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1.
Dealt with in this paper are some geochemical characteristics of porphyry copper mineralization, especially those observed in intrusive bodies, wall rocks, alteration zones, ores and pyrites. Ore bearing bodies have been correlated with barren ones from such aspects as major and trace elements, copper contents of biotite and pyrite, and distribution pattern of copper. In the mineralized rocks, trace elements show apparent zoning surrounding ore bodies; major and trace elements seem to show some regularities with respect to their variations in the process of alteration, and as a result each alteration zone displays its own peculiar element association. Trace elements in ores can provide information on the genetic types of ore deposits, thus of great help in distinguishing ore types, while those in pyrites may be indicative of the main mineralizing stage, providing clues for distinguishing ore-bearing from barren rocks, and of the extent of denudation of ore bodies.  相似文献   

2.
In order to test a hypothesis on the origin of copper in the Cornwall district, 270 samples of mafic rocks, 88 samples of sedimentary rocks and 78 samples of granitic rocks have been analysed for their copper contents. Among the mafic rocks, the intrusive microgabbro has a higher mean copper content (59±32 PPM) than the spilitic pillow lavas (43±27 PPM). The abundance of copper in the sedimentary rocks appears to be related to their lithological characters. The average copper content of the grey slates with carbonaceous material (47±16 PPM) is higher than that for the noncarbonaceous grey slates (29±20 PPM) The distribution of copper in the granitic rocks shows a marked relationship with the degree of mineralisation in the region. The average copper content of the granitic rocks from the intensely mineralized region is 73±18 PPM while the granitic rocks from the less mineralized region contain an average of 21±9 PPM copper. Further, it appears that there has been a general enrichment of copper from early granitic stage to the late pegmatites. These geochemical features can be of potential use in selecting intrusive bodies for detailed exploration. The high copper content in the country rock and in the mineralized intrusion plus a likelihood of assimilation of crust in forming granitic magmas suggest that the copper deposited as hydrothermal lodes may have been derived from the country rocks of the region.The work was completed at the Department of Geology, University of Birmingham, Birmingham 15, England.  相似文献   

3.
The Haldzan-Buregtey group of alkali granitoid massifs with an age of 391–395 Ma is located among the Early Caledonides of the Ozernaya zone of western Mongolia and consists of seven intrusive phases, including two rare-metal phases with Zr, Mn, Y, and REE mineralization. In order to identify the magma sources of the massifs, the abundances and canonical ratios of incompatible trace elements in the rocks of various intrusive phases are analyzed and compared with those in the volcanic rocks of Pantelleria island. The latter rocks were taken as the reference association of rocks linked through crystallization differentiation. The rocks of the Haldzan-Buregtey Complex were formed by mixing an OIB source (with participation of MORB) and host ophiolites, while alkali granitoids of phase 2 originated via mixting these sources with the host non-alkaline granitoids. Practically all rocks have mixed sources, with all transitional varieties from OIB, MORB to ophiolites. OIB was the main source for the rocks, while the host ophiolites could serve as sources for anatectic magmas or contaminants of the magmas of other considered rocks. The rare-metal granitoids were produced from the same sources as the barren magmatic rocks of the Haldzan-Buregtey Complex. The rocks of the Haldzan-Buregtey Complex show a bimodal distribution, with the practically complete absence of intermediate varieties between basite dikes and syenite-granite rocks. This seems to be related to the formation of the least differentiated sialic rocks (nordmarkites, pantellerites, some alkali granites) by anatexis of their own parental basite rocks (dolerites and basites), their cumulates, or ophiolites. Most of the phase-2 alkali granites likely resulted from the differentiation of the phase-1 nordmarkites coupled with assimilation of the host ophiolites. Ekerites are geochemically similar to the nordmarkites and can be interpreted as their residual in situ melts or their anatectic melts.  相似文献   

4.
陕南凤凰岭南缘变质镁铁质—超镁铁质侵入岩为富含Fe、Ti等有用元素的含矿岩体。利用岩石地球化学方法、偏光显微镜和电子探针技术对该区镁铁质—超镁铁质侵入岩的岩石学、地球化学和矿物学特征进行了研究,并对Fe-Ti氧化物的形成、富集进行了初步探讨,对成岩、成矿作用具有一定的参考意义。结果表明,成矿镁铁质—超镁铁质侵入岩与非成矿镁铁质—超镁铁质侵入岩为不同岩浆源区、同期岩浆作用的产物,镁铁质—超镁铁质侵入岩类的Fe-Ti矿化作用与初始岩浆的源岩之间具有密切关系。Fe-Ti氧化物主要以钛铁矿和榍石的形式存在,局部见少量金红石。化学成分上,钛铁矿具富锰贫镁特征,本区Fe-Ti氧化物的形成和富集过程经历了岩浆结晶分异阶段和热液蚀变阶段。  相似文献   

5.
Major-element analyses (by electron microprobe) and copper contents (by ion-probe) are reported for primary biotite, amphibole, magnetite, pyroxene, ilmenite, sphene and secondary biotite from intrusive rocks from mineralizing and barren stocks. The districts studied include Christmas, Globe-Miami, Sierrita and Tombstone, in Arizona; Bingham and Alta, Utah; Ely, Nevada; and Brenda, British Columbia. Amphiboles from barren rocks are relatively iron-rich and display only minor compositional variation. In contrast, amphiboles from mineralizing rocks span the range from magnesio-hornblende to actinolite, commonly even within one grain. Barren intrusions (type B) that are temporally distinct from mineralizing intrusions, and barren intrusions outside areas of known mineralization have higher Cu contents in their constituent minerals than do mineralizing intrusions. Barren intrusions (type A) that are deep-level temporal equivalents of Cu-bearing porphyritic rocks are depleted in copper. This suggests that copper is abstracted from not only the apical portions of porphyries but from parts of the deeper parent intrusions. The Cu contents of biotites (av. 23 ppm) and magnetites (97 ppm) from barren type B intrusions contrast with those from mineralizing intrusions, with biotites containing 7 ppm Cu and magnetites 3 ppm Cu. Primary amphiboles from all intrusive rock types have low copper contents, typically 2 to 5 ppm. In the continental North American deposits, the amount of copper available by liberation from or non-incorporation into amphibole, biotite and magnetite during magmatic crystallization or the early hydrothermal stage is low, perhaps too low to be the sole source of copper mineralization, unless copper is abstracted from large volumes (∼ 100 km3) of rock. These results contrast with a study of the island-arc porphyry copper at Koloula, Guadalcanal, where it was argued that sufficient copper for mineralization could have been abstracted from relatively small volumes of host rocks that originally contained as much Cu as the contemporaneous barren rock types.  相似文献   

6.
作者近几年在青海省化隆地区开展了岩浆型铜镍矿资源潜力评价,重点对下什堂岩体进行了实地调查和研究.岩体地质特征、岩石地球化学特征及区域对比分析表明,下什堂岩体为一铁质系列的超基性-基性岩杂岩体,岩体分异好,有用元素Ni、Cu、Co丰度高,系有利成矿岩体;元素丰度和相关性揭示,该岩体在岩浆成岩演化过程中,硫逸度对元素富集起...  相似文献   

7.
Rare earth element (REE) geochemistry on monomineral has been widely used in various fields of geosciences to reveal the origin of ore-forming materials and fluid. Quartz are ubiquitous mineral in the Shihu gold deposit that is situated in central shear zone of mesocenozoic Fuping metamorphic core complex in the middle-northern part of Taihang Mountains. Gold-bearing quartz veins are their most important industrial orebodies. Rare earth element abundances in quartz from the Shihu gold mine, as determined by laser ablation-indutively coupled plasma-mass spectrometry (LA-ICP-MS) analysis, are shown to be sensitive to identify barren quartz and mineralized quartz. Amounts of REE concentrations in barren quartz and mineralized quartz are 97 × 10−9 and 85 × 10−9, respectively. The average (La/Yb)N and (La/Sm)N ratios for the barren quartz are 0.25 and 0.13, and the ratios for mineralized quartz are 0.28 and 0.19, respectively. There is a pronounced positive correlation between (La/Yb)N and (La/Sm)N ratios. There is no obvious correlation between REE characteristics and sampling sites. The mineralized quartz show the most pronounced negative Ce anomalies, whereas weak negative Ce anomalies are typical of barren quartz vein. A negative Eu anomaly becomes more significant in mineralized quartz than barren quartz. δCe have a broadly positive correlation with δEu. Y/Ho ratio of barren quartz and mineralized quartz are ranging from 2.14–28.75, and from 1.28–9.92, respectively. The REE characteristics of quartz indicate that the ore-forming fluids of the gold deposit were derived from the deep fluid and its formation was dually controlled by Precambrian metamorphic basement and Mesozoic granitoids. The results significantly enhance the usefulness of quartz in tracing the sources of ore-forming fluid to discuss the genesis of the gold deposit, and as an indicator mineral in mineral exploration in Taihang mountain region.  相似文献   

8.
The gold deposit at La Josefina, in the Deseado Massif of Argentina, is a low-sulfidation epithermal deposit with some features of the intermediate sulfidation style; the Au occurs in quartz veins and hydrothermal breccias hosted by acid pyroclastic rocks produced by Jurassic bimodal volcanism. Exploration for this deposit type uses geochemical data for vectoring to mineralized rocks. Although a general suite of elements with anomalous concentrations around low-sulfidation deposits is known, that suite varies amongst individual deposits, which should be studied individually. The aim of this study was to determine, in the La Josefina deposit, geochemical indicators of Au-rich rocks at different scales and to assess the effects of weathering on those indicators. To reach these objectives, a mineralized zone (hosting Au-rich veins) and a non-mineralized zone (hosting barren veins) were compared in terms of vein mineralogy, alteration minerals and geochemistry. These zones were also compared with estimated element concentrations of the protolith. Element concentrations in the mineralized zone were then plotted against distance to the Au-rich veins, separating the dataset into two subsets: one from strongly oxidized rocks and the other from weakly oxidized rocks, considering the degree of oxidation as indicative of relative degree of weathering. Based on alteration and vein mineralogy, we interpret that the mineralized zone was hydrothermally active before, during and after Au-mineralization, while the non-mineralized zone was active only before Au-mineralization. Therefore, differences in element concentrations between the estimated protolith and the non-mineralized zone represent geochemical changes produced before mineralization, whereas differences between mineralized and non-mineralized zones represent changes produced during and after mineralization. We conclude that in rhyolitic to rhyodacitic pyroclastic rocks of the study area, affected by predominantly argillic and silicic hydrothermal alterations, high concentrations of Au, Cu, Hg, V, Co and P, and low concentrations of Ba are probably the best deposit-scale geochemical indicators to distinguish Au-mineralized zones from non-mineralized zones. High concentrations of As, Mn, Fe, Pb, Cr, Ni, MgO and Zn (as well as high values of chlorite-carbonate-pyrite index), and low concentrations of Be and CaO can also distinguish mineralized from non-mineralized zones. High concentrations of Au, Cu, Pb, As, Hg, and Co indicate Au-rich zones, independently of lithology and alteration, because they were introduced into the veins and host rocks together with Au. At detailed-scale, the concentrations of 15 elements vary with distance to Au-rich veins; therefore, those elements are considered potential indicators of proximity to Au-rich veins. Of those elements, Au, P, Cu, Pb, Hg, Ba and MgO are the strongest indicators of proximity to the Au-rich veins. In strongly oxidized rocks, some indicators of mineralized zones (Co, Mn, Pb, Zn and MgO) and some indicators of proximity to Au-rich veins (P, Au, Cu, Hg and Ba) should be used with caution or be avoided because weathering modifies their quality as indicators.  相似文献   

9.
Abstract: The North granitic body of the Miyako pluton is located in the Northern Kitakami belt, Northeast Japan. The formation of the scheelite–chalcopyrite–magnetite–bearing aplitic veins and scheelite–chalcopyrite–magnetite–bearing Yamaguchi skarn deposit was closely associated with the formation of the Miyako plutons. Petrographic facies of the North granitic body vary from quartz diorite in marginal zone (zone A), to tonalite and granodiorite (zone B), and to granite (zone C) in the central. The large numbers of aplitic veins distributed around the Yamaguchi mining area are divided into two groups: barren and scheelite–mag–netite–chalcopyrite–bearing aplitic veins. The latter cut massive clinopyroxene skarns of the Yamaguchi deposit, and are composed of plagioclase, K‐feldspar and titanite. Some plagioclase crystals have dusty cores with irregularly shaped K‐feldspar flakes, and clear rims of albite. Textures of plagioclase in the mineralized aplitic veins are different from the idiomorphic textures with sharp plagioclase crystal boundaries that occur in the North granitic body and barren aplitic veins. These textural data suggest that the mineralized aplitic veins were formed from hydrothermal fluid. Changes in the contents of major and minor (Rb, Sr, Sc, Co, Th, U) elements in the North Miyako granitic body are similar to those of zoned plutons formed by typical magmatic differentiation processes. On the other hand, concentrations of REE, especially middle to heavy REE, of granitic rocks in zone C and barren aplitic veins are significantly lower than those of granitic rocks in zones A and B. The hypothetical chondrite‐normalized REE patterns, calculated assuming fractional crystallization from zone B granitic melt, suggest that REE concentrations of the residual melt increased with the degree of fractional crystallization, and changed into a pattern with enriched LREE and strongly negative Eu anomaly. However, the REE patterns of granitic rocks in zone C are different from the hypothetical patterns. Moreover, the REE patterns of magnetite–scheelite–chalcopyrite aplitic veins are quite different from those of granitic rocks. The Cu contents of granitic rocks in the North Miyako body increase from zone A (5–26 ppm) to zone B (10–26 ppm), and then clearly decrease to zone C (5–7 ppm) and drastically increase to the barren aplitic veins (39–235 ppm). Concentrations of Cu in the mineralized aplitic veins are also higher than those of the granitic rocks in zone C. The decrease in REE and Cu contents of granitic rocks from zone B to zone C is not a result of simple magmatic fractional differentiation. Fluid inclusions in quartz from mineralized aplitic veins contain 3.3 wt% NaCl equivalent and 5.8 wt% CO2. It was also demonstrated experimentally that the removal of MREE and HREE by fluid from melt enabled the formation of complexes of REE and ligands of OH‐ and CO32‐. Based on the possibility that the melt of the granitic rocks of zone C and the mineralized aplitic veins coexisted with CO2‐bearing fluid, it is thought that REE were extracted from the melt to the CO2‐bearing fluid, and that the REE in the mineralized aplitic veins were transported by the CO2‐bearing fluid. It is likely that the low HREE and Cu contents of the granitic rocks in zone C could have been caused by the removal of those elements from the granitic melt by the fluid coexisting with the melt. The expelled materials could have been the sources of scheelite–magnetite–chalcopyrite–bearing aplitic veins and copper mineralization of the Yamaguchi Cu‐W skarn deposit.  相似文献   

10.
The Ransko gabbro–peridotite massif in Eastern Bohemia is a strongly differentiated intrusive complex, which hosts low-grade Ni–Cu ores mainly developed close to the contact of olivine-rich rocks with gabbros, in troctolites, and to a much lesser extent in both pyroxene and olivine gabbros and plagioclase-rich peridotites. Gabbro, troctolite, peridotite and Ni–Cu ores from the Jezírka Ni–Cu (PGE) deposit, considered to be a typical example of the liquid segregation style of mineralization, were analyzed for Re–Os concentrations and isotopic ratios. Seven barren and mineralized samples from the Jezírka deposit yielded a Re–Os regression of 341.5?±?7.9 Ma (MSWD?=?69). Strongly mineralized peridotite with mantle-like initial 187Os/188Os ratio of 0.125 suggests that Os as well as other PGE present in the Ni–Cu mineralization are predominantly of mantle origin. On the other hand, barren and low-mineralized samples have radiogenic initial 187Os/188Os ratios of 0.14–0.16 suggesting some import of Re and/or radiogenic 187Os most likely through contamination by continental crust during magma emplacement. The Re–Os age of the Ransko Massif is significantly younger than the previously suggested Lower Cambrian age, but it is similar to and/or younger than the age of metamorphism of the adjacent Kutná Hora crystalline complex and the Moldanubian unit. Therefore, it is likely that the emplacement of the Ransko massif and its Ni–Cu mineralization was closely connected with the late-stage evolution of the Kutná Hora crystalline complex.  相似文献   

11.
The concentrations of platinum-group elements (PGE) have been analyzed in primary magmatic magnetite samples from the Zhireken,Shakhtama and Aksug porphyry Cu-Mo deposits (Siberia,Russia) by laser abla...  相似文献   

12.
Based on a review of the available petrological and petrochemical data on magmatic rocks in a certain region in China, the average chemical composition of them has been calculated, and the frequency distribution of elements in the rocks, the mineralization of rock bodies and the regional geochemical characteristics have been discussed. In response to temporal and spatial variations during the evolutionary process of magmatic activity, a systematic variation is obvious from this study in the chemical composition of magmatic rocks, the frequency distribution patterns of elements, the concentration levels of various elements and the calc-alkali index of the rocks as well as in the average atomic weight and average atomic valence. Particularly, different geochemical indicators have been established for mineralized and barren rock bodies, respectively. Crystallization-differentiation and post-magmatic metasomatism constitute the most important mechanism controlling mineralization.  相似文献   

13.
《International Geology Review》2012,54(11):1500-1503
The "oxidation ratio" of igneous rocks (F = Fe2O3:FeO) depends on the partial pressure of oxygen during crystallization and therefore, in part, on depth of crystallization. For this reason F increases in the order: deep intrusives, dike rocks, extrusives, pyroclastics. Also, in general, F increases with increasing silica content, although there are exceptions. As it is not always easy to distinguish intrusive rocks from extrusive ones, or extrusives from pyroclastics, it is proposed that the oxidation ratio be used as a criterion of fades of igneous rocks. --F. E. Ingersoll.  相似文献   

14.
Seventeen granitoid samples from batholiths in central Chile (33 °–34 ° S) have been analyzed for trace element content. The samples range in age from Paleozoic to Tertiary, and in rock type from quartz diorite to granite. In general, compared to andesites from central-south Chile these rocks are more siliceous with lower abundances of compatible trace elements and higher abundances of incompatible trace elements. However, Upper Tertiary granodiorites have important geochemical similarities, such as highly fractionated rare-earth element (REE) distributions relative to chondrites, to some modern andesites in this region; e.g., Marmolejo. Similar highly fractionated REE distributions are also common in the cores of zoned intrusive sequences in the Sierra Nevada of the western U.S. Based on limited sampling of central Chile Cretaceous and Tertiary plutonics, there may be a west to east increase in light REE/heavy REE ratio and in Sr content. Compared to the Upper Tertiary granodiorites, the Paleozoic granodiorites have similar REE abundances but lower Sr, Sc, Cr, Co, and Ni contents.  相似文献   

15.
This article reports new zircon laser ablation-multicollector-inductively coupled plasma-mass spectrometry U–Pb and Hf isotope, whole-rock major and trace element, and Sr–Nd isotope data for mineralized and barren intrusions associated with the Duolong porphyry–epithermal copper–(gold) deposit (DPCD, a mining camp containing several individual deposits) in the western Qiangtang Terrane (QT), central Tibet. These data are used to further our understanding of the geological evolution of this region. The mineralized and barren DPCD intrusions are typical I-type granitoids that were synchronously emplaced at ca. 112.6–125.9 Ma. These igneous rocks show arc affinities that are characterized by enrichments in the light rare earth elements (LaN/YbN = 4.08–15.23) and the light ion lithophile elements (Rb, Th, U, K, and Pb), and depletions in the high field strength elements (Nb, Ta, and Ti). They have 87Sr/86Sr(i) values of 0.7046–0.7079, Nd(t) values of –6.0 to +1.1, and two-stage Nd model ages of ca. 823–1410 Ma. Zircons from these intrusive rocks have variable but generally positive εHf(t) values (–2.7 to +13.7) and relatively young zircon Hf crustal model ages of 335–1351 Ma. Combining these data with geochemical data reported in recent studies, we infer that the mineralized and barren DPCD intrusions formed in a continental marginal arc setting and likely originated from a common parental magma that was result of magma mixing of juvenile crust-derived basaltic melts and old lower crust-derived melts. The formation of the DPCD intrusions indicates that the Bangongco–Nujiang oceanic lithosphere was still undergoing northward subduction beneath the western QT at ca. 112.6–125.9 Ma, suggesting in turn that the oceanic basin have not closed completely during the Early Cretaceous. These new data also indicate that the processes that occur during the subduction of oceanic crust in continental marginal arc settings produce and preserve juvenile crustal material, leading to net continental crust vertical growth and thickening.  相似文献   

16.
内蒙古达茂旗北部奥陶纪埃达克岩类的识别及其意义   总被引：19，自引：0，他引：19  
内蒙古达茂旗北部奥陶纪侵入岩分布于槽台边界断裂(乌兰布拉格—哥舍深大断裂)以北,岩石类型主要有闪长岩、石英闪长岩、英云闪长岩和花岗闪长岩。该套侵入岩具高w(Sr)、低w(Y)和w(Yb)的特征,具高的w(Sr)/w(Y)和w(La)/w(Yb)比值;轻稀土富集,重稀土亏损,具正铕异常或微弱的负铕异常;微量元素蛛网图中具明显的Sr峰和Nb、Ti低谷,与典型的埃达克岩(adakite)特征一致。通过与典型adakite、太古代TTD(G)及岛弧和大陆边缘弧ADR的对比,表明本区奥陶纪侵入岩以具轻、重稀土强烈分馏型而与岛弧和大陆边缘弧ADR区别明显,而与adakite和TTD(G)相似,同时又以具明显的Sr正异常而区别于太古代的TTD(G)。地球物理、重力及航磁资料显示槽台边界断裂两侧有完全不同的地壳结构。北侧可能是在晚古生代早期拼贴到华北陆块的一个小微地块,拼贴过程中二者之间的加里东洋壳向微地块之下俯冲消减,俯冲板片在榴辉岩相或角闪岩相—榴辉岩相过渡相发生部分熔融形成adakite岩浆,熔融残留物主要为石榴石。  相似文献   

17.
区内矿产资源丰富，有铜、铅—锌、金、铁、汞、镍六种成型矿床。区内古生代、中生代地层中海相火山岩层可作为有利的赋矿层，中生代沉积地层，尤其是三叠系地层可作为有利找矿层。铜、铁矿床形成与侵入岩有关。成矿带明显受北西、北西西、北西转南北向区域性深、大断裂控制。与中—酸侵入岩有关的矿床，局部重力异常多表现为圆形、椭圆形的重力低，矿床主要位于负异常中心及边部地带。航磁异常多有异常反映，幅值一般在50nT以下。与赵基性—基性侵岩有关矿床，局部重力异常表现为椭圆形的正异常，矿床位于正异常边部，且与一正磁异常对应。  相似文献   

18.
鲁西金矿成矿组分的聚集与演化   总被引：3，自引：2，他引：1  
在地质研究的基础上, 以统计分析为主要手段, 通过对鲁西隆起区太古宙地层、中生代岩体以及不同时代金矿床化学组成的研究, 探索了成矿组分的可能来源、演化和聚集趋势, 提出了矿源层(岩) 中元素成矿活度的概念及定量计算方法.研究表明: (1) 在鲁西隆起区, 金的初始矿源是太古宙绿岩带, 金在其中具有双成分分布; (2) 从太古宙至中生代, 虽然成矿时代不同, 成矿作用各异, 但各类金矿床在成矿组分上对含矿建造具有明显的继承性; (3) 含矿建造中成矿组分超量点群与其背景点群的比例以及超量点群中成矿组分的平均质量分数在很大程度上决定了其后生热液矿床的成矿特征.   相似文献   

19.
A detailed study of apatite and biotite compositions in multiple intrusive phases from five composite plutons in the northern Canadian Cordillera was undertaken with the aim of determining the composition of magmatic fluids relative to F:Cl:OH for several plutons―both barren and mineralizing―and for specific intrusive phases from each pluton that may be related to nearby tungsten skarns. Magmatic apatite and biotite compositions are consistent with a crustal source of magma, either derived from predominantly supracrustal rocks, and (or) derived from predominantly infracrustal rocks and fractionated to felsic compositions. Increasing MnO (± FeO and XF:XCl) with decreasing CaO in apatite broadly correlates with an increasing degree of magmatic differentiation, although Fe# vs. total aluminum in biotite is a better indicator of inter- and intra-plutonic differentiation. Anomalously iron-rich biotites occur in highly fractionated and (or) wallrock-contaminated phases of plutons associated with tungsten skarns.Estimates of magmatic fluid composition―calculated as the activity ratios log[aHCl / aHF] and log[aHOH / aHF] from apatite and biotite compositions―show several trends with respect to magmatic differentiation. Two barren plutons demonstrate that fluids in silicic magmas become HF enriched relative to HCl with increasing differentiation, although re-equilibration with late-stage sub-solidus or hydrothermal fluids may obscure this trend. The three intrusions with associated tungsten skarn mineralization, including the world-class Cantung deposit, also become HF-enriched with magmatic evolution. However, magmatic apatite and biotite in individual intrusive phases that are the most closely associated with mineralization have equilibrated with compositionally distinct fluids. In these particular intrusive phases, apatite appears to have equilibrated with an earlier HCl- and H2O-rich magmatic fluid, and biotite appears to have equilibrated with a later HCl- and (a particularly) H2O-rich magmatic fluid. The fluid in these magmas apparently evolved to a H2O-rich (or less saline) composition as the temperature of the magma decreased. None of the other intrusive phases, from either the barren or tungsten-associated plutons, have apatite and biotite activity ratios that are suggestive of equilibration with such an HCl/HF- and H2O/HF-rich fluid. Instead, the activity ratios calculated from apatite and biotite in intrusive phases that are not as closely associated with mineralization are well-coupled and unremarkable (although small variations are common), which would suggest that both minerals equilibrated with similar fluids. These intrusive phases do not appear to have produced a large quantity of saline hydrous fluid capable of seggregating and transporting tungsten. The identification of intrusive phases that did produce magmatic fluids that were anomalously enriched in HCl and H2O could, therefore, be a predictor of nearby tungsten skarn mineralization.  相似文献   

20.
新疆谢米斯台地区斑岩型铜矿化的发现及其意义   总被引：3，自引：0，他引：3  
继在新疆谢米斯台地区玄武岩中发现自然铜矿化后,在谢米斯台地区中-酸性次火山岩中发现具有一定规模的斑岩型铜矿化。原生硫化物主要为黄铜矿、黄铁矿和斑铜矿。斑岩型铜矿化主要发育于蚀变的英安斑岩、流纹斑岩和安山玢岩中,矿化岩石中发育强烈的绿帘石化、绿泥石化、碳酸盐化、硅化,局部发育泥化。区内斑岩型铜矿化的发现,表明新疆谢米斯台地区存在两种类型铜矿化,有望取得铜矿找矿新突破。矿化次火山岩及其下部的浅成侵入体可能是区内斑岩型铜矿床找矿评价的重要目标。  相似文献   

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