclude that, because active transport is such a large component of the total P flux and significantly impacts ecosystem stoichiometry, export processes involving migrant zooplankton must be included in large-scale efforts to understand biogeochemical cycles.  相似文献   

20.
Particle export from the upper waters of the oligotrophic ocean may play a crucial role in the global carbon cycle. Mesoscale eddies have been hypothesized to inject new nutrients into oligotrophic surface waters, thereby increasing new production and particle export in otherwise nutrient deficient regimes. The E-Flux Program was a large multidisciplinary project designed to investigate the physical, biological and biogeochemical characteristics of cold-core cyclonic eddies that form in the lee of the Hawaiian Islands. There, we investigated particle dynamics using 210Pb–210Po disequilibrium. Seawater samples for 210Pb and 210Po were collected both within (IN) and outside (OUT) of two cyclones, Noah and Opal, at different stages of their evolution as well as from the eddy generation region. Particulate carbon (PC), particulate nitrogen (PN) and biogenic silica (bSiO2) export fluxes were determined using water-column PC, PN, and bSiO2 inventories and the residence times of 210Po. PC and PN fluxes at 150 m ranged from 1.58±0.10 to 1.71±0.16 mmol C m−2 d−1 and 0.22±0.02 to 0.30±0.02 mmol N m−2 d−1 within Cyclones Opal and Noah. PC and PN fluxes at OUT stations sampled during both cruises were of similar magnitudes, 1.69±0.16 to 1.67±0.16 mmol C m−2 d−1 and 0.30±0.03 to 0.26±0.03 mmol N m−2 d−1. The bSiO2 fluxes within Cyclone Opal were 0.157±0.010 mmol Si m−2 d−1 versus 0.025±0.002 mmol Si m−2 d−1 at OUT stations. These results of minimal PC and PN export, but significant eddy-induced bSiO2 fluxes, agree very well with other studies that used a variety of direct and indirect methods. Thus, our results suggest that using elemental inventories and residence times of 210Po is another independent and robust method for determining particle export and should be investigated more fully.  相似文献   

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